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Biodegradable Polymers, Blends and Composites Woodhead Publishing Series in Composites Science and Engineering Biodegradable Polymers, Blends and Composites Edited by Sanjay Mavinkere Rangappa Jyotishkumar Parameswaranpillai Suchart Siengchin M. Ramesh Editor-in-Chief Professor Costas Soutis Series Editor Professor Suresh G. Advani Professor Leif Asp Professor Yuris A. Dzenis Professor Ing. Habil. Bodo Fiedler Professor Adrian Mouritz Professor Chun H. Wang WoodheadPublishingisanimprintofElsevier TheOfficers’MessBusinessCentre,RoystonRoad,Duxford,CB224QH,UnitedKingdom 50HampshireStreet,5thFloor,Cambridge,MA02139,UnitedStates TheBoulevard,LangfordLane,Kidlington,OX51GB,UnitedKingdom Copyright©2022ElsevierLtd.Allrightsreserved. Nopartofthispublicationmaybereproducedortransmittedinanyformorbyanymeans, electronicormechanical,includingphotocopying,recording,oranyinformationstorage andretrievalsystem,withoutpermissioninwritingfromthepublisher.Detailsonhowto seekpermission,furtherinformationaboutthePublisher’spermissionspoliciesandour arrangementswithorganizationssuchastheCopyrightClearanceCenterandthe CopyrightLicensingAgency,canbefoundatourwebsite:www.elsevier.com/permissions. Thisbookandtheindividualcontributionscontainedinitareprotectedundercopyrightby thePublisher(otherthanasmaybenotedherein). Notices Knowledgeandbestpracticeinthisfieldareconstantlychanging.Asnewresearchand experiencebroadenourunderstanding,changesinresearchmethods,professional practices,ormedicaltreatmentmaybecomenecessary. Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgein evaluatingandusinganyinformation,methods,compounds,orexperimentsdescribed herein.Inusingsuchinformationormethodstheyshouldbemindfuloftheirownsafety andthesafetyofothers,includingpartiesforwhomtheyhaveaprofessionalresponsibility. Tothefullestextentofthelaw,neitherthePublishernortheauthors,contributors,or editors,assumeanyliabilityforanyinjuryand/ordamagetopersonsorpropertyasamatter ofproductsliability,negligenceorotherwise,orfromanyuseoroperationofanymethods, products,instructions,orideascontainedinthematerialherein. LibraryofCongressCataloging-in-PublicationData AcatalogrecordforthisbookisavailablefromtheLibraryofCongress BritishLibraryCataloguing-in-PublicationData AcataloguerecordforthisbookisavailablefromtheBritishLibrary ISBN:978-0-12-823791-5 ForinformationonallWoodheadPublishingpublicationsvisit ourwebsiteathttps://www.elsevier.com/books-and-journals Publisher:MatthewDeans AcquisitionsEditor:GwenJones EditorialProjectManager:JoshuaMearns ProductionProjectManager:SwapnaSrinivasan CoverDesigner:VictoriaPearson TypesetbyTNQTechnologies Table of Contents 1. Introduction to biodegradable polymers 2. Natural rubber-based polymer blends, composites and nanocomposites 3. Soy protein-based polymer blends, and composites 4. Extraction and characterization of cellulose 5. Cellulose based blends and composites 6. Chitin and chitosan-based blends and composites 7. Starch based blends and composites 8. PLA-based blends and composites 9. PHBV based blends and composites 10. PVA-based blends and composites 11. PBAT-based blends and composites 12. Hydrogel- and aerogel-based composites 13. Polyolyhydroxybutyrate (PHB)-based blends and composites 14. Active and intelligent biodegradable films and polymers 15. Biodegradable biosourced epoxy thermosets, blends, and composites 16. Analysis and characterization of starches from alternative sources 17. Biocomposites potential for nanotechnology 18. Zein-based blends and composites 19. Biodegradable polymer blends and composites from renewable resources 20. Electrically conductive biodegradable polymer blends and composites 21. Biodegradable polymer blends and composites for biomedical applications 22. Biodegradable