AGROPRODUCT PROCESSING TECHNOLOGY PRINCIPLES AND PRACTICE B. K. Bala Agro-Product Processing Technology Agro-Product Processing Technology Principles and Practice B. K. Bala Bangabandhu Sheikh Mujibur Rahman Science and Technology University Gopalganj, Bangladesh First edition published 2020 by CRC Press 6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742 and by CRC Press 2 Park Square, Milton Park, Abingdon, Oxon, OX14 4RN © 2020 Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, LLC Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. 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ISBN: 978-1-138-59668-9 (hbk) ISBN: 978-0-429-48750-7 (ebk) Typeset in Times by Lumina Datamatics Limited Contents Foreword ..........................................................................................................................................xv Preface............................................................................................................................................xvii Author .............................................................................................................................................xix Chapter 1 Introduction ..................................................................................................................1 1.1 Introduction .........................................................................................................1 1.2 Impotence of Postharvest Technology .................................................................2 1.3 Importance of Postharvest Losses .......................................................................2 1.4 Postharvest Technology .......................................................................................3 References ....................................................................................................................5 Chapter 2 Physical, Thermal, and Chemical Properties of Food and Biological Materials .........7 2.1 Introduction .........................................................................................................7 2.2 Physical Properties ..............................................................................................7 2.2.1 Physical Dimensions ................................................................................7 2.2.2 1000-Grain Weight ..................................................................................7 2.2.3 Bulk Density ............................................................................................8 2.2.4 Shrinkage .................................................................................................8 2.2.5 Friction ....................................................................................................9 2.2.5.1 Angle of Internal Friction and Angle of Repose ......................9 2.2.5.2 Coefficient of Friction .............................................................10 2.3 Thermal Properties ............................................................................................11 2.3.1 Specific Heat ..........................................................................................11 2.3.2 Thermal Conductivity ...........................................................................13 2.3.2.1 Theory .....................................................................................13 2.3.2.2 Apparatus and Measurement ..................................................14 2.3.3 Latent Heat of Vaporization ..................................................................15 2.3.3.1 Determination of Latent Heat of Vaporization .......................16 2.3.4 Heat Transfer Coefficient of Product Bed .............................................18 2.3.4.1 Dimensional Analysis .............................................................19 2.3.4.2 Comparison of Theory and Experiment .................................19 2.3.4.3 Theory .....................................................................................20 2.3.4.4 Determination of Volumetric Heat Transfer Coefficient ........22 2.4 Chemical Properties ..........................................................................................24 2.4.1 Starch .....................................................................................................24 2.4.2 Protein ...................................................................................................24 2.4.3 Fat ..........................................................................................................24 2.4.4 Vitamin ..................................................................................................24 Key to Symbols ..........................................................................................................24 Exercises .....................................................................................................................26 References ..................................................................................................................27 v vi Contents Chapter 3 Cleaning, Grading, and Sorting .................................................................................29 3.1 Grade Factor ....................................................................................................29 3.2 Washing ...........................................................................................................30 3.3 Sorting Fruits and Vegetables ..........................................................................30 3.4 Sorting Grain ...................................................................................................30 3.5 Spiral Separator ...............................................................................................32 3.6 Indent Cylinder Separator ...............................................................................33 3.7 Color Separator ................................................................................................33 3.8 Centrifugal Separation ....................................................................................34 3.8.1 Stokes’ Equation .................................................................................34 3.9 The Centrifuge.................................................................................................35 3.10 The Cream Separator .......................................................................................35 3.11 Cyclone Separator ............................................................................................36 3.12 Machine Vision................................................................................................39 3.12.1 Image Acquisition .............................................................................39 3.12.1.1 Computer Vision System ..................................................39 3.12.1.2 Ultrasound and Infrared ...................................................40 3.12.1.3 Tomographic Imaging ......................................................40 3.12.2 Preprocessing ....................................................................................40 3.12.3 Segmentation .....................................................................................41 3.12.4 Feature Extraction .............................................................................42 3.12.4.1 Color Features ..................................................................42 3.12.4.2 Morphological Features....................................................43 3.12.4.3 Texture Features ...............................................................43 3.12.5 Classification .....................................................................................44 Bibliography ...............................................................................................................45 Chapter 4 Psychrometry ..............................................................................................................47 4.1 Introduction .....................................................................................................47 