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7th International Symposium on High-Temperature Metallurgical Processing PDF

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1th Inlernalional Symposium on High-Temperature Metallurgical Processing FEBRUARY 14-18 DOWNTOWN NASHVILLE, TENNESSEE MUSIC CITY CENTER New proceedings volumes from the TMS2016 Annual Meeting: (cid:115) 7th International Symposium on High-Temperature Metallurgical Processing (cid:115) CFD Modeling and Simulation in Materials Processing 2016 (cid:115) Characterization of Minerals, Metals, and Materials 2016 (cid:115) Energy Technology 2016: Carbon Dioxide Management and Other Technologies (cid:115) EPD Congress 2016 (cid:115) Light Metals 2016 (cid:115) Magnesium Technology 2016 (cid:115) Rare Metal Technology 2016 (cid:115) REWAS 2016 (cid:115) Shape Casting: 6th International Symposium (cid:115) TMS 2016 Supplemental Proceedings Proceedings of a symposium sponsored by the Pyrometallurgy Committee of the Extraction and Processing Division (EPD) of The Minerals, Metals & Materials Society (TMS) held during FEBRUARY 14-18 DOWNTOWN NASHVILLE, TENNESSEE MUSIC CITY CENTER Edited by: Jiann-Yang Hwang, Tao Jiang, P. Chris Pistorius, (cid:39)(cid:69)(cid:82)(cid:65)(cid:82)(cid:68)(cid:79)(cid:0)(cid:50)(cid:14)(cid:38)(cid:14)(cid:0)(cid:33)(cid:76)(cid:86)(cid:69)(cid:65)(cid:82)(cid:0)(cid:38)(cid:14), Onuralp Yücel, Liyuan Cai, Baojun Zhao, Dean Gregurek, and Varadarajan Seshadri Editors .Tiann-Yang Hwang Liyuan Cai Tao Jiang Baojun Zhao P. Chris Pistorius Dean Gregurek Gerardo R.F. Alvear F. Varadarajan Seshadri Onuralp Yiicel ISBN 978-3-319-48617-8 ISBN 978-3-319-48093-0 (eBook) DOI 10.1007/978-3-319-48093-0 Chemistry and Materials Science: Professional Copyright © 2016 by The Minerals, Metals & Materials Society Published by Springer International Publishers, Switzerland, 2016 Reprint of the original edition published by John Wiley & Sons, Inc., 2016, 978-1-119-22575-1 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore tree for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer In ternational Publishing AG The registered company address is: Gewerbestrasse 11,6330 Cham, Switzerland TABLE OF CONTENTS 7th International Symposium on High-Temperature Metallurgical Processing Preface ....................................................................................................................xv About the Editors .................................................................................................xvii Energy Efficient Clean Metallurgical Technology Flash Reduction of Magnetite and Hematite Concentrates with Hydrogen in a Lab-Scale Reactor for a Novel Ironmaking Process ........................3 Yousef Mohassab, Mohamed Elzohiery, and Hong Yong Sohn Investigation of Coal Tar Pitch Binder for the Production of Formed Coal Briquettes for COREX from High Volatile Coal Powder ......................................11 Yongbin Yang, Yaxuan Wang, Qian Li, Bin Xu, Qiang Zhong, and Wei Gao Upgrading of Iron-Rich Titanium Minerals Using a Molten Salt Process .............19 Farzin Fatollahi-Fard and Petrus Christiaan Pistorius Direct Electrolytic Production of Mo-Si-Ti-C Composites from Their Oxides/Sulfide/Carbon Mixture Precursor in Molten Salt .....................................27 Xingli Zou, Xionggang Lu, Qian Xu, Hongwei Cheng, Shuhua Geng, and Zhongfu Zhou Reduction Kinetics of Magnetite Concentrate Particles with H + CO at 2 1200 to 1600 °C Relevant to a Novel Ironmaking Process ....................................35 Mohamed Elzohiery, Yousef Mohassab, Jagannath Pal, Shengqin Zhang, and Hong Yong Sohn Advanced Oxygen Lances for Safer Furnace Tapping Operations ........................43 Peter Sylvén and Darwin Morales Utilization of Pine Nut Shell for Preparation of High Surface Area Activated Carbon by Microwave Heating and KOH Activation ............................51 Xuefeng Liao, Jinhui Peng, Shengzhou Zhang, Hongying Xia, Libo Zhang, Guo Chen, and Tu Hu v Research on High Temperature Mechanical Properties of 50Cr5MoV Roll Steel ................................................................................................................59 Dong-chang Huang, GuangliangWu, and Xin-bin Liu Extraction and Recovery of Metals Separation of Rhenium and Molybdenum from Molybdenite Concentrate by Microwave-Assisted Roasting ..........................................................................69 Tao Jiang, Linfeng Zhou, Zhiwei Peng, Guanghui Li, and Rong Sun Active Oxidation and Fume Formation from Liquid SiMn ...................................77 Ida Kero and Gabriella Tranell Research on Enrichment of MFe and RO Phase from Converter Steel Slag by Super Gravity ....................................................................................................85 Chong Li, Jintao Gao, and Zhancheng Guo Volatilization of Rhenium from Molybdenite Concentrate by Oxidative Roasting .................................................................................................93 Guanghui Li, Rong Sun, Zhiwei Peng, Linfeng Zhou, and Yuanbo Zhang Kinetic Investigation of the Electric Furnace Copper Slag Treatment ................101 Stephan R. Steinacker and Juergen Antrekowitsch The Extraction of Zinc from Willemite by Calcified-Roasting and Ammonia-Leaching Process Based on Phase Reconstruction .............................109 Wei Chen, Yufeng Guo, Feng Chen, Tao Jiang, and Xudong Liu An Investigation on Antimony Production by Using Niederschlag Process ...........................................................................................117 Sedef Pinar Basag, Ahmet Turan, and Onuralp Yucel Oxygen-Rich Side Blow Bath Smelting Technology – New Developments in China ................................................................................................................123 Lin Chen, Wei Chen, Hui Xiao, Tianzu Yang, Weifeng Liu, and Duchao Zhang Carbon Refractories in an Oxidizing Process? Copper Smelting in an Outotec® Ausmelt TSL Furnace With a UCAR® ChillKote™ Refractory System ................................................................................................131 Jacob Wood, Stefanie Creedy, and Peter Duncanson vi Enrichment of Gold in Low Grade Copper Matte from Arsenical Refractory Gold Concentrate via Matte Smelting Method ..................................139 Duchao Zhang, Qingkai Xiao, Tianzu Yang, Weifeng Liu, and Lin Chen Alloys and Materials Preparation Zinc and Refractories – A Nasty Relation ...........................................................149 D. Gregurek, S. Redik, C. Wenzl, and A. Spanring Preliminary Study on Preparation of Al-Sc Master Alloy in Na AlF -K AlF -AlF Melt .................................................................................157 3 6 3 6 3 Zhongliang Tian, Yanqing Lai, Kai Zhang, Xun Hu, Hongliang Zhang, and Jie Li Effect of the Reductants on the Production of Iron Based Alloys from Mill Scale by Metallothermic Process .................................................................165 Mehmet Bug˘daycı, Ahmet Turan, Murat Alkan, and Onuralp Yücel Experimental Study on Iron-Based Alloy as Cladding Layer—Improving High Temperature Oxidation Resistance of Furnace Alloy .................................173 Wang Yanze, Chen Chen, and Hong Xin Production of FeMn Alloys with Heat Treated Mn-Nodules ...............................181 Merete Tangstad, Eli Ringdalen, Edmundo Manilla, and Daniel Davila Thermodynamic Analysis and Experiments on Vacuum Separation of Sn-Sb Alloy ..........................................................................................................189 Junjie Xu, Lingxin Kong, Yifu Li, Bin Yang, Yongnian Dai, Kunhua Wu, and Anxiang Wang Simulation of Solidification Microstructure of 30Cr2Ni4MoV Steel Ingot under Different Intensities of Mechanical Oscillation Condition ..............197 ShuangYu Du, JieYu Zhang, Bo Wang, SenYang Qian, and Jian Zhao Production of ZrB -B C Composite Materials via SHS Process .........................205 2 4 Kag˘an Benzes¸ik, Mehmet Bug˘daycı, Ahmet Turan, and Onuralp Yücel Research on Microwave Roasting of ZnO and Application in Photocatalysis ......................................................................................................211 