Binary Liquid Systems of Nonelectrolytes I

1982 Pages·2011·18.217 MB·English

by  I. Cibulka, J.-C. Fontaine (auth.), H. V. Kehiaian (eds.)

Lanndolt-Börrnstein
Nummerical Dataa and Functiional Relatioonships in SScience andd Technologgy
New Series

Grooup IV: PPhysical CChemistrry
Vollume 26

Heats of MMixingg,
Vaapor-Liquuid EEquillibriuum,
annd Voolummetricc Propertiies
off Mixxturess andd Soluutionns

Subbvolume A
Binnary Liquuid Systems of NNonelectrolytes II

Suppplement too Vols. IVV/10A, 13AA1, 13A2, and 23AA

I. CCibulka, JJ.-C. Fonntaine
K. SSosnkowwska-Kehhiaian, H..V. Kehiaian

Edited by HH.V. Kehiiaian
ISSN 1615-2018 (Physical Chemistry)

ISBN 978-3-642-02934-9 Springer Berlin Heidelberg New York

Library of Congress Cataloging in Publication Data
Zahlenwerte und Funktionen aus Naturwissenschaften und Technik, Neue Serie
Editor in Chief: W. Martienssen
Vol. IV/26A: Editor: H.V. Kehiaian
At head of title: Landolt-Börnstein. Added t.p.: Numerical data and functional relationships in science and technology.
Tables chiefly in English.
Intended to supersede the Physikalisch-chemische Tabellen by H. Landolt and R. Börnstein of which the 6th ed. began publication in 1950 under title:
Zahlenwerte und Funktionen aus Physik, Chemie, Astronomie, Geophysik und Technik.
Vols. published after v. 1 of group I have imprint: Berlin, New York, Springer-Verlag
Includes bibliographies.
1. Physics--Tables. 2. Chemistry--Tables. 3. Engineering--Tables.
I. Börnstein, R. (Richard), 1852-1913. II. Landolt, H. (Hans), 1831-1910.
III. Physikalisch-chemische Tabellen. IV. Title: Numerical data and functional relationships in science and technology.
QC61.23 502'.12 62-53136

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Editor
H.V. Kehiaian
University of Paris VII, France

Contributors
I. Cibulka
Institute of Chemical Technology, Prague, Czech Republic
e-mail: [email protected]

J.-C. Fontaine
ITODYS, Université Paris-Diderot, Paris, France
e-mail: [email protected]

K. Sosnkowska-Kehiaian
ITODYS, Université Paris-Diderot, Paris, France
e-mail: [email protected]

H. V. Kehiaian
ITODYS, Université Paris-Diderot, Paris, France

Landolt-Börnstein
Springer
Tiergartenstr. 17, D-69121 Heidelberg, Germany
fax: [phone]
e-mail: [email protected]
Internet
http://www.springermaterials.com
Henry Vartan Kehiaian
1929 - 2009
Publication of this Series was initiated and edited by Henry V. Kehiaian. Henry was not only a dedicated
Editor of the Volumes but he did most of the work himself, including searches in the literature, the input
and reformatting of the data and the arrangement of the final output. This Volume is the final one in the
Series representing the compilation of experimental data on several properties of binary liquid mixtures.

