16th Radiochemical Conference

194 Pages·2010·1.78 MB·English

Czech Chemical Society
Ian Marcus Marci Spectroscopic Society
Czech Technical University in Prague
Organised on behalf of the
Division of Nuclear - and Radiochemistry of the
European Association for Chemical and Molecular Sciences
16
th
Radiochemical
Conference
18 - 23 April 2010
Mariánské Lázně
Czech Republic
Editorial Board
J. John, P. Beneš, L. Havela, O. Lebeda, V. Křížová, J. Kučera,
V. Plaček, M. Vobecký, A. Vokál
BOOKLET OF ABSTRACTS
CONFERENCE PROGRAMME

Chem. Listy 104, s71-s262 (2010) RadChem 2010

elcome to the 16th Radiochemical Conference. The conference is held in Mariánské Lázně, the second largest Czech spa and
the largest and most beautiful city – garden in the Czech Republic. RadChem 2010 aims at maintaining the 50 year tradition
of radiochemical conferences, dealing with all aspects of nuclear- and radiochemistry, organised in the Czech Republic (or
formerly in Czechoslovakia). We strive to continue in the tradition of organising a fruitful and well attended platform for contacts
between experts working in both basic and applied research in all aspects of nuclear- and radiochemistry.
More than 200 scientists from 45 countries registered for the conference. The verbal sessions, where more than 130 plenary,
invited and contributed presentations are scheduled to be presented, will be complemented by the corresponding poster sessions. In
conjunction with the technical programme, an exhibition covering technologies, equipment, technical and management services in
areas pertaining to the theme of the conference will be held.
The extensive social programme is expected to provide an opportunity for informal contacts and discussions among the
participants. The interaction of all the above activities is hoped to maintain the high standard of this long-lasting series of
conferences and through this contribute to the flourish of our Science.

RadChem 2010 Organising Committee
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Chem. Listy 104, s73-s262 (2010) RadChem 2010 Table of Contents

TABLE OF CONTENTS

PROGRAMME AT A GLANCE......................................................................................................................................................s74
PROGRAMME OF THE CONFERENCE........................................................................................................................................s76
1. PLENARY SESSION (PLN)........................................................................................................................................................s91
Lectures.........................................................................................................................................................................................s91
2. CHEMISTRY OF NUCLEAR FUEL CYCLE, RADIOCHEMICAL PROBLEMS IN NUCLEAR WASTE MANAGEMENT
(NFC)............................................................................................................................................................................................s94
Lectures.........................................................................................................................................................................................s94
Posters.........................................................................................................................................................................................s107
3. NUCLEAR ANALYTICAL METHODS (NAM).......................................................................................................................s122
Lecture.........................................................................................................................................................................................s122
Posters.........................................................................................................................................................................................s137
4. CHEMISTRY OF ACTINIDE AND TRANS-ACTINIDE ELEMENTS (TAN).......................................................................s158
Lectures.......................................................................................................................................................................................s158
Posters.........................................................................................................................................................................................s164
5. RADIONUCLIDES IN THE ENVIRONMENT, RADIOECOLOGY (REG)............................................................................s172
Lectures.......................................................................................................................................................................................s172
Posters.........................................................................................................................................................................................s181
6. PRODUCTION AND APPLICATION OF RADIONUCLIDES (PAR)....................................................................................s198
Lectures.......................................................................................................................................................................................s198
Posters.........................................................................................................................................................................................s203
7. RADIATION CHEMISTRY (RCH)...........................................................................................................................................s206
Lectures.......................................................................................................................................................................................s206
Posters.........................................................................................................................................................................................s209
8. NUCLEAR METHODS IN MEDICINE, RADIOPHARMACEUTICALS AND DIAGNOSTICS, LABELLED COMPOUNDS
(RFD).....................................................................................................................................................................................................s212
Lectures.......................................................................................................................................................................................s212
Posters.........................................................................................................................................................................................s216
9. SEPARATION METHODS, SPECIATION (SEP).....................................................................................................................s222
Lectures.......................................................................................................................................................................................s222
Posters.........................................................................................................................................................................................s228
10. EDUCATION / COORDINATION (EDU)..............................................................................................................................s235
Lectures.......................................................................................................................................................................................s235
LIST OF CONTRIBUTIONS.........................................................................................................................................................s237
AUTHOR INDEX...........................................................................................................................................................................s253

