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A bench scale evaluation of organic substrates for use in constructed wetlands for the treatment of acid mine drainage PDF

212 Pages·1994·6.8 MB·English
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Preview A bench scale evaluation of organic substrates for use in constructed wetlands for the treatment of acid mine drainage

S Schafer and 622*5 Associates M26bseo A bench scale 1991 evaluation of organic substrates for use in construe ted Schafer & Associates P.O. Box 6186 Bozeman, Ml 59715 (406) 587-3478 A BENCH SCALE EVALUATION OF ORGANIC SUBSTRATES FOR USE CONSTRUCTED IN WETLANDS FOR THE TREATMENT OF ACID MINE DRAINAGE Submitted To: Montana Department of State Lands Abandoned Mine Reclamation Bureau Helena, MT 59620 Submitted By: mn DOCUMENTS COLLECTION Schafer and Associates Bozeman, MT 59715 JUN 22 1994 MONTANA STATE LIBRARY 1515 E. 6th AVE. HELENA, MONTANA 59620 September 1991 9, MONTANASTATE LIBRARY S622.5M26bseo1991C.1 Abenchscaleevaluationoforganicsubs MAY 4 - 1994 3 0864 00085741 0 OCT 4 1995 SEP 111991 STATE LANDS DISCLAIMER The use of or reference to a product name in this report does not constitute an endorsement of that product by Schafer and Associates or the State of Montana. TABLE OF CONTENTS INTRODUCTION 1.0 1 OBJECTIVES 2.0 1 MATERIALS AND METHODS 3.0 3.1 Materials 2 3.2 Methods 4 RESULTS 4.0 4.1 Effluent Analysis 8 4.2 Depth Sampling Chemistry 23 4.3 Lactate Addition 31 4.4 Substrate Metal Fractionation 32 4.5 Substrate Neutralization Potential 37 4.6 Hydraulic Conductivity 39 4.7 Observations 40 5.0 DISCUSSION 42 6.0 CONCLUSIONS 44 7.0 LITERATURE CITED 46 APPENDIX A COLUMN INFLUENT AND EFFLUENT CHEMISTRY APPENDIX B MUSHROOM COMPOST AVAILABLE PHYSICAL AND CHEMICAL CHARACTERISTICS APPENDIX C COLUMN PORE WATER CHEMISTRY APPENDIX D COLUMN SUBSTRATE METALS FRACTIONATION RESULTS APPENDIX E SUBSTRATE METALS FRACTIONATION METHODS i Digitized by the Internet Archive 2014 in https://archive.org/details/benchscaleevalua1991scha LIST OF TABLES Table 1. Mean AMD influent chemistry 2 Table 2. Substrate physical and hydraulic characteristics 3 Table 3. Substrate pH, neutralization potential and neutralization capacity 38 ii LIST OF FIGURES Figure 1. Typical column design employed in substrate evaluation column study 5 Figure 2a. Substrate mean influent and effluent pH and acidity/alkalinity concentrations 10 Figure 2b. Substrate mean influent and effluent pH, Al and Fe concentrations 11 Figure 2c. Substrate mean influent and effluent pH, Mn and Zn concentrations 12 Figure 3a. Substrate mean influent and effluent pH and acidity/alkalinity concentrations 14 Figure 3b. Substrate mean influent and effluent pH, Al and Fe concentrations 15 Figure 3c. Substrate mean influent and effluent pH, Mn and Zn concentrations 16 Figure 4a. Substrate mean influent and effluent pH and acidity/alkalinity concentrations 18 Figure 4b. Substrate mean influent and effluent pH, Al and Fe concentrations 19 Figure 4c. Substrate mean influent and effluent pH, Mn and Zn concentrations 20 Figure 5a. Substrate pore water Eh, pH, S2", Al and Fe concentrations by depth 24 Figure 5b. Substrate pore water Eh, pH, S2", Mn and Zn concentrations by depth 25 iii

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