B Boron Compounds: Boron and Cl, Br, I, S, Se, Te, Carboranes

274 Pages·1988·15.903 MB·English

by  Gert Heller, Anton Meller, Thomas Onak (auth.), Karl-Christian Buschbeck, Kurt Niedenzu (eds.)

l I I I I I l I I I 31
2 He 10 Ne 18 Ar 36 Kr 54 Xe 86 Rn Hl
~
I
2 5 6 7 8 a
I H 9 F 17 CI 35 Br 53 I 85 8At
8 03 16 S 9 34 Se 10 52 Te II 84 Pl2 o 71 Lu 03 Lr 71
1
7 N 4 15 P 16 33 As 17 51 Sb 18 83 Bi 19 70 Vb 102 No 71
6 C 14 14 Si 15 32 45 Ge 50 Sn 46 82 Pb 47 69 Tm 101 Md 71
bers 5 B 13 13 AI35 31 36 Ga 49 In 37 81 TI38 68 Er 100 Fm 71
m
m Nu 30 Zn 32 48 Cd 33 80 H34 g 67 Ho 99 Es 71
e Gmelin Syste : 28 29 Ni 57 Cu 60 46 47 Pd 65 Ag 61 78 79 Pt 68 Au 62 65 66 Tb Oy 98 97 Bk71 Cf 71
with th 27 Co 58 45 64 Rh 77 Ir 67 64 Gd 96 71 Cm
ments 26 Fe 59 44 Ru 63 76 Os 66 63 Eu 95 Am71
of the Ele : 25 Mn 56 43 To 69 75 Re 70 62 Sm 94 Pu 71
Table 24 Cr 52 42 MS3 o 74 54 W 61 Pm 93 Np 71
eriodic 23 V 48 41 49 Nb 73 50 Ta 105 71 60 Nd 92 U 55
P
22 Ti 41 40 Zr 42 72 Hf 43 104 71 59 Pr 91 Pa 51
21 So 39 39 Y 39 57** La 39 89*** A40 0 58 Ce 90 Th44
4 26 8e 12 Mg27 20 Ca 28 38 Sr 29 56 Ba 30 88 Ra 31 an ides 39 nides
I H 2 3 Li 20 II 21 Na 19 * K 22 37 24 Rb 55 Cs 25 87 Fr25a *Lanth ** Acti --
'* 1* "
~ -~ o ~ C') I s' en ~ 3 iii' "" c' !J g ~ ~ a: .. co = ... ... C") ~ III
Gmelin Handbook of Inorganic Chemistry
8th Edition
Gmelin Handbook
of Inorganic Chemistry
8th Edition
Gmelin Handbuch der Anorganischen Chemie
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Gmelin Handbook
of Inorganic Chemistry
8th Edition
B
Boron Compounds
3rd Supplement Volume 4
Boron and Cl, Br, I, S, Se, Te. Carboranes
With 19 illustrations
AUTHORS Gert HeUer, Institut fur Anorganische und
AnaLytische Chemie, Freie Universitat Berlin
Berlin, FederaL Republic of Germany
Anton MeUer, Anorganisch-Chemisches Institut,
Universitat G6ttingen
G6ttingen, FederaL Republic of Germany
Thomas Onak, Department of Chemistry,
CaLifornia State University
Los AngeLes, California, USA
EDITORS KarL-Christian Buschbeck, GmeLin-lnstitut, Frankfurt/Main
Kurt Niedenzu, Department of Chemistry,
University of Kentucky, Lexington, Kentucky, USA
System Number 13
Springer-Verlag Berlin Heidelberg GmbH 1988
LITERATURE CLOSING DATE: END OF 1984
IN SOME CASES MORE RECENT DATA HAVE BEEN CONSIDERED
Library of Congress catalog card Number: Agr 25-1383
ISBN 978-3-662-06140-4 ISBN 978-3-662-06138-1 (eBook)
DOI 10.1007/978-3-662-06138-1
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© by Springer-Verlag, Bertin· Heidelberg 1988
Originally published by Springer-Verlag Berlin Heidelberg New York in 1988.
Softcover reprint of the hardcover 8th edition 1988
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Preface
The present VoLume 4 of "Boron Compounds" 3rd SuppLement concLudes the 3rd suppLe
ment issue on boron compounds, but will be augmented by a separate index voLume for the
boron compounds discussed in the four voLumes of this specific suppLement. This 3rd suppLe
ment adds on to the previous voLumes dealing with boron compounds beginning (in paren
theses: Literature cLosing dates) with the Main VoLume (end of 1925), SuppLement VoLume 1
(end of 1949), SuppLement VoLume 2 (end of 1975 for boron carbides, mid-1980 for eLementaL