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Chem. Listy 104, s74-s262 (2010) RadChem 2010 Programme at a Glance

PROGRAMME AT A GLANCE

Activity / Session Time Room
SUNDAY 18 th April
Registration 14:00-18:45 Foyer
Opening Ceremony & Welcoming Reception 19:00-20:30 Marble Hall
MONDAY 19 th April
Registration 07:30-18:45 Foyer
Plenary Session 1 08:30-10:00 Mirror Hall
Plenary Session 2 10:30-12:00 Mirror Hall
Lunch Marble Hall
Chemistry of Nuclear Fuel Cycle, Radiochemical Problems in Nuclear Waste Management 1 13:30-15:00 Red Hall
Nuclear Analytical Methods 1 13:30-15:00 Mirror Hall
Chemistry of Actinide and Trans-actinide Elements 1 15:30-17:00 Red Hall
Nuclear Analytical Methods 2 15:30-17:00 Mirror Hall
Poster Session – TAN, REG 17:15-18:45 Gallery
Concert 20:00-21:15 Marble Hall
TUESDAY 20 th April
Production and Application of Radionuclides 1 08:30-10:00 Red Hall
Radionuclides in the Environment, Radioecology 1 08:30-10:00 Mirror Hall
Production and Application of Radionuclides 2 10:30-12:00 Red Hall
Radionuclides in the Environment, Radioecology 2 10:30-12:00 Mirror Hall
Lunch Marble Hall
Chemistry of Nuclear Fuel Cycle, Radiochemical Problems in Nuclear Waste Management 2 13:30-15:00 Red Hall
Nuclear Analytical Methods 3 13:30-15:00 Mirror Hall
Chemistry of Nuclear Fuel Cycle, Radiochemical Problems in Nuclear Waste Management 3 15:30-17:00 Red Hall
Nuclear Analytical Methods 4 15:30-17:00 Mirror Hall
Poster Session – NAM, PAR 17:15-18:45 Gallery
Conference Dinner 19:30-23:50 Marble Hall
WEDNESDAY 21th April
Conference Excursions 09:00-21:30
THURSDAY 22th April
Chemistry of Actinide and Trans-actinide Elements 2 08:30-10:00 Red Hall
Radionuclides in the Environment, Radioecology 3 08:30-10:00 Mirror Hall
Radiation Chemistry 10:30-12:00 Red Hall
Radionuclides in the Environment, Radioecology 4 10:30-12:00 Mirror Hall
Lunch Marble Hall
Nuclear Methods in Medicine, Radiopharmaceuticals and Diagnostics, Labelled Compounds 1 13:30-15:00 Red Hall
Separation Methods, Speciation 1 13:30-15:00 Mirror Hall
Nuclear Methods in Medicine, Radiopharmaceuticals and Diagnostics, Labelled Compounds 2 15:30-17:00 Red Hall
Separation Methods, Speciation 2 15:30-17:00 Mirror Hall
Poster Session – NFC, EDU, RFD, RCH, SEP 17:15-18:45 Gallery
Singing Fountain Performance 21:00-21:30
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Chem. Listy 104, s75-s262 (2010) RadChem 2010 Programme at a Glance

FRIDAY 23 th April
Chemistry of Nuclear Fuel Cycle, Radiochemical Problems in Nuclear Waste Management 4 08:30-10:00 Red Hall
Nuclear Analytical Methods 5 08:30-10:00 Mirror Hall
Chemistry of Nuclear Fuel Cycle, Radiochemical Problems in Nuclear Waste Management 5 10:30-12:00 Red Hall
Nuclear Analytical Methods 6 10:30-12:00 Mirror Hall
Education / Coordination 13:30-14:30 Mirror Hall
Closing Ceremony 14:30-15:00 Mirror Hall

