Table Of Content

oft Chemistry x= LSEVIER Journal of Organometallic Chemistry 522 (1996) 319-320 Author Index of Volume 522 Ackermann, M.N., 105 Frohmader, G., 185 Minguez, J., 87 Ahmed, M.J., 55 Moragas, R., 59, 87 Albert, J., 59, 87 Gonzalez, M., 123 Moreau, C., 213 Almond, M.J., 265 Granell, J., 59, 87 Alonzo, G., 237 Grdeni¢é, D., 297 Neibecker, D., 117 Alt, H.G., 39, 177 Grée, R., 311 Nierlich, M., 249 Amberger, H.-D., 317 Novikov, Y.N., 147 Amo-Ochoa, P., 97 Hall, B.C., 307 Angelici, R.J., 21 Hamers, H., 197 Offermann, W., 237 Antonio, B.J., 105 Herberhold, M., 185 Au- Yeung, S.C.F., 155 Herd, O., 69 Pawelke, G., 129 HeBler, A., 69 Pfeffer, M., 197 Hingst, M., 69 Barron, M.C., 105 Postel, M., 303 Holloway, C.E., 167 Bartsch, R.A., 9 Holwerda, R.A., 9 Berthet, J.C., 249 Rheingold, A.L., 1 Humphrey, P.A., 259 Biran, C., 213 Ricard, L., 223 Boisson, C., 249 Rice, D.A., 265 Ibrahim, A.M.A., 77 Bordeau, M., 213 Rodriguez, J.G., 231 Ilarraza, R., 1 Borja, M., 123 Rosenberg, L., 117 Brauer, D.J., 129 Rosenthal, U., 241 Breunig, H.J., 237 Jacobson, R.A., 21 Rothe, J., 129 Bruce, M.I., 259, 307 Rudolf, B., 313 Klaui, W., 197, 207 Brunet, J.-J., 117 Korpar-Colig, B., 297 Burger, H., 129 Salisbury, G., 265 Kou, X., 9 Burlakov, V.V., 241 Sanz, J., 231 Kruger, V., 223 Satyanarayana, C.V.V., 291 Kudin, K.N., 147 Cassidy, P.E., 55 Schwarz, W., 137 Kus, P., 9 Chan, J.C.C., 155 Sekar, P., 291 Chen, J., 21 Serein-Spirau, F., 213 Lance, M., 249 Cherkaoui, H., 311 Shur, V.B., 241 Lang, H., 277 Chupa, A.L., 105 Skelton, B.W., 259, 307 Le Menn, C., 223 Commenges, G., 117 Solans, X., 59, 87 Li, S.-L., 155 Czech, B.P., 9 Stelzer, O., 69 Liles, D.C., 33 Struchkov, Yu.T., 241 Lin, G., 271 Dalley, N.K., 9 Luna, S., 97 Damiano, J.P., 303 Taylor, M.J., 265 Luque, A., 87 Day, C.L., 21 Tepper, M., 69 Denker, M., 237 Thewalt, U., 241 Mahon, M.F., 291 Dolgushin, F.M., 241 Mak, T.C.W., 155 Tikkanen, W., 123 Domhiover, B., 197, 207 Todd, M.J., 105 Manning, J., 123 Drew, M.G.B., 265 Marinetti, A., 223 Dunogués, J., 213 Martelli, J., 311 Urtutia, A., 231 Martinez-Cruz, L.A., 97 Usatov, A.V., 147 Ebert, K.H., 237 Mathur, P., 291 Edelmann, F.T., 317 Matkovié-Calogovié, D., 297 Vegas, A., 97 Ephritikhine, M., 249 Maitzger, A.J., 105 Verhoeven, P.F.M., 33 Eiaiw, S.E.H., 77 Meeker, K., 105 Vinogradova, L.E., 147 Meléndez, E., | Vorontsov, E.V., 147 Fitch, III, J.W., 55 Melnik, M., 167 Fonseca, I., 231 Mikulec, F.V., 105 Watkins, P., 123 Font-Bardia, M., 59, 87 Milius, W., 185 Weinmann, M., 277 Elsevier Science S.A. 320 Author Index of Volume 522 Westerhausen, M., 137 Yanovsky, A.I., 241 Zamora, F., 97 White, A.H., 259, 307 Yap, G.P.A., | Zenk, R., 39, 177 Wieneke, M., 137 Zhang, Z.-Z., 155 Wong, W.-T., 271 Zaitseva, N.N., 307 Zsolnai, L., 277 Woods, C., 105 Zakrzewski, J., 313 ELSEVIER Journal of Organomeiallic Chemistry 522 (1996) 321-327 Subject Index of Volume 522 Acetylenes Amide Reaction of iron dicarbonyl phosphine complexes of 2- Reactivity of the cationic uranium amide compound [U(7- (phen ylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- H,XNEt, XOC,H,),[BPh,] (C. Boisson, J.C. Berihet, M. thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. Ephritikhine, M. Lance and M. Nierlich), 249 Ackermann, F.V. Mikulec, AJ. Matzger, B.J. Antonio, M.C. Amido rhodium(I) complexes Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Variable temperature multidimensional NMR study of anionic