Advanced Thermoforming Wiley Series on Polymer Engineering and Technology Richard F. Grossman and Domasius Nwabunma, Series Editors Polyolefi n Blends Edited by Domasius Nwabunma and Thein Kyu Polyolefi n Composites Edited by Domasius Nwabunma and Thein Kyu Handbook of Vinyl Formulating, Second Edition Edited by Richard F. Grossman Total Quality Process Control for Injection Molding, Second Edition M. Joseph Gordon, Jr. Microcellular Injection Molding Jingyi Xu Poly(lactic acid): Synthesis, Structures, Properties, Processing, and Applications Edited by Rafael Auras, Loong - Tak Lim, Susan E.M. Selke, and Hideto Tsuji Hyperbranched Polymers: Synthesis, Properties, and Applications Edited by Deyue Yan, Chao Gao, and Holger Frey Advanced Thermoforming: Methods, Machines and Materials, Applications and Automation Sven Engelmann Advanced Thermoforming Methods, Machines and Materials, Applications and Automation Sven Engelmann Director of Polymer Technology Gerhard Schubert GmbH Crailsheim, Germany A John Wiley & Sons, Inc., Publication Copyright © 2012 by John Wiley & Sons, Inc. All rights reserved Published by John Wiley & Sons, Inc., Hoboken, New Jersey Published simultaneously in Canada No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/ permissions. Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifi cally disclaim any implied warranties of merchantability or fi tness for a particular purpose. No warranty may be created or extended by sales representatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profi t or any other commercial damages, including but not limited to special, incidental, consequential, or other damages. For general information on our other products and services or for technical support, please contact our Customer Care Department within the United States at (800) 762-2974, outside the United States at (317) 572-3993 or fax (317) 572-4002. Wiley also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic formats. For more information about Wiley products, visit our web site at www.wiley.com. Library of Congress Cataloging-in-Publication Data Engelmann, Sven. Advanced thermoforming : methods, machines and materials, applications and automation by / Sven Engelmann. p. cm. Includes index. ISBN 978-0-470-49920-7 (cloth) 1. Thermoforming. I. Title. TP1151.T48E64 2012 668.4'23–dc23 2011037218 Printed in the United States of America 10 9 8 7 6 5 4 3 2 1 For my lovely wife Ulrike and my wonderful children Leo, Peter, and Luzy. Contents Preface xi 1. Introduction 1 2. Basics of Thermoforming and Thermoplastics 5 3. Production of Semifi nished Products, Extrusion, and Coextrusion 12 4. Introduction to Technical Parts 28 5. Antenna Radome Manufacturing 29 6. Fuel Tank Production on Sheet Machines 33 7. Automotive Body and Commercial Vehicle Applications 41 8. Production of Refrigerator Liners 48 9. Paint Replacement in Automotive Applications 61 10. Motor Air Intake Made from PA 6 GF 15 70 11. Sanitary Equipment (Sheet Machine) 72 12. Thermoforming and Milling of Large-Scale Formed Parts (Sheet Machine) 76 13. Changeover of Sheet Machines 84 14. Chromed Parts 92 15. Applications in Aircraft and Mass Transportation 94 16. High-Quality and Fully Transparent Products (Sheet Machines) 103 17. Deco Molding and Multi-deco Molding 106 vii viii Contents 18. Automotive Body Parts Made of PA + ABS 119 19. Softfeel Made from ABS/TPU Material 121 20. Introduction to Packaging 124 21. Optimizing a Thermoforming Process for Packaging 125 22. Analysis of Thermoforming Films 137 23. Advanced Analysis of Thermoforming Films 144 24. Analysis of Thermoformed Products 151 25. Analysis of Completely Formed, Filled, and Sealed Containers 160 26. Automated Packaging 167 27. Production of Flowerpots 179 28. Steel Rule Die Punching 197 29. Production of Meat Trays 200 30. Multilayer Films for Thermoforming Applications 208 31. PET in Thermoforming Applications 211 32. Thermoformed Packaging Made of PLA 227 33. Peel and Reseal 232 34. Foam Packaging with PP and PS 250 35. Blister Packaging of Syringes 257 36. The Production of Drinking Cups 264 37. Ultrasonic Sealing and Cutting in Thermoforming 287 38. Understanding the Brittle Behavior of Polystyrene Cups 293 39. Preprinted Film for Lid Thermoforming 308 Contents ix 40. Flexible Films 311 41. Simulation 316 42. Recycling 324 Glossary 328 Index 329 Preface T his book focuses on practical applications. It deals with technical parts, but also with packaging (the topics range from bathtubs to syringe blisters). Beside the applications, the respective machine and tooling technologies, automation, and, of course, semifi nished products and materials are described. Also a large part of the book is dedicated describing innovations in materials, so that the book can serve as a useful reference work on raw materials and semifi nished products. Also discussed are multilayer structures, which are fi nding increasing use for fuel tanks as well as cheese packaging. Reliable applications of machine, tooling, and materials are dem- onstrated. The basic principles of extrusion, which are important for thermoforming are named for clarity ’ s sake without going into depth. The basic principles of thermoforming and thermoplastics are covered briefl y, as there are already several standard works dealing with these subjects. The present book is intended to complement, not replace the existing literature on thermoform- ing, and to open up new perspectives on the applications considered within. The author is grateful to all those writers who have advanced, described, and explained thermoforming and made it popular. The aim of the book is to communicate points worth knowing about thermo- forming and to arouse interest. The author hopes this book will show the reader the diversity and sophistication of the thermoforming industry and ways of implement- ing cost - effective production. S ven E ngelmann xi 1 Chapter Introduction R eference books can be diffi cult to read and understand. Often technical connec- tions and contexts are described by using a lot of mathematics — and often right from the beginning — so that a large part of the target group is overcharged or quickly loses interest. However, reading books on technology and engineering can be fun. Books dealing with technology should impart knowledge at an adequate pace. We live in a world that is dependent on a multitude of technologies. Yet it can be observed that fewer and fewer young people are interested in technical professions. What are the reasons for this development? It is true that the rush of today ’ s technol- ogy can initially have a discouraging effect. A lot of technology has become so complex and abstract that it is no longer possible to understand the connections through mere refl ection or observation. As the modifi cations to technologies and processes come even faster, is it possible to keep up with these developments? The answer is yes! There will always be technological development because economic issues and ecology are driving forces. Technological advancements, however, depend on the degree to which enthusiasm for technology can be aroused in persons with a certain talent and a disposition toward engineering. To some extent this book is based on a series of lectures called the “ Basics of Thermoforming. ” Among these lectures the discussions range over many topics, even to the “ mere ” production of a yogurt cup. There are many people who are not directly involved in the development of technologies but who exert nonetheless an infl uence on technological developments. These decision makers, however, do depend on basic knowledge of the technological linkages and contexts. This book is intended as a reference book for the relatively small industrial sector of thermoforming applications. This book focuses on thermoformed products and applications. All of us once had the experience of asking ourselves, when con- templating a formed part, how was this part produced? This book is subdivided into the description of technical formed parts and of packaging. Some parts may not even look like thermoformed parts to the casual observer. This book will discuss the enormous possibilities of thermoforming at a level that Advanced Thermoforming: Methods, Machines and Materials, Applications and Automation, First Edition. Sven Engelmann. © 2012 John Wiley & Sons, Inc. Published 2012 by John Wiley & Sons, Inc. 1