Coffee breaks : morning 10:00-10:20
afternoon 15:00-15:20

Topics abbreviations:
Plenary Session – PLN
Chemistry of Nuclear Fuel Cycle, Radiochemical Problems in Nuclear Waste Management - NFC
Nuclear Analytical Methods – NAM
Chemistry of Actinide and Trans–actinide Elements – TAN
Radionuclides in the Environment, Radioecology – REG
Production and Application of Radionuclides – PAR
Radiation Chemistry – RCH
Nuclear Methods in Medicine, Radiopharmaceuticals and Diagnostics, Labelled Compounds – RFD
Separation Methods, Speciation – SEP
Education / Coordination – EDU
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Chem. Listy 104, s76-s262 (2010) RadChem 2010 Programme of the Conference

PROGRAMME OF THE CONFERENCE

Sunday 18 April 2010
Registration (14:00-18:45)
Opening Ceremony & Welcoming Reception - MARBLE HALL (19:00-20:30)

Monday 19 April 2010
Reg Tolmachevistration (07:30-18:45)
Plenary Session 1 - MIRROR HALL (08:30-10:00) - Conveners: J. John, A. Chatt
08:30 PLN.L01 (Id: 122) Radiochemical analysis for the determination of radionuclides difficult to X. Hou
measure for characteristics and decommissioning of nuclear facilities
09:00 PLN.L02 (Id: 370) Speciation analysis of radionuclides in the environment B. Salbu
09:30 PLN.L03 (Id: 365) Accelerator Mass Spectrometry - from archaeology to astrophysics and W. Kutschera
human DNA
Plenary Session 2 - MIRROR HALL (10:30-12:00) - Conveners: W. Kutschera, B. Salbu
10:30 PLN.L04 (Id: 288) Chemistry of the transactinides J. V. Kratz
11:00 PLN.L05 (Id: 366) Electrochemical separation of actinides from molten LiCl-KCl on solid J. Glatz
Al cathodes
11:30 PLN.L06 (Id: 297) Radioactive and gastrin releasing peptide receptor specific gold nanopar- K. Katti
ticles in molecular imaging and therapy of cancer
Chemistry of Nuclear Fuel Cycle, Radiochemical Problems in Nuclear Waste Management 1 - RED HALL (13:30-15:00)
Conveners: J-P. Glatz, A. Vokál
13:30 NFC.L01 (Id: 92) Kinetics of reduction of hexavalent neptunium by nitrous acid in soluti- M. Precek
ons of nitric acid
13:45 NFC.L02 (Id: 164) Electro-fluid analysis of a molten-salt electrorefiner for pyrochemical K. R. Kim
nuclear waste treatment
14:00 NFC.L03 (Id: 295) Electrochemical separation of actinides from molten LiCl-KCl on solid P. Soucek
Al cathodes
14:15 NFC.L04 (Id: 279) Advanced ORIENT Cycle - progress on research, with focusing on safety S. Koyama
and engineering
14:30 NFC.L05 (Id: 191) Cobalt bis(dicarbollide) ions with covalently bonded TODGA-like sub- M. Lučaníková
stituents for actinide and lanthanide extractions
14:45 NFC.L06 (Id: 35) Extraction of radionuclides with solutions of complexing agents in super- M. Alyapyshev
critical fluids and compressed gases
Nuclear Analytical Methods 1 - MIRROR HALL (13:30-15:00) - Conveners: J. Kučera, F. De Corte
13:30 NAM.L01 (Id: 201) Simultaneous speciation analysis of arsenic, antimony and selenium in A. Chatt
natural waters by neutron activation coupled to HPLC, solvent extraction
and solid-phase extraction
14:00 NAM.L02 (Id: 211) NAA for life sciences at FLNP JINR: present and future M. Frontasyeva
14:15 NAM.L03 (Id: 190) Use of neutron activation analysis for the characterization of single-wall R. Zeisler
carbon nanotube materials
14:30 NAM.L04 (Id: 318) Determination of silicon in beer and beer processing materials by fast J. Kučera
neutron activation analysis. Is beer a possible protective factor in preven-
ting Alzheimer´s disease?
14:45 NAM.L05 (Id: 170) Total and bioaccessible fractions of trace elements in cultivated oyster M. Fukushima
tissues by INAA, PIXE and ICP-MS
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Chemistry of Actinide and Trans-actinide Elements 1 - RED HALL (15:30-17:00) - Conveners: L. Havela, A. Türler
15:30 TAN.L01 (Id: 286) New nucleus 277Hs: in between two islands of stability A. Türler
15:45 TAN.L02 (Id: 282) Chemical identification of element 114 at TASCA A. Yakushev
16:00 TAN.L03 (Id: 252) Independent verification of element 114 J. Dvorak
16:15 TAN.L04 (Id: 133) Element 114 chemistry and what is next? A. Serov
16:30 TAN.L05 (Id: 172) Vacuum thermochromatography - theory and Monte Carlo simulation I. Zvara
16:45 TAN.L06 (Id: 143) Gas phase chemical studies of superheavy elements using the Dubna D. Wittwer
Gas-Filled Recoil Separator - stopping range determination
Nuclear Analytical Methods 2 - MIRROR HALL (15:30-17:00) - Conveners: A. Chatt, M. Frontasyeva
15:30 NAM.L06 (Id: 181) Neutron and photon activation and ion beam techniques in geochemical J. Mizera
characterization of moldavites and other impact glasses
15:45 NAM.L07 (Id: 193) Development of a Radiochemical Neutron Activation Analysis Procedure R. Paul
for Determination of Arsenic in Biological Materials
16:00 NAM.L08 (Id: 225) NAA for studying detoxification of Cr and Hg by Arthrobacter globiformis M. Frontasyeva
16:15 NAM.L09 (Id: 368) Neutron activation analysis for assessment of beef origin E. A. De Nadai
Fernandes
16:30 NAM.L10 (Id: 210) Elemental concentrations in vegetable species from industrial zones in A. Pantelica
Romania determined by INAA
16:45 NAM.L11 (Id: 131) Selected trace elements in pottery of Guarani ethnic group J. F. Facetti-Masulli

