Applications of Metal-organic Frameworks and Their Derived Materials

481 Pages·2020·18.92 MB·English

by  Inamuddin, Rajender Boddula, Mohd Imran Ahamed, Abdullah M. Asiri

Applications of
Metal–Organic Frameworks
and Their Derived Materials
Scrivener Publishing
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Martin Scrivener ([email protected])
Phillip Carmical ([email protected])
Scrivener Publishing
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Beverly, MA 01915-6106
Publishers at Scrivener
Martin Scrivener ([email protected]) Applications of
Phillip Carmical ([email protected])
Metal–Organic Frameworks
and Their Derived Materials
Edited by
Inamuddin, Rajender Boddula,
Mohd Imran Ahamed
and Abdullah M. Asiri
This edition first published 2020 by John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, USA
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Library of Congress Cataloging-in-Publication Data
Names: Inamuddin, 1980– editor. | Boddula, Rajender, editor. | Ahamed, Mohd
Imran, editor. | Asiri, Abdullah M., editor.
Title: Applications of metal-organic frameworks and their derived materials /
edited by Inamuddin, Rajender Boddula, Mohd Imran Ahamed, and Abdullah M. Asiri.
Description: Hoboken, NJ : Wiley-Scrivener, 2020. | Includes
bibliographical references and index.
Identifiers: LCCN 2020015462 (print) | LCCN 2020015463 (ebook) | ISBN
9781119650980 (cloth) | ISBN 9781119651161 (adobe pdf) | ISBN
9781119650959 (epub)
Subjects: MESH: Metal-Organic Frameworks–chemistry |
Nanostructures–chemistry | Biosensing Techniques
Classification: LCC QD411 (print) | LCC QD411 (ebook) | NLM QD 411 | DDC
547/.05–dc23
LC record available at https://lccn.loc.gov/2020015462
LC ebook record available at https://lccn.loc.gov/2020015463
Cover image: Kris Hackerott
Cover design by Russell Richardson
Set in size of 11pt and Minion Pro by Manila Typesetting Company, Makati, Philippines
Printed in the USA
10 9 8 7 6 5 4 3 2 1
Contents
Preface xiii
1 Application of MOFs and Their Derived Materials in Sensors 1
Yong Wang, Chang Yin and Qianfen Zhuang
1.1 Introduction 1
1.2 Application of MOFs and Their Derived Materials in Sensors 3
1.2.1 Optical Sensor 3
1.2.1.1 Colorimetric Sensor 3
1.2.1.2 Fluorescence Sensor 7
1.2.1.3 Chemiluminescent Sensor 11
1.2.2 Electrochemical Sensor 13
1.2.2.1 Amperometric Sensor 13
1.2.2.2 Impedimetric, Electrochemiluminescence,
and Photoelectrochemical Sensor 16
1.2.3 Field-Effect Transistor Sensor 19
1.2.4 Mass-Sensitive Sensor 21
1.3 Conclusion 22
Acknowledgments 23
References 23
2 Applications of Metal–Organic Frameworks (MOFs)
and Their Derivatives in Piezo/Ferroelectrics 33
H. Manjunatha, K. Chandra Babu Naidu, N. Suresh Kumar,
Ramyakrishna Pothu and Rajender Boddula
2.1 Introduction 34
2.1.1 Brief Introduction to Piezo/Ferroelectricity 34
2.2 Fundamentals of Piezo/Ferroelectricity 34
2.3 Metal–Organic Frameworks for Piezo/Ferroelectricity 40
2.4 Ferro/Piezoelectric Behavior of Various MOFs 40
2.5 Conclusion 52
References 53
v
vi Contents
3 Fabrication and Functionalization Strategies of MOFs
and Their Derived Materials “MOF Architecture” 63
Demet Ozer
3.1 Introduction 63
3.2 Fabrication and Functionalization of MOFs 65
3.2.1 Metal Nodes 65
3.2.2 Organic Linkers 68
3.2.3 Secondary Building Units 76
3.2.4 Synthesis Methods 77
3.2.4.1 Hydrothermal and Solvothermal Method 77
3.2.4.2 Microwave Synthesis 78
3.2.4.3 Electrochemical Method 80
3.2.4.4 Mechanochemical Synthesis 81
3.2.4.5 Sonochemical (Ultrasonic Assisted) Method 81
3.2.4.6 Diffusion Method 82
3.2.4.7 Template Method 82
3.2.5 Synthesis Strategies 83
3.3 MOF Derived Materials 89
3.4 Conclusion 90
References 90
4 Application of MOFs and Their Derived Materials
in Molecular Transport 101
Arka Bagchi, Partha Saha, Arunima Biswas
and SK Manirul Islam
4.1 Introduction 102
4.2 MOFs as Nanocarriers for Membrane Transport 102
4.2.1 MIL-89 103
4.2.2 MIL-88A 103
4.2.3 MIL-100 104
4.2.4 MIL-101 104
4.2.5 MIL-53 104
4.2.6 ZIF-8 104
4.2.7 Zn-TATAT 105
4.2.8 BioMOF-1 (Zn) 105
4.2.9 UiO (Zr) 105
4.3 Conclusion 106
References 106
Contents vii
5 Role of MOFs as Electro/-Organic Catalysts 109