Qin Guo, Linqing Dai, Shenghui Guo, Libo Zhang, and Jinhui Peng vii Fundamental Research of Metallurgical Process Reduction Kinetics of Hematite Concentrate Particles by CO+H 2 Mixture Relevant to a Novel Flash Ironmaking Process......................................221 Yousef Mohassab, Feng Chen, Mohamed Elzohiery, Amr Abdelghany, Shengqin Zhang, and Hong Yong Sohn SO Formation in Copper Smelting Process: Thermodynamic Consideration ....229 3 Mao Chen, Zhixiang Cui, Leonel Contreras, Chuanbing Wei, and Baojun Zhao Effect of Oxidation on Wetting Behavior between Silicon and Silicon Carbide ........237 Yaqiong Li, Lifeng Zhang, and Zineb Benouahmane Effect of CaO/SiO and P O on the Viscosity of 2 2 5 FeO-SiO -V O -CaO-P O Slags ........................................................................243 2 2 3 2 5 Zhen Zhang, Bing Xie, Pan Gu, Jiang Diao, and Hongyi Li Heat Losses to Furnace Coolers as a Function of Process Intensity ....................251 M.W. Kennedy, A. MacRae, and H. Haaland Viscosity of Partially Crystallized BOF Slag .......................................................263 Zhuangzhuang Liu, Bart Blanpain, and Muxing Guo Origin and Evolution of Non-Metallic Inclusions for Al-Killed Steel during EAF-LF-VD-CC Process ..........................................................................271 Hai-yan Tang, Xiao-chen Guo, Peng-fei Cheng, Yong-cang Liang, Jing-she Li, and Baojun Zhao The Dynamic Dissolution of Coke with Slag in Melting and Dropping Zone ..........279 Yingli Liu, Qingguo Xue, Wentao Guo, Haibin Zuo, Xuefeng She, and Jingsong Wang Research on Oxidation Kinetics of SPHC Steel at 500~900° C ..........................287 Dongchang Huang, Guangliang Wu, and Xinbin Liu Direct Reduction and Smelting Reduction Experiment Research on Direct Reduction of Celestine by Rotary Hearth Furnace Process ............................................................................297 Dongping Duan, Hongliang Han, Siming Chen, E Zhou, and Li Zhong viii Influence of Slag Basicity on the Silicon Within the Stainless Steel Master Alloy Prepared by Smelting Reduction of Fe-Ni-Cr Sinters ...............................303 Yanhui Liu, Pingsheng Lai, Xuewei Lv, and Chenguang Bai Reduction Behavior of Chromic Oxide in Ti–Bearing BF Slag ..........................309 Baohua Li, Xuewei Lv, Yun Chen, Yanhui Liu, and Shengping Li Effects of Mineral Oxides on the Precipitation Micro-Morphology of Metallic Iron in the Reduction of Iron Oxides Under CO Atmosphere ...............317 Zhancheng Guo, ZhiLong Zhao, Huiqing Tang, Jingtao Gao, and Lin Lin Influence of Operation Parameters on Mass Fraction of Sulfur in the Hot Metal in COREX Process .............................................................................327 Laixin Wang, Shengli Wu, Minyin Kou, Xinliang Liu, Yujue Wang, and Weidong Zhuang Influence of Operation Parameters on Sticking Behavior of Pellets in COREX Shaft Furnace .........................................................................................335 Xinliang Liu, Shengli Wu, Zhe Wang, Laixin Wang, and Mingyin Kou Relationship between Coking Properties of Lump Coal and Its Pulverization in COREX Process ........................................................................343 Qihang Liu and Peng Zang Thermogravimetric Analysis of Coal Used in Rotary Kiln of Iron Ore Oxide Pellet ..........................................................................................................351 Qiang Zhong, Yongbin Yang, Qian Li, and Tao Jiang Sintering and Pelletizing of Iron Ores Enhancing the Removal of Sodium and Potassium of Sinter by CO-Containing Flue Gas Circulation Sintering Process ......................................361 Chen Lui, Guanghui Li, Ruijun Wang, Zhengwei Yu, Qian Li, Zhao Jing, and Yuanbo Zhang The Preheating and Roasting Properties of Fluorine-Bearing Iron Concentrate Pellets and Main Influence Factors ..................................................369 Lu Yang, Shuai Wang, Gang-hua Fu, Yu-feng Guo, and Tao Jiang ix

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