boron), "Boron Compounds" VoLumes 1 to 20 and FormuLa Index, "Boron Compounds" 1st
SuppLement (3 voLumes, end of 1977), and "Boron Compounds" 2nd SuppLement (2 voLumes,
through 1980). In the 3rd suppLement the Literature is covered uniformLy through 1984.
The present voLume contains the description of boron compounds with CL, Br, and I, as weLL
as the systems of boron with S, Se, Te, and Po. The finaL chapter describes the carboranes; it
contains the description of carboranes as weLL as brief discussions of metaLLacarboranes and a
Listing of carborane-containing poLymers.
The IUPAC nomencLature is mostly adhered to; occasionaL abbreviations for compounds
are expLained in the text. UnLess otherwise noted, a positive sign for the chemical shifts on the
NMR signaLs indicates downfieLd from the references: (CH3)4Si for [)'H and [)'3C, (C2H5hO-BF3
for [)"B, aqueous NaN03 for [)'4N, and CFCL3 for [)'9F.
Lexington, Kentucky (USA) Kurt Niedenzu
Frankfurt am Main KarL-Christian Buschbeck
JuLy 1988
Boron and Boron Compounds in the GmeLin Handbook (Syst. No. 13)
"Bor" (Main VoLume) Historical. Occurrence. The ELement. Compounds of B with H, 0, N,
the HaLogens, S, Se, and Te.
Literature cLosing date: end of 1925.
"Bor" Occurrence. The ELement. Compounds of B with H, 0, N, the
(SuppLement VoLume 1) HaLogens, S, and C.
Literature cLosing date: end of 1949.
"Borverbindungen" 1 Boron Nitride. B-N-C HeterocycLes. PoLymeric B-N Compounds.
Literature coverage from 1950 up to 1972.
"Borverbindungen" 2 Carboranes, Part 1. NomencLature and Types of Carboranes.
Carboranes (without Hetero- and MetaLLocarboranes, and Higher
Carboranes).
Literature coverage from 1950 up to 1973 or 1970, respectiveLy.
"Borverbindungen" 3 Compounds of B Containing Bonds to S, Se, Te, P, As, Sb, Si, and
MetaLs.
Literature coverage from 1950 to the end of 1973.
"Borverbindungen" 4 Compounds with IsoLated TrigonaL Boron Atoms and CovaLent Boron
Nitrogen Bonding (Aminoboranes and B-N HeterocycLes).
Literature coverage from 1950 to the end of 1973.
"Borverbindungen" 5 Boron-PyrazoLe. Derivatives and Spectroscopic Studies on TrigonaL
B-N Compounds.
Literature coverage from 1950 to the end of 1973.
"Borverbindungen" 6 Carboranes, Part 2. Hetero- and MetaLLocarboranes. PoLymeric
Carborane Derivatives. ELectronic Properties.
Literature coverage from 1950 up to 1974 or 1971, respectiveLy.
"Borverbindungen" 7 Boron Oxides. Boric Acids. Borates.
Literature coverage from 1950 to the end of 1973.
"Borverbindungen" 8 The Tetrahydroborate Ion and Its Derivatives.
Literature coverage from 1950 to the end of 1974.
"Borverbindungen" 9 Boron-HaLogen Compounds, Part 1.
Literature coverage from 1950 to the end of 1974.
"Borverbindungen" 10 Boron Compounds with Coordination Number 4.
Literature coverage from 1950 to the end of 1975.
"Borverbindungen" 11 Carbo ranes, Part 3. Dicarba-c/oscrdodecaboranes.
Literature coverage from 1950 to the end of 1975.
"Borverbindungen" 12 Carboranes, Part 4. Dicarba-c/oscrdodecaboranes.
Literature coverage from 1950 to the end of 1975.
"Borverbindungen" 13 Boron-Oxygen Compounds, Part 1.
Literature coverage from 1950 to the end of 1975.