339. Absolute Cross Sections for Molecular Photoabsorption, Partial Photoionization, and Ionic ...

145 Pages·07.75 MB·English

Absolute Cross Sections for Molecular Photoabsorption, Partial
Photolonization, and lonle Photofragmentation Processes

We, Gobagher,6.€. Belon JAR, Sarneon.” and. Langhott”

a evteirLsvm doh diy bd nl Rafi Ri, MFO

teialeatunenescnioge foc loucsaballaf assed aoleuls sided celaees
(Gh, CO, YOY nnd err (0, NO} ape hye Hy, CT),
jure Rn (HN, CE, MB HL), sur congo 9.8, C8, OLS SO, 5),
sedcenigecnpponde(Ch.CC,) The paral angel tosses reat
Fete ed pete dguent na futon of skit plod ease, ical om
“aoe I e¥ Trl phonation no ein nee non ach
sae tepatel fe csaolal oil ears and wy neat tn
‘ora at fn "gualer phot? yale) esren materngeeriert Par
‘il puctonizan ros secioa fc podueinnofeaxulesttesflooecUntnc a
"hina om phenom spacey snd tote 20 cnncdenoe en:
beet Phtsonwinn mae spestrsy snd aie, fm) oars
fvkiswnabunsrat of pr ass week i agosto (2 ds
"oe poco). Photon snetrepe Ee, ach ose mi ls
‘rode grt cut one pve ster non een ponent a
"ingle tes renaneh Thro cently seo eran bone ls
‘hema tnephyandy dine pend pele arene mets Teer
‘Soon ap ante Str en aman fray wi ld 3 i a ae
fecal (pln eka whack presi ha rtwarpsauen be me

ey ocrd nym ames ean aber pra
(cocoa suapocenias pee

Contents,
2 Detwtion sod Nowe. re E25 TeenPhocetocnioaCroaseims 2
4 Ragen etna i 22h fara! Phosonbriog Cre Soe
3 Floto Mateos " toe
iatow Casa Stat a” At Ciussectial Erosion
ut. Boral Peteonzton ees 6 442 Denemin Appeonauacins
cone 20 _ 43 Cometnvond Apprninions
5. Dam Aantion ond Prot,
=e cts titntn mse, Orla anD

. 2 Daten . x
Thesmyegi'icesger wile serian Remsen! Mp rx Date REN, #
10 GALLAGHER Er aL

we Bree. 1 Mii cyanea
yee Ei eae mae
ote 2 Tee neem cre OO
eon ey serene
Soar eeec— B mew nmnuted :
Praca ence Se ec aaa
ender see Ceapemaci *
soon a tales reine ms
Tiger gemma engiomae pore oR
17. (a) Pastial phaussom-zation. oraes section for (L) ined Soule seme eb es 6 oes tow
(a9 float jae ate —.YH1,%, Cb) Final ionic ion Oe wr Fhe ~ el

——
6

».

‘CROSS SECTIONS FOR MOLECULAR PHOTOIONIZATION PROCESSES

Pas petit fe tina
{Aig sore sake = My <P) Soa
a
fate MES ea 0120-40 °¥.
Phooey pace COs
(fa foe se = 2M (8) ore
ate= 41, (ead eis = BE,
(a) Pal penn ree Sn for
{GOs fal ontte= C3, (Thee
from marty psa £6 CO ale
‘Yona nie ploatrnemstioneresenetions
fer G0: (al peat n= CO? (1 poe
ten CO" fe) procs ien 0
[Pstancis podtmgneraten em toa
fn COy a) dee on — CU Post
iow = G02" (6 podectica

‘Torn housing seas aesin for Nth
a) Komaneray rng) eeu ane.
Pari phoeinian easscadoos fo NO
{ad i miedo, (0) B01 Foe
aon 25,0) Ieestate= JT
Pholrtro yr patie G20,
(> dt tye nae =, (0) Ba oe
tenn, (o) naling Sale FM
(Cand plteeiztion ree sti for
1b, al eo se 28 pach
‘tom aerate oy 4,0, Al ie
Bure C22" Ce) parla. yheriozain
(he sea fx 80) lore ate 18
paket.