Rh(1) Acyl derivatives anilido [((R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. Preparation, characterization and carbonylation of the ring-functional- Commenges, D. Neibecker and L. Rosenberg), 117 ized dibenzyl zirconocenes, (n°-C;H;),(n°-C5H 4)P(Ce- Amines H5),)>-,ZM(CH,C,¢H;)> (x =1, (1); x= 0, (2) (W. Tikkanen, J. Cyclometallation of 2-phenylaniline and (R)-a-methylbenzylamine by Manning, P. Watkins, M. Gonzalez and M. Borja), 123 alladium(II) acetate. X-ray molecular structure of [Pd{2-(2’- Addition to the ethylenic bond NH,C,H4)C,H4}Br(PPh,)] (J. Albert, J. Granell, A. Luque, J. Addition of imidazoles and aminoacids to the ethylenic bond in Minguez, R. Moragas, M. Font-Bardia and X. Solans), 87 (7°-C.5H;)Fe(CO),(7'-N-maleimidato) (B. Rudolf and J. Za- Amino acid krzewski), 313 Addition of imidazoles and aminoacids to the ethylenic bond in Alk ylzinc-amide (n°-C;H)Fe(CO),(n'-N-maleimidato) (B. Rudolf and J. Za- 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- krzewski), 313 zink-Verbindungen: Zusammenhang zwischen Zn-N-Abstand und Anilides R—Zn—R-Bindungswinkel (M. Westerhausen, M. Wieneke und Variable temperature multidimensional NMR study of anionic Rh(1) W. Schwarz), 137 anilido [((R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. Alkylzinc-chloride Commenges, D. Neibecker and L. Rosenberg), 117 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- Antimony zink-Verbindungen: Zusammenhang zwischen Zn-N-Abstand und 'H NMR spectra of Ph,SbX, PhSbX,, and Ph,SbX, (X= Cl, Br, D; R-—Zn—R-Bindungswinkel (M. Westerhausen, M. Wieneke und "Sb Mossbauer spectra of PhSbX, sd cove structure of W. Schwarz), 137 Ph, SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. Alkyne Offerman), 237 FeCl,-H,O: a specific system for arylacetylene hydration (J.P. Adduct formation between (Ph,SbI),0 and I, (M.J. Almond, M.G.B. Damiano and M. Postel), 303 Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 Alkyne complexes 7-Bonding Interaction of carbon dioxide with the bis(trimethylsilyl)acetylene Reaction of iron dicarbonyl phosphine complexes of 2- complex of permethyltitanocene: synthesis and structure of the (phenylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- binuclear carbonate complex of permethyltitanocene (Cp; Ti),CO; thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. (V.V. Burlakov, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, Ackermann, F.V. Mikulec, A.J. Matzger, B.J. Antonio, M.C. V.B. Shur, U. Rosenthal and U. Thewalt), 241 Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Alkyne dimerization Synthesis, *'P NMR data and X-ray analysis of a ruthenium(II) Boron dimethylphenylphosphine complex with dimerized phenylacety- [2 + 3] Cycloaddition reactions of dimethylamino-bis(trifluorometh- lene: the structure of [(PhMe, P),Ru(n°-PhC,;CHPh)KPF,) (D.C. yl)borane, (CF,),BNMe,, with nitrile oxides, nitrones and Liles and P.F.M. Verhoeven), 33 Me,C= SO,. Crystal and_molecular structure of (CF,), B-NMe,- Alkynyl chlorosilanes ‘BuC=N-O and (CF,), B-NMe,—CMe,-S(=O)-O (D.J. Brauer, Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- H. Biirger, G. Pawelke andJ . Rothe), 129 lane (H. Lang, M. Weinmann und L. Zsolnai), 277 Bromide Allyl Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- Synthese von 7-Allyl—Palladium-Komplexen, stabilisiert durch pling reactions between primary or secondary phosphines and dreizihnige