A Complete Resource Book in Chemistry for JEE Main 2019

1386 Pages·2018·96.166 MB·English

by  Atul Singhal

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A Complete Resource Book in
chemistry
JEE Main 2019
for
A.K. Singhal
U.K. Singhal
Dedicated to
my grandparents,
parents and teachers
Copyright © 2018 Pearson India Education Services Pvt. Ltd
Published by Pearson India Education Services Pvt. Ltd, CIN: U72200TN2005PTC057128.
No part of this eBook may be used or reproduced in any manner whatsoever without the publisher’s
prior written consent.
This eBook may or may not include all assets that were part of the print version. The publisher
reserves the right to remove any material in this eBook at any time.
ISBN: 9789353062156
eISBN: 9789353063412
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Website: in.pearson.com, Email: [email protected]
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Contents
Preface. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
Acknowledgements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . viii
JEE Mains 2018 Paper. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .xi
JEE Mains 2017 Paper. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .xviii
Chapter 1 Basics of Chemistry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.1–1.32
Chapter 2 Solid State . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.1–2.34
Chapter 3 Gaseous State . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.1–3.36
Chapter 4 Atomic Structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.1–4.38
Chapter 5 Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.1–5.38
Chapter 6 Energetics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.1–6.40
Chapter 7 Chemical Equilibrium. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.1–7.42
Chapter 8 Ionic Equilibrium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8.1–8.54
Chapter 9 Redox Reactions and Electrochemistry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9.1–9.50
Chapter 10 Chemical Kinetics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10.1–10.46
Chapter 11 Surface Chemistry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11.1–11.34
Chapter 12 Periodic Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12.1–12.26
Chapter 13 Chemical Bonding . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13.1–13.38
Chapter 14 Chemistry of Representive Elements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14.1–14.26
Chapter 15 Chemistry of Non-Metals I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .15.1–15.30
Chapter 16 Chemistry of Non-Metals II. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16.1–16.60
Chapter 17 Chemistry of Lighter Elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17.1–17.28
Chapter 18 Chemistry of Heavier Elements (Metallurgy) . . . . . . . . . . . . . . . . . . . . . . . . . . .18.1–18.34
Chapter 19 Transition Metals Including Lanthanides and Actinides . . . . . . . . . . . . . . . . . . . . .19.1–19.26
Chapter 20 Coordination Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20.1–20.40
Chapter 21 Nuclear Chemistry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21.1–21.28
Chapter 22 Purifi cation and Characterization of Carbon Compounds . . . . . . . . . . . . . . . . . . . .22.1–22.26
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vi Contents
Chapter 23 General Organic Chemistry I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .23.1–23.54
Chapter 24 General Organic Chemistry II. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .24.1–24.52
Chapter 25 Hydrocarbons and Petroleum . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25.1–25.58
Chapter 26 Organic Compounds with Functional Groups Containing Halogens (X) . . . . . . . . . . . . .26.1–26.36
Chapter 27 Alcohol Phenol Ether . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27.1–27.56
Chapter 28 Organic Compounds Containing Oxygen-II . . . . . . . . . . . . . . . . . . . . . . . . . . .28.1–28.70
Chapter 29 Organic Compounds with Functional Groups Containing Nitrogen . . . . . . . . . . . . . . .29.1–29.44
Chapter 30 Polymers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .30.1–30.20
Chapter 31 Biomolecules and Biological Processes . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31.1–31.40
Chapter 32 Chemistry in Everyday Life. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .32.1–32.22
Chapter 33 Environment Chemistry. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .33.1–33.16
Chapter 34 Practical Chemistry. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .34.1–34.34
Appendix . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .35.1–35.20
Mock Test 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .M1.1–M1.6
Mock Test 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .M2.1–M2.6
Mock Test 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .M3.1–M3.6
Mock Test 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .M4.1–M4.6
Mock Test 5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .M5.1–M5.6
