New Concepts in Oxidation Processes

134 Pages·2020·8.984 MB·English

by  Ciro Bustillo-Lecompte (editor), Cédric Barroo (editor)

N
e
w
C
o
n
c
e
p
t
s
in
O
x
id
a
t
io
n
P
r
o
c
e
s
s
e
s
• E
r
ic
G
e
n
t
y
, C
ir
o
B
u
s
t
illo
-L
e
c
o
m
p
t
e
, C
é
d
r
ic
B
a
r
r
o
o
, R New Concepts in
e
n
a
u
d
C
o
u
sin Oxidation Processes
a
n
d
J
o
s
e
C
o
lin
a Edited by
-M
á
r Eric Genty, Ciro Bustillo-Lecompte, Cédric Barroo,
q
u
ez Renaud Cousin and Jose Colina-Márquez
Printed Edition of the Special Issue Published in Catalysts
www.mdpi.com/journal/catalysts
New Concepts in Oxidation Processes

New Concepts in Oxidation Processes
SpecialIssueEditors
EricGenty
CiroBustillo-Lecompte
Ce´dricBarroo
RenaudCousin
JoseColina-Ma´rquez
MDPI•Basel•Beijing•Wuhan•Barcelona•Belgrade
Special Issue Editors
Eric Genty Ciro Bustillo-Lecompte Ce´dricBarroo
Starklab/Terraotherm School of Occupational and ChemicalPhysicsofMaterials
France Public Health, Ryerson andCatalysis(CPMCT),
University Universite´LibredeBruxelles
Canada Belgium
Renaud Cousin Jose Colina-Ma´rquez Department
Unite´ de Chimie of Chemical Engineering,
Environmentale et Interactions Universidad de Cartagena, Sede
sur le Vivant (UCEIV EA 4492) Piedra de Bol´ıva Colombia
France
Editorial Office
MDPI
St. Alban-Anlage 66
4052 Basel, Switzerland
ThisisareprintofarticlesfromtheSpecialIssuepublishedonlineintheopenaccessjournalCatalysts
(ISSN2073-4344)from2018to2019(availableat:https://www.mdpi.com/journal/catalysts/special
issues/oxidationprocesses).
Forcitationpurposes,citeeacharticleindependentlyasindicatedonthearticlepageonlineandas
indicatedbelow:
LastName,A.A.; LastName,B.B.; LastName,C.C.ArticleTitle. JournalNameYear,ArticleNumber,
PageRange.
ISBN978-3-03928-160-2(Pbk)
ISBN978-3-03928-161-9(PDF)
(cid:2)c 2020bytheauthors. ArticlesinthisbookareOpenAccessanddistributedundertheCreative
Commons Attribution (CC BY) license, which allows users to download, copy and build upon
publishedarticles,aslongastheauthorandpublisherareproperlycredited,whichensuresmaximum
disseminationandawiderimpactofourpublications.
ThebookasawholeisdistributedbyMDPIunderthetermsandconditionsoftheCreativeCommons
licenseCCBY-NC-ND.
Contents
AbouttheSpecialIssueEditors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
EricGenty,CiroBustillo-Lecompte,JoseColina-Ma´rquez,Ce´dricBarrooandRenaudCousin
Editorial:SpecialIssue“NewConceptsinOxidationProcesses”
Reprintedfrom:Catalysts2019,9,878,doi:10.3390/catal9110878 . . . . . . . . . . . . . . . . . . . 1
Augusto Arce-Sarria, Fiderman Machuca-Martı´nez, Ciro Bustillo-Lecompte, Aracely
Herna´ndez-Ramı´rezandJose´Colina-Ma´rquez
Degradation and Loss of Antibacterial Activity of Commercial Amoxicillin with
TiO2/WO3-AssistedSolarPhotocatalysis
Reprintedfrom:Catalysts2018,8,222,doi:10.3390/catal8060222 . . . . . . . . . . . . . . . . . . . 3
De´yler Castilla-Caballero, Fiderman Machuca-Martı´nez, Ciro Bustillo-Lecompte and Jose´
Colina-Ma´rquez
Photocatalytic Degradation of Commercial Acetaminophen: Evaluation, Modeling, and
Scaling-UpofPhotoreactors
Reprintedfrom:Catalysts2018,8,179,doi:10.3390/catal8050179 . . . . . . . . . . . . . . . . . . . 17
Julien Brunet, Eric Genty, Ce´dric Barroo, Fabrice Cazier, Christophe Poupin, Ste´phane
Siffert,DianeThomas,GuyDeWeireld,ThierryVisartdeBocarme´andRenaudCousin
TheCoAlCeOMixedOxide: AnAlternativetoPalladium-BasedCatalystsforTotalOxidation
ofIndustrialVOCs
Reprintedfrom:Catalysts2018,8,64,doi:10.3390/catal8020064 . . . . . . . . . . . . . . . . . . . . 32
NiinaKoivikko,TiinaLaitinen,AnassMouammine,SatuOjalaandRiittaL.Keiski
Catalytic Activity Studies of Vanadia/Silica–Titania Catalysts in SVOC Partial Oxidation to
Formaldehyde:FocusontheCatalystComposition
Reprintedfrom:Catalysts2018,8,56,doi:10.3390/catal8020056 . . . . . . . . . . . . . . . . . . . . 52
M.V.Grabchenko, N.N.Mikheeva, G.V.Mamontov, M.A.Salaev, L.F.LiottaandO.V.
Vodyankina
Ag/CeO2CompositesforCatalyticAbatementofCO,SootandVOCs
Reprintedfrom:Catalysts2018,8,285,doi:10.3390/catal8070285 . . . . . . . . . . . . . . . . . . . 70
FudongLiu,HailiangWang,AndrasSapi,HironoriTatsumi,DanyloZherebetskyy,Hui-Ling
Han,LindsayM.CarlandGaborA.Somorjai
Molecular Orientations Change Reaction Kinetics and Mechanism: A Review on Catalytic
AlcoholOxidationinGasPhaseandLiquidPhaseonSize-ControlledPtNanoparticles
Reprintedfrom:Catalysts2018,8,226,doi:10.3390/catal8060226 . . . . . . . . . . . . . . . . . . . 106
v

