MATERIALS SCIENCE AND TECHNOLOGIES A I N NTRODUCTION TO CONTACT RESISTANCE No part of this digital document may be reproduced, stored in a retrieval system or transmitted in any form or by any means. The publisher has taken reasonable care in the preparation of this digital document, but makes no expressed or implied warranty of any kind and assumes no responsibility for any errors or omissions. No liability is assumed for incidental or consequential damages in connection with or arising out of information contained herein. This digital document is sold with the clear understanding that the publisher is not engaged in rendering legal, medical or any other professional services. M S ATERIALS CIENCE T AND ECHNOLOGIES Additional books and e-books in this series can be found on Nova’s website under the Series tab. MATERIALS SCIENCE AND TECHNOLOGIES A I N NTRODUCTION TO CONTACT RESISTANCE ZUOGUANG LIU EDITOR Copyright © 2020 by Nova Science Publishers, Inc. All rights reserved. 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In addition, no responsibility is assumed by the Publisher for any injury and/or damage to persons or property arising from any methods, products, instructions, ideas or otherwise contained in this publication. This publication is designed to provide accurate and authoritative information with regard to the subject matter covered herein. It is sold with the clear understanding that the Publisher is not engaged in rendering legal or any other professional services. If legal or any other expert assistance is required, the services of a competent person should be sought. FROM A DECLARATION OF PARTICIPANTS JOINTLY ADOPTED BY A COMMITTEE OF THE AMERICAN BAR ASSOCIATION AND A COMMITTEE OF PUBLISHERS. Additional color graphics may be available in the e-book version of this book. Library of Congress Cataloging-in-Publication Data ISBN: 978-1-53618-501-0 Names: Liu, Zuoguang, editor. Title: An introduction to contact resistance / Zuoguang Liu (editor). Description: New York : Nova Science Publishers, Inc., [2020] | Series: Materials science and technologies | Includes bibliographical references and index. | Identifiers: LCCN 2020038446 (print) | LCCN 2020038447 (ebook) | ISBN 9781536185010 (paperback) | ISBN 9781536185836 (adobe pdf) Subjects: LCSH: Semiconductor-metal boundaries. | Electric contacts. | Electric resistance. Classification: LCC TK7872.C68 I58 2020 (print) | LCC TK7872.C68 (ebook) | DDC 621.3815/2--dc23 LC record available at https://lccn.loc.gov/2020038446 LC ebook record available at https://lccn.loc.gov/2020038447 Published by Nova Science Publishers, Inc. † New York CONTENTS Preface vii Chapter 1 Introduction to Semiconductor Transistor Resistances 1 Zuoguang Liu Chapter 2 Physics and Materials of Semiconductor-Metal Contacts 25 Zuoguang Liu and Nicolas Breil Chapter 3 Electrical Characterization of Contact Resistance 51 Zuoguang Liu Chapter 4 Contact Resistance Reduction Approaches 79 Heng Wu Chapter 5 Meta-Stable Alloys for Ultra-Low Contact Resistance 101 Zuoguang Liu and Heng Wu Chapter 6 Low-Resistance Contact Integration in CMOS Technology 123 Heng Wu vi Contents Chapter 7 Contact Engineering of Two-Dimensional Transition Metal Dichalcogenides 137 Zhihui Cheng and Aaron D. Franklin About the Editor 167 Index 169 PREFACE Metal-Oxide-Semiconductor Field-Effect Transistor (MOSFET) has been the fundamental building block in integrated circuits (IC) over the past fifty years. Performance of the MOSFET is increased in each technology node according to the famous Moore’s Law. In the 1970s to 1990s, performance gain was mainly from the reduction of transistor gate length, thus charge carriers could travel a shorter distance for fast switching and high drive current. In the 1990s to 2000s, scaling the thickness of gate oxide SiO was the focus in performance step-up as 2 higher gate capacitance with thinner oxide brings more drive current at the same operating voltages. Around end of the 2000s, scaling the SiO 2 reached its limit, and high-K oxide replaced SiO to continue the Moore’s 2 Law. As the MOSFETs become smaller and smaller, device parasitics start to dominate the performance since 22nm node in the 2010s. The resistance part in the MOSFET RC delay is mainly from external components particularly the source/drain contact. This is quite unexpected by a lot of semiconductor community who was betting on high mobility channels and carbon-based devices for future logic technology because those exotic devices all try to address device internal components rather than the external. In the past decade, 3-D MOSFETs, also named FinFETs, became the leading technology device structure, and it brings a unique opportunity viii Zuoguang Liu for the contact resistance engineering. Among the device performance elements, contact resistance surpasses gate dielectrics, SiGe channel, and low-k materials in major semiconductor forums and journals in the past five years. MOSFET contact resistance is both an old and new topic. It is old because principles of the MOSFETs are well established since the early 1960s, and even earlier than the MOSFETs are the fundamentals of semiconductor-metal contacts which were established in the 1930s. In Chapter 1, we will go over basic device physics of modern MOSFETs with focus on the resistance components. Chapter 2 introduces Schottky-type and ohmic-type semiconductor-metal contacts. This is to provide background for the contact resistance topics in the following chapters. The new knowledge is on material and integration aspects for contact resistance reduction. Chapter 2 also discusses the contact metal, semiconductor substrate, and silicide materials for a low contact resistivity. Chapter 3 introduces the test structures and measurements of contact resistance, and explains how to calibrate the contact resistivity. Chapter 4 and Chapter 5 discuss the approaches for contact resistance reduction. State-of-the-art process techniques and material engineering are introduced. Integration of the contact resistance reduction into CMOS FinFET flow is presented in Chapter 6. Beside standard Si-based CMOS technology, 2-D devices based on transition metal dichalcogenides (TMDs) have attracted a lot of attention in recent years for energy storage, photonics, and sensors. However, the metal-2D contacts suffer from high resistance, which limits the 2-D devices in product application. As an expansion in this book, we introduce the 2-D TMDs and important aspects of their contact interface engineering in Chapter 7. The authors acknowledge IBM Research where the Si CMOS related content in this book is conducted. We thank Dr. O. Gluschenkov, for his guidance in the CMOS contact resistance work with his deep knowledge in thermal process, SPE, and LPE. I would like to acknowledge my doctoral advisor Professor T.P. Ma for his academic guidance; my colleagues in IBM for research and career support: Drs. H. Bu, T. Yamashita, D.C. Guo,