polymer blends for tissue engineering 23. Additive manufacturing with biodegradable polymers 24. Production of biodegradable films and blends from proteins 25. Biodegradable polymer blends and composites for food-packaging applications 26. Biodegradable polymers and green-based antimicrobial packaging materials Index Contributors V. Abinaya Department of Mechanical Engineering, PSG Institute of Technology and Applied Research, Coimbatore, Tamil Nadu, India Radhamanohar Aepuru Materials Engineering Division, Defence Institute of AdvancedTechnology,Pune,Maharashtra,India;CentralInstituteofPetrochemicals EngineeringandTechnology(CIPET):InstituteofPlasticsTechnology(IPT),Kochi, Kerala,India;DepartamentodeIngenieríaMec(cid:1)anica,FacultaddeIngeniería,Univer- sidad Tecnol(cid:1)ogica Metropolitana, Santiago, Chile AnnaRafaelaCavalcanteBraga DepartmentofChemicalEngineering,Universi- dade Federal deS~aoPaulo(UNIFESP), Diadema,Brazil Monize Burck Department of Biosciences, Universidade Federal de S~ao Paulo (UNIFESP), Santos, S~ao Paulo, Brazil Jesu(cid:1)s María Frías Celayeta Dublin Institute of Technology, Environmental Sustainability and Health Institute (EHSI), College of Sciences and Health, Dublin, Ireland Pijush Kanti Chattopadhyay Department of Leather Technology, Government College of Engineering and Leather Technology (Post-Graduate), Maulana Abul KalamAzad University ofTechnology, Kolkata, West Bengal, India NagaSrilathaCheekuramelli CentralInstituteofPetrochemicalsEngineeringand Technology (CIPET): Institute of Plastics Technology (IPT), Kochi, Kerala, India; Materials Engineering Division, Defence Institute of Advanced Technology, Pune, Maharashtra, India; Departamento de Ingeniería Mec(cid:1)anica, Facultad de Ingeniería, Universidad Tecnol(cid:1)ogica Metropolitana, Santiago,Chile Kraipat Cheenkachorn Department of Chemical Engineering, Faculty of Engineering, King Mongkut’s University of Technology North Bangkok, Bangkok, Bangkok, Thailand Yu-Shen Cheng Department of Chemical and Materials Engineering, National YunlinUniversity of Science andTechnology,Douliu,Yunlin, Yunlin, Taiwan SantiChuetor DepartmentofChemicalEngineering,FacultyofEngineering,King Mongkut’sUniversity ofTechnology NorthBangkok,Bangkok, Bangkok, Thailand xiv Contributors Jorge Alberto Vieira Costa College of Chemistry and Food Engineering, Federal University ofRio Grande (FURG),Rio Grande,RS, Brazil MousumiDeb AdvancedPolymerLaboratory,DepartmentofPolymerScienceand Technology, Government College of Engineering and Leather Technology (Post- Graduate), Maulana Abul Kalam Azad University of Technology, Kolkata, West Bengal, India B.D.S. Deeraj Department of Chemistry, Indian Institute of Space Science and Technology,Kerala, Thiruvananthapuram, India MarianaBuraneloEgea GoianoFederalInstituteofEducation,ScienceandTech- nology, Rio Verde, Goi(cid:1)as, Brazil Ant^onio Gilberto Ferreira Federal University of S~ao Carlos (UFSCar), Nuclear Magnetic Resonance Laboratory,S~aoCarlos, Brazil Michele Giaconia Department of Biosciences, Universidade Federal de S~ao Paulo (UNIFESP), Santos,S~aoPaulo,Brazil R.K. Gond Department of Mechanical Engineering, Motilal Nehru National Institute ofTechnology,Allahabad, Prayagraj, Uttar Pradesh, India M.K. Gupta Department of Mechanical Engineering, Motilal Nehru National Institute ofTechnology,Allahabad, Prayagraj, Uttar Pradesh, India Nishar Hameed Factory of the Future, Swinburne University of Technology, Hawthorn, VIC, Australia NamanJain DepartmentofMechanicalEngineering,MeerutInstituteofEngineer- ing and Technology, Meerut,Uttar Pradesh,India FarahHidayahJamaludin SchoolofBiomedicalEngineeringandHealthSciences, FacultyofEngineering,UniversitiTeknologiMalaysia,Skudai,Johor,Malaysia Aswathy Jayakumar School of Biosciences, Mahatma Gandhi