To our great sorrow, Henry’s work was interrupted on December 18, 2009. He passed away in the course
of his legendary enthusiastic activity. The present Volume was extremely important for Henry − he was
intensively working on it until the last days of his life. Actually, the book was nearing completion while
he left us, yet he provided us, the co-authors, with clear final instructions and source materials in order to
complete the Volume. Since then, we were acting to fulfill the mission Henry left us with.
Preface
Volume IV/26 is a compilation of selected thermodynamic data on subcritical binary homogeneous
(single-phase) or heterogeneous (two-phase) liquid–liquid mixtures. Compiled data are supplementary to
those collected in the previous related volumes of Landolt- Börnstein New Series, i.e., data on heat of
mixing (Vol. IV/10A [04GRO1]), data associated with vapor-liquid equilibria (Vols. IV/13A1, 13A2
[07WIC1, 08WIC1]), and data for volumetric properties (Vol. IV/23A [09CIB1]). Totally 2846 data sets
were collected for Volume IV/26, 678 of them present data of the property group H (HMSD, heat of
mixing), 131 data sets are of the property group E (EVLM, vapor-liquid equilibrium), and 2037 data sets
of the property group V (VMSD, volumetric properties). Volume IV/26 is divided into three subvolumes
(26A, 26B, 26C). Representative data sets that cover all property groups and types of chemical systems
are selected for subvolume 26A (800 data sets). Rest of data is collected in two consequent volumes: 26B
(binary mixtures containing one or two hydrocarbons, 1032 data sets) and 26C (non-hydrocarbon binary
mixtures, 1014 data sets). All the components are well-defined pure substances, which are organic
nonelectrolytes and water. The data sets contain non-smoothed experimental data compiled from the
original literature published to 2009 and derived data.
Data selected for present subvolume IV/26A are printed in Chapters 2.2 and 2.3; 147 data sets for the
property group H, 32 data sets for the property group E, and 621 data sets for the property group V. Data
for 63 aqueous organic systems are also included. Only data obtained by, or derived from, direct
experimental measurements are considered.
Four printed indexes covering all three subvolumes are included in Chapter 3:
- Formula Index of Substances with main names and relative molar masses
- Name Index of Substances with Chemical Abstract Service Registry Numbers, synonyms, and
acronyms
- Formula Index of Organic Systems
- Formula Index of Aqueous-Organic Systems.
For details see Chapter 3.
Unlike as in previous volumes cited above no specific database (the ELBT program and related data
files) is associated with Volume IV/26. Files presenting fully documented complete data, each for a
particular property, binary system and data source, are extractable from the Web portal SpringerMaterials
(www.springermaterials.com, DOI: 10.1007/978-3-642-02935-6).
In a compilation of this scope it is impossible to avoid errors in reproducing correctly the data from
the original literature and assigning the uncertainties, even after careful checking. The authors will be
grateful to users who call our attention to mistakes and make suggestions for improvements.
Many researchers and colleagues over the world have contributed to this book with their advices,
comments, data, or a help of other kinds. Not being sure that we have their list complete we express
Henry’s and our sincere thanks to all of them, not mentioning the individuals by names. Finally, we wish
to express our appreciation to the editorial office in Heidelberg, Germany, with special thanks to Dr.
Wolfgang Finger and Dr. Rainer Münz, for their excellent work and help in preparing the volume for the
publisher.