c.f) Pail phowimaoaa cas ton fer

Nolin neato PES phon 12-426

(é} Balle photfrgmettion oe

tous Er NO, itn 2,0". ) Pt

Nay peda n = NO

asics phototramaeainn cm ten
2 pct

“Ta powctorgtion cme section fr 40>
{a lomcocey ae <0) Rehenenes ae
‘Pai portation erga
{35 asl ni to = Fy Hal om
fae, (2) Bato Se
Photoderm anys garamace F750,
2) al nie te = "8 (D) oie
item ay (2 aul ate — 227,
{e) Fara! photic essa sxion for
1,0 he sat>= Cb) phate:
(eveyone 0. a ere
preeray
{a> Pat ptsonittion rr san fe
H0foniioniemn C74, oleate
Faoge (9) Parl oie platfegacnation
‘oye Ta 0, pret on ~ BO
andes pladagheuon cee eo
{an HA (pod on OFT bl prt
8) prodeetion =O"

o

©

%

‘Tena phatstaptiog en ton en NAL
(i Tom anergy range fo Mec ny
Prac es trns ft NE
(2) Gaal fale ete = Fy, (8) stile
sate", (6 Ba inistue — 4,
Phetcactron ener arian Wy
4) foie sme Ty, (07 gic
Partalioniclragmetaio cs aus
(or NB (prone on — IL, prod
ction = NA (2) agus oe — NH
Perla pbstadagumuou steers
fou Nig te) poet on = Nr (0) peut
‘Te otabnorsion cree acon fo CH
a Voanergy rage ch higenery cng
Phin phrase cna or
Xo) tae ioe ce 82.0 al ie
Exte—a%d, (9) Ol lone al many
bed te sig rer en on
rei vi pstaftgmenonin ce tne
Fine a) psc km = CH (0S prot
Pavalianc phcrmgmentatinemsacons
fie Tg fa ratactinn CHF) pt
Sno a) pocr fone
Paral pecan ron cin or HF;
(2) deal fois ste ATL, by Aa ons
lure at produtina =H", () potas
jw (9) peavet ion = B

G3) Toto phausharpton vow ac fe
fee HEL Gah aloe! Pai
plaiting se wot lor HC, Gel
fee ate 3

{a} Paris phtinization messin for
HC tiene tn ~ arg hs tains
itp fom ine valeace enero) Pho
fleezon esenmacy pene fr HO, Sal
lorena 1c) Protretrom nse
yperemact2e HU: aomoweatne = 42"
Fail ioiephotoagnetiouercas scene
fer HEC (opreducsion HCI", (6 prosut
(ep otal puctasocplon aoe sion
Bs, (b) Parl phono cross sevian
So Hy fl state oH) Pl hr
{imine Som le Oy

(a Pant phomnclna ss set fot
Bs, lett = a body
‘np tom iar vleacetoietin() Ps.
Semis = 718 (2) Ppt ae
wy paraeeter Jor Hf, Aol one

"

6

8

*
a

es

Pentre merry
fb poeta He pat
Ste) ie
ill tien tr a fh
Ce ei se,
ars
orcs ey prc
Corte pms suin= Pe
sia
Po pinot cigs eo
(ar ee a om a
say anne 8
Broce nuemes pra er
fa) te ey lo
seed) tain ae
{ey re furore wear
Hishinwsade te ty pas
eum pannwer et tals
see ro in ute
Shtsosscabuter BS poate = a
Ferengi apne cco
(oar poate Aa Oat
Toul pace en eC
ed pmo on
(ot wae Uy oa
Shetty, crhalitan ts,
(al ae = oi oe
tie cesta,
(oy rat patron ct cto
Creates Ob Onin
Shane rote, i ea es
hea,
ices acy pacer
(oral ease se Sy G0 fot
cr nen in =
Pevromevery warrior
nicl mon
ck; ch pono 9 net
Rotiieputcaeoen acs
eek coin Ce pat
Tasananern cain i 08
‘i elt cena OCS
te at nate (al oe
‘ibe dS" a ates
nba nereee
Efe eae 0 ln
sites dante
Js) Pa praia oa sen ar
Seria dis eateca Phowee

nw

a

a

08

ws

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1

1,

sm ra OS os
Rr es tina wh
onaclnsn tos on ae
og pum so pn
ene Uinonatane sth

ea pects cee acl 2
Cohen ae ero
Hocutineraaae tS,
Beuttigur i ramcarese
Fisrateen tease

