11th International Congress on Catalysis - 40th Anniversary

741 Pages·1996·38.2 MB·English

Studies in Surface Science and Catalysis 101
11TH INTERNATIONAL CONGRESS ON CATALYSIS -
40TH ANNIVERSARY
This Page Intentionally Left Blank
Studies in Surface Science and Catalysis
Advisory Editors: B. Delrnon and J.T. Yates
Vol. 101
II TH INTERNATIONAL CONGRESS
ON CATALYSIS 40TH ANNIVERSARY
=
PART A
Proceedingso f the 1I th ICC, Baltimore, MD, USA, June 30 -July 5,1996
Editors
Joe W. Hightower
Department of Chemical Engheering, Rice University, Houston,
TX 7725 1- 1892, USA
W. Nicholas Delgass
School of Chemical Engineering, Purdue University, West Lafayette,
IN 47907,U SA
Enrique lglesia
Alexis T. Bell
Department of Chemical Engineering, University of California, Berkeley,
CA 94720-9989,U SA
1996
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V
TABLE OF CONTENTS
Part A
Preface
J.W. Hightower xix
Plenary Lectures
P- 1 Driving Forces for Innovation in Applied Catalysis
I.E. Maxwell 1
P-2 Constrained Geometry and Other Single Site Metallocene Polyolefin Catalysts:
A Revolution in Ole@ Polymerization
J.C. Stevens 11
P-3 Characterizationa nd Chemical Design of Oxide Surfaces
Y.I wasawa 21
P-4 Photocatalysis: State of the Art and Perspectives
K.I. Zamaraev 35
P-5 Towards Molecular Design of Solid Catalysts
A. Baiker 51
40th Anniversary Lectures
R- 1 A Retrospective View of Advances in Heterogeneous Catalysis: 1956-1996, Science
R.L. Bunvell, Jr. 63
R-2 A Retrospective View of Advances in Heterogeneous Catalysis: 1956-1996 Technology
H. Heinemann 69
Catalysis on Carbides, Nitrides, and Sulfides
A- 1 An Example of Novel Basic Catalysts: The Aluminophosphate Oxynitrides or
“AIPONs
”
A. Massinon, E. Gueguen, R. Conanec, R. Marchand, Y. Laurent, and P. Grange 77
The figures before the articles indicate the numbers used during the Conference
vi
A-2 Reaction Kinetics of the Hydrodenitrogenation of Decahydroquinoline over
NiMo(P)/AI,O, Catalysts
M. Jim and R. Prins 87
A-3 Effect of Spillover Hydrogen on Amorphous Hydrocracking Catalysts
A.M. Stumbo, P. Grange, and B. Delmon 97
A- 5 Hydrodesulfirization of Benzothiophene Catalyzed by Molybdenum Surfde Cluster
Encapsulated into 5eolites
M. Taniguchi, S. Yasuda, Y. Ishii, T. Murata, M. Hidai, and T. Tatsumi 107
A-6 Role of Adsorbed Hydrogen Species on Ruthenium and Molybdenum Suljdes.
Characterization by Inelastic Neutron Scattering, Thermoanalysis Methods and
Model Reactions
M. Lacroix, H. Jobic, C. Dumonteil, P. Afanasiev, M. Breysse, and S. Kasztelan 117
General Papers
A-7 Characterization of a Zeolite Membranef or Catalytic Membrane Reactor
Application
A. Giroir-Fendler, J. Peureux, H. Mouanega, and J.-A. Dalmon 127
A-8 Catalytic Reduction of SO, Stored in So, Transfer Catalysts -A Temperature-
Programmed Reaction Study
G. Kim and M.V. Juskelis 137
A-9 Effect of Tunnel Structures of BaTi,O, and Na,Ti,O,, on Photocatalytic Activity and
Photoexcited Charge Separation
M. Kohno, S. Ogura, K. Sato, and Y. Inoue 143
A-10 Organochromium Complexes in Homogeneous Olejn Polymerization
G. Bhandari, J.L. Kersten, R.R. Kucharczyk, P.A. White, Y. Liang, and
K.H. Theopold 153
Synthesis of Fine Chemicals
