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Rogalla Physics Kes 100 Years of superconductivitY Edited by Horst Rogalla and Peter H. Kes Even a hundred years after its discovery, superconductivity continues to bring us new surprises, from superconducting magnets used in MRI to quantum detectors s1 in electronics. 100 Years of Superconductivity presents a comprehensive 100 Years of collection of topics on nearly all the subdisciplines of superconductivity. Tracing 0 u the historical developments in superconductivity, the book includes contributions from many pioneers who are responsible for important steps forward in the field. superconductivitY 0 p The text first discusses interesting stories of the discovery and gradual progress e of theory and experimentation. Emphasizing key developments in the early 1950s Y and 1960s, the book looks at how superconductivity started to permeate society r e and how most of today’s applications are based on the innovations of those c years. It also explores the genuine revolution that occurred with the discovery of a high temperature superconductors, leading to emerging applications in power o storage and fusion reactors. r n Features s • Reviews the history of superconductivity, from the early years to the d experimental and theoretical progress in the 1950s and 1960s to the o use of magnets in high energy physics and electronics in astronomy u • Includes contributions from those responsible for important steps f forward in the field or who have worked closely with these leaders c • Covers superconductor materials, including cuprates, Fe-pnictides, Fe- chalcogenides, magnesium diboride, and strontium ruthenate t • Describes applications of superconductors in mineral exploration, i nondestructive testing, quantum computing, digital electronics, space v telescopes, MEG, MRI, NMR, and much more • Provides numerous figures, some in color, as well as further readings i in each chapter t Superconductivity has become a vast field and this full-color book shows how Y far it has come in the past 100 years. Along with reviewing significant research and experiments, leading scientists share their insight and experiences working in this exciting and evolving area. K12240 Edited by ISBN: 978-1-4398-4946-0 90000 Horst Rogalla Peter H. Kes 9 781439 849460 K12240_COVER_final.indd 1 9/12/11 3:22 PM 100 Years of superconductivitY TThhiiss ppaaggee iinntteennttiioonnaallllyy lleefftt bbllaannkk 100 Years of superconductivitY Edited by Horst Rogalla and Peter H. Kes CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2012 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20110811 International Standard Book Number-13: 978-1-4398-4948-4 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the valid- ity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or uti- lized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopy- ing, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copyright.com (http:// www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com Contents Preface xvii ListofAuthors xix Glossary xxv 1 EarlyHistory 1 Editor:PeterH.Kes 1.1 TheDiscoveryandEarlyHistoryofSuperconductivity Rudolf de Bruyn Ouboter, Dirk van Delft and Peter H. Kes . . . . . . . . . 1 1.1.1 TheRealStory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.1.2 ElementalSuperconductors . . . . . . . . . . . . . . . . . . . . . . . . . . 15 1.1.3 SuperconductiveAlloys,theSpongyRoadtoTypeIISuperconductors. . . 24 1.2 TheHistoricalContextofJosephson’sDiscovery A. B. Pippard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 1.3 FurtherReading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 2 Theory 51 Editor:JanZaanen 2.1 Ginzburg–LandauEquations V. M. Vinokur and T. I. Baturina . . . . . . . . . . . . . . . . . . . . . . . . 