EES poakat ta) 154 (0) Thad eo) 8
Feit Late prone s
rang ogee aR gee
foedre, yamine se
Police
Resign penta po
ii ain
ocieutcse i
Cees anne pet
peas (OneanenS
testy pluses th ges
Soe ned

Fo iaabrgionr een rh
Fei ere ae sae 8
Uo ace wey ta oa
ene Oana
(Sad ete he oe
ere One a
rae umpeatn las
GL fear et
mont geen cn
roadie CO
Heston poet Sy
‘GHOSE SECTIONS FOR MOLECULAR PHOTOIONIZATION PROCESSES ry

Glossary

tote photons seston
isin sci
saat
ot oe evi ptionratio ease ton Boe
reining (or lay) here
Finntroll
yum sa Pahing ri Fao
Sholom raat ene
» Tyrone spats peririetr

aR

4. Introduction

oul pointe graces ec af abdomen
re parece aad apn im ag ees oF
hye unedy esas and aban che.
oye, wa lege Wenn Usa asin oie
Rube allo sae eats for aa psec,
pomeranian for pment
om prance tor ide secralrangespstioaa fre
Inprdting aia tandiaocrermental ha
anal ey tous ae rere fal ean
thease on cept apreiateos niece
‘olan proses

‘Aiongh mtn ose ta ben mae nee
ent ef aa tl hone
hoirnealon ces soe im re vactbon laNO
{PO aod a way me Hace ts ety 1
qn rete stets asi yronson we
‘venagaaererty> Thee alates?
usted plotlononign crac nll ofp
Jrotioson hess appease ens
Sree vat oho of red enon
‘Yat ctl connate?" view erating mt
‘ol poeta prceon paola he pur
Sstchenons cout to tbs vce Peoria
nnn of url weasel dt aed ay
‘ntrint nade imenaaron fae ah sod
‘rl pont Calpe, et ee 0

“The poceesf primary mice ests cpt,
singeiouboianand nue agen sen Oe
hate, mle nae ane ao be pm aed
Tih ove Me poo on Ream enon
Tht and ape of exper a Ao
‘led daca fhe epi ee as
ttcoafsteletdemion mere onc fete
ovingien indus 2-reome peen ei sok
‘Shean agrimtain veel bewrfora LD
Thnemmtcale AB eras

Awe ay

seams sats mer ian Pe

oe tal oie phrtapmanaion ese
econ Fr pin of aoe 3
etre rect re pst

new ‘Sei enfin asta 0
fen peductin abghy ni)
‘Shaye part or rpm 2, seek
‘hve ening ose pai

a

fa = sient pin aniotor sng

e eluant egy

Tas 2A anor Ha

en vinta plone. ABs age mate
Gollathegrund ital rows ney
eenbanitk retool ates TAD [ne Rakeahes9
Rticrceronvercintatejande™uthegesed enc
‘Sreyngufanlincnaay. roar ies seforthe
ioren pironicina pecs af Ll) gurls
troche (= 1) un ye ane of she
(eealertni ldsatinprooae =D "57 of Bu
U3) then TAB! Teton experimetay
pment othe ge erm Koc (i
‘dingo ng paelecruneosreso (PTS) a
Thera sagen ile ede) pectcope
ogee reel sla ih ein,
fies a Dna sal ests ori wh
Sine lea a este patel 25
Seton proveoon, fr sch acmabis sro in
Ste Fines I apse ding wey pce fr
‘aera arcleouoiotxttng Their uch
site suru iv ase 0h reduction of he at
Tet destoue sits of HO Which erty ea
{lyr como dorms rom theo eter eal
Sena hw inte THO"! Toy Bq. 123] cae
RSF pias wast metres :P1NS) oF (oe
‘ioeop, In Fg i saoyr a photons aos ae
{cnn dieting the ena a Une ft water
Inelvule vetrcunoe tamer
Iinehe suet nl a eco ems Pgmen
Titel case the stand ction te
cin exit fiingun ene Csi
{nlser il leur ownsecoe 2 Theres
{engin rin lending emt om decsonieeses
‘Dor energy ot amt oe ouron pas)
"The actual din ep exten oc the At
‘Miiiey vasa om iy ie an vols Fe weet
“Thecnoeh comers mpiecending ne = De
Ae ever) Pande las ace al prea ar
“ GALLAGHER ET AZ,