A-1 1 Selective Catalytic Oxidation with Air of Glycerol and Oxygenated Derivatives on
Platinum Metals
P. Fordham, R. Garcia, M. Besson, and P. Gallezot 161
A-I2 Selective Methylation of Catechol: Catalyst Development and Characterisation
L. Kiwi-Minsker, S. Porchet, P. Moeckli, R. Doepper, and A. Renken 171
A-I3 Selective Oxidation with Copper Complexes incorporated in Molecular Sieves
R. Raja and P. Ratnasamy 181
A- 14 Discovering the Role of Au and KOAc in the Catalysis of Vinyl Acetate Synthesis
W.D. Provine, P.L. Mills, and J.J. Lerou 191
vii
A-15 Formation of Citraconic Anhydride by Vapor-Phase Decarboxy-Condensation
of Pyruvic Acid
M. Ai and K. Ohdan 201
A-16 Heterogeneous Enantioselective Dehydration of Butan-2-01
S. Feast, D. Bethell, P.C.B. Page, M.R.H. Siddiqui, D.J. Willock, G.J. Hutchings,
F. King, and C.H. Rochester 21 1
A-17 Enantioselective Hydrogenation Catalysed by Palladium
T.J. Hall, P. Johnston, W.A.H. Vermeer, S.R. Watson, and P.B. Wells 22 1
A-18 Stereochemical Studies of the Enantio-diferentiating Hydrogenation of Various
Prochiral Ketones over Tartaric Acid-Mod$ed Nickel Catalyst
T. Sugimura, T. Osawa, S. Nakagawa, T. Harada, and A. Tai 23 1
A-19 Enantio-diflerentiation over Heterogeneous Catalysts. The Shielding Eflect Model
J.L. Margitfalvi, M. Hegedus, and E. Tfirst 24 1
A-20 Racemization of (IS)-(-)-exo-2,4-Dideuteroapopineneo ver Pd: Evidence
for an Intramolecular I,3-Deuterium Shij
G.V.S mith, B. Rihter, A. Zsigmond, F. Notheisz, and M. Bartok 25 1
A-2 1 Fe/MgO Catalysts for the Selective Hydrogenation of Nitriles
G. Bond and F.S. Stone 257
A-22 Selective Synthesis of Ethylenediaminef rom Ethanolamine over Modified
H-Mordenite Catalyst
K. Segawa, S. Mizuno, M. Sugiura, and S. Nakata 267
A-23 Competitive Reaction Pathways in Propane Ammoxidation over V-Sb-Oxide
Catalysts: An IR and Flow Reactor Study
G. Centi and F. Marchi 277
Research on Model Catalysts
A-25 ‘Seeing’t he Active Site in Catalysis. STM and Molecular Beam Studies of
Surface Reactions
M. Bowker 287
A-26 Catalytic Formation of Carbon-Carbon Bonds in Ultrahigh Vacuum:
Cyclotrimerization of Alkynes on Reduced TiO, Surfaces
K.G.P ierce, V.S.L usvardi, and M.A. Barteau 297
A-27 A New Approach to Understanding the Rochow Process: Synthesis of
Methylchlorosilanesfrom CH, + C1 Monolayers on Cu,Si in Vacuum
D.-H. Sun, A.B. Gurevich, L.J. Kaufman, B.E. Bent, A.P. Wright, and B.M. Naasz 307
A-28 Ruthenium as Catalystf or Ammonia Synthesis
M. Muhler, F. Rosowski, 0. Hinrichsen, A. Homung, and G. Ertl 317
viii
A-29 Surface-Structure-Dependent Reaction Pathways of Methyl Groups on Ni(lO0) and
Ni(ll1) Surfaces
R.B. Hall, M. Castro, C.M. Kim, and C.A. Mims 327
A-3 0 Normalization by oxygen Uptake of the Rates of Oxidative Dehydrogenation of
Methanol and Ethanol
S. Tanabe, H.E. Davis, Jr., D. Wei, and R.S. Weber 337
Environmental Catalysis
A-3 1 Some Evidences of a Bifunctional Mechanismf or the Reduction of NO on Pd Based
Catalysts
H. Praliaud, A. Lemaire, J. Massardier, M. Prigent, and G. Mabilon 345
A-32 Characterization of Pd-based Automotive Catalysts
R.W. McCabe and R.K. Usmen 355
A-33 Process Development for the Selective Hydrogenolysis of CCIF, (CFC-12) into
CHZF2 (HFC-32)