Sauerstoffliganden [(C;H;)Co{P(OR),0},]” (B. functional aryliodides — a novel synthetic route to water soluble Domhéver, H. Hamers, W. Kaui und M. Pfeffer), 197 phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. Allyl, Oxygen ligand Stelzer), 69 a-Allyl-Palladium-Komplexe stabilisiert durch den tripodalen Sauer- stoffliganden [(C,H,;)Cof{P(OMe),0},I] . Eliminierung - statt Coo C—C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten Organometallic hydrides as reaciants in fullerene chemistry. Interac- Carbanionen (B. Domhiver und W. Kaui), 207 tion of the fullerenes C,,. and C7. with HM(COXPPh,), (M = Rh Elsevier Science S.A. Subject Index of Volume 522 and Ir) and HI(C,H,,PPh,), (A.V. Usatov, K.N. Kudin, E.V. Chromic behaviour Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 Unusual chromic behaviour of the solid supramolecular 3D polymers [((Me,Sn),, Fe(CN),]. (n= 3/4) (S.E.H. Etaiw and A.M.A. Cro Organometallic hydrides as reactants in fullerene chemistry. Interac- Ibrahim), 77 tion Of the fullerenes Cg and C7) with HM(COXPPh,), (M = Rh Chromium and Ir) and HIXC,H,,PPh;), (A.V. Usatov, K.N. Kudin, E.V. Synthesis reactivity and molecular structure of 2’-methylspiro{cyclo- Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 hexane-1,3’-3H-indole] chromium tricarbonyl complex (J.G. Cadmium Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Organometallic and carbonyl compounds of cadmium: analysis of Cluster crystallographic and structural data (C.E. Holloway and M. Reactions of Ru,(y-dppmXCO),. with unsaturated hydrocarbons. Melnik), 167 Pentamethylcyclopentadiene. X-ray structure of Ru,( u-HX p;- Carbon dioxide PPhCH, PPh, u-7': n°-CH,C;Me,XCO), (M.I. Bruce, P.A. Interaction of carbon dioxide with the bis(trimethylsilyl)acetylene Humphrey, B.W. Skelton and A.H. White), 259 complex of permethyltitanocene: synthesis and structure of the Synthesis and characterisation of CpCoFe,(CO),( 43-SX u3-Te). binuclear carbonate complex of permethyltitanocene (Cp; Ti),CO, Crystal structure of CpCoFe,(CO),( 2 3-SeX 2 3-Te) (P. Mathur, P. (V.V. Burlakov, F.M: Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 V.B. Shur, U. Rosenthal and U. Thewait), 241 C-metallation Carbonyl C- and O-metallation of N-benzylideneamines by palladium (II). Addition of imidazoles and aminoacids to the ethylenic bond in Synthesis and X-ray crystal structure of [Pd(2-(CH=N-~(CH,),- (n°-C5H,)Fe(CO),(y!-N-maleimidato) (B. Rudolf and J. Za- 4'-(MeO)C,H ,}-4,5-(MeO),€,H,)Br(PPh,)] (J. Albert, J. krzewski), 313 Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Bond shift isomerization in a heterodiene complexed to Fe(CO), (H. Cobalt Cherkaoui, J. Martelli and R. Grée), 311 Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- Organometallic and carbonyl compounds of cadmium: analysis of lane (H. Lang, M. Weinmann und L. Zsolnai), 277 crystallographic and structural data (C.E. Holloway and M. Synthesis and characterisation of CpCoFe,(CO),( 1 3-SX w3-Te). Melnik), 167 Crystal structure of CpCoFe,(CO),( w3-SeX 3-Te) (P. Mathur, P. Reactions of SmI,(THF), with [Cp’'Mo(CO),],Hg (Cp’= C,H; or Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 C,Me;): crystal and molecular structures of [(THF),1,Sm( p- Coordination ability OC)Mo(CO),(C;H)] and [((C;Me,)Mo(CO),], (G. Lin and W.-T. Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- Wong), 271 lane (H. Lang, M. Weinmann und L. Zsolnai), 277 Synthesis and characterisation of CpCoFe,(CO),( 3-SX u;-Te). Crystal structure Crystal structure of CpCoFe,(CO),( w3-SeX s23-Te) (P. Mathur, P. 'H NMR spectra of Ph, SbX, PhSbX, , and Ph,SbX, (X = Cl, Br, 1); Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 '?'Sb Mossbauer spectra of PhSbX, and crystal structure of Synthesis and structural characterization of a phosphido-bridged het- Ph,SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. erobimetallic transition metal complex, (CO),Fe( 4-PPh,),Mo- Offermann), 237 (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Au-Yeung and Adduct formation between (Ph,SbI),O and I, (M.J. Almond, M.G.B. T.C.W. Mak), 155 Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 Synthesis reactivity and molecular structure of 2’-methylspiro[cyclo- Organometailic and carbonyl compounds of cadmium: analysis of hexane-],3’-3H-indole] chromium tricarbonyl complex (J.G. crystallographic and structural data (C.E. Holloway and M. Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Melnik), 167 Carbonylation Reactions of Ru,(y-dppmXCO),. with unsaturated hydrocarbons. Preparation, characterization and carbonylation of the ring-functional- Pentamethylcyclopentadiene. X-ray structure of Ru,( u-HX p,- ized dibenzyl zirconocenes, (n°-C5H5),((n°-C;H4)P(C,- PPh,C PPHh, X u-7' : 7°-CH,C,Me,XCO), (M.I. Bruce, P.A. H,)2)2_ ,ZMCH,C,H;)> (x= 1, (I); x = 0, (2) (W. Tikkanen, J. Humphrey, B.W. Skelton and A.H. White), 259 Manning, P. Watkins, M. Gonzalez and M. Borja), 123 Reactions of Sm1,(THF), with [Cp’Mo(CO),],Hg (Cp’ = C,H5 or Catalysis C;Me; ): crystal and molecular structures of [(THF),I,Sm( p- Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- OC)MoACO),(C;H,)] and [(C; Me, )Mo(CO),], (G. Lin and W.-T. stituierte Metallocenkomplex des Typs (C,,Hg_,,R,,CR>C5H,)- Wong), 271 MCI,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = Some neutral ruthenium vinylidene complexes and a novel 1,3- Zr, Hf) (H.G. Alt und R. Zenk), 39 elimination reaction: preparation of chiral ruthenium acetylides Cation (M.I. Bruce, B.C. Hall, N.N. Zaitseva, B.W. Skelton and A.H. Reactivity of the cationic uranium amide compound [U(7- White), 307 C,Hg XNEt,XOC,4H,),I[BPh,] (C. Boisson, J.C. Berthet, M. Synthese von 7-Allyl—Palladium-Komplexen, _ stabilisiert durch Ephritikhine, M. Lance and M. Nierlich), 249 dreizahnige Sauerstoffliganden [(C;H;)Co{P(OR),O},]> (B. Chirality Domhiéver, H. Hamers, W. Klaui und M. Pfeffer), 197 DiastereOselective synthesis of a-silylphosphetanes. An approach to Synthesis, *'P NMR data and X-ray analysis of a ruthenium(II) monodentate, P—O chelating and trans-chelating chiral ligands dimethylphenylphosphine complex with dimerized phenylacety- (A. Marinetti, V. Kruger, C. Le Menn and L. Ricard), 223 lene: the structure of [(PhMe,P),Ru(°-PhC ;CHPh)KPF,) (D.C. Some neutral ruthenium vinylidene complexes and a novel 1,3- Liles and P.F.M. Verhoeven), 33 elimination reaction: preparation of chiral ruthenium acetylides Synthesis and structural characterization of a phosphido-bridged het- (M.I. Bruce, B.C. Hall, N.N. Zaitseva, B.W. Skelton and A.H. erobimetallic transition metal complex, (CO), Fe( y-PPh,),Mo- White), 307 Subject Index of Volume 522 (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Au- Yeung and Ferrocenes T.C.W. Mak), 155 New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ Cubane cluster (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden N.K. Dalley), 9 (M. Herberhold, G. Frohmader und W. Milius), 185 Ferrocenophanes Cycloaddition reactions New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ [2 + 3] Cycloaddition reactions of dimethylamino-bis(trifluorometh- (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and ylborane, (CF,),BNMe,, with nitrile oxides, nitrones and N.K. Dalley), 9 Me,C=SO,. Crystal and_molecular structure of (CF;),B-NMe>- Fluorenyl ‘BuC=N-O and (CF, ),B—NMe,-CMe,—S(=0)—O (D.J. Brauer, Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- H. Birger, G. Pawelke and J. Rothe), 129 stituierte Metallocenkomplex des Typs (C,,Hg_ ,R,,CR’C5H ,)- Cyclometallation MCI,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = C- and O-metallation of N-benzylideneamines by palladium (II). Zr, Hf) (H.G. Alt und R. Zenk), 39 Synthesis and X-ray crystal structure of [Pd(2-(CH=N-(CH,),- 4'-(MeO)C, H,}-4,5-(MeO),C,H>)Br(PPh,)] (J. Albert, J. Group 12 Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Organometallic and carbonyl compounds of cadmium: analysis of Cyclometallation of 2-phenylaniline and (R)-a-methylbenzylamine by crystallographic and structural data (C.E. Holloway and M. alladium(II) acetate. X-ray molecular structure of [Pd{2-(2’- Melnik), 167 NH ,C,H,)C,H ,}Br(PPh,)] (J. Albert, J. Granell, A. Luque, J. Group 15 Minguez, R. Moragas, M. Font-Bardfa and X. Solans), 87 'H NMR spectra of Ph,SbX, PhSbX,, and Ph,SbX , (X = Cl, Br, I); Cyclooctatetraene 2'Sb Mossbauer spectra of PhSbX, and crystal structure of Reactivity of the cationic uranium amide compound [U(7- Ph, SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. C,gH,KXOC N,HEg),t][B,Ph, ] (C. Boisson, J.C. Berthet, M. Offermann), 237 Ephritikhine, M. Lance and M. Nierlich), 249 Cyclopalladation A way to obtain cyclopalladation of unsubstituted 2-phenylimidazole Hafnium derivatives (F. Zamora, S. Luna, P. Amo-Ochoa, L.A. Martinez- Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- Cruz and A. Vegas), 97 stituierte Metallocenkomplex des Typs (C,,Hg_ ,R,,CR>C;4H) - C- and O-metallation of N-benzylideneamines by palladium (II. MC1,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = Synthesis and X-ray crystal structure of [Pd(2-(CH=N-(CH,),- Zr, Hf) (H.G. Alt und R. Zenk), 39 4'-(MeO)C, H,}-4,5-(MeO),C,H>)BAPPh;)] (J. Albert, J. Halide Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothieny])di- Diene complexes methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. Synthesis and structure of ruthenium(II)—diene complexes (E. Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), Meléndez, R. Ilarraza, G.P.A. Yap and A.L. Rheingold), | 213 trans-Diene coordination Heterobimetallic complex Synthesis and structure of ruthenium(II)—diene complexes (E. Synthesis and structural characterization of a phosphido-bridged het- Meléndez, R. Ilarraza, G.P.A. Yap and A.L. Rheingold), | erobimetallic transition metal complex, (CO),Fe( 4.