5
is
i]
=

© Ba oe Bo
BINDING ENERGY (eV)

VHcrout
il? og

INTENSITY (arbitrary units}

za 3 Oe
TIME OF FLIGHT (4 sec)
(CROSS SECTIONS FOR MOLECULAR PHOTOIONIZATION PROGESSES 6

oda Th deo an i ee
‘Soa enlist hts Rolle oe ato a Sh
{ct cosa yi ape ial onto the es 2
Ste teas rection al ho sal isc
Save nine ith staal eet Thecus
Tun acpon (Wt feof sider ret eae
ars ft epee lag coma ima as
Inpecreenectina na rg pete rej. The ua
Fnnortmt yexctonle siier which have Tac ade ok
rings nti info cede pheohtuan p
tasenogy sional rene rte sain,” gh
[eehaten unmesais eldeenssmens ih ms
tos lst photedarghi and puoaeizaton wit
thon sone ain holeeeon prong, a
‘man res Om eo ae
ioc sae vba re al cea
‘i be ele within ser yen. tbe enon co
‘am sgn Foran a prt pe
‘omission bert nord sg he
Ts aeocl eat ap gered ch a5Y
[Golatous Toms see aie ot ro
‘pperinersrrpne Lunt ig los a eae ar
Sout tere be lets npr ny ane
oven inser reston ams nage ie
Dene aman mel soteauogian, pot oa
Phonan i erin ro ti
Joel acres goer dt. Specs
‘hide Seu poen ine arrestee
“The rent repre vl be sandal ale 20
‘seus arise corgsinsandcereplemertars 8
(ren eal tia Ea ob vepRerabonpi
Fel ein ert tina eval see
eri U8) game at S58 ote
{sve spaces ib on rr rm a
Inu fennel tea: hone
‘uke dite ac seable?™= The sompncemive men
(ol of Barkow prt srvilen dete
Sesotof macrotis ee ad apt
1918 Despre expr chr or tag,
Thoniownliagempinicg salts opal
Pr e08 Lad teen pempatons

frovied be

‘at phieniaaton eves wating aa wll as brine 0
She ebtane Boer pa Cy ei, 9 fe =)
‘pecnncips massa spoURe SH 1852 Me
(Bea vediacl bee

2. Definitions ead Nomenclature

els Un piers aston! oh endo
sted taming Sales BR, HRM, ba prime
Liye weak te, Tso, a oe
“nhs anor args toi Thee nf
“Rullevaaion ad ye potion em messore aee
fe dnewed- AD ee nine und rated gear
stinat lie photon caay he ntecahbe depen

spread ol iad easly te follow
Te orovidug he ppp defuins i heflso
couse he hae ences pepe hace a
‘ocerest bere. These wre he ellowing.
11} Eualalin by plecshoepico into sable ander

DE ADAT aie 1B ap
(2) etatie aloe iat pos setasng
Seo ARobe Afamtoray AB. (22h

eeatibaiouefiem men groeramnecnet ei bleand
‘Seon silent
(2) Pitosation sobre by the
9) PES 7-10 4)
Be ABADI!
whew AB?" easing oc ain harem 1)
te ()) which mn be sable cr ere with expec 0

A) PINS (721079)

