NASA Technical Reports Server (NTRS) 19910019089: Chemistry of electronic ceramic materials. Proceedings of the International Conference on the Chemistry of Electronic Ceramic Materials

516 Pages·56.1 MB·English

by  NASA Technical Reports Server (NTRS)

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PB91-178822
Chemistry of Electronic Ceramic Materials
Proceedings of the International Conference on the
Chemistry of Electronic Ceramic Materials
Held in Jackson, Wyoming on August 17-22, 1990
(U.S.) National Inst. of Standards and Technology
Gaithersburg, MD
Prepared for:
National AerDnautics and Space Administration, Washington, DC
Jan 91
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PB91-178822
NIST-114A U.S. DEPARTMENT OF COMMERCE 1. PUBLICATION OR REPORT NUMBER !
(REV s.") NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY NISI/SP-804
2. PERFORMING ORGANIZATION REPORT NUMBER
BIBLIOGRAPHIC DATA SHEET
PUBLICATION DATE
January 1991
A. TITLE AND SUBTITLE
CHEMISTRY OF ELECTRONIC CERAMIC MATERIALS
N ST cArgr aoty *360
S. AUTHOR(S)
Peter K. Davies and Robert S. Roth
6. PERFORMING ORGANIZATION (IF JOINT OR OTHER THAN NIST. SEE INSTRUCTIONS) 7. CONTRACT/GRANT NUMBER
U.S. DEPARTMENT OF COMMERCE
NATIONAL INSTRUTE OF STANDARDS AND TECHNOLOGY
GAITHERSBURG. MD 20699 6 TYPE OF REPORT AND PERIOD COVERED
Final
9. SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (STREET, CITY, STATE, ZIP)
NASA, ONR, DuPont, Idaho National Engineering Laboratory, and University of Pennsylvania
10. SUPPLEMENTARY NOTES
DOCUMENT DESCRIBES A COMPUTER PROGRAM; SF-165, FIPS,SOFTWARE SUMMARY, IS ATTACHED.
11. ABSTRACT (A 2WWORD OR LESS FACTUAL SUMMARY OF MOST SIGNIFICANT INFORMATION. IF DOCUMENT INCLUDES A SIGNIFICANT BIBLIOGRAPHY OR
LITERATURE SURVEY, MENTION IT HERE.)
The International Conference on The Chemis ry of Electronic Ceramic Materials was held at
the Sojourner Inn, in the Teton Village, Jdc4son Hole, Wyoming from August 17-22, 1990.
In an attempt to maximize the developmento. this rapidly moving, multidisciplinary field,
this conference brought together major nat iao l and international researchers to bridge the
gap between those primarily interested in`thpure Chemistry of Inorganic Solids and those
interested in the Physical and Electronic Pro erties of Ceramics. With the many major
discoveries that have occurred over the last cade, one of the goals of this meeting was
to evaluate our current understanding-'of the emistry of Electronic Ceramic Materials, and
to assess the state of a field that,has become ne of the most important areas of Advanced
Materials Research.
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12. KEY WORDS (6 TO 12 ENTRIES; ALPHABETICAL ORDER; CAPITALIZE ONLY PROPER NAMES; AND SEPARATE KEY WORDS BY SEMICOLONS) j
crystal chemistry; dielectric ceramics; low temperature synthesis and characterization; !^(
solid state synthesis and characterization; surface chemistry; superconductors; theory 1
and modelling
12. AVAILABILITY 14. NUMBER OF PRINTED PAGES
UNLIMITED :5'
5-3
FOR OFFICIAL DISTRIBUTION. DO NOT RELEASE TO NATIONAL TECHNICAL INFORMATION SERVICE (NMS).
15. MICE
ORDER FROM SUPERINTENDENT OF DOCUMENTS, U.S. GOVERNMENT PAINTING OFFICE.
WASHINGTON, DC 20402.
ORDER FROM NATIONAL TECHNICAL INFORMATION SERVICE (11113). SPRINGFIELD,VA 22161.
ELECTRONIC FORM
P341-178822
United States Department of Commerce
National Institute of Standards and Technology
NIST Special Publication 804
Chemistry of Electronic Ceramic Materials
Peter K. Davies and Robert S. Roth, Editors
REPRODUCED BY
U.S. DEPARTMENT OF COMMERCE
NATIO14AL TECHNICAL
INFORMATION SERVICE
SPRINGFIELD, VA 22161
NIST Special Publication 804
Chemistry of Electronic Ceramic Materials
Proceedings of the International Conference on
the Chemistry of Electronic Ceramic Materials,
August 17-22, 1990 held at Jackson, NW
Edited by
Peter K. Davies
University of Pennsylvania
Robert S. Roth
National Institute of Standards and Technology
Editorial Assistant
Mary A. Clevinger
National Institute of Standards and Technology
Spons^red by
NIST
NASA
ONR
DuPont
Idaho National Engineering Laboratory
University of Pennsylvania
January 1991
00" OF Fql^
40'
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*P4r1s Of
U.& Deputunut of commerce
Pjb:rt A. Mosbacher, Secretary
National Institute of Standards and Technology
John W. Lyons, Director
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National Institute of Standards U.S. Government Printing Office For sale by the Superintendent
and Technology Washington: 1991 of Documents
Special Publication 804 U.S. Government Printing Office
Natl. Inst. Stand. Technol. Washington, DC 20402
Spec. Publ. 804
513 pages (Jan. 1991)
CODEN: NSPUE2
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PREFACE
The International Conference on the Chemistry of Electronic Ceramic Materials was
held at The Sojourner Inn, in the Teton Village, Jackson Hole, Wyoming from August
17-22, 1990. In an attempt to maximize the development of this rapidly moving,
multidisciplinary field, this conference brought together major national and international
researchers to bridge the gap between those primarily interested in the pure Chemistry
of Inorganic Solids and those interested in the Physical and Electronic Properties of
Ceramics. With the many major discoveries that have occurred over the last decade, one
