Self-assembly: from surfactants to nanoparticles

366 Pages·2019·13.282 MB·English

by  Nagarajan, Ramanathan

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Self-Assembly
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WileySeriesonSurfaceandInterfacialChemistry
PonisserilSomasundaranandNissimGarti,SeriesEditors
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Self-Assembly:FromSurfactantstoNanoparticles
EditedbyRamanathanNagarajan
January2019
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Self-Assembly
FromSurfactantstoNanoparticles
Editedby
Dr.RamanathanNagarajan
(cid:2) NatickSoldierResearch (cid:2)
Development&EngineeringCenter
Natick,USA
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Thiseditionfirstpublished2019
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LibraryofCongressCataloging-in-PublicationData
Names:Nagarajan,R.(Ramanathan),editor.
Title:Self-assembly:fromsurfactantstonanoparticles/editedby
RamanathanNagarajan.
Description:Firstedition.|Hoboken,NJ:Wiley,2018.|Series:Wiley
seriesonsurfaceandinterfacialchemistry|Includesbibliographical
referencesandindex.|
Identifiers:LCCN2018028409(print)|LCCN2018028986(ebook)|ISBN
9781119001393(AdobePDF)|ISBN9781119001386(ePub)|ISBN9781119001362
(hardback)
Subjects:|MESH:Nanoparticles|MolecularStructure|Molecular
Biology–methods
Classification:LCCQP801.P64(ebook)|LCCQP801.P64(print)|NLMQT36.5|
DDC572/.33–dc23
LCrecordavailableathttps://lccn.loc.gov/2018028409
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CoverImages:CourtesyofRamanathanNagarajan
Setin10/12ptWarnockProbySPiGlobal,Chennai,India
PrintedinUnitedStatesofAmerica
10 9 8 7 6 5 4 3 2 1
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v
Contents
ListofContributors xi
Preface xv
Acknowledgments xxi
1 Self-AssemblyfromSurfactantstoNanoparticles–Headvs.
Tail 1
RamanathanNagarajan
1.1 Introduction 1
(cid:2) 1.2 ClassicalSurfactantsandBlockCopolymers 4 (cid:2)
1.2.1 TanfordModelforSurfactantMicelles 4
1.2.2 deGennesModelforBlockCopolymerMicelles 11
1.2.3 SurfactantSelf-AssemblyModelIncorporatingTailEffects 13
1.2.4 StarPolymerModelofBlockCopolymerSelf-Assembly
IncorporatingHeadgroupEffects 15
1.2.5 MeanFieldModelofBlockCopolymerSelf-AssemblyIncorporating
HeadgroupEffects 17
1.2.6 TailEffectsonShapeTransitionsinSurfactantAggregates 20
1.2.7 HeadgroupEffectsonShapeTransitionsinBlockCopolymer
Aggregates 22
1.3 Self-AssemblyofNonclassicalAmphiphilesBasedonHead−Tail
Competition 24
1.3.1 DendriticAmphiphiles 25
1.3.2 DNAAmphiphiles 27
1.3.3 PeptideAmphiphiles 29
1.3.4 Protein−PolymerConjugates 31
1.3.5 AmphiphilicNanoparticles 34
1.4 Conclusions 37
Acknowledgments 37
References 38
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vi Contents
2 Self-AssemblyintoBranchesandNetworks 41
AlexeyI.Victorov
2.1 Introduction 41
2.2 RheologyandStructureofSolutionsContainingWormlike
Micelles 44
2.2.1 ViscoelasticityofEntangledWormlikeMicelles 44
2.2.2 GrowthofNonionicMicelles 50
2.2.3 GrowthofIonicMicelles 51
2.2.4 PersistenceLengthofanIonicMicelle 52
2.2.5 NetworksofBranchedMicelles 53
2.2.6 Ion-SpecificEffectonMicellarGrowthandBranching 55
2.3 BranchingandEquilibriumBehaviorofaSpatialNetwork 56
2.3.1 TheEntropicNetworkofChains 56
2.3.2 TheShapeofMicellarBranchandtheFreeEnergy 61
2.4 Conclusions 66
Acknowledgments 69
References 69
3 Self-AssemblyofResponsiveSurfactants 77
TimothyJ.SmithandNicholasL.Abbott
(cid:2) 3.1 Introduction 77 (cid:2)
3.2 Redox-ActiveSurfactants 77
3.2.1 ReversibleChangesinInterfacialProperties 78
3.2.2 ReversibleChangesinBulkSolutionProperties 82
3.2.3 ControlofBiomolecule-SurfactantAssemblies 84
3.2.4 SpatialControlofSurfactant-BasedProperties 87