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Preface
About the Series
A Complete Resource Book for JEE Main series is a must-have resource for students preparing for JEE Main examination.
There are three separate books on Physics, Chemistry, and Mathematics; the main objective of this series is to strengthen
the fundamental concepts and prepare students for various engineering entrance examinations. It provides class-tested
course material and numerical applications that will supplement any ready material available as student resource.
To ensure high level of accuracy and practicality, this series has been authored by highly qualifi ed and experienced
faculties for all three titles.
About the Book
A Complete Resource Book in Chemistry for JEE Main 2018 is an authentic book for all the aspirants preparing for the
joint entrance examination (JEE). This title is designed as per the latest JEE Main syllabus, where the important topics
are covered in 34 chapters. It has been structured in user friendly approach such that each chapter begins with topic-wise
theory, followed by suffi cient solved examples and then practice questions.
The chapter end exercises are structured in line with JEE questions; with ample number of questions on single choice
correct question (SCQ), multiple-type correct questions (MCQ), assertion and reasoning, column matching, passage based
and integer type questions are included for extensive practice. Previous 15 years’ questions of JEE Main and AIEEE are also
added in every chapter. Hints and Solutions at the end of every chapter will help the students to evaluate their concepts and
numerical applications. Because of its comprehensive and in-depth approach, it will be especially helpful for those students
who prefers self-study than going for any classroom teaching.
Series Features
• Complete coverage of topics along with ample number of solved examples.
• Large variety of practice problems with complete solutions.
• Chapter-wise Previous 15 years’ AIEEE/JEE Main questions.
• Fully solved JEE Main 2017 questions.
• 5 Mock Tests based on JEE Main pattern in the book.
• 5 Free Online Mock Tests as per the recent JEE Main pattern.
Despite of our best eff orts, some errors may have crept into the book. Constructive comments and suggestions to
further improve the book are welcome and shall be acknowledged gratefully. Kindly share your feedback with me at
[email protected] or [email protected].
A.K. Singhal
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Acknowledgements
The contentment and ecstasy that accompany the successful completion of any work would remain essentially incomplete
if I fail to mention the people whose constant guidance and support has encouraged me.
I am grateful to all my reverend teachers, especially, late J.K. Mishra, D.K. Rastogi, late A.K. Rastogi and my honour-
able guide, S.K. Agarwala. Their knowledge and wisdom has continued to assist me to present in this work.
I am thankful to my colleagues and friends, Deepak Bhatia, Vikas Kaushik, A.R. Khan, Vipul Agarwal, Ankit Arora
(ASO Motion, Kota), Manoj Singhal, Yogesh Sharma, (Director, AVI), Vijay Arora, (Director, Dronacharya), Rajneesh
Shukla (Allen, Kota), Anupam Srivastav, Rajeev Jain (M V N), Sandeep Singhal, Chandan Kumar (Mentor, Patna),
P.S. Rana (Vidya Mandir, Faridabad).
I am indebted to my father, B.K. Singhal, mother Usha Singhal, brothers, Amit Singhal and Katar Singh, and sister,
Ambika, who have been my motivation at every step. Their never-ending aff ection has provided me with moral support and
encouragement while writing this book.
Last but not the least, I wish to express my deepest gratitude to my wife Urmila and my little, —but witty beyond her
years, daughters Khushi and Shanvi who always supported me during my work.
A.K. Singhal
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Chemistry Trend Analysis
(2007 to 2018)
S. No Chapters 07 08 09 10 11 12 13 14 15 16 17 18
1 Basics of Chemistry 3 – – – – 1 1 – 1 – 2 2
2 Solid State – 1 1 2 1 1 2 1 1 1 2 –
3 Gaseous State 1 – – – 1 1 1 2 1 1 1 –
4 Atomic Structure 1 2 2 2 1 1 1 1 1 1 1 –
5 Solutions 2 2 2 2 2 1 1 1 1 1 1 1
6 Energetics 3 2 3 2 1 1 1 1 1 2 2 1
7 Chemical Equilibrium – 2 1 – 1 1 1 1 1 2 2 1
8 Ionic Equilibrium – 2 1 3 – 1 1 – – – 1 3
Redox Reactions and
9 2 1 1 2 1 1 1 3 1 1 1 1
Electrochemistry
10 Chemical Kinetics 1 3 – 2 1 1 1 – – 1 1 1
11 Surface Chemistry – 1 1 – 1 1 1 – 2 2 1 –
12 Periodic Properties – – 1 1 1 1 1 1 1 1 1 –
13 Chemical Bonding 2 1 1 – 3 1 2 – 1 1 1 3
Chemistry of Representive
14 1 – 1 – 2 1 1 – – – – –
Elements
15 Chemistry of Non-Metals I – 4 – – – – – – – – 1 1
16 Chemistry of Non-Metals II 2 – 2 1 2 – 1 – – 1 2 1
Chemistry of Lighter
17 1 – – – – 1 – – – 1 1 1
Elements
Chemistry of Heavier
18 – 1 – – – 2 – 1 1 2 – –
Elements (Metallurgy)
Transition Metals Including
19 – 1 2 – 2 – 2 – 1 1 – –
Lanthanides and Actinides
20 Coordination Compounds 1 2 2 2 2 1 1 1 – 2 1 3
21 Nuclear Chemistry 2 – – – – – – 1 1 – – –
(Continued )
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