ZnO Nanocrystals and Allied Materials PDF
Preview ZnO Nanocrystals and Allied Materials
Springer Series in Materials Science 180 M. S. Ramachandra Rao Tatsuo Okada Editors ZnO Nanocrystals and Allied Materials Springer Series in Materials Science Volume 180 Series Editors Robert Hull, Charlottesville, VA, USA Chennupati Jagadish, Canberra, ACT, Australia Richard M. Osgood, New York, NY, USA Jürgen Parisi, Oldenburg, Germany Zhiming M. Wang, Chengdu, P.R. China For furthervolumes: http://www.springer.com/series/856 The Springer Series in Materials Science covers the complete spectrum of materialsphysics,includingfundamentalprinciples,physicalproperties,materials theory and design. Recognizing the increasing importance of materials science in future device technologies, the book titles in this series reflect the state-of-the-art in understanding and controlling the structure and properties of all important classes of materials. M. S. Ramachandra Rao Tatsuo Okada Editors ZnO Nanocrystals and Allied Materials 123 Editors M.S. RamachandraRao TatsuoOkada Department of Physics Department of ElectricalEngineering Indian Instituteof TechnologyMadras Kyushu University Chennai Fukuoka TamilNadu Japan India ISSN 0933-033X ISSN 2196-2812 (electronic) ISBN 978-81-322-1159-4 ISBN 978-81-322-1160-0 (eBook) DOI 10.1007/978-81-322-1160-0 SpringerNewDelhiHeidelbergNewYorkDordrechtLondon LibraryofCongressControlNumber:2013945152 (cid:2)SpringerIndia2014 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpartof the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation,broadcasting,reproductiononmicrofilmsorinanyotherphysicalway,andtransmissionor informationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodology now known or hereafter developed. Exempted from this legal reservation are brief excerpts in connection with reviews or scholarly analysis or material supplied specifically for the purposeofbeingenteredandexecutedonacomputersystem,forexclusiveusebythepurchaserofthe work. Duplication of this publication or parts thereof is permitted only under the provisions of theCopyright Law of the Publisher’s location, in its current version, and permission for use must always be obtained from Springer. Permissions for use may be obtained through RightsLink at the CopyrightClearanceCenter.ViolationsareliabletoprosecutionundertherespectiveCopyrightLaw. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexempt fromtherelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. While the advice and information in this book are believed to be true and accurate at the date of publication,neithertheauthorsnortheeditorsnorthepublishercanacceptanylegalresponsibilityfor anyerrorsoromissionsthatmaybemade.Thepublishermakesnowarranty,expressorimplied,with respecttothematerialcontainedherein. Printedonacid-freepaper SpringerispartofSpringerScience+BusinessMedia(www.springer.com) Foreword Newopportunitiesareopeningupforinnovativematerialsresearchacrossphysics, electrical sciences, chemistry, surface science, and nanotechnology. Keeping in line with this, the Department of Physics at IIT Madras organized a two-day workshoponZnOnanocrystalsandalliedmaterials.Thistwo-dayconferencewas conducted by Indian collaborators from IIT Madras and Japanese collaborators fromKyushuUniversity,Japan.ResearchersfromtheacademicworldofIndiaand JapanpresentedtheirrecentresultsonthedevelopmentofnanostructuredZnOand allied materials and their applications in key areas of Applied Physics and Elec- tricalEngineering.Theworkpresentedbyalltheexpertsduringtheworkshophas been compiled into this book form with carefully written contributory articles. This book thus presents complete articles summarizing 17 invited talks and con- tributions. It is well complemented by research work from various scientists well known in the field of ZnO and Allied Materials. Progress in the nano-research based on ZnO, during the last decade, has been very fast. Various research programs have been renewed and revisited and efforts are on to remove the deadlocks with the help of accurate research on ZnO nanostructuresandappliedmaterialsforroutineuseinindustryworldwide.Itwas therefore considered timely to organize an Indo–Japan workshop. It takes a good collaborativeefforttounderstandandexplorethevariedphysicalpropertiesandto envisage device applications of ZnO in thin films, heterostructures, and nano- structures.ZnOhasbeenthecentralthemeofresearchinthepastdecadeduetoits