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Atmospheric Ozone Dynamics: Observations in the Mediterranean Region PDF

342 Pages·1997·18.863 MB·English
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NATO ASI Series Advanced Science Institutes Series A series presenting the results of activities sponsored by the NA TO Science Committee, whic'1 aims at the dissemination of advanced scientific and technological knowledge, with a view to strengthening links between scientific communities. The Series is published by an International board of publishers In conjunction with the NATO Scient fic Affairs Division A Life Sciences Plenum Publishing Corporation B Physics London and New York C Mathematical and Physical Sciences Kluwer Academic Publishers D Behavioural and Social Sciences Dordrecht, Boston and London E Applied Sciences F Computer and Systems Sciences Springer -Verlag G Ecological SCiences Berlin Heidelberg New York H Cell Biology London Paris Tokyo Hong Kong I Global Environmental Change Barcelona Budapest PARTNERSHIP SUB-SERIES 1. Disarmament Technologies Kluwer Academic Publishers 2. Environment Springer-Verlag/Kluwer Acad. Publishers 3. High Technolc,gy Kluwer Academic Publishers 4. Science and Technology Policy Kluwer Academic Publishers 5. Computer NetNorking Kluwer Academic Publishers The Partnership Sub-Series incorporates activities undertaken in collaboration with NATO's Cooperation Partners, the countries of the CIS and Central and Eastern Europe, in Priorily Areas of concern to those countries. NAT O-PCO DATABASE The electronic index to the NATO ASI Series provides full bibliographical references (with keywords and/or abstracts) to about 50000 contributions from international sciE:ntists published in all sections of the NATO ASI Series. Access to the NATO-PCO DATABASE compiled by the NATO Publication Coordination Office is possible in tWI) ways: -via online FILE 128 (NATO-PCO DATABASE) hosted by ESRIN, Via Galileo Galilei, 1-00044 Frascati, Italy. -via CD-ROM "~IATO Science & Technology Disk" with user-friendly retrieval software in Enqlish, French and German (© WTV GmbH and DATAWARE Technologies Inc. 1992) The CD-ROM can be ordered through any member of the Board of Publishers or through NATO-FCO, Overijse, Belgium. Series I: Global Environmental Change, Vol. 53 Springer Berlin Heidelberg New York Barcelona Budapest Hong Kong London Milan Paris Santa Clara Singapore Tokyo Atmospheric Ozone Dynamics Observations in the Mediterranean Region Edited by Costas Varotsos University of .Athens Department of Physics, Division of Applied Physics Laboratory of \t1eteorology Panepistimioupolis, Build PHYS.V Athens, GR 1E ll 84, Greece With 139 Figures (12 Colour Plates) Springer Published in cooperation with NATO Scientific Affairs Division Proceedings of the NATO Advanced Research Workshop "Ground Level and Satellite Ozone Observations. Changes in the Mediterranean Region", held in Athens, Greece, October 31 - November4, 1995 Cataloging-in-Publication Data applied for Die Deutsche Bibliothek - CIP-Einheitsaufnahme Atmospheric ozone dynamics : observations in the Mediterranean region; [proceedings of the NATO Advanced Research Workshop "Ground Level and Satellite Ozone Observations. Changes in the Mediterranean Region", held in Athens, Greece, October 31 - November 11, 1995] / ed. by Costas Varotsos. Publ. in cooperation with NATO Scientific AtTairs Division. - Berlin; Heidelberg; New York ; Barcelona ; Budapest ; Hong Kong ; London ; Milan ; Paris ; Santa Clara ; Singapore ; Tokyo : Springer, 1997 (NATO ASI series: Ser. I. Global environmental cbange ; Vol. 53) ISBN-13: 978-3-642-64558-7 eISBN-13: 978-3-642-60797-4 DOl: 10.1007/978-3-642-60797-4 This work is subject to copyright All rights are reserved. whether the whole or part of the material is concerned, speCifically the rights of translation, reprinting, reuse of illustrations. recitation. broadcasting. reproduction on microfilm or in any other way. and storage in data banks Duplication of this publication or parts thereof is permitted only under the provIsions of the German COPYright Law of September 9. 