51 2.1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 2.1.2 AHistory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 2.1.3 TheEquation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 2.1.4 ConsequencesandApplications . . . . . . . . . . . . . . . . . . . . . . . 58 2.1.5 Conclusion:Strings,theUniverse,andAlltheRest... . . . . . . . . . . . . 64 2.2 TheEmergenceofBCS David Pines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 2.2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 2.2.2 AWelcomingEnvironment . . . . . . . . . . . . . . . . . . . . . . . . . . 65 2.2.3 StartingWorkwithBardeen . . . . . . . . . . . . . . . . . . . . . . . . . 66 2.2.4 PolaronTheory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 2.2.5 EffectiveElectronInteractionsinMetals . . . . . . . . . . . . . . . . . . . 67 2.2.6 Cooper’sPairInstability . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 2.2.7 SeattleandStockholm . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 2.2.8 TheSchriefferWave-Function . . . . . . . . . . . . . . . . . . . . . . . . 70 2.2.9 Deciphering,Teaching,andApplyingBCS . . . . . . . . . . . . . . . . . 70 2.2.10 BCSTheory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71 2.3 TheoryofSuperconductivity:FromPhenomenologytoMicroscopicTheory Lev P. Gor’kov . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 2.3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 2.3.2 EarlyDays . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 2.3.3 The1950s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 v vi 100YearsofSuperconductivity 2.3.4 MicroscopicTheory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 2.3.5 InsteadofConclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 2.4 AModern,butWayTooShortHistoryoftheTheoryofSuperconductivityataHigh Temperature Jan Zaanen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92 2.4.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92 2.4.2 PushingBCStotheLimits:TheSpinFluctuationSuperglue . . . . . . . . 94 2.4.3 TheLegacyofPhilipW.Anderson(I):Mottness . . . . . . . . . . . . . . 99 2.4.4 The Legacy of Philip W. Anderson (II): Resonating Valence Bonds and TheirDescendants . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 2.4.5 TheorythatWorks:TheCompetingOrdersofthePseudogapRegime . . . 106 2.4.6 QuantumCriticalMetalsandSuperconductivity . . . . . . . . . . . . . . . 110 2.5 IntrinsicJosephsonEffectinLayeredSuperconductors L. N. Bulaevskii and A.E. Koshelev . . . . . . . . . . . . . . . . . . . . . . . 115 2.5.1 Introduction:LayeredSuperconductorsandLawrence-DoniachModel . . . 115 2.5.2 VortexMatterinLayeredSuperconductors. . . . . . . . . . . . . . . . . . 118 2.5.3 JosephsonPlasmaResonance. . . . . . . . . . . . . . . . . . . . . . . . . 122 2.5.4 RadiationfromIntrinsicJosephsonJunctions . . . . . . . . . . . . . . . . 124 2.6 MixedStateProperties Ernst Helmut Brandt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 2.6.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 2.6.2 Abrikosov’sPeriodicVortexLatticeNearB . . . . . . . . . . . . . . . . 126 c2 2.6.3 DistortedVortexLatticeandVacancyNearB . . . . . . . . . . . . . . . 127 c2 2.6.4 NonlocalElasticityoftheVortexLattice . . . . . . . . . . . . . . . . . . . 129 2.6.5 VortexArrangementsatLowInductions . . . . . . . . . . . . . . . . . . . 131 2.6.6 VortexLatticeSolutionforAllκandB¯ . . . . . . . . . . . . . . . . . . . . 132 2.6.7 VortexMotion,Pinning,andThermalDepinning . . . . . . . . . . . . . . 135 2.6.8 AnisotropicSuperconductors . . . . . . . . . . . . . . . . . . . . . . . . . 136 2.7 ThermomagneticEffectsintheMixedState R. P. Huebener . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137 3 Experiments 145 Editor:J.Mannhart 3.1 TunnelingandtheJosephsonEffect John M. Rowell . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 3.1.1 TheJosephsonEffect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 3.2 TheDiscoveryofFluxoidQuantization Dietrich Einzel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161 3.2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161 3.2.2 TheoreticalFoundations . . . . . . . . . . . . . . . . . . . . . . . . . . . 