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ADVANCED POLYMERIC MATERIALS FOR SUSTAINABILITY AND INNOVATIONS ADVANCED POLYMERIC MATERIALS FOR SUSTAINABILITY AND INNOVATIONS Edited by Sajith Thottathil Sabu Thomas Nandakumar Kalarikkal Didier Rouxel Apple Academic Press Inc. Apple Academic Press Inc. 3333 Mistwell Crescent 9 Spinnaker Way Oakville, ON L6L 0A2 Waretown, NJ 08758 Canada USA © 2019 by Apple Academic Press, Inc. Exclusive worldwide distribution by CRC Press, a member of Taylor & Francis Group No claim to original U.S. Government works International Standard Book Number-13: 978-1-77188-633-8 (Hardcover) International Standard Book Number-13: 978-1-315-10243-6 (eBook) All rights reserved. No part of this work may be reprinted or reproduced or utilized in any form or by any electric, mechanical or other means, now known or hereafter invented, including photocopying and re- cording, or in any information storage or retrieval system, without permission in writing from the publish- er or its distributor, except in the case of brief excerpts or quotations for use in reviews or critical articles. This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with permission and sources are indicated. Copyright for individual articles remains with the authors as indicated. A wide variety of references are listed. Reasonable efforts have been made to publish reliable data and information, but the authors, editors, and the publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors, editors, and the publisher have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged, please write and let us know so we may rectify in any future reprint. Trademark Notice: Registered trademark of products or corporate names are used only for explanation and identification without intent to infringe. Library and Archives Canada Cataloguing in Publication Advanced polymeric materials for sustainability and innovations / edited by Sajith Thottathil, Sabu Thomas, Nandakumar Kalarikkal, Didier Rouxel. Includes bibliographical references and index. Issued in print and electronic formats. ISBN 978-1-77188-633-8 (hardcover).--ISBN 978-1-315-10243-6 (PDF) 1. Polymers. I. Thomas, Sabu, editor II. Kalarikkal, Nandakumar, editor III. Rouxel, Didier, editor IV. Thottathil, Sajith, editor TA455.P58A42 2018 620.1’92 C2018-904504-3 C2018-904505-1 CIP data on file with US Library of C ongress Apple Academic Press also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic format. For information about Apple Academic Press products, visit our website at www.appleacademicpress.com and the CRC Press website at www.crcpress.com CONTENTS About the Editors .............................................................................. vii List of Contributors ............................................................................ xi Preface .............................................................................................. xv 1. Still Looking for the Magic Spot: Dispersing Modified Magnetic Nanoparticles into Nanostructured Block Copolymers ............................................. 1 I. Barandiaran and G. Kortaberria 2. Applications of Ionic Liquids in Polymeric Composites ...........29 Anjali Bishnoi, Sunil Kumar, Sandeep Rai, and Ankit Mishra 3. Role of Equine Ordure in Enhancing Physical and Mechanical Properties of Natural Bio-Active Composites ..................................................................49 Raj Kumar Satankar, Amrita Kaurwar, Sandeep Gupta, K. Usha, Salifu T. Azeko, Winston O. Soboyejo, Alfred B. O. Soboyejo, and Anand Plappally 4. Preparation and Characterization of Polybenzoxazine/Plasticized PVC-Based Fumed Silica Composites .............................................................75 Hussein Ali, S. Radhakrishnan, and M. B. Kulkarni 5. Investigation on the Thermal Characteristics of Dry Bonding System for Tire Applications .................................95 D. Jeyabala, J. Dhanalakshmi, and C. T. Vijayakumar 6. Novel Bioactive Strontium Containing Composites for Medical Applications ........................................123 Vibha C. and P. P. Lizymol vi Contents 7. Hybrid Natural Fibers Reinforced Polymer Composite: Thermal Analysis ....................................................143 M.K. Gupta and R. K. Srivastava 8. Mechanical and Thermal Analysis of Unidirectional Jute-Fiber-Reinforced Polymer Composite ..............................157 M.K. Gupta and R. K. Srivastava 9. A Comparative Study of Metachromasy Induced in Acridine Orange by Anionic Polyelectrolytes ...........................177 Nandini R. and Vishalakshi B. 10. Reclamation of Natural Rubber Waste .....................................191 S. A. Yawalkar, P. S. Joshi, P. V. Patil, J. M. Gadgil, and H. V. Joshi 11. Preparation and Characterization of Polymer Matrix Composites with Reinforced Fly Ash and Silicon Carbide .....227 K.Aruna, B. Sudheer Reddy, B. R. P. Nayak, and B. Haritha Bai 12. Ion-Conducting Polymers ..........................................................243 C.S. Sunandana 13. Effect of Modified Calcium Carbonate Filler on Properties of Poly(Propylene)/Layered Double Hydroxide Composites ................................................................263 Mahendra R. Nevare and Vikas V. Gite 14. Different Fabrication Techniques of Aerogels and Its Applications .................................................................................283 Fathima Parveen and Raghvendra Kumar Mishra 15. Role of Nanodispersoids on Corrosion Inhibition Behavior of Smart Polymer Nanocomposite Coatings ............303 Sarah B. Ulaeto, Jerin K. Pancrecious, Ramya Rajan, T. P. D. Rajan, and B. C. Pai 16. Thermal and Dynamic Mechanical Analysis of Jute Polypropylene Composites .........................................................349 Harichandra U. Chandekar, Vikas V. Chaudhari, Sachin D. Waigaonkar, and Narendra N. Ghosh Index ................................................................................................. 