of the goals of this meeting was to evaluate our current understanding of the Chemistry
of Electronic Ceramic Materials, and to assess the state of a field that has become one of
the most important areas of Advanced Materials Research.
The conference consisted of 18 extended invited lectures, 10 contributed oral
presentations, and 37 poster presentations. The meeting was attended by scientists from
a broad spectrum of fields based at universities, industries, and national laboratories.
Approximately one-third of the attendees were from outside the United States and
represented 10 different countries. In addition to the quality of the science, the meeting
was also memorable for the large number of family members who were able to attend,
resulting in many new friendships.
The scientific presentations covered many topics including new methods for the
synthesis of ceramics, the structures and properties of dielectric and ferroelectric
materials, crystal chemistry, surface chemistry, high-T, superconductors, and theory and
modeling. The papers appearing in these proceedings provide an up-to-date review of
many aspects of these areas. For most of the oral presentations the discussions following
the paper were successfully transcribed. Edited versions appear in these proceedings after
each paper. In addtion to clarifying certain aspects of the material covered in the lecture,
the unedited comments, transcribed by a local court reporting service, also provided
considerable amusement for the editors and speakers.
The success of a meeting depends on many parameters ranging from the science to
the weather. One of the most important is sponsorship and support. For this we are
grateful to KIST, NASA, ONR, DuPont, the Idaho National Engineering Laboratory, and
the University of Pennsylvania. The smooth running of a meeting also depends upon
considerable work by those who often receive little recognition. In this respect we were
truly fortunate to have Mary Clevinger as our conference coordinator who has also
ensured that these proceedings appeared in an accurate form in a timely manner. We
would also like to thank Audrey Roth and Kathy Davies for organizing an outstanding
activities program for the many family members who attended the meeting. Thanks are
also due to, Denice Gilbert, Nancy Dickinson, and Tony Kostick in the Materials Science
Department at Penn, who assisted in many typing duties and several tedious budgetary
matters.
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We hope that these proceedings will contribute to the development of the Chemistry
of Electronic Ceramic Materials and, judging from the enthusiastic response of all who
attended this meeting, we look forward to the Second International Conference sometime
in not too distant future.
October 1990 Peter K. Davies (Univ. of Pennsylvania)
Robert S. Roth (KIST)
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TABLE OF CONTENTS
PREFACE
I. DIELECTRIC CERAMICS
CHEMICAL REACTION CONTROLLED MICROSTRUCTURES 3
AND PROPERTIES OF FERROELECTRIC CERAMICS,"(Invited)
D.. Kolar
CHEMISTRY AND PROPERTIES OF TEMPERATURE 21
COMPENSA'T'ED MICROWAVE DIELECTRICS "(Invited)
T. Negas, G. Yeager, S. Bell, and R. Amen
TUNABLE TRANSDUCERS: NONLINEAR PHENOMENA IN 39
ELECTROCERAMICS (Invited)
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R. E. Newnham
STRUCTURAL AND ELECTRONIC PROPERTIES OF SOME 53
PEROVSKITES (Invited)
P. D. Battle
FERROELECTRIC AND FERROELATTIC DOMAIN STRUCTURES 67
IN PIEZOELECTRIC CERAMICS (Invited)
L. A. Bursill and P. JuLin
CATION SUBSTITUTION IN BARIUM TITANATE FOR 77
DIELECTRIC CERAMIC APPLICATIONS
F. Batllo, A. Beauger, B. Jannot, J. C. Jules, M. Laurent, M.
Maglione, and J. C. Niepce
LIQUID PHASE SINTERING OF LiF-FLUXED BaTiO3 85
S. F. Wang, W. Huebner, and C. Randall
A REAL SPACE ANALYSIS OF SHORT RANGE ORDER IN 93
FERROELECTRIC Pb(Mg1/3Nbv3)03
H. D. Rosenfeld, T. Egami, and A. Bhalla
V
MECHANISM OF PNN BASED PEROVSKITE CERAMICS 99
FORMATION
Y. Sasaki, A. Nagai, and T. Yoshimoto
CONVENTIONALLY PREPARED SUBMICRON ELECTRO- 105
CERAMIC POWDERS BY REACTIVE CALCINATION
T. R. Shrout
II. LOW-TEMPERATURE SYNTHESIS AND CHARACTERIZATION
PREPARATION OF YBa2Cu307_a FROM HOMOGENEOUS METAL 113
ALKOXIDE SOLUTION: SYNTHESES OF MIXED-LIGAND
COPPER (II) ALKOXIDES
D. M. Millar and D. A. Payne
'-MOLECULAR CHEMISTRY AND THE SYNTHESIS OF 123
PRECURSORS TO ELECTRONIC CERAMIC MATERIALS "(Invited)
J. J. Ritter, J. F. Kelly, D. E. Newbury, and D. B. Minor
ION EXCHANGE REACTIONS OF LAYERED 137
t.
PHOSPHATOANTIMONIC ACIDS: A ROUTE FOR NEW
CATALYSTS AND LUMINESCENT MATERIALS (Invited)
Y. Piffard
MIXED METAL OXIDES WITH THE PYROCHLORE STRUCTURE 151
AS CATALYSTS FOR METHANE OXIDATIVE COUPLING
(Invited)
A. J. Jacobson, J. T. Lewandowski, C. A. Mims, R. B. Hall,
and G. R. Myers
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` SOFT CHEMICAL SYNTHESIS OF METASTABLE TITANIUM, 163
VANADIUM, AND MOLYBDENUM OXIDES
T. P. Feist and P. K. Davies
PRELIMINARY SOLID-STATE MULTINUCLEAR NMR OF 173
TITANIUM AND ZIRCONIUM OXIDE CERAMICS AND
PRECURSORS
J. J. Fitzgerald, S. S. Han, S. F. Dec, M. F. Davis, C. E.
Bronnimann, and G. E. Maciel
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POLYMERIC SYNTHESIS OF PEROVSKITE POWDERS AND 179
FILMS a
H. U. Anderson, M. M. Nasrallah, F. D. Blum, and M. S.
Smith