Bye AB TAB Vo nem
“An an
ers 28

‘whe Bg. (24) sles produto f soa or mail
[rooneston cf Paget tre ef eearge 5 vo whan
Do jeep) nde pur gay Ge 0. sd i, 2.0)
{elo ooo ut predonion r= 0). All er proces,
Tien defnedny Pe CL2)-(24 seine ne
Solel by Ue td “aio beryl moins
ince peso mack

The wlporeron ees enon Co) ete
sng the ne tes grog nets [031 uy he

mh na 4 en
‘bee 2, fsb crc seston fr acuta roca 1) and
2 Bll potato tart (3) Thaler
‘any i detaed yee ein
ma Pea ray
hse Tithe ttt phtsounaton cue or quanta
Fide ie
~ Bunter of phous absorb
“The preeate fdr len ad finentton te
sea ined wih Cay (21) an 4) (28, em
‘alate wa cles of evening eens
{Sank POMS) rove to tint ae a Ue
lees“ ees” appearing ie aero of
{29}, Su FSS messeotas [By (23) enor dee
lbiaepir practioner [Ba (0), she pion
Ao eBeeaey chatted s roel se dn tha bia

Linge em, e003, VoL 4
16 GALLAGHER ETAL,

tle ionaiog come “sah Py (20%, ne. TO
Sule pense, sie the quota all payor
reo sata ue cohsonerti sce are
speccal tend ale partnergy evehe re oi
Fuleoeg by. (29) the plenary ba
‘Risscanstewumea
‘Fuapetof poms cee
ft sug, cauble ssuitalisa ossirs on ths sort irs
rsdedrige Me 1 Thequantien Ny ane wer
poldvanclae Lies ba eluroesucauate nde

‘ata or oui shag leslie AR™ [036
wee 8 an,
ww Rao)

amo ths on, Withee ton he aa
aly arp lec es se fe

Comput 3.26) ml 21) es the
fener sation tiny ones deer
[howienivwian provases Ey. 2-4). ually drub-oeid
Fate oetasoo tes ul ADS> Pon Iv ane vt iersy
omg sting by he ve uy oune gece desta, rele
[np te ow tasty breed pon PAA The brsle
item Saletoraon stn sper es Cine
'opee3 tnkon ima zonooet we obaimiegsr-aletron BR?
{atest the wa coun orks iS
‘Sits subcsotil rom the pence signal =" Mine
in nly cl hence eta
Seen ihe sce ered wien DP

tom enti ethan, We srrxpcetie pomnleeon
Syumsey gaat oy wah areteay ene Tn
theca: sitheeusllorzason prema eeral
‘hela eased pkcuienentinn orceesccrion rer il
Ba "

LP ha aon Yok 7.

(Bef 28) 605 cL AB Bae BED, L184
one feud sees Eagar ono
EM ftheaugiehewam the nhicy gro ea) gor
Avent ise so g,
{Bonn Higa (229) wt un ie ae AO
fn cad bow af ten ee

Felling Fa 2, the PMS a ghia
eftesnce tm tow ton ae

ere x0 tb sna gh, So
{Tata ine ior aynt/sncre ans tun
fe panini tury ane. ge be aa OF
Ferg eens Wh eons) ao
Sv he seep af ts opel tac bere Bo. 5ir
proaiten sooner,

“Altbongh 3 denon of Fico soe
rte (Syd (2) ay practi reat 9
Thagahe seen gy $2) ua 28 Hy
Senet aie 9 "ae na dna fat uses
Tigh (TOP) wat pastentcer na, Tis Seo
Tinea profsetaapon diesen mais care
com (23H, OoeaughTI ee
{ste on fnation cen for = age rep
ten arene oes sae otha oy
Tic lotar sme ete ried the deine