3.3 Light-ResponsiveSurfactants 90
3.3.1 InterfacialProperties 90
3.3.2 BulkSolutionProperties 90
3.3.3 Biomolecule-SurfactantInteractions 91
3.3.4 SpatialControlofSurfactant-BasedPropertiesUsingLight 93
3.4 Conclusion 93
Acknowledgments 96
References 96
4 Self-AssemblyandPrimitiveMembraneFormation:Between
StabilityandDynamism 101
MartinM.HanczycandPierre-AlainMonnard
4.1 Introduction 101
4.2 BasisofSelf-AssemblyofSingle-Hydrocarbon-Chain
Amphiphiles 104
4.2.1 vanderWaalsForcesandHydrophobicEffect 104
4.2.2 Headgroup-to-HeadgroupInteractions 105
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Contents vii
4.2.3 InteractionsBetweentheAmphiphileHeadgroupsand
Solute/SolventMolecules 106
4.3 TypesofStructures 106
4.3.1 CriticalAggregateConcentration 107
4.3.2 PackingParameter 108
4.4 Self-AssemblyofaSingleTypeofSingle-Hydrocarbon-Chain
Amphiphile 109
4.4.1 SingleSpeciesofSingle-Hydrocarbon-ChainAmphiphile 109
4.4.2 MixturesofSingle-Hydrocarbon-ChainAmphiphiles 110
4.4.2.1 MixturesofAmphiphileswiththeSameFunctional
Headgroups 111
4.4.2.2 MixturesofSingle-HydrocarbonChainAmphiphilesandNeutral
Co-surfactants 111
4.4.2.3 MixturesofChargedSingleHydrocarbonChainAmphiphiles 112
4.4.2.4 MixturesofSingle-ChainAmphiphilesandLipids 113
4.4.3 MixturesofSingle-Hydrocarbon-ChainAmphiphilesandOther
Molecules 114
4.4.4 Self-AssemblyonSurfaces 115
4.5 CatalysisCompartmentalizationwithSingle-Hydrocarbon-Chain
Amphiphiles 116
(cid:2) 4.5.1 EnclosedProtocellModels 118 (cid:2)
4.5.2 InterfacialProtocellModels 120
4.5.3 MembranesasEnergyTransductionSystems 124
4.5.3.1 LinkingLightEnergyHarvestingandChemicalConversion 124
4.5.3.2 FormationofChemicalGradients 125
4.5.3.3 EnergyHarvestingandItsConversionintoHigh-EnergyBondsof
Phosphate-Chemicals 125
4.6 Dynamism 126
4.7 Conclusion 128
Acknowledgments 129
References 129
5 ProgrammingMicelleswithBiomolecules 137
MatthewP.ThompsonandNathanC.Gianneschi
5.1 Introduction 137
5.2 Peptide-ContainingMicelles 138
5.2.1 PeptideAmphiphiles 139
5.2.2 Peptide−PolymerAmphiphiles(PPAs) 141
5.3 DNA-ProgrammedMicelleSystems 151
5.3.1 Lipid-LikeDNAAmphiphiles 154
5.3.2 DNA−PolymerAmphiphiles 159
5.4 Summary 172
References 172
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viii Contents
6 ProteinAnalogousMicelles 179
LorraineLeonandMatthewTirrell
6.1 Introduction 179
6.2 PhysicochemicalPropertiesofPeptideAmphiphiles 181
6.2.1 TheRoleofSecondaryStructuresinPAMs 182
6.2.2 TheRoleofDifferentTailsinPAMs 185
6.2.3 TheRoleofMultipleHeadgroupsinPAMs 186
6.2.4 StabilizingSphericalStructures 187
6.2.5 ElectrostaticInteractions 188
6.2.6 MixedMicelles 188
6.2.7 Stimuli-ResponsivePAMs 190
6.3 PAMsinBiomedicalApplications 192
6.3.1 TissueEngineeringandRegenerativeMedicine 192
6.3.2 DiagnosticandTherapeuticPAMs 195
6.4 Conclusions 199
Acknowledgments 199
References 200
7 Self-AssemblyofProtein−PolymerConjugates 207
XuehuiDong,AaronHuang,AllieObermeyer,andBradleyD.Olsen
(cid:2) 7.1 Introduction 207 (cid:2)
7.2 HelicalProteinCopolymers 209
7.3 β-SheetProteinCopolymers 215
7.4 CyclicProteinCopolymers 220
7.5 Coil-LikeProteinCopolymers 223
7.6 GlobularProteinCopolymers 229
7.7 Outlook 236
Acknowledgments 237
References 237
8 MultiscaleModelingandSimulationofDNA-Programmable
NanoparticleAssembly 257
TingLi,RebeccaJ.McMurray,andMonicaOlveradelaCruz
8.1 Introduction 257
8.2 AMolecularDynamicsStudyofaScale-AccurateCoarse-Grained
ModelwithExplicitDNAChains 259
8.3 ThermallyActiveHybridization 263
8.4 DNA-MediatedNanoparticleCrystallizationinWulff
Polyhedra 268
8.5 Conclusions 272
Acknowledgments 273
References 273
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