Poly(lactic acid)

176 Pages·2011·7.45 MB·English

The Third Thai-Japan Bioplastics and
Biobased Materials Symposium
(AIST - NIA - TBIA Joint Symposium)
20-21 December 2011
Organized by
National Institute of Advanced Industrial Science and Technology (Japan)
National Innovation Agency (Public Organization) (Thailand)
Thai Bioplastics Industry Association (Thailand)
Supported by
[JENESYS Program 2011]
JSPS Exchange Program for East Asian Young Researchers (Japan)
National Institute of Advanced Industrial Science and Technology (Japan)
National Innovation Agency (Public Organization) (Thailand)
Scope
To create a sustainable society, biobased plastics produced from renewable resources
(biomass) and biodegradable plastics should be the critical materials in 21st century. The
purpose of this symposium is to overview the current research activities and global tends on
bioplastics (biobased and biodegradable plastics) and biobased materials and to promote
these activities in both countries. In addition researcher exchange between Thailand and Japan
will be expected.
Topics
• Biobased polymers and biodegradable polymers
• Production of biomass-containing materials; adhesive, composite, and resin
• Conversion of biomass-related materials to monomers and polymers
• Biosyntheses of polymers; in vitro and in vivo
• Polymerization of biobased monomers
• Functional biobased polymers
• High performance bioplastics
• Processing of biobased polymers; blend, molding, and spinning
• Biodegradation evaluation
• Application
Symposium Programme
Tuesday, December 20, 2011
9:10-9:30 Opening Remarks
Dr. Sei-ichi Aiba, National Institute of Advanced Industrial Science and
Technology (Japan)
Dr. Supachai Lorlowhakarn, National Innovation Agency (Thailand)
Dr. Pipat Weerathaworn, Thai Bioplastics Industry Association (Thailand)
9:30-10:20 Green Polymer Synthesis: Developments of Biobased Polymers by
Using Lactic Acid as Starting Material
Prof. Shiro Kobayashi, Kyoto Institute of Technology (Japan)
10:20-10:40 Refreshment
10:40-11:15 R & D of Biobased Engineering Plastics
Dr. Atsuyoshi Nakayama, National Institute of Advanced Industrial
Science and Technology (Japan)
11:15-11:50 Utilization of Carbon Dioxide as Carbon Resource: Synthesis of olefin
and alcohol
Dr. Hisanori Ando, National Institute of Advanced Industrial Science
and Technology (Japan)
11:50-13:40 Lunch break /Poster session
13:40-14:15 Saccharification of Lignocellulosic Biomass by Cellulolytic Enzymes
from Acremonium cellulolyticus
Dr. Hiroyuki Inoue, National Institute of Advanced Industrial Science
and Technology (Japan)
14:15-14:50 Preparation of PBS Copolymers by using Biobased Succinic Acid and
Dibutyl 2,5-Furandicarboxylate
Dr. Akihiro Oishi, National Institute of Advanced Industrial Science and
Technology (Japan)
14:50-15:10 Refreshment/Poster session
15:10-15:45 Biobased Additives for Bioplastics
Dr. Kazuhiro Taguchi, National Institute of Advanced Industrial Science
and Technology (Japan)
15:45-16:20 Standardisation for Bioplastics
Dr. Masahiro Funabashi, National Institute of Advanced Industrial
Science and Technology (Japan)
16:30-16:40 Poster Award Ceremony
Dr. Wantanee Chongkum, National Innovation Agency (Thailand)
Wednesday, December 21, 2011
9:30-10:00 Updated Applications for Bioplastics in Global
Takehiko Tsuchiyama, BASF Japan Ltd., Tokyo (Japan)
10:00-10:30 Applications of Green ABS (Acrylonitrile Butadiene Styrene)
Suthep Kwampian, IRPC (Thailand)
10:30-10:50 Refreshment
10:50-11:20 New Technology of Bioplastics and Application of PLA
Dr. Kazue Ueda, Research & Development Center, Unitika ltd. (Japan)
11:20-11:50 PBS in Papercoating Application-Alternative to LDPE
Dr. Chinnawat Srirojpinyo, PTT MCC Biochem Company Limited
11:50-12.30 Latest Development for Compound Bioplastics
Dr. Phietoon Trivijitkasem, Novamont/Thantawan Industry PLC
12:30 Lunch
Contents
Invited Speaker Powerpoint Presentations
Overview of AIST
Dr. Seichi Aiba ........................................................................................................................7
Green Polymer Synthesis: Developments of Biobased Polymers
by Using Lactic Acid as Starting Material
Prof. Shiro Kobayashi ............................................................................................................9
R & D of Biobased Engineering Plastics
Dr. Atsuyoshi Nakayama......................................................................................................19
Utilization of Carbon Dioxide as Carbon Resource:
Synthesis of olefin and alcohol