-PPh,),Mo Dimethylamino-bis(trifluormethy])borane (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Au-Yeung and [2 + 3] Cycloaddition reactions of dimethylamino-bis(trifluorometh- T.C.W. Mak), 155 yl)borane, (CF,),BNMe,, with nitrile oxides, nitrones and Heterodiene complex Me,C=SO,. Crystal and _m olecular structure_of (CF,), B-NMe,- Bond shift isomerization in a heterodiene complexed to Fe(CO), CH. BuC=N-O and (CF, ),B—NMe,-CMe,—S(=0)-O (D.J. Brauer, Cherkaoui, J. Martelli and R. Grée), 311 'H NMR spectra H. Birger, G. Pawelke and J. Rothe), 129 Diphosphine 'H NMR spectra of Ph,SbX, PhSbX,, and Ph,SbX , (X = Cl, Br, D); Diastereoselective synthesis of a-silylphosphetanes. An approach to '21Sb Mossbauer spectra of PhSbX, and crystal structure of monodentate, P—O chelating and trans-chelating chiral ligands Ph, SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. (A. Marinetti, V. Kruger, C. Le Menn and L. Ricard), 223 Offermann), 237 Hydration Electrochemical synthesis FeCl,—H,O: a specific system for arylacetylene hydration (J.P. Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- Damiano and M. Postel), 303 lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothienyl)di- Hydroamination methylchlorosilane, precursors of polyl[(silanylene)thiophene]s (C. Variable temperature multidimensional NMR study of anionic Rh(1) Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunoguss), anilido [(R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. 213 Commenges, D. Neibecker and L. Rosenberg), 117 Electrochemistry Hydroarylation New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ Variable temperature multidimensional NMR study of anionic Rh(1) (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and anilido [(R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. N.K. Dalley), 9 Commenges, D. Neibecker and L. Rosenberg), 117 Elimination reaction Hydrodesul furization a-Allyl—Palladium-Komplexe stabilisiert durch den tripodalen Sauer- Unexpected products resulting from reactions of Cp * In7>-2,5- stoffliganden [(C;H;)Co{P(OMe),O},]~ II. Eliminierung statt Me,T)?* (Me,T = 2,5-dimethylthiophene) with (-S),Fe,- C-C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten (CO){~ and ( u-COX u-RS)Fe,(CO); (J. Chen, C.L. Day, R.A. Carbanionen (B. Domhéver und W. Klaui), 207 Jacobson and R.J. Angelici), 21 324 Subject Index of Volume 522 Hydrogen bonding Kinetic studies New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ Bond shift isomerization in a heterodiene complexed to Fe(CO), (H. (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and Cherkaoui, J. Martelli and R. Grée), 311 N.K. Dalley), 9 Ligand substitution at-Allyl—Palladium-Komplexe stabilisiert durch den tripodalen Sauer- Imidazole stoffliganden [(C;H;)Co{P(OMe),O},]~ II. Eliminierung _ statt Addition of imidazoles and aminoacids to the ethylenic bond in C-—C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten (n>-C,H,)Fe(CO),(7'-N-maleimidato) (B. Rudolf and J. Za- Carbanionen (B. Domhéver und W. Klaui), 207 krzewski), 313 Lithium Imidazoles Lithiation and silylation reactions of 1,4-bis(1,1,1,3,3,3-hexafluoro-2- A way to obtain cyclopalladation of unsubstituted 2-phenylimidazole hydroxy-2-propyl)benzene (J.W. Fitch, III, P.E. Cassidy and M.J. derivatives (F. Zamora, S. Luna, P. Amo-Ochoa, L.A. Martinez- Ahmed), 55 Cruz and A. Vegas), 97 Iodide Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- Maleimide anion pling reactions between primary or secondary phosphines and Addition of imidazoles and aminoacids to the ethylenic bond in functional aryliodides — a novel synthetic route to water soluble (n°-C;H,)Fe(CO),(7'-N-maleimidato) (B. Rudolf and J. Za- phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. krzewski), 313 Stelzer), 69 Manganese Iodine Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- Adduct formation