About the Special Issue Editors
Eric Genty obtained his PhD in Chemistry from the Universite´ du Littoral Coˆte d’Opale (ULCO)
in2014. AfteratwoyearpostdoctoralstayattheUniversite´ LibredeBruxelles(CPMCTservice),
hecontinuedattheEcoleNationaledeChimiedeLille(ENSCL)atUnite´ deCatalyseetChimiedu
Solide(UCCS)foroneyearinapostdoctoralpositioninordertostudytheelementalreactionofCO
oxidationoverPt-basedcatalysts.Followingtheseexperiences,ErictookapositionasR&DEngineer
at Starklab/Terraotherm to develop the depollution aspect of the Terrao heat exchanger. He has
co-authoredover20peer-reviewedscientificpapersandonepatent.
Ciro Bustillo-Lecompte has a multidisciplinary background in the areas of civil, environmental,
andchemicalengineering.HecompletedhisBachelorofEngineeringattheUniversityofCartagena,
Colombia, in 2008 and obtained his MASc (2012) and PhD (2016) at Ryerson University, Canada.
CiroisacertifiedProfessionalEngineer(PEng),EnvironmentalProfessional(EP),aFraternalMember
of the Canadian Institute of Public Health Inspectors (CIPHI), and a 2017–2018 Queen Elizabeth
Scholar (QES). He is currently an Associate Member in the Environmental Applied Science and
Management Graduate Programs, Program Coordinator at the Real Institute, and a Lecturer in
the School of Occupational and Public Health at Ryerson University. He has co-authored over
20peer-reviewedscientificpapers,aswellasseveralconferenceproceedings,chapters,andbooks.
His research interests include advanced oxidation processes, advanced treatment of water and
wastewater, waste minimization, water reuse, water, soil and air quality, energy and resource
recovery,andheterogeneouscatalysis.
Ce´dricBarrooobtainedhisPhDinChemistryfromtheUniversite´LibredeBruxellesin2014.Aftera
two year postdoctoral stay at Harvard University, he is currently a postdoctoral student at the
Universite´ LibredeBruxelles. Hisresearchfocusesontheimagingandcharacterizationofcatalytic
processesusinginsitumicroscopytechniques.
RenaudCousin(Professor)receivedhisPh.D.degreeinSpectroscopyandChemistryfromLittoral
Coˆte d’Opale University in Dunkirk, France, in 2000, on the topic of “Soot Oxidation”. After a
postdoctoralpositionattheUniversityofStrasbourg,sponsoredbyDaimler,HeworkedasAssistant
ProfessorattheLittoralCoˆted’OpaleUniversity, France, from2003to2016. In2014, heobtained
an accreditation to Supervise Research (Habilitation Thesis). In 2016 he was promoted to Full
Professor.Currently,hisresearchfocusesonthedevelopmentandcharacterizationofheterogeneous
catalysts,forapplicationtotheeliminationofenvironmentalpollutants(Soot,CO,VOCs,...).Hehas
co-authoredover70peer-reviewedscientificpapersandonepatent.
vii
Jose´ Colina-MarquezhasbeenanAssociateProfessorintheChemicalEngineeringDepartmentof
the University of Cartagena, since 2010. He obtained his B.Sc. in Chemical Engineering in the
UniversityofAtla´ntico(1996)andhisM.Sc. andPh. DinChemicalEngineeringintheUniversity
of Valle (2008 and 2010, respectively). Currently, he is leading the Research Group of Modeling
andApplicationsofAdvancedOxidationProcesses, thataimstosolvewaterdetoxificationissues
usingthesetechnologies.HeisalsoamemberoftheEditorialCommitteeoftheRevistaIngenier´ıay
Competitividad(UniversityofValle,2012)andamemberoftheEditorialCommitteeoftheRevista