Dr. Hisanori Ando.................................................................................................................35
Saccharification of Lignocellulosic Biomass by Cellulolytic
Enzymes from Acremonium cellulolyticus
Dr. Hiroyuki Inoue................................................................................................................41
Biobased Additives for Bioplastics
Dr. Kazuhiro Taguchi............................................................................................................59
Standardisation for Bioplastics
Dr. Masahiro Funabashi......................................................................................................77
New Technology of Bioplastics and Application of PLA
Dr. Kazue Ueda.....................................................................................................................95
Poster Presentation Abstracts
Session A: Upstream and Intermediate (Fermentation and Polymerization)......................109
Session B: Downstream (Processing and Application)......................................................135
Session C: Degradation and Standard................................................................................163
Session D: General.............................................................................................................173
The Third Thai-Japan Bioplastics and Biobased Materials Symposium
Poster Presentations
Ref. No Title Aurthor Organization
Session A: Upstream and Intermediate (Fermentation and Polymerization)
A-1 Metabolic Engineering of Klebsiella oxytoca to Maytawadee Sangproo Suranaree University of
Produce D-(-)-Lactic Acid in Minimal Salts Medium Technology
A-2 Screening of Succinate Producing Bacteria Panwana Khunnonkwao Suranaree University of
from A Rumen Fluid Technology
A-3 Validation of Carbon and Nitrogen Sources, Apichai Sawisit Suranaree University of
pH, and Temperature for Efficient Succinate Technology
Production by Actinobacillus succinogenes
A-4 Enhanced Poly(3-Hydroxybutyrate) Pawut Kanjanachumpol Chulalongkorn University
Production by High-Cell-Density Fed-Batch
Cultivation of Bacillus megaterium BA-019
from Sugarcane Molasses
A-5 Bioproduction of Short-Chain-Length-co-Medium- Chitwadee Phithakrotchanakoon Mahidol University
Chain-Length-Polyhydroxyalkanoate from Crude
Glycerol by Engineered Escherichia coli.
A-6 1,3-Propanediol (PDO) Production via Raw Anchana Pattanasupong Thailand Institute of Scientific
Glycerol Fermentation for Bioplastic Sheet and Technological Research
A-7 Production of Biopolymer Pullulan from Sehanat Prasongsuk Chulalongkorn University
a High-yielding Tropical Strain of
Aureobasidium pullulans
A-8 Double Induced Mutation of Aureobasidium Tuenchai Kosakul Chulalongkorn University
pullulans Using Gamma Irradiation and EMS
A-9 Purification of Succinic Acid from Synthetic Sebastien Molina Suranaree University of
Solutions Using Esterification Coupled with Technology
Reactive Distillation Technique
A-10 Study of the Thermal Properties of Rectangular Suppamart Ngenruangroj Kasetsart University
Bars of Poly (lactic acid) Stereocomplexes
A-11 Linear/star-shaped Poly(L-lactide) Blends Yodthong Baimark Mahasarakham University
Synthesized Through Single-Step ring-Opening
Polymerization
A-12 Synthesis of Polylactide Using Parichat Piromjitpong Mahidol University
Bis(amidinate)tin(II) Complexes
A-13 Effect of Talc Particle Size on Crystallization Paveena Prachayawasin National Metal and Materials
Behavior of Polylactic Acid Technology Center
A-14 Multi-Branched Poly (Lactic Acid): A Novel Yupin Phuphuak Chulalongkorn University
Approach for Enhancing PLLA Crystallization
from Biobased Compounds
A-15 Synthesis of Poly(D-lactic acid) Weraporn Pivsa-Art Rajamangala University of
Using Direct Polycondensation Process Technology Thanyaburi
A-16 Synthesis of D-Lactide and Poly(D-Lactide) Winita Punyodom Chiang Mai University
Using Novel Catalyst / Initiator System
A-17 A Pilot Scale Synthesis of Poly(L-lactic acid) Sommai Pivsa-Art Rajamangala University of
Using a Direct Polycondensation Method Technology Thanyaburi
A-18 Synthesis of TiO Impregnated Bacterial Nattakammala Janpetch Chulalongkorn University
2
Cellulose for Photocatalytic Decomposition
and Antibacterial Applications
A-19 Effect of Heat Pretreatment and Acremonium Sirapan Sukontasing Kasetsart University
Cellulolyticus Enzymes on Saccharification of
Cassava Pulp
AIST - NIA Joint Symposium 5
No. Ref. No Title Aurthor Organization
A-20 Sugar Production from Rice Straw Using Combined Metinee Wasoontharawat Suranaree University