Paris/Prague, November 2010 The Authors
Contents
1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1
1.1 General Thermodynamic Relations . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1
2 Tables on Thermodynamic Properties . . . . . . . . . . . . . . . . . . . . . . . . 2-1
2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1
2.1.1 Property Types . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-2
2.2 Organic Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-13
2.3 Aqueous-organic Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-384
3 Indexes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1
3.1 Formula Index of Substances . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-2
3.2 Name Index of Substances . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-8
3.3 Formula Index of Organic Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-27
3.4 Formula Index of Aqueous-Organic Systems . . . . . . . . . . . . . . . . . . . . . . 3-72
4 General References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-1
Totality of Data . . . . . . . . . . . . . . . . . . . . SpringerMaterials: www.springermaterials.com
DOI: 10.1007/978-3-642-02935-6
Introduction 1
Introduction
Quantities for which experimental data have been collected in previous volumes of Landolt-Börnstein New
Series along with those included in this volume, i.e., heat of mixing (Volume IV/10A [04GRO1]), data
associated with vapor-liquid equilibria (Volumes IV/13A1, IV/13A2 [07WIC1, 08WIC1]), and volumetric
properties (Volume IV/23A [09CIB1]) for binary liquid mixtures are not self-standing quantities but they are
linked together through exact formulas that can be derived from laws and definitions of classical
thermodynamics. Basic relations are briefly summarized and commented below, detailed overviews (including
the aspects concerning experimental determinations, error analyses, and data correlations) are presented for each
particular property group in the volumes of the Landolt-Börnstein New Series cited above.
General Thermodynamic Relations
Properties of real liquid mixtures (formulas below are written for a binary mixture of components 1 and 2 with a
composition expressed using mole fractions x , x ) are described either in terms of molar excess quantities YE as
1 2
deviations from properties of ideal mixture, i.e., as corrections added to the properties of the ideal mixture
(cid:1851) (cid:3404)(cid:1851)ideal(cid:3397)(cid:1851)E , Y = V, H, S, G , (1.1)
m m
or in terms of partial molar quantities of components,
(cid:1851)(cid:3364) (cid:3404)(cid:4672)(cid:3105)(cid:4666)(cid:3041)(cid:3026)m(cid:4667)(cid:4673) , i = 1, 2 , (cid:1851) (cid:3404)(cid:1876) (cid:1851)(cid:3364) (cid:3397)(cid:1876) (cid:1851)(cid:3364) , Y = V, H, S, G , (1.2)
(cid:3036) m (cid:2869) (cid:2869) (cid:2870) (cid:2870)
(cid:3105)(cid:3041)(cid:3284) (cid:3021),(cid:3017),(cid:3041)(cid:3285)(cid:3247)(cid:3284)
where V, H, S, and G stand for volume, enthalpy, entropy, and Gibbs energy, respectively, and n = n + n is the
1 2
total amount of substance in a system. Subscript m denotes a molar quantity and is usually omitted for excess
and partial molar quantities.
Mixing quantities YM are defined as a difference between the molar quantity of a system and the mole
fraction average of pure component quantities
(cid:1851)M (cid:3404)(cid:1851) (cid:3398)(cid:3435)(cid:1876) (cid:1851)(cid:2868) (cid:3397)(cid:1876) (cid:1851)(cid:2868) (cid:3439) , Y = V, H, S, G , (1.3)
m (cid:2869) m,(cid:2869) (cid:2870) m,(cid:2870)
where (cid:1851)(cid:2868) , Y = V, H, S, G, are molar properties of pure component i, i = 1, 2. It is clear (see Eqs. (1.6) below)
m,(cid:3036)
that VM = VE , HM = HE , SM = SE – R(x ln x + x ln x ), GM = GE + RT(x ln x + x ln x ) .
1 1 2 2 1 1 2 2
Partial molar Gibbs energy
