Laser growth and processing of photonic devices © Woodhead Publishing Limited, 2012 Related titles: Biomaterials, artifi cial organs and tissue engineering (ISBN 978-1-85573-737-2) Biomaterials are materials and devices that are used to repair, replace or augment the living tissues and organs of the human body. The purpose of this wide-rang- ing introductory textbook is to provide an understanding of the needs, uses and limitations of materials used in the human body and to explain the biomechani- cal principles and biological factors involved in achieving the long-term stability of replacement parts in the body. This book examines the industrial, governmental and ethical factors involved in the use of artifi cial materials in humans and discusses the principles and applications of engineering of tissues to replace body parts. 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This book provides a thorough review of shape memory metals and devices for medical applications. The fi rst part of the book discusses the materials, primarily Ti–Ni based alloys; chapters cover the mechanical properties, thermodynamics, composition, fabrication of parts, chemical reactivity, surface modifi cation and biocompatibility. Medical and dental devices using shape memory metals are reviewed in the following section; chap- ters cover stents, orthodontic devices and endodontic instruments. Finally, future developments in this area are discussed including alternatives to Ti–Ni based shape memory alloys. 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Vainos Oxford Cambridge Philadelphia New Delhi © Woodhead Publishing Limited, 2012 Published by Woodhead Publishing Limited, 80 High Street, Sawston, Cambridge CB22 3HJ, UK www.woodheadpublishing.com www.woodheadpublishingonline.com Woodhead Publishing, 1518 Walnut Street, Suite 1100, Philadelphia, PA 19102–3406, USA Woodhead Publishing India Private Limited, G-2, Vardaan House, 7/28 Ansari Road, Daryaganj, New Delhi – 110002, India www.woodheadpublishingindia.com First published 2012, Woodhead Publishing Limited © Woodhead Publishing Limited, 2012 The authors have asserted their moral rights. This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with permission, and sources are indicated. Reasonable efforts have been made to publish reliable data and information, but the authors and the publisher cannot assume responsibility for the validity of all materials. 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Typeset by Newgen Publishing and Data Services, India Printed by TJ International Ltd, Padstow, Cornwall, UK © Woodhead Publishing Limited, 2012 Contents Contributor contact details xi Woodhead Publishing Series in Electronic and Optical Materials xvii Preface xxi 1 Laser growth and processing of photonic structures: an overview of fundamentals, interaction phenomena and operations 1 N. A. VAINOS, University of Patras, Greece and National Hellenic Research Foundation, Greece 1.1 Laser processing concepts and processes: an introduction 1 1.2 Laser radiation, propagation and delivery 5 1.3 Summary of the interactions of laser radiation with condensed matter 14 1.4 Radiation absorption and energy transfer 16 1.5 Materials processing phenomena: appraisal of energy dependencies 20 1.6 Laser-based materials processing for photonics 23 1.7 Specifi c laser processing schemes for photonics applications 33 1.8 A suite of emerging concepts driving future trends 47 1.9 Acknowledgements 49 1.10 References 50 Part I Laser-induced growth of materials and surface structures 53 2 Emerging pulsed laser deposition techniques 55 R. W. EASON, T. C. MAY-SMITH, K. SLOYAN, R. GAZIA, M. DARBY and A. SPOSITO, University of Southampton, UK v © Woodhead Publishing Limited, 2012 vi Contents 2.1 Current state-of-the-art in pulsed laser deposition (PLD) 55 2.2 Problems for growth of thick fi lms and designer refractive index profi les 58 2.3 Multi-beam PLD 63 2.4 Use of three different targets: combinatorial growth 78 2.5 Future work in complex PLD geometries 81 2.6 Conclusions 82 2.7 Acknowledgements 83 2.8 References 83 3 The formation of nanocones on the surface of semiconductors by laser-induced self-assembly 85 A. MEDVID’, Riga Technical University, Latvia and Institute of Semiconductor Physics of NAS Ukraine, Ukraine 3.1 Introduction 85 3.2 Experiments and discussion 88 3.3 Two-stage mechanism of nanocones formation in semiconductors 100 3.4 Applications in nanoelectronics and optoelectronics 102 3.5 Conclusions 109 3.6 Acknowledgements 109 3.7 References 109 4 Fabrication of periodic photonic microstructures by the interference of ultrashort pulse laser beams 113 Q-Z. ZHAO, Shanghai Institute of Optics and Fine Mechanics, CAS, China 4.1 Review of periodic photonic devices induced by the interference of ultrashort pulse laser beams 113 4.2 Theoretical aspects of the interference of ultrashort pulse laser beams 114 4.3 Microstructures induced by the interference of two femtosecond laser beams 120 4.4 Microstructures induced by the interference