1965. in its current version. and permission for use must always be obtained from Springer-Verlag. Violations are ilable tor prosecution under the German COPYright Law. © Springer-Verlag Berlin Heidelberg 1997 Softcover reprint of the hardcover 1s t edition 1997 Typesetting. Camera ready by the authors/editors Printed on acid-free paper SPIN. 10525492 31/3137 -5 43210 Preface An increasing allllo~/allce because of the anthropogenically induced ozone depletion and relevant illcrca5e of the surface ultraviolet (UV) radiation (including erythemal part of the UV spectrum) has resulted in the growth of interest to total ozone (TOZ) surface and satellite observations, surface UV measurements (with an emphasis on UV -B) and. the interpretation of observation results to assess potential impacts of the UV radiation enhancement on man and biosphere. The significance of this phenomenon is diJIcrent in various cowltries. Special attention has been paid, for instance, to ozone depletion and UV radiation increase at high latitudes (this problem has also been discussed during the Workshop). It is equally clear, however, that low and mid-latitude environmental dynamics requires carefuU monitoring and assessment of environm(:ntal trends as well. Such a conclusion is especially true for the Mediterranean Region where numerous resort places are located and subject to excessive levels of Solar Ultraviolet Radiation. This is why the NATO Advanced Rcsearch Workshop "Ground-Level and Satellite Ozone Observations: Changes in the Mediterranean Region" was organized and took place in Athens (Grcccc) during the Lime period 31 October - 4 November 1995. It should be pointed out, however, that presentations discussed during the Workshop went far beyond the regional scale of consideration. This has been very important, because it opened an opportwlity to analyse the Mediterrane:an environmental situation in the broader contcx1 of the European global changes. An important advantage of the Workshop's programme has also been the considleration of not only problems of TOZ and UV-B variability but also tropospheric ozone dynamics as well as those causes (chemical and photochemical reactiom: coupled with air transport) which are responsible for changes of the ozone colllcentration in the troposphere. Total and tropospheric ozone variability takes place due to impacts of a number of factors which contributions have not been reliably asscssed as yet. A critical issue is a relationship between natural and anthropogenically induced changes. It is important that impacts of various 'actors have been discussed (chemical and photochemical processes, meteorological conditions, impacts of stratospheric aerosols, solar activity etc.). In a substantial part of the papers tropospheric pollution has been considered in the context of ozone changes. Apart from the analysis of observation data some .key problems of numerical modelling have been discussed, such as tropospheric chemical composition changes, Monte Carlo radiative transfer calculations, and others. The subjcct of a number of papers has been the development VI of remote sensing techniques to retrieve minor optically active components of the atmosphere. Thus, the programme of the Workshop has been characterised by a system's approach to the solution of the problems considered which has been the basis of the successful accomplishment of the Workshop's aims. It has been equally important that many outstanding experts presented their contributions. The Workshop more than justified the expectations. The support from NATO and local sources (Training Centre of National Bank SA and others) has helped to reach a high level of the organisation. The contribution of the collaborators of the University of Athens and other Greek institutions to the success of the Workshop was outstanding. The editor is grateful to the NATO Scientific Affairs Division, the European Environment Agency, the Greek Ministry of Development, the Greek Ministry of Environment, Physical Planning and Public Works, the Greek Ministry of National Economy, the Greek Ministry of Culture, the University of Athens, the Hellenic Airline Association, the Hellenic Opticians Association, the Hellenic Civil Aviation