(cid:2020) (cid:3404)(cid:1833)(cid:1191) (cid:3404)(cid:4672)(cid:3105)(cid:4666)(cid:3041)(cid:3008)m(cid:4667)(cid:4673) (cid:3404)(cid:2020)ideal(cid:3397)(cid:2020)E , i = 1, 2 , (cid:1833) (cid:3404)(cid:1876) (cid:2020) (cid:3397)(cid:1876) (cid:2020) , (1.4)
(cid:3036) (cid:3036) (cid:3105)(cid:3041)(cid:3284) (cid:3021),(cid:3017),(cid:3041)(cid:3285)(cid:3247)(cid:3284) (cid:3036) (cid:3036) m (cid:2869) (cid:2869) (cid:2870) (cid:2870)
is called the chemical potential μ and plays a fundamental role since it is directly related to the activity a of a
i i
component in the mixture
(cid:2020) (cid:3404)(cid:2020)(cid:2868)(cid:3397)(cid:1844)(cid:1846)ln(cid:1853) , i = 1, 2 , (1.5)
(cid:3036) (cid:3036) (cid:3036)
where (cid:2020)(cid:2868) is the chemical potential of a component i in a properly selected standard state.
(cid:3036)
Ideal mixture is a system where the fugacity of a particular component is proportional to its mole fraction
(consequently the Amagat's rule holds). Properties of the ideal mixture are then given by relations
(cid:1848)ideal (cid:3404)(cid:1876) (cid:1848)(cid:2868) (cid:3397)(cid:1876) (cid:1848)(cid:2868) , (cid:1834)ideal (cid:3404)(cid:1876) (cid:1834)(cid:2868) (cid:3397)(cid:1876) (cid:1834)(cid:2868) ,
m (cid:2869) m,(cid:2869) (cid:2870) m,(cid:2870) m (cid:2869) m,(cid:2869) (cid:2870) m,(cid:2870)
(cid:1845)ideal (cid:3404)(cid:1876) (cid:1845)(cid:2868) (cid:3397)(cid:1876) (cid:1845)(cid:2868) (cid:3398)(cid:1844)(cid:4666)(cid:1876) ln(cid:1876) (cid:3397)(cid:1876) ln(cid:1876) (cid:4667) , (1.6)
m (cid:2869) m,(cid:2869) (cid:2870) m,(cid:2870) (cid:2869) (cid:2869) (cid:2870) (cid:2870)
(cid:1833)ideal (cid:3404)(cid:1876) (cid:1833)(cid:2868) (cid:3397)(cid:1876) (cid:1833)(cid:2868) (cid:3397)(cid:1844)(cid:1846)(cid:4666)(cid:1876) ln(cid:1876) (cid:3397)(cid:1876) ln(cid:1876) (cid:4667)(cid:3404)(cid:1876) (cid:2020)ideal(cid:3397)(cid:1876) (cid:2020)ideal .
m (cid:2869) m,(cid:2869) (cid:2870) m,(cid:2870) (cid:2869) (cid:2869) (cid:2870) (cid:2870) (cid:2869) (cid:2869) (cid:2870) (cid:2870)
Landolt-Börnstein DOI: 10.1007/978-3-642-02935-6_1
New Series IV/26A ©Springer-Verlag Berlin Heidelberg 2011
2 Introduction
Chemical potentials (cid:2020)ideal (cid:3404)(cid:1833)(cid:2868) (cid:3397)(cid:1844)(cid:1846)ln(cid:1876) , i = 1, 2, correspond to the standard state of pure liquid component at
(cid:3036) m,(cid:3036) (cid:3036)
temperature and pressure of the system, (cid:2020)(cid:2868) (cid:3404)(cid:1833)(cid:2868) , i = 1, 2.
(cid:3036) m,(cid:3036)
Excess quantities are mutually interrelated through derivatives with respect to temperature and pressure
(cid:1834)E (cid:3404)(cid:3398)(cid:1846)(cid:2870)(cid:4672)(cid:3105)(cid:4666)(cid:3008)E/(cid:3021)(cid:4667)(cid:4673) , (cid:1845)E (cid:3404)(cid:3398)(cid:4672)(cid:3105)(cid:3008)E(cid:4673) ,
(cid:3105)(cid:3021) (cid:3017),(cid:3051) (cid:3105)(cid:3021) (cid:3017),(cid:3051)
(1.7)
(cid:4672)(cid:3105)(cid:3009)E(cid:4673) (cid:3404)(cid:1848)E(cid:3398)(cid:1846)(cid:4672)(cid:3105)(cid:3023)E(cid:4673) , (cid:4672)(cid:3105)(cid:3020)E(cid:4673) (cid:3404)(cid:3398)(cid:4672)(cid:3105)(cid:3023)E(cid:4673) , (cid:4672)(cid:3105)(cid:3008)E(cid:4673) (cid:3404)(cid:1848)E ,
(cid:3105)(cid:3017) (cid:3021),(cid:3051) (cid:3105)(cid:3021) (cid:3017),(cid:3051) (cid:3105)(cid:3017) (cid:3021),(cid:3051) (cid:3105)(cid:3021) (cid:3017),(cid:3051) (cid:3105)(cid:3017) (cid:3021),(cid:3051)
analogical relations hold for partial molar quantities. Excess Gibbs energy of a mixture and partial molar excess
Gibbs energies (excess chemical potentials) of components lead to activity coefficients γ = a /x
i i i
(cid:1833)E (cid:3404)(cid:1844)(cid:1846)(cid:4666)(cid:1876) ln(cid:2011) (cid:3397)(cid:1876) ln(cid:2011) (cid:4667)(cid:3404)(cid:1876) (cid:2020)E(cid:3397)(cid:1876) (cid:2020)E ,
(cid:2869) (cid:2869) (cid:2870) (cid:2870) (cid:2869) (cid:2869) (cid:2870) (cid:2870)