ELECTRODEPOSITION OF NANOMODULATED ELECTRONIC 185
CERAMIC THIN FILMS'
J. A. Switzer
III. SOLID-STATE SYNTHESIS AND CHARACTERIZATION

.PROPERTIES OF SOME MIXED URANIUM OXIDES 195
P. G. Dickens, A. V. Powell, and G. P. Stuttard

INVESTIGATIONS ON THE STRUCTURAL, ELECTRICAL AND 207
MAGNETIC PROPERTIES OF Nd2_XM.NiO4+81 M = Ca2+ and Bat+
B. W. Arbuckle, Z. Zhang, and M. Greenblatt
SYNTHESIS AND CHARACTERIZATION OF Lal_XSr.TiO3

(0sxs0.05) 217
S. M. Kauzlarich, J. E. Sunstrom, IV, and P. Klavins
SYNTHESIS AND CHARACTERIZATION OF PHASES IN THE

SYSTEM Ba-Au-Ag-02 225
R. S. Roth, C. J. Rawn, and M. D. Hill
STRUCTURE AND PROPERTIES OF REDUCED EARLY

TRANSITION METAL OXIDE SINGLE CRYSTALS GROWN 237
FROM BORATE FLUXES
S. A. Sunshine, B. Hessen, T. Siegrist, A. T. Fiory, and J. V.
Waszczak
THE KINETICS AND MECHANISM OF THE CRYSTALLIZATION

OF M92A14Si5018 FROM MgAl204 AND SiO2 IN THE PRESENCE 245
OF A BISMUTH OXIDE FLUX
R. W. Dupon, A. C. Tanous, and M. S. Thompson