359 ABOUT THE EDITORS Sajith Thottathil, MTech, is an assistant professor at the International and Interuniversity Center for Nanoscience& Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala, India. He was previously a research scholar at the same university. He completed his BTechde- greein mechanical engineering from Kerala University, Kerala, India, and went on to earn his MTech innanotechnology from the National Institute of Technology, Calicut, Kerala, India. His MTech project was “Effect of Graphene Oxides on Mechanical and Tribological properties of Epoxy nanocomposites.” His research areas include nanotechnology, mechanical engineering, and polymer nano- composites. He won an award for his poster presentation at the Interna- tional Conference on Polymer Processing and Characterization, 2016, ICPPC 16. E-mail: [email protected] Sabu Thomas, PhD, is the Pro-Vice Chancellor of Mahatma Gandhi University and Founding Director of the International and Inter University Center for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala, India. He is also a full professor of polymer science and engineering at the School of Chem- ical Sciences of the same university. He is a fellow of many professional bodies. Professor Thomas has (co-) authored many papers in inter- national peer-reviewed journals in the area of polymer science and nano- technology. He has organized several international conferences. Professor Thomas’s research group has specialized in many areas of polymers, which includes polymer blends, fiber-filled polymer composites, viii About the Editors particulate-filled polymer composites and their morphological character- ization, ageing and degradation, pervaporation phenomena, sorption and diffusion, interpenetrating polymer systems, recyclability and reuse of waste plastics and rubbers, elastomeric crosslinking, dual porous nano- composite scaffolds for tissue engineering, etc. Professor Thomas’s research group has extensive exchange programs with different industries and research and academic institutions all over the world and is performing world-class collaborative research in various fields. Professor Thomas’s Center is equipped with various sophisticated instruments and has estab- lished state-of-the-art experimental facilities, which cater to the needs of researchers within the country and abroad. Professor Thomas has published over 750 peer-reviewed research papers, reviews, and book chapters and has a citation count of 31,574. The H index of Prof. Thomas is 81, and he has six patents to his credit. He has delivered over 300 plenary, inaugural, and invited lectures at national/international meetings over 30 countries. He is a reviewer for many international jour- nals. He has received MRSI, CRSI, nanotech medals for his outstanding work in nanotechnology. Recently Prof. Thomas has been conferred an Honoris Causa (DSc) by the University of South Brittany, France, and University Lorraine, Nancy, France. E-mail: [email protected], [email protected] Dr. Nandakumar Kalarikkal is the Joint Director at the International and Inter University Centre for Nanoscience and Nanotechnology and Asso- ciate Professor at the School of Pure and Applied Physics, Mahatma Gandhi University, Kottayam, Kerala, India. His research activities involve applications of nanostructured materials, laser plasma, phase transitions, etc. He is the recipient of research fellowships and associateships from prestigious government organizations such as the Department of Science and Technology and the Council of Scientific and Industrial Research of the Government of India. He has active collabora- tion with national and international scientific institutions in India, South Africa, Slovenia, Canada, France, Germany, Malaysia, Australia, and US. About the Editors ix He has more than 130 publications in peer-reviewed journals. He has also co-edited nine books of scientific interest and co-authored many book chapters.He has supervised 8 PhD theses, and currently 12 PhD students are working under him. E-mail: [email protected], [email protected] Didier Rouxel was born in Lyon, France, on March 5, 1965. He received an Engineer degree (5-year degree) in materials in 1989 from the Ecole Supérieure des Sciences et Techniques de l’Ingénieur de Nancy, Vandoeuvre, France. He received his Ph.D. in material sciences and engi- neering from the University of Nancy I, France in 1993. He is now fulltime professor in the Univer- sité de Lorraine and he leads the team “Micro and Nano Systems” in Institut Jean Lamour in Nancy, France. His research has been mainly focused on physical chemistry of surfaces and thin films, piezoelectric materials, elastic properties of mate- rials studied by Brillouin spectroscopy, and development of micro-devices based on polymer–nanoparticles nanocomposite materials, in particular for biomedical applications. He was expert for the French agency ANSES for the topic “Nanomaterials and Health” and Member of the Year of the French Society of Nanomedicine in 2014.

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