ADVANCED POLYMERIC MATERIALS From Macro- to Nano-Length Scales © 2011 by Woodhead Publishing India Pvt. Ltd. © 2011 by Woodhead Publishing India Pvt. Ltd. ADVANCED POLYMERIC MATERIALS From Macro- to Nano-Length Scales Edited by Sabu Thomas, PhD Nandakumar Kalarikkal, PhD Maciej Jaroszewski, PhD Josmin P. Jose © 2011 by Woodhead Publishing India Pvt. Ltd. CRC Press Woodhead Publishing India Pvt. Ltd. Taylor & Francis Group 303, Vardaan House, 7/28, Ansari Road 6000 Broken Sound Parkway NW, Suite 300 Daryaganj, New Delhi – 110002, India Boca Raton, FL 33487-2742 © 2011 by Woodhead Publishing India Pvt. Ltd. Exclusive worldwide distribution by CRC Press an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20150818 International Standard Book Number-13: 978-93-80308-79-1 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. 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CONTENTS List of Contributors ....................................................................................vii List of Abbreviations ...................................................................................xi Preface ........................................................................................................xv About the Editors......................................................................................xvii 1. Polymer Hydrogel Dressing in Wound Management .............................1 Ajith James Jose, Vinu Varghese, and Sam John 2. AC Impedance and FTIR Studies on Proton Conducting Polymer Electrolyte Membrane Based on PVP and Methanesulfonic Acid...............................................................................17 C. Ambika, G. Hirankumar, S. Karthickprabhu, and R. S. Daries Bella 3. Dendritic Organic Semiconductors Based on Pyrene and Triazine Derivatives ..........................................................................31 Renji R. Reghu and Juozas V. Grazulevicius 4. Rheological Characteristics of Linear Low Density Polyethylene – Fumed Silica Nanocomposites .......................................61 V. Girish Chandran and Sachin Waigaonkar 5. Rational Design of Molecularly Imprinted Polymers: A Density Functional Theory Approach ..................................................................77 Shashwati Wankar, Aakanksha Jha, and Reddithota J. Krupadam 6. Preparation of Polymer and Ferrite Nanocomposites for EMI Applications .....................................................................................99 P. Raju and S. R. Murthy 7. Macro Level Investigation on Thickness Variation of Rot Moulded LLDPE Product ..............................................................121 P. L. Ramkumar, Dhananjay M. Kulkarni, and Sachin D. Waigaonkar © 2011 by Woodhead Publishing India Pvt. Ltd. vi Contents 8. Molecular Structure and Property Relationship of Commercial Biaxially Oriented Polypropylene (BOPP) by DSC, GPC and NMR Spectroscopy Techniques ............................................................135 Ravindra Kumar, Veena Bansal, S. Mondal, Nitu Singh, A. Yadav, G. S. Kapur, M. B. Patel, and Shashikant 9. Lead and Cadmium Ion Removal by Novel Interpenetrating Polymer-Ceramic Nanocomposite ........................................................143 K. Sangeetha and E. K. Girija 10. Microwave Assisted Synthesis of Polyacrylamide Grafted Casein (CAS-g-PAM) as an Effective Flocculent for Wastewater Treatment ...........................................................................153 Sweta Sinha, Gautam Sen, and Sumit Mishra 11. Polymer Assisted Synthesis of CdS Nanostructure for Photoelectrochemical Solar Cell Applications .....................................173 S. A. Vanalakar, J. H. Kim, and P. S. Patil 12. Synthesis and Characterization Chitosan-Starch Crosslinked Beads........................................................................................................205 Virpal Singh 13. Dendrimer Polymer Brushes .................................................................219 Wei Cui, Holger Merlitz, and Chen-Xu Wu 14. Photo-Bactericidal Polyacrylonitrile Matrix for Protective Apparels ................................................................................227 G. Premika, K. Balasubramanian, and Kisan M. Kodam Index .........................................................................................................237 © 2011 by Woodhead Publishing India Pvt. Ltd. LIST OF CONTRIBUTORS C. Ambika C-SAR, School of Basic Engineering and Sciences, PSN College of Engineering and Technology, Melathediyoor, Tirunelveli, Tamilnadu, India; E-mail: [email protected] K. Balasubramanian Department of Materials Engineering, Defence Institute of Advanced Technology, Ministry of Defence, Girinagar, Pune 411025, India; Email: [email protected], [email protected] Veena Bansal Indian Oil Corporation Limited, Research and Development Centre, Sector-13, Faridabad–121007, India R. S. Daries Bella C-SAR, School of Basic Engineering and Sciences, PSN College of Engineering and Technology, Melathediyoor, Tirunelveli, Tamilnadu, India; E-mail: [email protected] V. Girish Chandran Department of Mechanical Engineering, BITS Pilani K K Birla Goa Campus, Zuarinagar Goa, India–403726; Email: [email protected]; [email protected] Wei Cui Department of Physics and ITPA, Xiamen University, 361005 Xiamen, China; E-mail: [email protected] E. K. Girija