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Materials Horizons: From Nature to Nanomaterials Bhuvanesh Gupta Anup K. Ghosh Atsushi Suzuki Editors Sunita Rattan Advances in Polymer Sciences and Technology Select Papers from APA 2017 Materials Horizons: From Nature to Nanomaterials Series editor Vijay Kumar Thakur, School of Aerospace, Transport and Manufacturing, Cranfield University, Bedford, UK Materialsareanindispensablepartofhumancivilizationsincetheinceptionoflife onearth.Withthepassageoftime,innumerablenewmaterialshavebeenexplored aswellasdevelopedandthesearchfornewinnovativematerialscontinuesbriskly. Keeping in mind the immense perspectives of various classes of materials, this series aimsatprovidingacomprehensivecollectionofworksacrossthebreadthof materials research at cutting-edge interface of materials science with physics, chemistry, biology and engineering. This series covers a galaxy of materials ranging from natural materials to nanomaterials. Some of the topics include but not limited to: biological materials, biomimeticmaterials,ceramics,composites,coatings,functionalmaterials,glasses, inorganic materials, inorganic-organic hybrids, metals, membranes, magnetic materials, manufacturing of materials, nanomaterials, organic materials and pigments to name a few. The series provides most timely and comprehensive informationonadvancedsynthesis,processing,characterization,manufacturingand applications ina broad range ofinterdisciplinary fields inscience, engineering and technology. This series accepts both authored and edited works, including textbooks, monographs,referenceworks,andprofessionalbooks.Thebooksinthisserieswill provide a deep insight into the state-of-art of Materials Horizons and serves students, academic, government and industrial scientists involved in all aspects of materials research. More information about this series at http://www.springer.com/series/16122 Bhuvanesh Gupta Anup K. Ghosh (cid:129) Atsushi Suzuki Sunita Rattan (cid:129) Editors Advances in Polymer Sciences and Technology Select Papers from APA 2017 123 Editors Bhuvanesh Gupta Atsushi Suzuki Department ofTextile Technology Yokohama National University Indian Institute of Technology Delhi Yokohama,Japan NewDelhi, Delhi, India Sunita Rattan Anup K.Ghosh Amity Institute of Applied Sciences Department ofMaterials Science Amity University andEngineering, Centrefor Polymer Noida, Uttar Pradesh, India ScienceandEngineering (CPSE) Indian Institute of Technology Delhi NewDelhi, Delhi, India ISSN 2524-5384 ISSN 2524-5392 (electronic) Materials Horizons:From Nature toNanomaterials ISBN978-981-13-2567-0 ISBN978-981-13-2568-7 (eBook) https://doi.org/10.1007/978-981-13-2568-7 LibraryofCongressControlNumber:2018954040 ©SpringerNatureSingaporePteLtd.2018 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpart of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission orinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfrom therelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authorsortheeditorsgiveawarranty,expressorimplied,withrespecttothematerialcontainedhereinor for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictionalclaimsinpublishedmapsandinstitutionalaffiliations. ThisSpringerimprintispublishedbytheregisteredcompanySpringerNatureSingaporePteLtd. Theregisteredcompanyaddressis:152BeachRoad,#21-01/04GatewayEast,Singapore189721, Singapore Preface Polymers offer enormous opportunities towards newer applications in technologi- cally important areas. There is a great necessity to have an integral approach towardsthiscomplementaryrelationshipofpolymersandtheirperformance.These polymeric materials have shown multidirectional growth in several areas of tech- nological innovations, which ranges from biomedical polymers to the fascinating field of smart materials. A precise understanding of the molecular architecture and itsroleingoverningphysicalcharacteristicsisextremelyusefultounderstandtheir applications. TheInternationalConferenceonAdvancesinPolymerScienceandTechnology was organized with the aim to provide a common forum for eminent scientists, technologists,entrepreneursandresearchscholarstopresenttheirworkanddiscuss the latest advances in this exciting area of research and add on new dimensions in different application areas. It is with great pleasure that we bring out this volume, which includes papers selected from the presentations made at the International Conference on Advances in Polymer Science and Technology held during 23–25 November 2017 at New Delhi,India.Thiseventwasattendedbyabout450participantsfromallcontinents. TheconferencewasorganizedundertheauspicesofAsianPolymerAssociation (APA),aprofessionalsocietydedicatedtothescienceofpolymers,incollaboration with Indian Institute of Technology (IIT) Delhi, Central Institute of Plastics Engineering & Technology (CIPET), Society for Biomaterials & Artificial Organs (Delhi, India) and Indo-Italian Forum on Biomaterials & Tissue. The conference was dedicated to the world of polymers with an extensive interaction among aca- demicians, researchers, technologists and policy planners. This special edition introduces new classes of polymeric materials with unique applications. The articles cover health, medicine and biotechnology, a rapidly developing domain based largely on known materials but moving to designed and engineered polymers, and information and communications, an emerging field for polymers significantly based on their electronic