Chemical and Biological Treatment
A-21 Application of Thermophilic Enzymes Siriporn Chaikaew Prince of Songkla University
and Water Jet System to Cassava Pulp
A-22 Development of Biomass Conversion Process Yuka Maeno National Institute of Advanced
using Water Jet and Hyperthermophilic Cellulase Industrial Science and Technology
A-23 Chitosan Nanoscaffold Gel via Water-based Noppadol Trirong Chulalongkorn University
Heterogeneous System
A-24 Structural Studies on Enzymatic Reaction of Misumi Kataoka National Institute of Advanced
Bacterial Copper Amine Oxidase Industrial Science and Technology
Session B: Downstream (Processing and Application)
B-1 Preparation, Characterization and Properties of Ternary Tarinee Nampitch Kasetsart University
Blends with Epoxidized Natural Rubber, Poly(lactic
acid) and Poly(butylene adipate-co-terephthalate)
B-2 The Influence of CaCO on Morphology and Bawornkit Nekhamanurak Silpakorn University
3
Thermal Stability of PLA Extrusion Sheet
B-3 Development and Thermal Behavior of Chamaiporn Yamoum The National Center of
Carboxymethylcellulose/Poly Lactic Scid Excellence for Petroleum
Composite Films
B-4 Development of Biodegradable Nanofibers Jackapon Sunthornvarabhas National Center for Genetic
from Poly-L-lactic Acid and Starch Blend Engineering and Biotechnology
by Electrospinning
B-5 Structure and Properties of Multi-Phase Piyawan Pukpanta Mahidol University
Poly (lactic acid) Blends in the Presence
of Antioxidant
B-6 Synthesis of Poly(lactic acid)/Clay Composites Kulwadee Kaewprapan Chulalongkorn University
by in situ Polycondensation
B-7 Poly(lactic acid) – Based Thermoplastic Pranee Bunkaew Prince of Songkla University
Natural Rubber
B-8 Preparation, Characterization and Properties of Kanyarat Suthapakti Chiang Mai University
Biodegradable Polymer Blends of Poly(lactic acid)
and Poly(L-lactide-co-caprolactone)
B-9 Preparation of Polymer Blends between Weraporn Pivsa-Art Rajamangala University of
Poly(L-lactic acid), Poly(butylene-succinate-co- Technology Thanyaburi
adipate) and Poly(butylene adipate terephthalate)
for Blow Film Industrial Application
B-10 Study of In situ Crossslink Reaction of Epoxidized Wilairat Supmak National Metal and Materials
Natural Rubber (ENR) and PLLA-g-GMA Blend Technology Center
by Moving Die Rheometer
B-11 Preparation of Polymer Blends of Poly(lactic Sommai Pivsa-Art Rajamangala University of
acid) and (Poly[(R)-3-hydroxybutyrate-co-(R)-3- Technology Thanyaburi
hydroxyvalerate] (PHBV) for Textile Applications
B-12 Polylactic Acid Graft Polyvinyl Acetate as Suthawan Buchatip National Metal and Materials
a Compatibilizer for Starch Blending Technology Center
B-13 Physical Properties of PLA-Nanocomposite Nantana Jiratumnukul Chulalongkorn University
for Packaging Applications
B-14 Development of Poly(lactic acid) Film Clarity Raksit Supthanyakul Chulalongkorn University
B-15 Poly(butylene succinate) Conjugated with Nutcha Prasertnasung Chulalongkorn University
Chitosan: A Novel Bioplastics with Function
of Metal Complexation
B-16 Development of Enzymatic Treated Raw Granular Sirirat Thothong Mahidol University
Starch /PBAT Blends as Biodegradable Materials
B-17 Studies on Compatibility of Polymer Blends Sommai Pivsa-art Rajamangala University of
between Poly (trimethylene terephthalate) and Technology Thanyaburi
Polyamide 4 Prepared by Melt Blend Technique
6 The Third Thai-Japan Bioplastics and Biobased Materials Symposium
No. Ref. No Title Aurthor Organization
B-18 Effect of Cassava Starch Foam Blended with Kaisangsri, N King Mongkut’s University of
Natural Polymers on Water Resistance and Technology Thonburi
Mechanical Properties
B-19 Production of Carboxymethylcellulose (CMC) Suthaphat Kamthai Chiang Mai University
from Bleached Bagasses Pulp
B-20 Surface Modification of Natural Rubber Latex Sakkawet Yorsaeng Chulalongkorn University
from Medical Surgical Gloves using DBD Plasma
Treatment for Chitosan Coating
B-21 Preparation of Chitosan-based Microcapsules Sasiprapha Rattanadilok Kasetsart University
Containing Phlai oil for Multifunctional Properties Na Phuket
B-22 Formulation and Production of Cassava Roungrong Thongtan Kasetsart University
Starch-Based Biodegradable Material
B-23 Self-Organising Nanostructures of Poly(e-caprolactone) Supatra Wangsoub Naresuan University
Using Sorbitol Derivatives
B-24 Starch/Cellulose Biocomposites Prepared by High- Saniwan Srithongkham Mahidol University
Shear Homogenization/Compression Molding
B-25 Physical Properties and Antioxidant Activity of Wirongrong Tongdeesoontorn Mae Fah Luang University