162 3.2.3 TheDoll-Na¨bauerExperiment . . . . . . . . . . . . . . . . . . . . . . . . 163 3.2.4 TheDeaver-FairbankExperiment . . . . . . . . . . . . . . . . . . . . . . 165 3.2.5 TheIBMConference1961 . . . . . . . . . . . . . . . . . . . . . . . . . . 167 3.2.6 Post-1961 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168 3.2.7 SummaryandConclusion . . . . . . . . . . . . . . . . . . . . . . . . . . 169 3.3 TheSearchforthePairingSymmetryintheHighTemperatureSuperconductors Dale J. Van Harlingen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 3.3.1 WhytheSymmetryIsImportant . . . . . . . . . . . . . . . . . . . . . . . 171 3.3.2 DeterminingtheSymmetry . . . . . . . . . . . . . . . . . . . . . . . . . . 171 3.3.3 Samples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 173 3.3.4 Parity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 TableofContents vii 3.3.5 PenetrationDepth . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 3.3.6 ARPES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175 3.3.7 JosephsonInterferometry . . . . . . . . . . . . . . . . . . . . . . . . . . . 177 3.3.8 Beyondd-WaveSymmetry . . . . . . . . . . . . . . . . . . . . . . . . . . 182 3.4 Half-IntegerFluxQuantizationinUnconventionalSuperconductors C. C. Tsuei and J. R. Kirtley . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 3.4.1 TheDesignoftheTricrystalExperiments . . . . . . . . . . . . . . . . . . 183 3.4.2 DirectObservationoftheHalfFluxQuantization . . . . . . . . . . . . . . 187 3.4.3 ElucidationoftheNatureofHalfFluxQuantumEffect . . . . . . . . . . . 191 3.4.4 Universalityofthed PairState . . . . . . . . . . . . . . . . . . . . . 192 x2−y2 3.4.5 Large-ScaleArraysoftheHalfFluxVortices . . . . . . . . . . . . . . . . 194 3.4.6 ConcludingRemarks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 196 3.5 ElectricFieldEffectTuningofSuperconductivity Jean-Marc Triscone and Marc Gabay . . . . . . . . . . . . . . . . . . . . . . 197 3.5.1 Preamble . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 3.5.2 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 3.5.3 ElectricFieldEffectinComplexOxides . . . . . . . . . . . . . . . . . . . 197 3.5.4 ElectricFieldEffectinSuperconductors:PhysicsandLengthscales . . . . . 199 3.5.5 ThomasFermiScreeningandInterfaceQuality . . . . . . . . . . . . . . . 201 3.5.6 FieldEffectSetupsinaNutshell . . . . . . . . . . . . . . . . . . . . . . . 201 3.5.7 What’sNew? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203 3.5.8 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206 3.6 TheGrainBoundaryProblemofHigh-T Superconductors c J. Mannhart and D. Dimos . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206 3.7 OverviewoftheExperimentalHistory,StatusandProspectsofHTS M. R. Beasley . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213 3.7.1 TheAllureofHighTemperatureSuperconductivity . . . . . . . . . . . . . 213 3.7.2 TheBroadSweepofHistory . . . . . . . . . . . . . . . . . . . . . . . . . 213 3.7.3 FromOnnestoBednorzandMueller . . . . . . . . . . . . . . . . . . . . 215 3.7.4 AfterBednorzandMueller . . . . . . . . . . . . . . . . . . . . . . . . . . 218 3.7.5 ProspectsforHigherTemperatureSuperconductors . . . . . . . . . . . . . 219 3.8 VortexMatterinAnisotropicSuperconductors Eli Zeldov . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222 3.8.1 LocalMagnetizationandGeometricalBarriers . . . . . . . . . . . . . . . 223 3.8.2 VortexLatticeMelting . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225 3.8.3 VortexMatterPhaseDiagram . . . . . . . . . . . . . . . . . . . . . . . . 228 3.9 FurtherReading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231 4 Materials 233 Editor:C.W.Chu 4.1 Introduction C. W. Chu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 4.2 TheRoutetoHighTemperatureSuperconductivityinTransitionMetalOxides A. Bussmann-Holder and K. A. Mu¨ller . . . . . . . . . . . . . . . . . . . . . 