4.2 Psychrometric Terms .......................................................................................47 4.2.1 Humidity Ratio ..................................................................................48 4.2.2 Relative Humidity .............................................................................48 4.2.3 Specific Volume ................................................................................49 4.2.4 Vapor Pressure ..................................................................................49 4.2.5 Dry-Bulb Temperature ......................................................................49 4.2.6 Dew Point Temperature.....................................................................49 4.2.7 Wet-Bulb Temperature ......................................................................49 4.2.8 Enthalpy ............................................................................................50 4.2.9 Adiabatic Wet-Bulb Temperature ......................................................51 4.2.10 Psychrometric Wet-Bulb Temperature ..............................................52 4.3 Construction of Psychrometric Chart ..............................................................54 4.4 Use of Psychrometric Chart ............................................................................54 4.4.1 Sensible Heating and Cooling ...........................................................55 4.4.2 Heating with Humidification .............................................................55 4.4.3 Cooling with Humidification ............................................................56 4.4.4 Cooling with Dehumidification.........................................................56 4.4.5 Drying ...............................................................................................57 4.4.6 Mixing of Airstreams .......................................................................59 Contents vii 4.4.7 Heat Addition with Air Mixing ..........................................................61 4.4.8 Drying with Recirculation ..................................................................62 Key to Symbols ..........................................................................................................66 Exercises .....................................................................................................................68 Bibliography ...............................................................................................................68 Chapter 5 Drying of Agro Products ............................................................................................69 5.1 Principles of Drying ..........................................................................................69 5.2 Importance of Drying ........................................................................................69 5.3 Moisture Content ...............................................................................................70 5.3.1 Moisture Content Representation ..........................................................70 5.3.2 Determination of Moisture Content ......................................................72 5.3.2.1 Direct Methods .......................................................................73 5.3.2.2 Indirect Methods .....................................................................75 5.4 Equilibrium Moisture Content ..........................................................................76 5.4.1 Determination of Static Equilibrium Moisture Content ........................77 5.4.2 Static Equilibrium Moisture Content Models .......................................77 5.5 Mechanism of Drying........................................................................................82 5.6 Thin-Layer Drying ............................................................................................84 5.6.1 Thin-Layer Drying Equations ...............................................................84 5.6.1.1 Empirical Drying Equations ...................................................84 5.6.1.2 Theoretical Drying Equations ................................................84 5.6.1.3 Semi-Theoretical Drying Equations .......................................85 5.6.2 Drying Rate ...........................................................................................87 5.6.3 Drying Parameters .................................................................................87 5.6.4 Drying Rate Constant and Diffusion Coefficient ..................................88 5.6.4.1 Drying Rate Constant .............................................................88 5.6.5 Half Response Time ..............................................................................91 5.7 Deep-Bed Drying ..............................................................................................92 5.7.1 Logarithmic Model ................................................................................92 5.7.2 Partial Differential Equation Model ......................................................98 5.7.2.1 Method of Solution ...............................................................102 5.7.2.2 Comparisons of Simulated and Observed Results ................103 5.8 Fluidized Bed Drying Model ..........................................................................103 5.8.1 Heat Balance Equation ........................................................................104 5.8.2 Drying Rate Equation ..........................................................................104 5.8.3 Mass Balance Equation .......................................................................105 5.9 Agro-Product Drying Systems ........................................................................106 5.9.1 Solar Drying Systems ..........................................................................106 5.9.1.1 Solar Dryers ..........................................................................106 5.9.2 Batch Drying Systems .........................................................................110 5.9.2.1 Flatbed Dryer ........................................................................111 5.9.3 Continuous Flow Drying Systems .......................................................113 5.9.3.1 Cross-Flow Dryer .................................................................113 5.9.3.2 Cross-Flow Batch Dryer .......................................................113 5.9.3.3 Concurrent Flow Dryer .........................................................114 5.9.3.4 Counterflow Dryer ................................................................114 5.9.3.5 Mixed-Flow Dryer ................................................................116 viii Contents 5.10 Safe Temperature for Drying Grain ..............................................................117 5.11 Selection of Dryers ........................................................................................117 Key to Symbols ........................................................................................................118 Exercises ...................................................................................................................119 Bibliography .............................................................................................................120 Chapter 6 Parboiling of Rice ....................................................................................................123 6.1 Introduction ...................................................................................................123 6.2 Principles of Parboiling .................................................................................124 6.3 Soaking ..........................................................................................................124 6.3.1 Kinetics of Soaking ...........................................................................126 6.3.2 Finite Element Modeling of Soaking of Water by Paddy ..................132 6.3.3 Half Response Time ..........................................................................137 6.3.4 Kinetics