Tae tageeny apna ai phottepmenen
Tectia BL" proashou asus orm
Rogar an raga louie aor incd
ing ws Uomo, som be tan

shee te tte foe of ype eae tly
sated Astaleated bower PIMSpemesnetes
{ileinrconventio TOF mepecnoes tbe do
hor of ey (2 leisy rose iy. Chat

anes em

‘With hs ati, oa, Ue pati seen ere
se fpr at aioe of ane eee" re

eGgamerme, fry
sh jeleertnaauravar erates ae
Taco proves reece we og 2) Spe
Sale ody he Kt ae eed 0 Fogo
Tow dnp (oy Pot ont meta on 9b
Revshomers acinus wscommle mene
‘Bg fen cone eo pow so ar
‘¢ROeS SECTIONS FOR MOLECULAR PHOTOIONIZATION PROCESSES

lenceshell phono oem nee et,
‘fern colin nips argon bot
‘Sint andi) PM Smevoraments asec
fe lm

"To some th ogous gata eraeaction oe
restos nl PuS an FMS neesemens nh
Sng tema (lly nhl) teense een ie
(re ania iio ole

2g BRT

IRI,
ead
hmm aTme,
=e 220)

tp (215) ad (220) 9 erie ptconge
me nl pln 9

(tig ~ Sets 0

am

‘vin scanners (1 MO 10. oy), re olathe
{ier optaloien staph 4B hes

feo)

hc heen (eh te ae sad
eu
8. Experimental Methods

nce etin, scons ae sb poten od eo
‘zomg teen ies rset
rte trui phasor, cvon pail pei

Ieaedinteiee Xcmoahihepreen serie
scfeoinine ory seni a he apr en
loved ond mescurme.proselu ae pro. Ae
runes econ bass eeu petal ua

the eal mceuroneus of, pea phonics
can selon ge ered tpn een ae epi
epdctags lnc eioare sepals 5
ieprent meinem Vtvet noauenned es
Teromniion ara al opscocatl abbr es
Frorenery oles phtaorgton nt pee
thegal 3 eulenbg Speco aaleant
sail. rcviqes pnd seas one
nrc aceite sl pation
‘hetv aad set ry gene Teaco ebm
pad he -poormen ocho" ave eet
Iie boty ot dee tr septs stn Meas
[pte bce oan Le peepee
pone es rm phd ae dg sehr
‘Stecerring niurmebs nea wt pal pe
ane toch me ein igh og of seen
‘etweon bernard by Uo ifr etc
bl [dct ae poten a amon elect pac
pean clad in ennng a hd 3

2.1. Photan Hesouremenia

Aspeeot ths otoacape domain TEM ae
noes Wit ti avec,

Delerium uf aacrste se cr ets
pul plotconsatoy poanseneapeetiat aan
easton ofonegy of the otal sin eras stg

Photan aud ELectesa-Ingaet txpectments

Paoton Bxpertaent Quant ity Moacuend

oval thocotvateation of,
Photoelectron hag
botolonizs:ton som oft

Blecteumetergpriose epeccrosceny,
Taped (6)

Diyote (este) oF (eyatiou?
(Fram sume of partials)

Teciioa emetgy Lue -- ejeetad etecteon
coldeddeace, dipore (e,28)

Electron-tou coineldence,
ldbyote Ceverina)
. GALLAGHER EF AL

ore nisthexmist cay fe amp ed a
easebioa li deter ume usage, £3.14

hg = Mabini
sels gue sensing Ue ai ent
Spor ner at rat fy 9 he pth

[xg oad ie eter dey Soeralcongaes hace

an

consis of apple bsg ol af gt? at
svn nna: neem a ia Beaten reac,
{Theand tren cated anoint
eum telat ee sparen ir ¢PAY Tht

4.0m a sD Yo 17,100

ipl olen fyemating the ary el arse
‘Snitton estas polenta Tse a fla
goin to tscond toe intensity 2 towowiced thuoush the
{25 The tess of Ue aie Sopot upon eng
“aber ings the igh nas ote main consort
Scluy te vou f Ue eurenen. etree
{bls tio pods Uris pawulely Lge aeto10D8
Taultendeenava satay‘ as Hw Meanie
‘wbors ssuahveiou see tr ceplore ~

ae soitoean

Inftecitneranethn sted nig 4 apr of
fhysrved with a photons, fe rane af Phe nc
[PM Lube a te ca uf te borne Svea 0a the
‘oPMtcierer daar yawn genteel 8
‘aye nly Kt mos ous the eli he