Cassava Starch-Carboxymethyl Cellulose Films
Incorporated with Quercetin and TBHQ
B-26 Emulsion Copolymerization of a Poly(lactic Kiyoaki Ishimoto Kyoto Institute of Technology
acid)-methacrylate Macromonomer with an
Alkyl Methacrylate
B-27 Formulation and Optimization of Heat-Moisture Rungarun Sasanatayart Mae Fah Luang University
Treated Rice Starch-Glycerol-Carrageenan Composite
Film Using Response Surface Methodology
Session C: Degradation and Standard
C-1 Comparison of CO Emission and Energy Papondhanai The Joint Graduate School of
2
Consumption between Polylactic acid (PLA) Nanthachatchavankul Energy and Environment
and High Density Polyethylene (HDPE):
Thailand Case Study
C-2 Organic Fertilizer from Bioplastic Compost Rochana Tangkoonboribun Thailand Institute of Scientific
and Technological Research
C-3 Compostability Studies of PLA and PLA/Starch Yosita Rudeekit National Metal and Materials
Blends According to ISO 17088 Technology Center
C-4 Preliminary Poly lactic acid Disintegration Anchana Pattanasupong Thailand Institute of Scientific
and Toxicity Testing and Technological Research
C-5 Life Cycle Environmental Impact Assessment Pomthong Malakul National Metal and Materials
of Polylactic Acid Production from Cassava Na Ayudhaya Technology Center
C-6 System Development and Preliminary Walaiporn Timbuntam Kasetsart University
Biodegradable Evaluation Tests for
Bioplastic Industry by ISO 14855-2
C-7 Study of the Disintegration Behavior Pongsak Siriyota National Metal and Materials
of Polymers Starch Blend Technology Center
C-8 Determination of the Aerobic Biodegradability Parichat Intaruksa National Metal and Materials
of the Starch Based Biodegradable Plastics Technology Center
under Controlled Composting Conditions
Session D: General
D-1 Stimulation of Advanced Technology Research and Assoc.Prof. Klanarong Sriroth Kasetsart University
Development for Thailand Bioplastics Community
Invited Speaker
Overview of AIST
Dr. Sei-ichi Aiba
National Institute of Advanced
Industrial Science and Technology (AIST)
8 The Third Thai-Japan Bioplastics and Biobased Materials Symposium
Overview of AIST
Dr. Sei-ichi Aiba
Senior Researcher, Bioproduction Research Institute,
National Institute of Advanced Industrial Science and Technology (AIST)
AIST Tsukuba Central 6, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8566, JAPAN
E-mail: [email protected]
Sei-ichi Aiba obtained his Bachelor Degree, Master
Degree and Ph.D. from Tokyo University of
Agriculture and Technology, Department of Industrial
Chemistry. He started his profession at the Agency of
Industrial Science and Technology from 1978.
Since2001 to present, He has been working for
National Institute of Advanced Industrial Science and
Technology (AIST) as the Research Chemist in various divisions. He was the
President of the Japanese Society for Chitin and Chitosan from 2009 to 2010.
His current research focuses on chitin, chitosan, biobased polymers.
On behalf of the organizing committee of the Third Thai-Japan Bioplastics and Biobased
Materials Symposium, I would like to be allowed to give a brief address.
In 2009 and 2010, National Innovation Agency (NIA) and National Institute of
Advanced Industrial Science and Technology (AIST) organized the first and second
Thai-Japan Bioplastics and Biobased Materials Symposium with the support of NIA, Japan
Society for the Promotion of Science (JSPS), and AIST. The advanced progresses on Bioplastics
and Biobased Materials such as poly-lactic acid, poly-hydroxyalkanoates, biobased
polypropylene, saccharification of lignocellulose, and standards for the evaluation of their
biodegradability and biomass content, etc were discussed between Japanese speakers and
Thai participants. Many Thai researchers presented their posters, too. Thai researchers,
engineers, and businessmen had much attention in this field. We had good interactions.
This year the symposium is financially supported by two Thai institutions: NIA and
Thai bioplastics Industry Association (TBIA). And AIST and JSPS support too.
I would like to end this word of welcome with an earnest prayer for the great success
of this symposium. I sincerely hope that the symposium will reap fruitful results. And last but not
the least, we would like to extend our gratitude and thanks to all the staffs of NIA who have
been working hard to make this symposium a successful one.
Invited Speaker
Green Polymer Synthesis: Developments of Biobased
Polymers by Using Lactic Acid as Starting Material
Dr. Shiro Kobayashi
Kyoto Institute of Technology