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Antimony, Gold, and Jupiter’s Wolf: How the Elements Were Named PDF

290 Pages·2020·15.323 MB·English
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ANTIMONY, GOLD, AND JUPITER’S WOLF 1 Great Clarendon Street, Oxford, ox2 6dp, United Kingdom Oxford University Press is a department of the University of Oxford. It furthers the University’s objective of excellence in research, scholarship, and education by publishing worldwide. Oxford is a registered trade mark of Oxford University Press in the UK and in certain other countries © Peter Wothers 2019 The moral rights of the author have been asserted First Edition published in 2019 Impression: 1 All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, without the prior permission in writing of Oxford University Press, or as expressly permitted by law, by licence or under terms agreed with the appropriate reprographics rights organization. Enquiries concerning reproduction outside the scope of the above should be sent to the Rights Department, Oxford University Press, at the address above You must not circulate this work in any other form and you must impose this same condition on any acquirer Published in the United States of America by Oxford University Press 198 Madison Avenue, New York, NY 10016, United States of America British Library Cataloguing in Publication Data Data available Library of Congress Control Number: 2019945159 ISBN 978–0–19–965272–3 Printed and bound in Great Britain by Clays Ltd, Elcograf S.p.A. Links to third party websites are provided by Oxford in good faith and for information only. Oxford disclaims any responsibility for the materials contained in any third party website referenced in this work. I dedicate this book to Joanne and Keith Rutherford who not only share their name with the discoverer of the most abundant element in the atmosphere, but who, in the course of their valuable professions, save lives by administering the second most abundant element, just as foreseen by its discoverer 250 years ago. PREFACE In November 2016, the International Union of Pure and Applied Chemistry (IUPAC) officially announced the proposed names for four new elements— nihonium, moscovium, tennessine, and oganesson. These four additions finally ‘completed’ the periodic table, in that every space had a named element from number 1 (hydrogen) to number 118 (oganesson), and all seven rows of the table were now filled. It’s possible that other elements might be synthesized— research is certainly ongoing—but it’s unlikely that the table will ever appear as neat again, since to fill the next row, another fifty-four elements would need to be made. The naming process is not a trivial matter, and it usually takes several years. An independent body (a joint working party between the IUPAC and the International Union of Pure and Applied Physics) first has to scrutinize the evi- dence and confirm that atoms of the element in question were actually formed (albeit briefly), then establish who exactly made them first, and, finally, wait for all the concerned parties within the group who first made the discovery to agree on a name. Even then, the joint working party has to approve the sug- gested name. Despite the arduous process, it’s clear how these four elements were named: nihonium after one of the two ways to say ‘Japan’ in Japanese and literally meaning ‘the Land of Rising Sun’; moscovium after the Moscow region, home of the Joint Institute of Nuclear Research, where the experiments resulting in its discovery were conducted; tennessine in recognition of the con- tribution of the Tennessee region of the United States to superheavy research, and, finally, oganesson, named after one of the pioneers of transactinoid elem- ent research, Professor Yuri Oganessian. It’s easy to guess where the names of some of the other elements came from—for example, einsteinium or germanium. But for many others, their ori- gins are less clear or even not known with certainty. These are the elements of interest in this book. It isn’t a simple etymological list of the elements and their names; rather, it’s an exploration of why some of the elements eventually ended up with the names they did. For example, while it’s easy to find out that selenium was named after the goddess of the moon, why did the discoverer vii preface choose to do that in the first place? The answer to this question is much more involved. Similarly, the element oxygen is familiar to all of us, but it has a far- from-ideal name, supposedly meaning ‘acid-generator’, although others from the period thought it more precisely suggested ‘a sharp chin’, or even ‘the son of a vinegar merchant’. Exactly how it ended up with the name requires a tour through the history of chemistry and an understanding of some of the key sci- entists and their changing theories. Where possible, original sources have been used so that we can hear the lan- guage as used by the original discoverers (or, at least, an English translation). Old spellings have been retained, with the exception of the ‘long s’ character or the occasional v/u interchange. vviiiiii ACKNOWLEDGEMENTS First, I must thank my parents for giving me my very first chemistry set and believing me when I promised not to ‘blow the house up’. There was, I think, only one ‘minor’ disaster, when a jar of the intolerably smelly gas hydrogen sulfide toppled over and stank the house out. I can only apologize again, and I am sure it would not have helped at the time if I had pointed out that the gas was more toxic than hydrogen cyanide . . . I must also thank my brother John and his wife Tracy for their constant love and support; and my sister Joanne and her husband Keith, who are acknowledged in the dedication. I am grate- ful to my whole family for the encouragement and support that led to the first generation from our family attending university. From the home I grew up in, to what has now been home for most of my life: I must acknowledge the invaluable support I receive from the community that is St Catharine’s College, Cambridge. This has come in the form of moral support, guidance, and encouragement from the Master of the College, currently in the form of Sir Mark and Lady Welland, and previously from past Masters Dame Jean Thomas, Prof. David Ingram, and Sir Terrance English. I have been inspired by some great fellow scientists—notably the late Sir Alan Battersby, a highly dis- tinguished chemist, and also the late Dr John Shakeshaft, who admitted a ter- rified young teenager to the college many years ago. Our community thrives with a melting pot of great minds of different hues (rather like the elements of the periodic table); it is a privilege, for example, to end up sitting next a lead- ing expert on Shakespeare at lunch, or to have coffee with a medieval French linguist. I thank many of my fellow Fellows for their help with parts of this pro- ject, in particular Dr Paul Hartle (English), Dr Miranda Griffin (medieval French), Prof. Geoffrey Kantaris (Spanish), Drs John and Dorothy Thomson (History and Classics respectively), Dr Hester Lees-Jeffries (English), Prof. Richard Dance (Anglo-Saxon Norse and Celtic), and Dr River Chen and Prof. Hans van de Ven for their much-needed help as I tried to understand the meaning behind Chinese characters. I am also grateful to other members of our Fellowship who have played a key role, directly or indirectly, in the production of this book, namely Prof. John Pyle (Chemistry), Drs Ivan and Helen Scales (Geography and Marine ix

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