of Water Diffusion and Starch Gelatinization ....................137 6.4 Steaming ........................................................................................................140 6.5 Drying ............................................................................................................140 6.6 Effect of Parboiling on Milling, Nutritional, and Cooking Qualities of Rice ...........................................................................................................141 6.7 Parboiling Methods .......................................................................................142 6.7.1 Traditional Methods ..........................................................................142 6.7.1.1 Single Stage Parboiling ......................................................142 6.7.1.2 Double Stage Parboiling .....................................................142 6.7.2 Modern Methods ...............................................................................142 6.7.2.1 CFTRI (Central Food Technological Research Industries) Method .............................................................143 6.7.2.2 Jadavpur University Method ..............................................143 6.7.2.3 Malek Process ....................................................................143 6.7.2.4 Schule Process ....................................................................143 6.7.2.5 Crystal Rice Process ..........................................................144 6.7.2.6 Rice Conversion Process ....................................................144 6.7.2.7 Avorio Process ....................................................................144 6.7.3 Estimation of Heat Required for Parboiling ......................................144 6.7.3.1 Soaking Operation..............................................................144 6.7.3.2 Steaming Operation............................................................144 6.7.3.3 Drying Operation ...............................................................145 Exercises ...................................................................................................................159 Bibliography .............................................................................................................160 Chapter 7 Milling of Rice and Wheat .......................................................................................163 7.1 Introduction ...................................................................................................163 7.2 Rice Milling ..................................................................................................163 7.3 Traditional Methods ......................................................................................163 7.3.1 Home Pounding .................................................................................163 7.3.2 Huller Mills .......................................................................................164 7.3.3 Sheller Mills ......................................................................................164 7.3.4 Rubber Roll Sheller Mills ..................................................................164 7.4 The Modern Rice Milling Process ................................................................165 Contents ix 7.5 Modern Rice Milling Machinery ....................................................................167 7.5.1 Paddy Cleaner ......................................................................................167 7.5.2 Stoner ...................................................................................................167 7.5.3 Rubber Roll Sheller .............................................................................167 7.5.4 Paddy Separator ...................................................................................169 7.5.5 Whitening or Polishing........................................................................171 7.5.5.1 Cone-Type Polisher ...............................................................171 7.5.5.2 Horizontal Abrasive-Type Polisher .......................................172 7.5.5.3 Friction-Type Polisher ...........................................................172 7.5.6 Bran and Polished Rice Separator .......................................................173 7.5.7 Rice Grader .........................................................................................173 7.5.8 Rice Mixing .........................................................................................174 7.6 Wheat Milling .................................................................................................174 7.6.1 Conditioning/Hydrothermal Treatment ...............................................174 7.6.2 Milling .................................................................................................174 7.6.3 Storage of Finished Products ...............................................................175 7.7 Size Characteristics .........................................................................................175 7.7.1 Sieve .....................................................................................................175 7.7.2 Fineness Modulus ................................................................................176 7.7.3 Energy Requirements ..........................................................................177 Bibliography .............................................................................................................179 Chapter 8 By-Product Utilization .............................................................................................181 8.1 Introduction .....................................................................................................181 8.2 Fuels and Combustion .....................................................................................181 8.2.1 Furnaces ..............................................................................................182 8.3 Pyrolysis and Gasification ...............................................................................183 8.3.1 Pyrolysis (Destructive Distillation) and Gasification ..........................183 8.3.2 Types of Gasifiers ................................................................................184 8.3.2.1 Countercurrent Moving Bed Gasifiers ..................................185 8.3.2.2 Concurrent Moving Bed Gasifiers ........................................185 8.3.2.3 Crosscurrent Moving Bed Gasifiers .....................................185 8.3.2.4 Fluidized Bed Gasifiers ........................................................185 8.3.3 Gasification Process ............................................................................185 8.3.3.1 Oxidation ..............................................................................186 8.3.3.2 Reduction ..............................................................................186 8.3.3.3 Drying ...................................................................................186 8.3.4 Gasifier Units .......................................................................................186 8.4 Liquefaction .....................................................................................................187 8.5 Hydrolysis Followed by Fermentation .............................................................189 8.6 Biochar Production and Utilization .................................................................190 8.6.1 Biochar Carbonizer .............................................................................190 8.6.2 Types of Carbonizers ...........................................................................191 8.6.2.1 Application............................................................................192 8.7 Rice Husk Pelletizing and Briquetting ............................................................192 8.7.1 Need for Briquetting ............................................................................193 8.7.2 Principle and Technology ....................................................................193