Supplementary Materials for

101 Pages·2013·5.39 MB·English

www.sciencemag.org/content/341/6149/1230444/suppl/DC1

Supplementary Materials for

The Chemistry and Applications of Metal-Organic Frameworks

Hiroyasu Furukawa, Kyle E. Cordova, Michael O’Keeffe, Omar M. Yaghi*

*Corresponding author. E-mail: [email protected]

Published 30 August 2013, Science 341, 1230444 (2013)
DOI: 10.1126/science.1230444

This PDF file includes:
Materials and Methods
Figs. S1 to S8
Tables S1 to S5
References (135–363)
Related web sites

Other supplementary material for this manuscript includes the following:
CSD reference codes for MOFs

Fig. S1. The great number and diversity of inorganic SBUs (A) and organic linkers (B) used to
create metal-organic frameworks referred to in the text by abbreviations. C, black; O, red; N,
green; S, yellow; P, purple, Cl, light green; metal ions, blue polyhedra. Hydrogen atoms are
omitted for clarity.
Table S1: Structure of inorganic and organic SBUs used to form MOFs.
Zn O(BDC-NH )
Zn O(BDC) 4 2 3
4 3
IRMOF-3
MOF-5, IRMOF-1

Zn O(fumarate) Zn O(TPDC)
4 3 4 3
IRMOF-16

Zn O(BTB) Zn O(BTE)
4 2 4 2
MOF-177 MOF-180

Zn O(BBC) (Zn O) (BTE) (BPDC)
4 2 4 3 4 3
MOF-200 MOF-210
(Zn O) (BTB) (BDC-NH ) Zn O(BPP34C10DA)
4 3 4 2 3 4 3
UMCM-1-NH MOF-1001
2

Zn O[(BDC) (BDC-NH ) (BDC-Br) (BDC-NO ) (BDC-(Me) ) -
4 0.72 2 0.10 0.39 2 0.20 2 0.47
(NDC) (BATA) (BPEBDC) ]
0.39 0.34 0.39
MTV-MOF-5

Cu (BTC) Cu (TATB)
3 2 3 2
HKUST-1, MOF-199 PCN-6′
Cu (TATAB) Cu (TTCA)
3 2 3 2
Meso-MOF-1 PCN-20

Cu (HTB) Cu (BBC)
3 2 3 2
PCN-HTB′ MOF-399

Zn (TPBTM) Cu (BTPI)
3 3
NOTT-112
Cu (PTEI) Cu (BTEI)
3 3
NOTT-116, PCN-68 PCN-61

Cu (NTEI) Cu (BTTI)
3 3
PCN-66 PCN-69, NOTT-119

Cu (TTEI) Cu (TPBTM)
3 3
PCN-610, NU-100