(cid:2020)E (cid:3404)(cid:1844)(cid:1846)ln(cid:2011) (cid:3404)(cid:1833)(cid:1191)E (cid:3404)(cid:4672)(cid:3105)(cid:4666)(cid:3041)(cid:3008)E(cid:4667)(cid:4673) , i = 1, 2. (1.8)
(cid:3036) (cid:3036) (cid:3036) (cid:3105)(cid:3041)(cid:3284) (cid:3021),(cid:3017),(cid:3041)(cid:3285)(cid:3247)(cid:3284)
Using Eqs. (1.7) the relations for the derivatives of activity coefficients and excess chemical potential with
respect to temperature and pressure,
(cid:4672)(cid:3105)ln(cid:3082)(cid:3284)(cid:4673) (cid:3404) (cid:2869)(cid:3436)(cid:3105)(cid:4666)(cid:3091)(cid:3284)E/(cid:3021)(cid:4667)(cid:3440) (cid:3404)(cid:3398) (cid:3009)(cid:3365)(cid:3284)(cid:3254) (cid:3404)(cid:3398)(cid:3009)(cid:3365)(cid:3284)(cid:2879)(cid:3009)m(cid:3116),(cid:3284) , i = 1, 2. (1.9)
(cid:3105)(cid:3021) (cid:3017),(cid:3051) (cid:3019) (cid:3105)(cid:3021) (cid:3017),(cid:3051) (cid:3019)(cid:3021)(cid:3118) (cid:3019)(cid:3021)(cid:3118)
(cid:4672)(cid:3105)ln(cid:3082)(cid:3284)(cid:4673) (cid:3404) (cid:2869) (cid:3436)(cid:3105)(cid:3091)(cid:3284)E(cid:3440) (cid:3404)(cid:3023)(cid:3365)(cid:3284)(cid:3254) (cid:3404)(cid:3023)(cid:3365)(cid:3284)(cid:2879)(cid:3023)m(cid:3116),(cid:3284) , i = 1, 2. (1.10)
(cid:3105)(cid:3017) (cid:3021),(cid:3051) (cid:3019)(cid:3021) (cid:3105)(cid:3017) (cid:3021),(cid:3051) (cid:3019)(cid:3021) (cid:3019)(cid:3021)
where (cid:1834)(cid:3365)E and (cid:1848)(cid:3364)E are partial molar excess enthalpy and partial molar excess volume, respectively, can be
(cid:3036) (cid:3036)
obtained.
Equations that relate excess chemical potentials and activity coefficients of components in liquid phase to the
quantities measurable in vapor-liquid equilibrium experiments (equilibrium pressure, equilibrium temperature,
compositions of phases in equilibrium) are summarized in Volume IV/13A1 [07WIC1]. Relations among the
volumetric quantities (volume, density, isobaric expansivity, isothermal and isentropic compressibilities, speed
of sound) are summarized in Volume IV/23A [09CIB1].
General References
04GRO1 Grolier, J.-P.E., Wormald, C.J., Fontaine, J.-C., Sosnkowska-Kehiaian, K., Kehiaian, H.V.: Heats
of Mixing and Solution, in: Landolt-Börnstein Numerical Data and Functional Relationships in
Science and Technology, New Series, W. Martienssen (ed.), Vol. IV/10A, Springer-Verlag Berlin
Heidelberg 2004. SpringerMaterials - The Landolt-Börnstein Database
(www.springermaterials.com), DOI: 10.1007/b56530
07WIC1 Wichterle, I., Linek, J., Wagner, Z., Fontaine, J.-C., Sosnkowska-Kehiaian, K., Kehiaian, H.V.:
Vapor–Liquid Equilibrium in Mixtures and Solutions, in: Landolt-Börnstein Numerical Data and
Functional Relationships in Science and Technology, New Series, W. Martienssen (ed.), Vol.
IV/13A1, Springer-Verlag Berlin Heidelberg 2007. SpringerMaterials - The Landolt-Börnstein
Database (www.springermaterials.com), DOI: 10.1007/978-3-540-49315-0
08WIC1 Wichterle, I., Linek, J., Wagner, Z., Fontaine, J.-C., Sosnkowska-Kehiaian, K., Kehiaian, H.V.:
Vapor–Liquid Equilibrium in Mixtures and Solutions, in: Landolt-Börnstein Numerical Data and
Functional Relationships in Science and Technology, New Series, W. Martienssen (ed.), Vol.
IV/13A2, Springer-Verlag Berlin Heidelberg 2008. SpringerMaterials - The Landolt-Börnstein
Database (www.springermaterials.com), DOI: 10.1007/978-3-540-70745-5
DOI: 10.1007/978-3-642-02935-6_1 Landolt-Börnstein
©Springer-Verlag Berlin Heidelberg 2011 New Series IV/26A
Introduction 3
09CIB1 Cibulka, I., Hnědkovský, L., Fontaine, J.-C., Sosnkowska-Kehiaian, K., Kehiaian, H.V.:
Volumetric Properties of Mixtures and Solutions, in: Landolt-Börnstein Numerical Data and
Functional Relationships in Science and Technology, New Series, W. Martienssen (ed.), Vol.
IV/23A, Springer-Verlag Berlin Heidelberg 2009. SpringerMaterials - The Landolt-Börnstein
Database (www.springermaterials.com), DOI: 10.1007/978-3-540-73584-7

Landolt-Börnstein DOI: 10.1007/978-3-642-02935-6_1
New Series IV/26A ©Springer-Verlag Berlin Heidelberg 2011