University, Kottayam, Kerala, India; Department of Materials and Production Engineering, The Sirindhorn International ThaieGerman Graduate School of Engineering (TGGS), KingMongkut’s University ofTechnologyNorthBangkok, Bangkok, Thailand Jitha S. Jayan Department of Chemistry, School of Arts and Sciences, Amrita Vishwa Vidyapeetham, Amritapuri,Kerala, Kollam, India Kuruvilla Joseph DepartmentofChemistry,IndianInstitute ofSpaceScience and Technology,Kerala, Thiruvananthapuram, India Yong Chae Jung Institute of Advanced Composite Materials, Korea Institute of Science and Technology (KIST),Wanju-gun, Jeonbuk, Republicof Korea Young Nam Kim Institute of Advanced Composite Materials, Korea Institute of Science and Technology (KIST), Wanju-gun, Jeonbuk, Republic of Korea; Depart- ment of Chemical and Biomolecular Engineering, Yonsei University, Seodaemun- gu, Seoul,Republic ofKorea Contributors xv A.V. Kiruthika Seethalakshmi Achi College for Women, Karaikudi, Tamil Nadu, India Sukhila Krishnan Sahrdaya College of Engineering and Technology, Department of Applied Science and Humanities, Kodakara, Thrissur, Kerala, India SenthilkumarKrishnasamy DepartmentofMaterialsandProductionEngineering, TheSirindhornInternationalThaieGermanGraduateSchoolofEngineering(TGGS), King Mongkut’sUniversity ofTechnology NorthBangkok,Bangkok, Thailand SudheerKumar SchoolforAdvancedResearchinPetrochemicals(SARP),Labo- ratory for Advanced Research in Polymeric Materials (LARPM), Central Institute of Petrochemicals Engineering& Technology (CIPET), Bhubaneswar,Odisha, India Suelen Goettems Kuntzler College of Chemistry and Food Engineering, Federal University of Rio Grande (FURG),Rio Grande,RS, Brazil Maria Carolina Bezerra Di-Medeiros Leal Federal University of S~ao Carlos (UFSCar), Nuclear MagneticResonance Laboratory, S~ao Carlos,Brazil Xiau Yeen Lee Centre for Advanced Materials, Tunku Abdul Rahman University College (TARUC),Setapak, KualaLumpur,Malaysia Ailton Cesar Lemes Department of Biochemical Engineering, Universidade Federal do Rio de Janeiro (UFRJ), Technological Center, School of Chemistry, Ilha do Fund~ao, Rio de Janeiro, Brazil; Federal University of Rio de Janeiro (UFRJ), SchoolofChemistry,DepartmentofBiochemicalEngineering,RiodeJaneiro,Brazil Ravi Prakash Magisetty Materials Engineering Division, Defence Institute of AdvancedTechnology,Pune,Maharashtra,India;CentralInstituteofPetrochemicals EngineeringandTechnology(CIPET):InstituteofPlasticsTechnology(IPT),Kochi, Kerala,India;DepartamentodeIngenieríaMec(cid:1)anica,FacultaddeIngeniería,Univer- sidad Tecnol(cid:1)ogica Metropolitana, Santiago, Chile AbraMathew MaterialSciencesandTechnologyDivision,CSIR-NationalInstitute for Interdisciplinary Science and Technology, Thiruvananthapuram,Kerala, India SanjayMavinkereRangappa NaturalCompositeResearchGroup,Departmentof Materials and Production Engineering, The Sirindhorn International ThaieGerman GraduateSchoolofEngineering(TGGS),KingMongkut’sUniversityofTechnology NorthBangkok,Bangkok, Thailand Nyak Syazwani Nyak Mazlan Bioresource and Biorefinery Research Group, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, Bangi, Selan- gor, Malaysia C.D. Midhun Dominic Department of Chemistry, Sacred Heart College, Cochin, Kerala, India xvi Contributors K. Madhu Mitha Department of Mechanical Engineering, PSG Institute of Tech- nology and Applied Research, Coimbatore, Tamil Nadu,India SmitaMohanty SchoolforAdvancedResearchinPetrochemicals(SARP),Labora- toryforAdvancedResearchinPolymericMaterials(LARPM),CentralInstituteofPet- rochemicalsEngineering &Technology (CIPET), Bhubaneswar,Odisha,India Michele Greque de Morais College of Chemistry and Food Engineering, Federal University ofRio Grande (FURG),Rio Grande,RS, Brazil Juliana Botelho Moreira College of Chemistry and