Poster Session - Chemistry of Actinide and Trans-actinide Elements - GALLERY (17:15-18:45)
TAN.P01 (Id: 132) Thermochromatographic investigation of 113In, 125Sb and 125mTe in quartz A. Serov
columns
TAN.P02 (Id: 209) Application of coprecipitation for the study of chemistry of Rf N. Aksenov
TAN.P03 (Id: 212) Sorption of Ti, Zr, Hf and Nb, Ta as homologues of Rf and Db from N. Aksenov
mixed aqueous–organic HF solutions
TAN.P04 (Id: 15) Thermodynamic study on the U(VI) complexation with “aliphatic” and A. Kirishima
“aromatic” di-carboxylic acids by micro-calorimetry
TAN.P05 (Id: 64) A study of heterogeneous equilibria in the saturated aqueous solutions of O. Nipruk
uranoarsenates and uranophosphates of alkaline and alkaline-earth ele-
ments
TAN.P06 (Id: 78) Synthesis, structure and properties of synthetic trogerite (UO) (AsO4) . Y. Pykhova
23 2
2HO
2
TAN.P07 (Id: 147) Investigations on stability and structure of thorium colloids I. Dreissig
TAN.P08 (Id: 321) Structures of hydrated and hydrolyzed thorium(IV) determined by N. Torapava
EXAFS and LAXS
TAN.P09 (Id: 155) Electrochemical behaviour of curium in chloride melts A. Osipenko
TAN.P10 (Id: 156) Study of reaction of CmO+ and CmOCl formation in chloride melt by A. Osipenko
spectroscopic method
TAN.P11 (Id: 163) Kinetics of neptunium(V) conversion in strong nitric acid solutions, V. Chistyakov
containing potassium phosphotungstate , K10P2W17O61.
TAN.P12 (Id: 219) Electrochemical and spectroscopical investigation of uranium in room- A. Ölcer
temperature ionic liquids
TAN.P13 (Id: 220) Novel U(VI) Schiff base complexes: synthesis, structural characterizati- H. Tanh Jeazet
on, and extraction studies.
TAN.P14 (Id: 117) Production and investigation of thin films of metal actinides (Pu, Am, V. Radchenko
Cm, Bk, Cf)
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TAN.P15 (Id: 118) Radiographic examination of curium alloys with cobalt, iron, and carbon V. Radchenko
TAN.P16 (Id: 119) Formation of ruthenium alloys with curium and technetium V. Radchenko
TAN.P17 (Id: 139) Americium alloys with gold and copper V. Radchenko
TAN.P18 (Id: 272) High-resolution X ray study of electronic state of ions with non-stability N. A. Kulagin
nuclei in solids