234 4.3 Superconductivityabove10KinNon-CuprateOxides David C. Johnston . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 239 4.3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 239 4.3.2 LiTi O . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240 2 4 4.3.3 Ba(Pb Bi )O . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 242 1−x x 3 4.3.4 (Ba K )BiO . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 244 1−x x 3 4.4 Cuprates—SuperconductorswithaT upto164K c viii 100YearsofSuperconductivity C. W. Chu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 244 4.4.1 RBa Cu O . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 245 2 3 7 4.4.2 Bi2Sr2Can−1CunO2n+4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 250 4.4.3 Tl2Ba2Can−1CunO2n+4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252 4.4.4 HgBa2Can−1CunO2n+3−δ . . . . . . . . . . . . . . . . . . . . . . . . . . . 253 4.5 Fe-Pnictidesand-Chalcogenides Hideo Hosono . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 255 4.5.1 ResearchLedtoDiscoveryofIron-BasedSuperconductors . . . . . . . . . 255 4.5.2 DiscoveryofIron-basedSuperconductors . . . . . . . . . . . . . . . . . . 257 4.5.3 AdvancesinMaterials . . . . . . . . . . . . . . . . . . . . . . . . . . . . 260 4.5.4 CurrentStatus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 262 4.5.5 Perspective . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263 4.6 SuperconductivityinMgB 2 Takahiro Muranaka and Jun Akimitsu . . . . . . . . . . . . . . . . . . . . . . 265 4.6.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 265 4.6.2 CrystalStructureofMgB . . . . . . . . . . . . . . . . . . . . . . . . . . 266 2 4.6.3 ElectronicStructureofMgB . . . . . . . . . . . . . . . . . . . . . . . . . 268 2 4.6.4 Two-gapSuperconductingStateofMgB . . . . . . . . . . . . . . . . . . 270 2 4.6.5 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271 4.7 Fullerenes Kosmas Prassides and Matthew J. Rosseinsky . . . . . . . . . . . . . . . . . 272 4.7.1 AlkaliFullerideSuperconductors. . . . . . . . . . . . . . . . . . . . . . . 272 4.7.2 FullerideswithIncreasedInterfullereneSeparations . . . . . . . . . . . . . 274 4.7.3 Cs C —FullereneSuperconductivityReborn . . . . . . . . . . . . . . . . 275 3 60 4.8 ElementalSuperconductors K. Shimizu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 278 4.8.1 PeriodicTableforSuperconductingElements . . . . . . . . . . . . . . . . 279 4.8.2 ExperimentalTechnique . . . . . . . . . . . . . . . . . . . . . . . . . . . 280 4.8.3 ExampleofPressure-InducedSuperconductivityinElements . . . . . . . . 280 4.8.4 Summary:3DPeriodicTableforSuperconductingElements . . . . . . . . 282 4.9 Heavy-FermionSuperconductivity F. Steglich . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 283 4.10 RuthenateSuperconductorSr RuO 2 4 Yoshiteru Maeno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 288 4.10.1 SameCrystalStructurebutDifferentUnconventionalSuperconductivity . . 290 4.10.2 NovelSuperconductingPhenomena . . . . . . . . . . . . . . . . . . . . . 292 4.11 Magnetic Superconductors (and Some Recollections of Professor Bernd T. Matthias) M. Brian Maple . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293 4.11.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293 4.11.2 LocalizedMagneticMomentsinConventionalSuperconductors . . . . . . 294 4.11.3 CoexistenceofSuperconductivityandMagneticOrderInvolvingtheSame SetofElectrons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 299 4.11.4 SomeThoughtsaboutHighTemperatureSuperconductors . . . . . . . . . 304 4.11.5 SomePersonalRecollectionsofProfessorBerndT.Matthias . . . . . . . . 305 4.12 FurtherReading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 307 5 SQUIDsandDetectors 311 Editor:A.I.Braginski 5.1 Introduction John Clarke, Arnold Silver and A. I. Braginski . . . . . . . . . . . . . . . . . 