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Acidic Mining Lakes: Acid Mine Drainage, Limnology and Reclamation PDF

431 Pages·1998·25.184 MB·English
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Environmental Science Series editors: R. Allan . U. Forstner . W. Salomons Springer Berlin Heidelberg New York Barcelona Budapest Hong Kong London Milan Paris Santa Clara Singapore Tokyo Walter Geller . Helmut Klapper . Wim Salomons (Eds.) Acidic Mining Lakes Acid Mine Drainage, Limnology and Reclamation With 155 Figures and 55 Tables , Springer Prof. Dr. Walter Geller Prof. Dr. Helmut Klapper UFZ Centre for Environmental Research Leipzig-Halle pIc Dept. Inland Water Research Am Biederitzer Busch 12 D-39114 Magdeburg Germany Prof. Dr. Wim Salomons GKSS Research Centre Max-Planck -Strasse D-21502 Geesthacht Germany ISSN 1431-6250 ISBN-13:978-3-642-71956-1 Library of Congress Cataloging-in-Publication Data Acidic mining lakes: acid mine drainage, limnology, and reclamation / Walter Geller, Helmut Klapper, Wim Salomons, eds. p. cm. - (Environmental science) Includes bibliographical references and index. ISBN-13:978-3-642-71956-1 e-IsBN-13:978-3-642-71954-7 001: 10.1007/978-3-642-71954-7 1. Limnology - Congresses. 2. Acid pollution of rivers, lakes, etc. - Con- gresses. 3. Acid mine drainage - Environmental aspects - Congresses. I. Geller, Walter. II. Klapper, Helmut. III. Salomons, W. (Willem), 1945-Series Entry: GB1605.A28 1998 628.1/683221 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable for prosecution under the German Copyright Law. © Springer-Verlag Berlin Heidelberg 1998 Softcover reprint of the hardcover 1st edition 1998 The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesetting: Fotosatz-Service Kohler OHG, Wiirzburg Coverdesign: Struve & Partner, Heidelberg SPIN: 10509909 32/3020-5 43 2 1 0 - Printed on acid-free paper Preface Lignite was the most important source of primary energy in the former German Democratic Republic (GDR), reaching a share of 90% in 1988 with an output of 310 million tons of coal. This worldwide maximum of per-capita consumption of brown coal containing high amounts of sulfur, and out- dated technical equipment of power plants effected two kinds of acidification. The first is acid rain and long-distance acidification of soils and waters in sensitive areas via atmospheric transport. The second is more direct, affecting the near environment of the lignite open-cast mining sites due to geogenic acidification of the aerated overburden and groundwater from pyrite oxidation. Thus, the acid input into ground and surface waters has severe effects, resulting in mining lakes with pH values between 2 and 3. Initially, the lignite mining was planned over long time scales. After shift ing from lignite to other sources of primary energy after 1990, these plans became obsolete. The antedate for closing down the mines and filling the empty basins resulted in consecutive problems, which are now concentrat ed into one decade, while at least half a century was initially scheduled. Facing the now-apparent problems of ground and surface waters threatened by sulfuric acid, limnologists of concerned institutions, such as the UFZ Centre for Environmental Research, organized the collection of scientific data and knowledge and practical experiences of how to handle these acidification problems. One part of these activities was an International Symposium on the ''Abatement of Geogenic Acidification in Mining Lakes" held in September 1995 at the UFZ Department of Inland Waters Research in Magdeburg, Germany, where 26 invited presentations were discussed by 60 participants from the UK, Canada, the USA and Germany. The results of the meeting are presented in this volume which, hopefully, may be seen as an actual baseline for acid mining lakes. Since the symposium had a function to connect ideas and, thereby, to initiate new approaches, we are looking forward to a second symposium to bring together the large body of new results emerging from currently running work. Walter Geller April 1998, Magdeburg, Germany Contents Part 1 Introduction 1 Natural and Anthropogenic Sulfuric Acidification of Lakes W. Geller, H. Klapper and M. Schultze. . . . . . . . . . . . 3 2 Regional Geology of the Lignite Mining Districts in Eastern Germany p. Schreck and W. Glasser . . . . . . . . . . . . . 15 Part 2 Limnological Case Studies on Acid Lakes 3 Chemical Characteristics of Water and Sediment in Acid Mining Lakes of the Lusatian Lignite District K. Friese, M. Hupfer and M. Schultze . . . . . . . . . 25 4 In-Lake Neutralization of Acid Mine Lakes A. Peine and S. Peiffer . . . . . . . . . . . . 47 5 Acid Generation and Metal Immobilization in the Vicinity of a Naturally Acidic Lake in Central Yukon Territory, Canada Y. T.J. Kwong and J.R. Lawrence. . . . . . . . . . . . 65 6 Geochemical Behaviour of Submerged Pyrite-Rich Tailings in Canadian Lakes T.P. Pedersen, J.J. McNee, D.H. Flather, B. Mueller and C.A. Pelletier . . . . . . . . . . . . . . . . . . . . . . 