Department of Physics, Periyar University, Salem–636 011, India; Tel.: +91 9444391733; Fax: +91 427 2345124; E-mail: [email protected] Juozas V. Grazulevicius Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilenu pl. 19, LT-50254 Kaunas, Lithuania, Tel: +37037 300193; Fax: +37037 300152; E-mail: juozas. [email protected] G. Hirankumar C-SAR, School of Basic Engineering and Sciences, PSN College of Engineering and Technology, Melathediyoor, Tirunelveli, Tamilnadu, India; E-mail: [email protected] Maciej Jaroszewski High Voltage Laboratory, Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland; E-mail: [email protected] Aakanksha Jha National Environmental Engineering Research Institute, Jawaharlal Nehru Marg, Nagpur 440020, India; Tel.: +91-712-2249884; Fax: +91-712-2249896; E-Mail: [email protected] Sam John Research and Postgraduate Department of Chemistry, St. Berchmans College, Changanacherry, Kerala 686 101, India © 2011 by Woodhead Publishing India Pvt. Ltd. viii List of Contributors Josmin P. Jose School of Chemical Sciences, Mahatma Gandhi University, Kottayam, Kerala, India–686560; E-mail: [email protected] Ajith James Jose Research and Postgraduate Department of Chemistry, St. Berchmans College, Changanacherry, Kerala 686 101, India Nandakumar Kalarikkal International and Inter University Centre for Nanoscience and Nanotechnology, and School of Pure and Applied Physics, Mahatma Gandhi University, Kottayam, Kerala, India–686560; E-mail: [email protected] G. S. Kapur Indian Oil Corporation Limited, Research and Development Centre, Sector-13, Faridabad-121007, India S. Karthickprabhu Department of Physics, Kalasalingam University, Krishnankoil, Virudhunagar, Tamilnadu, India J. H. Kim Department of Materials Science and Engineering, Chonnam National University, Gwangju – 500 757, South Korea Kisan M. Kodam Department of Chemistry, University of Pune, Pune 411030, India Reddithota J. Krupadam National Environmental Engineering Research Institute, Jawaharlal Nehru Marg, Nagpur 440020, India; Tel.: +91-712-2249884; Fax: +91-712-2249896; E-Mail: [email protected] Dhananjay M. Kulkarni BITS PILANI, K. K. Birla Goa campus, Goa–403726, India Ravindra Kumar Indian Oil Corporation Limited, Research and Development Centre, Sector-13, Faridabad-121007, India; E-mail: [email protected] Holger Merlitz Leibniz-Institute of Polymer Research, 01069 Dresden, Germany Sumit Mishra Department of Applied Chemistry, Birla Institute of Technology, Mesra, Ranchi – 835215, Jharkhand, India S. Mondal Indian Oil Corporation Limited, Research and Development Centre, Sector-13, Faridabad-121007, India S. R. Murthy Department of Physics, Osmania University, Hyderabad–500 007, India M. B. Patel Indian Oil Corporation Limited, Research and Development Centre, Sector-13, Faridabad-121007, India © 2011 by Woodhead Publishing India Pvt. Ltd. List of Contributors ix P. S. Patil Thin Film Materials Laboratory, Department of Physics, Shivaji University, Kolhapur-416204, M.S., India G. Premika Department of Materials Engineering, Defence Institute of Advanced Technology, Ministry of Defence, Girinagar, Pune 411025, India P. Raju Department of Physics, Osmania University, Hyderabad–500 007, India P. L. Ramkumar BITS PILANI, K. K. Birla Goa campus, Goa–403726, India; Mobile: +919823256780; Email: [email protected], [email protected] Renji R. Reghu Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilenu pl. 19, LT-50254 Kaunas, Lithuania, Tel: +37037 300193; Fax: +37037 300152; E-mail: [email protected] K. Sangeetha Department of Physics, Periyar University, Salem–636 011, India Gautam Sen Department of Applied Chemistry, Birla Institute of Technology, Mesra, Ranchi – 835215, Jharkhand, India Shashikant Indian Oil Corporation Limited, Research and Development Centre, Sector-13, Faridabad-121007, India Nitu Singh Indian Oil Corporation Limited, Research and Development Centre, Sector-13, Faridabad-121007, India Virpal Singh Department of Chemical Technology, Sant Longowal Institute of Engineering and Technology, Longowal, Sangrur, Punjab–148106, India, E-mail: [email protected] Sweta Sinha Department of Applied Chemistry, Birla Institute of Technology, Mesra, Ranchi – 835215, Jharkhand, India; Tel.: +91 9801334228; E-mail: [email protected] Sabu Thomas International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Priyadarshini Hills P. O., Kottayam, Kerala–686560, India; E-mail: sabuchathukulam@ yahoo.co.uk, [email protected] S. A. Vanalakar Department of Materials Science and Engineering, Chonnam National University, Gwangju–500 757, South Korea Vinu Varghese Quality Control Department, Sance Laboratories Private Limited, Pala, Kottayam, Kerala 686573, India © 2011 by Woodhead Publishing India Pvt. Ltd. x List of Contributors Sachin D. Waigaonkar Department of Mechanical Engineering, BITS Pilani K K Birla Goa Campus, Zuarinagar, Goa, India–403726; Email: [email protected]; [email protected] Shashwati Wankar National Environmental Engineering Research Institute, Jawaharlal Nehru Marg, Nagpur 440020, India; Tel.: +91-712-2249884; Fax: +91-712-2249896; E-Mail: [email protected] Chen-Xu Wu Department of Physics and ITPA, Xiamen University, 361005 Xiamen, China A. Yadav Indian Oil Corporation Limited, Research and Development Centre, Sector-13, Faridabad-121007, India © 2011 by Woodhead Publishing India Pvt. Ltd.