properties. These two areas are attracting a great deal of attention, particularly among researchers who are not v vi Preface traditional specialists in polymer science. The growing importance of these fields makes the interdisciplinary aspect of polymer research abundantly clear. Wearesurethatallthelatestresultsandfindingsreportedherewillbeusefulto the researchers and scientists working in these areas. It will also be found immensely useful by the advanced-level students of physics, chemistry, materials science, electronics specializing in polymers, as well as students of electronics, chemical and metallurgical engineering having courses in polymer technology/ materials science and technology. Weapplaudtheeffortsoftheconferenceparticipantsandencouragetheircurrent and future personal and collaborative efforts in this important field of scientific endeavour. The proceedings and the rich scientific knowledge exchanged between the participants are the result of the sincere efforts of a large team of people who volunteered their time to contribute to this international conference. We are indebtedtothemfortheirassistanceandsupportandextendourheartfeltthanks,on behalf of the APA 2017, for their significant contributions. With warm regards, New Delhi, India Prof. Bhuvanesh Gupta New Delhi, India Prof. Anup K. Ghosh Yokohama, Japan Prof. Atsushi Suzuki Noida, India Prof. Sunita Rattan Contents Designing and Nanofunctionalization of Infection-Resistant Polyester Suture. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Sadiya Anjum and Bhuvanesh Gupta Mandelic Acid Incorporated Antimicrobial Soy Protein Film Fabricated by Solution Casting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 Rakesh Kumar and Priya Rani Structural and Morphological Analysis of Newly Synthesized CuO@Alginate Nanocomposite with Enriched Electrical Properties. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 Vasi Uddin Siddiqui, Imran Khan, Afzal Ansari, Weqar Ahmad Siddiqui and Md. Khursheed Akram Synthesis of Lysine Mimicking Membrane Active Antimicrobial Polymers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 Ankita Arora, Wan Zheng, Hongjun Liang and Abhijit Mishra Antibacterial Activity of Antimicrobial Peptide (AMP) Grafted Polystyrene Surface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Sasmita Majhi, Ankita Arora and Abhijit Mishra Novel Polymeric Adsorbent for the Remediation of Cu(II) Ions from Water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 Nida Fakhar, Weqar Ahmad Siddiqui and Masood Alam Artificial Neural Network Modeling to Predict Bacterial Attachment on Composite Biopolymeric Scaffold. . . . . . . . . . . . . . . . . . 65 Shailendra Singh Shera, Shraddha Sahu and Rathindra Mohan Banik Triboelectric-Based Kinetic Energy Harvesting Using Polydimethylsiloxane (PDMS). . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 Amit Sharma and Poonam Agarwal vii viii Contents Thermal Conductivity Enhancement of Epoxy Composite Based onHybridBNandGraphiteParticulateConductiveFillersandEffect of Hybrid Sample Thickness (t) and Filler Fraction on Thermal Resistance (R) and Thermal Conductivity (k). . . . . . . . . . . . . . . . . . . . . 83 Rajesh Kumar, Sagar Kumar Nayak, Bishnu P. Panda, Smita Mohanty and Sanjay K. Nayak Stabilization Studies of Epoxidized Soybean Oil Plasticized PVC Films in the Presence of Beta-Diketone Additives. . . . . . . . . . . . . . . . . . 97 M. B. Kulkarni, S. Radhakrishnan, Nikesh Samarth and P. A. Mahanwar Multifunctional Compatibilizer for Polypropylene Blends with PMMA and EVA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 A. M. Khare and S. Radhakrishnan Development of Hybrid Composites and Joining Technology for Lightweight Structures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123 S. Deepak, K. P. Bhuvana, R. Joseph Bensingh, K. Prakalathan and S. K. Nayak Starch–Chitosan Blend Cross-Linked with Calcium Chloride . . . . . . . . 133 Jaya Maitra and Neena Singh Titania–Gelatin-Based Nanohybrids: A Versatile Material for Removal of Organic Dyes (Congo Red, Malachite Green, Crystal Violet and Methylene Blue) from Aqueous Solution . . . . . . . . . 147 Samjeet Singh Thakur and Ghanshyam S. Chauhan Development of CNT–Polymer Film-Based Electrode for the Detection of Glucose. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177 Neha Gopal, Prashant Shukla and Rachana Sahney FormulationandCharacterizationofPoly(D,L-Lactide-Co-glycolide) Nanoparticles Loaded with Achyranthes aspera for Increasing Bioavailability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 Aditi Sangal and Sunita Rattan Anticancer Drug-Loaded Folate-Conjugated Multiwalled Carbon Nanotubes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Bharti Mangla, Kuldeep Singh Patel, Pankaj Kumar and Kanchan Kohli Efficient Extraction of Antioxidants and Lubricants from Commercial Polypropylene Pellets and Their Quantification Using HPLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 211 Pramod K. Hegde and M. G. Manjunatha Contents ix Polymer Nanocomposites: Modification Through Swift Heavy Ions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221 Payal Mazumdar, Prachi Singhal and Sunita Rattan Homopolymer, Copolymers, and Terpolymer Synthesis Via Esterification-Cum-Addition of N-Substituted Phthalimide with Acrylates: Studies on Influences of Macromolecule Compositions on Thermal and Microbial Performances. . . . . . . . . . . . . 231 Suman Jinger and Jyoti Chaudhary