of multiple femtosecond laser beams 123 4.5 Transfer of periodic microstructures by the interference of femtosecond laser beams 129 4.6 Conclusions and future trends 132 4.7 Sources of further information and advice 133 4.8 References 134 © Woodhead Publishing Limited, 2012 Contents vii Part II Laser-induced three-dimensional micro- and nano-structuring 137 5 Multiphoton lithography, processing and fabrication of photonic structures 139 J. FOURKAS, University of Maryland, USA 5.1 Introduction to multiphoton lithography 139 5.2 Principles of multiphoton absorption and lithography 140 5.3 Materials for multiphoton lithography 144 5.4 Applications of multiphoton lithography in photonics 151 5.5 Future prospects for multiphoton lithography in photonics 155 5.6 References 156 6 Laser-based micro- and nano-fabrication of photonic structures 162 V. SCHMIDT, Joanneum Research, Austria 6.1 Introduction and motivation 162 6.2 Fabrication of 2D and 3D photonic micro-structures 163 6.3 Laser lithography for the fabrication of photonic structures 172 6.4 Laser lithography based on one-, two- or multiple- photon absorption 184 6.5 Material modifi cation aspects 198 6.6 Device design, fabrication and applications 203 6.7 Conclusions and future trends 221 6.8 References 223 7 Laser-induced soft matter organization and microstructuring of photonic materials 238 L. ATHANASEKOS, University of Patras, Greece and National Hellenic Research Foundation, Greece, S. PISPAS, National Hellenic Research Foundation, Greece and N. A. VAINOS, University of Patras, Greece and National Hellenic Research Foundation, Greece 7.1 Introduction 238 7.2 The origin of radiation forces 239 7.3 Organization of entangled polymers and hybrids by laser radiation 242 7.4 Organization and microfabrication by radiation forces: an emerging technology 246 7.5 Conclusions and future prospects 264 © Woodhead Publishing Limited, 2012 viii Contents 7.6 Acknowledgments 264 7.7 References 265 7.8 Appendix 266 8 Laser-assisted polymer joining methods for photonic devices 269 C. H. WANG, Heriot-Watt University, UK 8.1 Introduction 269 8.2 Properties of benzocyclobutene (BCB) polymers for photonic applications 270 8.3 BCB as a planarization material for fabrication of semiconductor photonic devices 271 8.4 Laser-assisted polymer bonding for assembly of photonic and microelectromechanical systems (MEMS) devices 272 8.5 Laser microwelding for assembly of periodic photonic structures 280 8.6 Conclusions 283 8.7 References 283 Part III Laser fabrication and manipulation of photonic structures and devices 285 9 Laser seeding and thermal processing of glass with nanoscale resolution 287 J. CANNING, University of Sydney, Australia and S. BANDYOPADHYAY, Central Glass and Ceramic Research Institute (CGCRI), India 9.1 Introduction 287 9.2 The regeneration process 289 9.3 Estimating the retention of nanoscale information in regenerated grating structures 296 9.4 Conclusions 301 9.5 Acknowledgements 303 9.6 References 303 10 Femtosecond-laser-induced refractive index modifi cations for photonic device processing 305 M. AMS, D. J. LITTLE and M. J. WITHFORD, Macquarie University, Australia © Woodhead Publishing Limited, 2012 Contents ix 10.1 Introduction 305 10.2 Ultrafast laser interactions with dielectric materials 307 10.3 Refractive index modifi cation mechanisms 312 10.4 Photonic device processing 316 10.5 Photonic devices 322 10.6 Conclusions 328 10.7 References 329 11 Thermal writing of photonic devices in glass and polymers by femtosecond lasers 333 S. M. EATON, Istituto di Fotonica e Nanotecnologie (IFN)-CNR, Italy, G. CERULLO, Politecnico di Milano, Italy and R. OSELLAME, Istituto di Fotonica e Nanotecnologie (IFN)-CNR, Italy 11.1 Introduction 333 11.2 Femtosecond laser–material interaction in waveguide writing 334 11.3 Femtosecond laser waveguide writing in glasses 343 11.4 Waveguide writing in polymers 362 11.5 Conclusions 365 11.6 Future trends 366 11.7 Sources of further information and advice 367 11.8 References 368 12 Laser processing of optical fi bers: new photosensitivity fi ndings, refractive index engineering and surface structuring 374 S. PISSADAKIS, Foundation for Research and Technology – Hellas (FORTH), Institute of Electronic Structure and Laser (IESL), Greece 12.1 Introduction and historical overview 374 12.2 Glass photosensitivity using laser beams 378 12.3 Correlation of underlying photosensitivity mechanisms with refractive index changes 379 12.4 Types of photosensitivity in optical fi bers 383 12.5 Grating fabrication in standard, germanosilicate optical fi bers 389 12.6 Grating fabrication in standard, all-silica optical fi bers 403 12.7 Grating fabrication in phosphate and fl uoride glass fi bers 406 © Woodhead Publishing Limited, 2012 x Contents 12.8 Microstructured optical fi ber (MOF) gratings 413 12.9 Laser machining of optical fi bers 424 12.10 Future trends and prospects 432 12.11 Conclusions 435 12.12 Acknowledgments 436 12.13 References 436 Index 453 © Woodhead Publishing Limited, 2012