Poster Session - Radionuclides in the Environment, Radioecology - GALLERY (17:15-18:45)
REG.P01 (Id: 8) Translocation of radioactivity from substrate to macromycetes in some K. Popa
mining areas
REG.P02 (Id: 14) Radioactivity in soils and horticulture products near old uranium mining F. P. Carvalho
and milling sites
REG.P03 (Id: 21) Methods and results of the main negative factors of KOSHKAR-ATA A. Nurmukhanbetova
tailing pond with impacts on environment
REG.P04 (Id: 29) Determination of cation exchange capacity of fucoidic sands for Cs+ and Š. Palágyi
Sr2+ under dynamic column conditions
REG.P05 (Id: 36) Origin of 129I in the environment of Slovenia A. Osterc
REG.P06 (Id: 37) Background level of radioactive isotopes around a L/ILW disposal facili- R. Janovics
ty before it started operation at Bátaapáti, Hungary
REG.P07 (Id: 38) Testing automatic groundwater sampling unit by the isotope analytical R. Janovics
and dissolved ion tests
REG.P08 (Id: 50) Radiocesium activity concentration measurements in game meat as a tool A. Grosicki
for monitoring radioactive contamination in wildlife and ensuring radio-
logical safety for consumers
REG.P09 (Id: 65) Determination of strontium-90 in foodstuff I. Lopes
REG.P10 (Id: 68) Age dating of the hot spring waters in Korea using natural radionuclides Y. Y. Yoon
REG.P11 (Id: 79) Use of selected chelating agents to mobilize radiocesium from the body A. Grosicki
REG.P12 (Id: 89) Speciation of 129I and 127I in seawater profiles from the Kattegat and V. Hansen
Baltic Sea
REG.P13 (Id: 93) Radiation monitoring method features of contamination fields whitch D. Manzon
getting older in landscape
REG.P14 (Id: 96) Distribution of natural radionuclides and 137Cs in the sediments of a H. Papaefthymiou
Mediterranean fjord-like embayment, Amvrakikos Gulf, Greece
REG.P15 (Id: 105) Natural radioactivity in Tunisian and in some exported phosphate fertili- F. Gharbi
zers used in Tunisia
REG.P16 (Id: 107) Further results in search of transuranium isotopes in effluents discharged Z. Hölgye
to air from nuclear power plants
REG.P17 (Id: 116) Radioecological situation in areas of uranium legacy of Uzbekistan A. Vasidov
REG.P18 (Id: 125) Study of 7Be concentration in the north of the Spain A. Natalia
REG.P19 (Id: 152) Radioactivity concentration in soil samples taken from region of Banja B. Štrbac
Luka (Bosnia and Herzegovina)
REG.P20 (Id: 158) Speciation of 129I and 127I in soil and sediment samples V. Hansen
REG.P21 (Id: 168) Cs, Pu and Am sorption to natural clay and their various components: G. Lujaniene
laboratory experiments and modeling
REG.P22 (Id: 188) Antropogenic radiotracers assessment as a tool to environmental compli- M. Nisti
ance rules and management
REG.P23 (Id: 202) Plutonium 241 - importance and ways of determination M. Bunata
REG.P24 (Id: 226) Uranium and long-lived decay products in water of the Mulde river S. Bister
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