CienciaseIngenier´ıa(UniversityofCartagena,2011).Hewasawardedwiththe“Magnacumlaude”
gradeforhisPhDstudies,grantedbytheUniversityofValle(2010),and“JuniorResearcherofthe
year”,grantedbytheColombianSocietyofCatalysis(2012).
viii
catalysts
Editorial
Editorial: Special Issue “New Concepts in
Oxidation Processes”
EricGenty1,2,*,CiroBustillo-Lecompte3,4,JoseColina-Márquez5,CédricBarroo2,6,*and
RenaudCousin1,*
1 UnitédeChimieEnvironnementaleetInteractionssurleVivant,UniversitéduLittoralCôtéd’Opale,
MREI1—145AvenueMauriceSchumann,59140Dunkerque,France
2 ChemicalPhysicsofMaterialsandCatalysis,UniversitéLibredeBruxelles,FacultyofSciences,
CampusPlaineCP243,1050Brussels,Belgium
3 SchoolofOccupationalandPublicHealth,RyersonUniversity,350VictoriaStreet,
Toronto,ONM5B2K3,Canada;[email protected]
4 GraduateProgramsinEnvironmentalAppliedScienceandManagement,RyersonUniversity,350Victoria
Street,Toronto,ONM5B2K3,Canada
5 ChemicalEngineeringProgram,UniversidaddeCartagena,Av.ElConsulado48-152,
CartagenaA.A.130001,Colombia;[email protected]
6 InterdisciplinaryCenterforNonlinearPhenomenaandComplexSystems(CENOLI),UniversitéLibrede
Bruxelles,CP231,1050Brussels,Belgium
* Correspondence:[email protected](E.G.);[email protected](C.B.);
[email protected](R.C.)
Received:16October2019;Accepted:17October2019;Published:23October2019
Oxidation processes, as part of the catalysis field, play a significant role in both industrial
chemistryandenvironmentalprotection. Withoutadoubt,thetotaloxidationreactionsofvolatile
organiccompounds(VOCs)andhydrocarbonsarecriticalforenvironmentalpollutionprevention
andcontrol. Nevertheless,thehighincidenceofablendoforganicandinorganiccompounds(e.g.,
CO,NOx,SOx,VOC,amongothers)increasesthedifficultyofobtainingactive,stable,andselective
catalyticmaterialsfortotaloxidation. Anotherwaytoeliminatethesepollutantsisthroughtheir
selectiveoxidationtoproducehighlyvaluablechemicalcompounds,suchasfuelsandalcohols.This
approachhasalsobeenutilizedtoyieldchemicalcompoundsfrombiomass.Furthermore,advancesin
photocatalysisandplasmacatalysispermittheintensificationoflow-energyprocesses.
Therelevanceofoxidationprocessesinthefieldofenvironmentalcatalysisisstimulatinginterest,
asprovedbythemultiplicationofsuccessfulSpecialIssuesonthisverytopicinCatalysts:
• CatalyticOxidationinEnvironmentalProtection;
• NewDevelopmentsinHeterogeneousPartialandTotalOxidationCatalysis;
• NovelHeterogeneousCatalystsforAdvancedOxidationProcesses(AOPs);
• TrendsinCatalyticAdvancedOxidationProcesses;
• PhotocatalyticOxidation/OzonationProcesses;
• EnvironmentalCatalysisinAdvancedOxidationProcesses;
• HeterogeneousCatalysisandAdvancedOxidationProcesses(AOP)forEnvironmentalProtection(VOCs
Oxidation,AirandWaterPurification);
ThisSpecialIssueisfocusingon“NewConceptsinOxidationProcesses”andaimstocoverrecent
andnoveladvancementsaswellasfuturetrendsinthefieldofcatalyticoxidationreactions.Topics
addressedinthisSpecialIssueincludetheinfluenceofdifferentparametersoncatalyticoxidation
atvariousscales(atomic,laboratory, pilot,orindustrialscale),thedevelopmentofnewcatalytic
materialsofenvironmentalorindustrialimportance,aswellasthedevelopmentofnewmethods
Catalysts2019,9,878;doi:10.3390/catal9110878 1 www.mdpi.com/journal/catalysts