Manorama Singh, Ankita Rai, Vijai K. Rai, Smita R. Bhardiya
and Ambika Asati
5.1 What Is MOFs 109
5.2 MOFs as Electrocatalyst in Sensing Applications 111
5.3 MOFs as Organic Catalysts in Organic Transformations 114
5.4 Conclusion and Future Prospects 115
References 116
6 Application of MOFs and Their Derived Materials in Batteries 121
Rituraj Dutta and Ashok Kumar
6.1 Introduction 122
6.2 Metal–Organic Frameworks 126
6.2.1 Classification and Properties of Metal–Organic
Frameworks 127
6.2.2 Potential Applications of MOFs 130
6.2.3 Synthesis of MOFs 133
6.3 Polymer Electrolytes 135
6.3.1 Historical Perspectives and Classification
of Polymer Electrolytes 136
6.3.2 MOF Based Polymer Electrolytes 139
6.4 Ionic Liquids 142
6.4.1 Properties of Ionic Liquids 143
6.4.2 Ionic Liquid Incorporated MOF 145
6.5 Ion Transport in Polymer Electrolytes 147
6.5.1 General Description of Ionic Conductivity 147
6.5.2 Models for Ionic Transport in Polymer Electrolytes 148
6.5.3 Impedance Spectroscopy and Ionic Conductivity
Measurements 152
6.5.4 Concept of Mismatch and Relaxation 155
6.5.5 Scaling of ac Conductivity 156
6.6 IL Incorporated MOF Based Composite
Polymer Electrolytes 157
6.7 Conclusion and Perspectives 166
References 168
7 Fine Chemical Synthesis Using Metal–Organic Frameworks
as Catalysts 177
Aasif Helal
7.1 Introduction 177
7.2 Oxidation Reaction 179
7.2.1 Epoxidation 179
viii Contents
7.2.2 Sulfoxidation 181
7.2.3 Aerobic Oxidation of Alcohols 182
7.3 1,3-Dipolar Cycloaddition Reaction 183
7.4 Transesterification Reaction 183
7.5 C–C Bond Formation Reactions 184
7.5.1 Heck Reactions 184
7.5.2 Sonogashira Coupling 186
7.5.3 Suzuki Coupling 186
7.6 Conclusion 187
References 187
8 Application of Metal Organic Framework and Derived
Material in Hydrogenation Catalysis 193
Tejaswini Sahoo, Jagannath Panda, Jnana Ranjan Sahu
and Rojalin Sahu
8.1 Introduction 193
8.1.1 The Active Centers in Parent MOF Materials 195
8.1.2 The Active Centers in MOF Catalyst 195
8.1.3 Metal Nodes 196
8.2 Hydrogenation Reactions 197
8.2.1 Hydrogenation of Alpha–Beta Unsaturated Aldehyde 197
8.2.2 Hydrogenation of Cinnamaldehyde 198
8.2.3 Hydrogenation of Nitroarene 199
8.2.4 Hydrogenation of Nitro Compounds 201
8.2.5 Hydrogenation of Benzene 202
8.2.6 Hydrogenation of Quinoline 205
8.2.7 Hydrogenation of Carbon Dioxide 206
8.2.8 Hydrogenation of Aromatics 207
8.2.9 Hydrogenation of Levulinic Acid 207
8.2.10 Hydrogenation of Alkenes and Alkynes 208
8.2.11 Hydrogenation of Phenol 210
8.3 Conclusion 210
References 211
9 Application of MOFs and Their Derived Materials
in Solid-Phase Extraction 219
Adrián Gutiérrez-Serpa, Iván Taima-Mancera, Jorge Pasán,
Juan H. Ayala and Verónica Pino
9.1 Solid-Phase Extraction 220
9.1.1 Materials in SPE 223
9.2 MOFs and COFs in Miniaturized Solid-Phase
Extraction (µSPE) 225
Contents ix
9.3 MOFs and COFs in Miniaturized Dispersive Solid-Phase
Extraction (D-µSPE) 232
9.4 MOFs and COFs in Magnetic-Assisted Miniaturized
Dispersive Solid-Phase Extraction (m-D-µSPE) 239
9.5 Concluding Remarks 249
Acknowledgments 249
References 249
10 Anticancer and Antimicrobial MOFs and Their
Derived Materials 263
Nasser Mohammed Hosny
10.1 Introduction 263
10.2 Anticancer MOFs 264
10.2.1 MOFs as Drug Carriers 264
10.2.2 MOFs in Phototherapy 269
10.3 Antibacterial MOFs 272
10.4 Antifungal MOFs 278
References 280
11 Theoretical Investigation of Metal–Organic Frameworks
and Their Derived Materials for the Adsorption
of Pharmaceutical and Personal Care Products 287
Jagannath Panda, Satya Narayan Sahu, Tejaswini Sahoo,
Biswajit Mishra, Subrat Kumar Pattanayak and Rojalin Sahu
11.1 Introduction 288
11.2 General Synthesis Routes 290
11.2.1 Hydrothermal Synthesis 295
11.2.2 Solvothermal Synthesis of MOFs 296
11.2.3 Room Temperature Synthesis 296
11.2.4 Microwave Assisted Synthesis 296
11.2.5 Mechanochemical Synthesis 297
11.2.6 Electrochemical Synthesis 297
11.3 Postsynthetic Modification in MOF 297
11.4 Computational Method 297
11.5 Results and Discussion 299
11.5.1 Binding Behavior Between MIL-100 With
the Adsorbates (Diclofenac, Ibuprofen,
Naproxen, and Oxybenzone) 299
11.6 Conclusion 303
References 304