potentialasUV/bluelightemittingdiodematerialthatcanreplaceGaNifonlythe p-type doping problem is resolved. In nanostructured form, it offers ample opportunities to realize tunable optical and optoelectronic properties and it was also termed as a potential material to realize room temperature ferromagnetism. ZnOcanbeeasilydepositedinhighqualitythinfilmformbysputtering,CVD,and laserablationmethodsatlowtemperatures.Itcanbeeasilyfabricatedintodevices anditslatticeisamenableto3dand4felementdoping.ZnOisbiocompatibleand exhibitsmanyinterestingapplicationsintextileandbiomedicalindustries.Doping in ZnO can bring about changes in optical emissivity and by virtue of controlling theoxygenvacancies,ZnOlatticecanbeusedforlightemissioninawidespectral range. Al doped ZnO competes well with ITO for easy fabrication of conducting v vi Foreword backelectrodesforsolarcells.ZnOquantumdotsopennewtechnologicalavenues forthefabricationofphotoniccrystallattices.ZnOheterostructurescanplayakey role in band gap engineering. Alloys of MgZnO are useful in tuneable band gap systems and many of its allied material systems can be used in gas sensing applications. The fundamental challenge, however, remains the same: more stable p-type ZnO and itsapplication tolarger systems,andaccesstonew materials properties. Responding to these challenges will require substantial effort at various levels. Beingtheworkshoporganizersandeditorsofthisbook,wewouldliketothank all the contributors (especially those who accepted the burden of writing full chapter articles) and the members of the Advisory Board for helping to organize suchaneffectiveprogram.Wearesurethatthisbookwithanassortmentofarticles will be quite useful for researchers in this area. M. S. Ramachandra Rao Tatsuo Okada Preface Functional nanostructures are attracting much interest for use in sensing, energy harvesting, and flexible electronics. ZnO is a versatile material system that offers potentialapplicationsinhighpowerandhightemperatureelectronics,UV/Visible light emitting diodes for domestic lighting, and in colour displays. Due to its radiation hardness property, it also finds application in radiation hard transistors for high temperature sensors and spaceflight instrumentation. There have been many recent advances in this field, concerning nanostructure synthesis. ZnO has alsobeenreportedasanactivechannelmaterialforthin-filmtransistorsbecauseof its high electron mobility even for room temperature deposition in ZnO (as the semiconducting active layer)-based field effect transistors. ZnO has also attracted significant attention as a new candidate for transparent electrodes due to its good conductivity, high optical transparency, and surface smoothness. This book brings together articles contributed by experts working on various aspects of ZnO and allied materials detailing all the important recent advances. The topics begin with a brief review of ZnO followed by an important article on nano-SolderingofZnOnanowiresandGaNthinfilmsforthefabricationofhetero p-n junction using laser. The book also presents works on photoluminescence processes of ZnO thin films and quantum structures, Li–Ni co-doped ZnO films grown by pulsed laser deposition for realizing stable p-type conducting material, lasing characteristics of an optically pumped single ZnO nanocrystal, and nanomachining for controlling oscillation wavelength, deposition of Al-doped ZnO films by ICP-assisted sputtering. Advances in nanoparticle-assisted pulsed laser deposition, synthesis of silicon carbide (SiC) thin films using pulsed laser deposition, ZnO-based phosphors, related bio-material applications, experimental vii viii Preface and theoretical investigations of dopants, and defects in ZnO nanoparticles have also been discussed. The purpose of the book is to present a summary of the current state-of-the-art research aspects that can pave the way for new areas for future research. M. S. Ramachandra Rao Tatsuo Okada Acknowledgments Prof.M.S.R.RaowouldliketothanktheDepartmentofScienceandTechnology (DST) funding that facilitated the establishment of Nano Functional Materials Technology Centre (NFMTC) at IIT Madras. Prof.OkadawouldliketothankthefinancialsupportundertheprogramofSpecial Coordination Funds for Promoting Science and Technology from Japan Science and Technology Agency (JST). OurspecialthankstoDr.ShubraSinghforcarefuleditingandproofreadingofthe manuscripts. ix
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