Food Engineering, Federal University ofRio Grande (FURG),Rio Grande,RS, Brazil Marhaini Mostapha Bioresource and Biorefinery Research Group, Faculty of ScienceandTechnology,UniversitiKebangsaanMalaysia,Bangi,Selangor,Malaysia DaniellaCarisaMurador DepartmentofBiosciences,UniversidadeFederaldeS~ao Paulo(UNIFESP),Santos, S~ao Paulo, Brazil M. Muthukrishnan Department of Mechanical Engineering, KITe Kalaignarkarunanidhi Institute ofTechnology,Coimbatore, Tamil Nadu,India Indu C. Nair Department of Biotechnology, Sahodaran Ayyappan Smaraka Sree Narayana Dharma Paripalana Yogam (SAS SNDPYOGAM), Konni College, Pathanamthitta, Kerala, India Sanjay Kumar Nayak School for Advanced Research in Petrochemicals (SARP), LaboratoryforAdvancedResearchinPolymericMaterials(LARPM),CentralInstitute of Petrochemicals Engineering& Technology (CIPET),Bhubaneswar, Odisha, India Josemar Gonçalves de Oliveira Filho S~ao Paulo State University (UNESP), School of Pharmaceutical Sciences, Araraquara, Brazil Jyotishkumar Parameswaranpillai Department of Bioscience, Mar Athanasios CollegeforAdvancedStudiesThiruvalla(MACFAST),Pathanamthitta,Kerala,India Alessandro Pegoretti University of Trento, Department of Industrial Engineering, Trento, Italy G.L. Praveen Wimpey Laboratories, Wimpey Building, Al Quoz, Dubai, United Arab Emirates E.K. Radhakrishnan School of Biosciences, Mahatma Gandhi University, Kottayam, Kerala, India Sabarish Radoor Department of Mechanical and Process Engineering, The Sirindhorn International ThaieGerman Graduate School of Engineering (TGGS), King Mongkut’s University of Technology North Bangkok, Bangkok, Thailand; Department of Materials and Production Engineering, The Sirindhorn International ThaieGermanGraduateSchoolofEngineering(TGGS),KingMongkut’sUniversity of Technology North Bangkok,Bangkok, Thailand Contributors xvii G. Rajeshkumar Department of Mechanical Engineering, PSG Institute of Technologyand Applied Research, Coimbatore, Tamil Nadu, India L. Rajeshkumar Department of Mechanical Engineering, KPR Institute of Engineering and Technology, Coimbatore, Tamilnadu,India Abhinay Rajput Material Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram, Kerala, India M. Ramesh Department of Mechanical Engineering, KITeKalaignarkarunanidhi Institute ofTechnology, Coimbatore,Tamil Nadu, India Sergiana dos Passos Ramos Department of Biosciences, Universidade Federal de S~ao Paulo (UNIFESP),Santos, S~ao Paulo, Brazil Maria Luiza Rezende Ribeiro Federal University of Goi(cid:1)as (UFG), Nuclear MagneticResonance Laboratory,Goi^ania, Brazil Gislane Oliveira Ribeiro Federal University of Goi(cid:1)as (UFG), Nuclear Magnetic ResonanceLaboratory, Goi^ania, Brazil R. Ronia Richelle Department of Mechanical Engineering, PSG Institute of Technologyand Applied Research, Coimbatore, Tamil Nadu, India DanieleRigotti UniversityofTrento,DepartmentofIndustrialEngineering,Trento, Italy Haniyeh Rostamzad Fisheries Department, Faculty of Natural Resources, University of Guilan, Sowmeh Sara, Guilan, Iran Sushanta K. Sahoo Material Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram, Kerala, India Kushairi Mohd Salleh Bioresource and Biorefinery Research Group, Faculty of ScienceandTechnology,UniversitiKebangsaanMalaysia,Bangi,Selangor,Malaysia SathyarajSankarlal Department ofMechanicalEngineering, NationalInstitute of Technology,Calicut, Kerala, India Appukuttan Saritha Department of Chemistry, School of Arts and Sciences, AmritaVishwa Vidyapeetham, Amritapuri,Kerala, Kollam, India K.Sekar DepartmentofMechanicalEngineering,NationalInstituteofTechnology, Calicut,Kerala, India S. Arvindh Seshadri Department of Mechanical Engineering, PSG Institute of Technologyand Applied Research, Coimbatore, Tamil Nadu, India

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