311 TableofContents ix 5.2 HistoryandDeviceFundamentals John Clarke and Arnold Silver . . . . . . . . . . . . . . . . . . . . . . . . . . 313 5.2.1 InitialDiscovery . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 313 5.2.2 Thin-FilmJosephsonTunnel-JunctionQuantumInterferometer . . . . . . . 315 5.2.3 PointContactDevices—dcSQUID . . . . . . . . . . . . . . . . . . . . . 317 5.2.4 TherfSQUID . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 318 5.2.5 LinearSQUIDResponseandSingleFluxQuantumTransitions . . . . . . . 320 5.2.6 R-SQUID,OscillatorsandDetectors . . . . . . . . . . . . . . . . . . . . . 320 5.2.7 SLUGsatCambridge . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321 5.2.8 SQUIDsatBerkeley . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 324 5.2.9 TheSquareWasherSQUID . . . . . . . . . . . . . . . . . . . . . . . . . 326 5.2.10 TherfSQUIDRevisited . . . . . . . . . . . . . . . . . . . . . . . . . . . 327 5.2.11 Today’sSQUIDs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327 5.3 High-T SQUIDs c A. I. Braginski . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 328 5.3.1 PastandPresent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 328 5.3.2 High-T SQUIDLimitsofPerformance . . . . . . . . . . . . . . . . . . . 330 c 5.4 GeophysicalApplicationsofSQUIDs C. P. Foley . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 331 5.4.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 331 5.4.2 MagneticMeasurementsUsedinGeophysicalProspecting . . . . . . . . . 332 5.4.3 EarlySQUIDsinGeophysicalProspecting. . . . . . . . . . . . . . . . . . 333 5.4.4 TransientElectroMagneticsUsingHigh-T SQUIDs . . . . . . . . . . . . 335 c 5.4.5 TensorGradiometry. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 338 5.4.6 LaboratorySystems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 339 5.4.7 FinalComments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 340 5.5 ApplicationtoNondestructiveEvaluationofMaterialsandStructures A. I. Braginski . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 342 5.5.1 PastandPresent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 342 5.5.2 NDETestingMethodsUsingSQUIDs . . . . . . . . . . . . . . . . . . . . 344 5.5.3 BridgeTesting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 344 5.5.4 AirplaneTesting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 346 5.5.5 TwoExamplesofSQUIDNDENowintheField . . . . . . . . . . . . . . 346 5.5.6 SQUIDNDEMicroscopyinSemiconductorTechnology . . . . . . . . . . 348 5.5.7 ConcludingRemark. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349 5.6 SQUIDs—fromLaboratoryDevicestoCommercialProducts Ronald E. Sager . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349 5.6.1 EarlySQUIDsasLaboratoryDevices . . . . . . . . . . . . . . . . . . . . 349 5.6.2 FirstCommercializationofSQUIDs . . . . . . . . . . . . . . . . . . . . . 350 5.6.3 SHE—EarlySQUIDInstrumentation . . . . . . . . . . . . . . . . . . . . 351 5.6.4 QuantumDesign—AdvancedSQUIDInstruments . . . . . . . . . . . . . 353 5.6.5 TheMarketforSQUID-basedInstrumentsToday . . . . . . . . . . . . . . 356 5.6.6 FutureDirectionsforSQUIDsinLaboratoryInstrumentation . . . . . . . . 356 5.7 ElectromagneticandParticleDetectionandReadout John Clarke, Kent Irwin and Peter Michelson . . . . . . . . . . . . . . . . . 358 5.7.1 DCSQUIDAmplifiers . . . . . . . . . . . . . . . . . . . . . . . . . . . . 358 5.7.2 TransitionEdgeSensors . . . . . . . . . . . . . . . . . . . . . . . . . . . 361 5.7.3 PhotonEnergyResolvingDetectors . . . . . . . . . . . . . . . . . . . . . 362 5.7.4 X-RayAstronomyandMaterialsAnalysis . . . . . . . . . . . . . . . . . . 363 5.7.5 DarkEnergyandColdDarkMatter . . . . . . . . . . . . . . . . . . . . . 364 5.7.6 DarkEnergy:SearchingforGalaxyClusters . . . . . . . . . . . . . . . . . 366

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