87 7 Phytoplankton Composition and Biomass Spectra Created by Flow Cytometry and Zooplankton Composition in Mining Lakes of Different States of Acidification C. E. W. Steinberg, H. Schafer, J. Tittel, and W. Beisker. . . . . . . 127 VIII Contents 8 Ecological Potentials for Planktonic Development and Food Web Interactions in Extremely Acidic Mining Lakes in Lusatia B. Nixdorf, K. Wollmann and R. Deneke ......... .. 147 9 Colonization and Development of Vegetational in Mining Lakes of the Lusatian Lignite Area in Dependence on Water Genesis W. Pietsch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169 Part 3 Inorganic Processes of Acidification 10 Pyrite Chemistry: The Key for Abatement of Acid Mine Drainage V. p. (Bill) Evangelou . . . . . . . . . . . . ...... 197 11 Chemical Reactions in Aquifers Influenced by Sulfide Oxidation and in Sulfide Oxidation Zones F. Wisotzky. . . . . . . . . . . . . . . . . . . . .. ... . . 223 12 Oxygen as a Limiting Factor for Pyrite Weathering in the Overburden of Open Pit Lignite Areas A. Prein and R. Mull. . . . . . . . . . . . . .. .. . . . . . 237 13 Effects of Superficial Tertiary Dump Substrates and Recultivation Variants on Acid Output, Salt Leaching and Development of Seepage Water Quality J. Katzur and F. Liebner . . . . . . . . . . . . . . . . . . . . . . 251 Part 4 Remediation Concepts and Case Studies 14 Microbial Processes for Potential in Situ Remediation of Acidic Lakes K. Wendt-Potthoff and T.R. Neu . ................. 269 15 Biological Abatement of Acid Mine Drainage: The Role of Acidophilic Protozoa and Other Indigenous Microflora D. B. Johnson . . . . . . . . . . . . . . . . . . . . . . . . . . . . 285 16 Treatment of Mine Drainage by Anoxic Limestone Drains and Constructed Wetlands R. L. P. Kleinmann, R. S. Hedin and R. W. Nairn . . . . . . . . . . 303 Contents IX 17 Biological Polishing of Zinc in a Mine Waste Management Area M. Kalin . . . . . . . . . . . . . . . . . . . . . . . . . . 321 18 Development of a Long-Term Strategy for the Treatment of Acid Mine Drainage at Wheal Jane H. M. Lamb, M. Dodds-Smith and J. Gusek. . . . . . . . . . . . . 335 19 Bioremediation of Metals in Acid Tailings by Mixed Microbial Mats P. Phillips and J. Bender . . . . . . . . . . .... 347 20 Managing the pH of an Acid Lake by Adding Phosphate Fertiliser D.G. George and W. Davison ............. . ... 365 21 Model Calculations for Active Treatment of Acidic, Iron-Containing Lake Water Assuming Mining Lakes as Chemical Reactors R. Fischer, T. Guderitz and H. Reiflig . . . . . . . . . . . 385 22 Ways of Controlling Acid by Ecotechnology H. Klapper, K. Friese, B. Scharf, M. Schimmele and M. Schultze . . . . . . . . . . . . . . . . . . . . . . . . . . 401 Part 5 Summary of Group Discussions and Conclusions 23 Pyrite Oxidation Control V. P. Evangelou, Rapporteur . . . . . . . . 419 24 Limnological Fundaments of Acid Mining Lakes M. Kalin and W. Geller, Rapporteurs. . . . . . .. ....... 423 25 Approaches for the Restoration of Strongly Acidic Mining Lakes R. L. P. Kleinmann, Rapporteur . . . . . . . . . . . 427 Subject Index ............................. 431 List of Contributors Beisker, W. GSF-Forschungszentrum, AG DurchfluBzytometrie, Postfach 1129, D-85758, OberschleiBheim, Germany Bender, J. Clark Atlanta Univ., Georgia 30314, Atlanta, USA Davison, W. Lancaster Univ., Institute Environmental & BioI. Sciences, Lancaster, UK Deneke, R. Brandenburgische Technische Universitat Cottbus, LS Gewasserschutz, Seestr. 45, D-15526 Bad Saarow, Germany Dodds-Smith, M. Knight Piesold, 35/41 Station Road, Kent TN23 IPP, Ashford, UK Evangelou, v.P. (Bill) Univ. of Kentucky, Agronomy Dept., KY 40546-0091, Lexington, USA Fischer, R. TU Dresden, Inst. fiir Wasserchemie & WassertechnoI., Mommsenstr. 13, D-Ol062 Dresden, Germany Flather, D. H. Rescan Environmental Services, Vancouver, Canada Friese, K. UFZ-Umweltforschungszentrum, Gewasserforschung, Am Gouvernements berg 1, D-39104 Magdeburg, Germany XII List of Contributors Geller, W. UFZ-Umweltforschungszentrum, Gewasserforschung, Am Biederitzer Busch 12, D-39114 Magdeburg, Germany George, D. G. Institute for Freshwater Ecology, Windermere Laboratory, Ambleside, Cumbria LA22 oLP, UK w. Glasser, UFZ-Umweltforschungszentrum, Hydrogelogie, Hallesche Str. 44, D-06246, Bad Lauchstadt, Germany Guderitz, T. IDUS GmbH, BioI. Analyt. Environm. Lab., Dresdner Str. 43, D-01458, Ottendorf-Okrilla, Germany Gusek, J. Knight Piesold, Denver, USA Hedin, R.S. U. S. Bureau of Mines, P. O. Box 18070, PA 15236-0070, Pittsburgh, USA Hupfer, M. IGB-Insitut fUr Gewasserokologie & Binnenfischerei, Miiggelseedamm 310, D-12587 Berlin, Germany Johnson, D. B. University of Wales, School of BioI. Sciences, LL57 2UW, Bangor, UK Kalin, M. Boojum Research Ltd., 468 Queen Street East, M5A 1T7, Toronto, Canada Katzur, J. Forschungsinstitut fUr Bergbaufolgelandschaften, Brauhausweg 2, D-03238 Finsterwalde, Germany Klapper, H. UFZ-Umweltforschungszentrum, Gewasserforschung, Am Biederitzer Busch 12, D-39114 Magdeburg, Germany Kleinmann, R.L.P. US Dept of Energy, P. O. Box 10940, PA 15236-0940, Pittsburgh, USA

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