A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, H. van Bekkum, and J.A. Moulijn 369
A-34 Catalytic Fluorination over Chromium Oxides. Preparation of Hydrofluorocarbons
S. Brunet, B. Boussand, and J. Barrault 3 79
Oxidation of Methane
A-35 Oxidative Coupling of Methane to Ethylene with 85% Yield in a Gas Recycle
Electrocatalytic or Catalytic Reactor-Separator
M. Makri, Y.J iang, I.V. Yentekakis, and C.G. Vayenas 3 87
A-36 The Active wgenf or Direct Oxidation of Methane to Methanol in the
Presence of Hydrogen
Y.W ang and K. Otsuka 397
A-37 Photocatalytic Production of Methanol and Hydrogenf rom Methane and Water
C.E. Taylor, R.P. Noceti, J.R. D’Este, and D.V. Martello 407
Oxidation Catalysis
A-38 Role of A- and B-Cations in Catalytic Property of Substituted Hexaaluminate
(ABAI,,O,, a) for High Temperature Combustion
K. Eguchi, H. Inoue, K. Sekizawa, and H. Arai 417
A-39 AdMetal Oxidesf or Low Temperature CO Oxidation
G. Srinivas, J. Wright, C.-S. Bai, and R. Cook 427
A-40 Photocatalytic Oxidation of Air Contaminants by Chlorine (CL!o)r Hydroxyl (OH)
Radicals or Holes @+): Mechanistic Correlations
0.d ’Hennezel and D.F. Ollis 43 5
ix
A-4 1 Partial Oxidation of Methane to Synthesis Gas over Ru/TiO, Catalysts
Y. Boucouvalas, Z.L. Zhang, A.M. Efstathiou, and X.E. Verykios 443
A-42 The Oxidative Transformation of Methane over the Nickel-Based Catalysts
Modified by Alkali Metal Oxide and Rare Earth Metal Oxide
Q. Miao, G. Xiong, S. Sheng, W. Cui, and X. Guo 453
A-43 Design of Stable Catalysts for Methane-Carbon Dioxide Reforming
J.A. Lercher, J.H. Bitter, W. Hally, W. Niessen, and K. Seshan 463
A-44 Comparison of Perovskite and Hexaaluminate-type Catalysts for CO/H,-fieled
Gas Turbine Combustors
C. Cristiani, G. Groppi, P. Forzatti, E. Tronconi, G. Busca, and M. Daturi 473
A-45 Hydrocarbon Activation and Oxidation on Transition Metal Mixed Oxides.
Ft-IR and Flow Reactor Studies
E. Finocchio, R.J. Willey, G. Ramis, G. Busca, and V. Lorenzelli 483
A-46 Biomimetic Oxidation on Fe Complexes in Zeolites
(3.1. Panov, V.I. Sobolev, K.A. Dubkov, and AS. Kharitonov 493
A-4 A Molecular Approach to Synergy Generation in Co-Mo Binary Sulfide Catalysi‘s
for Hydrodesulfirization
Y. Okamoto and H. Katsuyama 503
A-24 Electrochemical Promotion of NO Reduction by CO and by Propene
A. Palermo, M.S. Tikhov,N.C. Filkin, R.M. Lambert, I.V. Yentekakis, and
C.G. Vayenas 5 13
Catalysis on Acids and Bases
B- 1 Promotion of Molecular Hydrogen on Solid Acid Cracking Activity
T. Shishido, T. Nagase, K. Higo, J. Tsuji, and H. Hattori 523
B-2 Selective Isomerization of Alkanes on Supported Tungsten Oxide Acids
E. Iglesia, D.G. Barton, S.L. Soled, S. Miseo, J.E. Baumgartner, W.E. Gates,
G.A. Fuentes, and G.D. Meitzner 533
B-3 Tungsta and Platinum-Tungsta Supported on Zirconia Catalysts for Alkane
Isomerization
G. Larsen, E. Lotero, and R.D. Parra 543
B-4 n-Butane Isomerization on Ni-promoted Sulfated Zirconia Catalysts
W.E. Alvarez, H. Liu, E.A. Garcia, E.H. Rueda, A.J. Rouco, and D.E. Resasco 553
B-5 Rare Earth Modified Silica-Aluminas as Supports for Bifunctional Catalysis
S.L. Soled, G. McVicker, S. Miseo, W. Gates, and J. Baumgartner 563
B-6 What NMR Has Told Us about Solid Acidity
J.F. Haw and J.B. Nicholas 573