Authority, the PHARMA-CARE, the EKO Lubricant and Refineries ABEE, the S. A Vairamoglou S.A. and the Ventouris Lines Companies, the Hellenic Foreign Trade Board the National Mortgage Bank of Greece, for their sponsorship. Finally, this Workshop is dedicated to the memory of the scientists Patrick Aimedieu and Kjell Henriksen, who passed away. The Organising Committee of this NATO ARW Contents EUROTRAC: Applications to Photo-Oxidants and the Future Project 1 P. Borrell, P. Builtjes, P. Grennfelt, /2f. Hov, R. van Aalst, D. Fowler, G. Megie, N. Moussiopoulos, P. Wameck, A. Volz-Thomas and R. Wayne The Spatial Variation of Ozone Depletion in Europe 9 A. P. Cracknell, C. P. D. McArthur and C. Varotsos Statistical Analyses of Total Ozone Spatial Variability in the Mediterranean 23 1. Dalyuk and 0. Pokrovsky Total Ozone Winter-Spring Deficiences in the Northern Mid-Latitudes 31 M Deg6rska and B. Ra/ewska-Wiech Regional Modelling of Tropospheric Ozone Distribution and Budgets .......... 37 A. Ebel, M Memmesheimer and H. J. Jakobs Weather-Pattern Dependent Total Column Ozone Trends in Central Europe 59 WEnke, G. Vogel and D. Spankuch Ozone Change in the Polar Atmosphere ..................................................... 73 H. Gemandt, P. von der Gathen andA. Herber Ozone and N~ Monitoring in Southern Spain: The 1994/95 Winter Record Low ......................... ................................................................................. 101 M Gil, C. Parrondo, M Yela and B. de la Morena The Middle Atmospher,e over Bulgaria at the Time of Strong Geomagnetic Storm on October lO-th 1988 ..................................................................... 113 T. Gogosheva, M Gogoshev and V Zachariev VIII Variations of Stratospheric Ozone at the Time of Extremely High Solar Activity ...................................................................................................... 125 M. Gogoshev, B. Petkov and T. Gogosheva Total Ozone Variations and Meteorological Processes 133 K. Henriksen and V Roldugin Decrease in Surface Ozone Related to Car Exhaust at High Latitudes 143 K. Henriksen and S. Sivasingarajah The Portuguese Ozone and UV- B Monitoring Stations 147 D. V Henriques Photochemical Air Pollution: A Regional Scale Problem 157 G. Kallos, V Kotroni and K. Lagouvardos Re-evaluation of Hohenpeissenberg Ozone Records 167 U. Kohler A Review on Greenhouse Effect and Ozone Dynamics over Greece 175 K. Ya. Kondratyev and C. 'Varotsos AMFTRAN: A New Monte Carlo Radiative Transfer Model for Calculating Air Mass Factors ................................. ....................................................... 229 L. Marquard and U. Platt Air Pollution Models and Their Role in Environmental Policy 241 N Moussiopoulos A Thermoluminescence Dosemeter for Solar Ultraviolet Irradiation 251 J. A. Munoz, 1. AgUirre de Cancer, G. Lifante, F Cuss6 and F Jaque On the Forecasting of Intermonth Total Ozone Variations 257 0. Pokrovsky and 1. Dalyuk Analysis of Stratospheric Aerosols in the Southern-Eastern Mediterranean Region as Deduced from SAGE I and SAGE II Measurements .... .............. 271 A. Retalis and C. Cartalis Atmospheric Soundings in Support of the Definition of the Tropopause Region in the South-Eastern Mediterranean Region ................................... 281 A. Retalis, C. Car/alis, AI Tombrou and C. Varotsos Retrieval of Height Profiles of Trace Gases by Optimal Parameter Estimation 285 E. Scheer, H. G. Bock, U. Platt and R. Rannacher IX Quality Checks for Satellite and Ground-Based Total Ozone Observations 293 D. Spankuch and E. Schulz Airline Crew, Cosmic: Radiation and Cancer. Status of the Current Norwegian Study and the Proposed European Study .................................. 303 U. Tveten, T Haldorsen and J. Reitan Regional Distribution of Total Column Ozone Changes in Central Europe 311 G. Vogel, V. Schubert and D. Spankuch Determination of Cloud Properties and Cloud Type from DOAS- Measurements ............................................................................................ 327 T Wagner, T Senne, F. ErIe, C. Otten, J. Stutz, K. Pfeilsticker and U. Platt

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