between (Ph,SbI),O and I, (M.J. Almond, M.G.B. lane (H. Lang, M. Weinmann und L. Zsolnai), 277 Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 Mercury Iridium Synthesis and crystal structures of tetrakis(nitratomercurio)methane Organometallic hydrides as reactants in fullerene chemistry. Interac- monohydrate and bis(sulphatomercurio)bis(aquamercurio)methane tion of the fullerenes C,, and C,, with HM(COXPPh,), (M = Rh (D. Grdenié, B. Korpar-Colig and D. Matkovié-Calogovié), 297 and Ir) and HIr(C,H,>PPh3), (A.V. Usatov, K.N. Kudin, E.V. Metallocenes Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 Preparation, characterization and carbonylation of the ring-functional- Unexpected products resulting from reactions of Cp* Ir(n>-2,5- ized dibenzyl zirconocenes, (n°-C,H,),((n°-C,H,4)P(C,- Me,T)?* (Me,T = 2,5-dimethylthiophene) with (u-S),Fe,- H5;),),_,ZMCH,C,H,;), (x= 1, (1); x = 0, (2) (W. Tikkanen, J. (CO)z~ and ( 4-COM p-RS)Fe,(CO); GW. Chen, C.L. Day, R.A. Manning, P. Watkins, M. Gonzalez and M. Borja), 123 Jacobson and R.J. Angelici), 21 Metallocycles Iron Reaction of iron dicarbonyl phosphine complexes of 2- Addition of imidazoles and aminoacids to the ethylenic bond in (phenylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- (n°-C,H,)Fe(CO),(7'-N-maleimidato) (B. Rudolf and J. Za- thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. krzewski), 313 Ackermann, F.V. Mikulec, A.J. Matzger, B.J. Antonio, M.C. Bond shift isomerization in a heterodiene complexed to Fe(CO), (H. Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Cherkaoui, J. Martelli and R. Grée), 311 Model complexes FeCl,—H,O: a specific system for arylacetylene hydration (J.P. Syndiospezifische Polymerisation von Propylen: Modellverbindungen Damiano and M. Postel), 303 des Typs (C,,H,_,,R,CMe,C;H,)ZrH,C=PCMHe,R) (n = Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- 0, 2; R= H, Me; R’ = Me, Et) (H.G. Alt und R. Zenk), 177 lane (H. Lang, M. Weinmann und L. Zsolnai), 277 Molecular adducts New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ Adduct formation between (Ph,SbI),O and I, (M.J. Aimond, M.G.B. (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 N.K. Dalley), 9 Molybdenum Reaction of iron dicarbonyl phosphine complexes of 2- Reactions of SmI,(THF), with [Cp’Mo(CO),],Hg (Cp’=C,;H5 or (phenylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- C;Me;s ): crystal and molecular structures of [(THF),1,Sm(p- thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. OC)MoACO),(C;H;)] and [(C;Me;)Mo(CO),], (G. Lin and W.-T. Ackermann, F.V. Mikulec, AJ. Matzger, B.J. Antonio, M.C. Wong), 271 Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Synthesis and structural characterization of a phosphido-bridged het- Synthesis and characterisation of CpCoFe,(CO),( 3-SX 3-Te). erobimetallic transition metal complex, (CO), Fe( u-PPh,),Mo- Crystal structure of CpCoFe,(CO),( 3;-SeX 3-Te) (P. Mathur, P. (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Au-Yeung and Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 T.C.W. Mak), 155 Synthesis and structural characterization of a phosphido-bridged het- erobimetallic transition metal complex, (CO), Fe( -PPh,)>Mo- (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, $.C.F. Au-Yeung and O-metallation ; T.C.W. Mak), 155 C- and O-metallation of N-benzylideneamines by palladium (II). Unexpected products resulting from reactions of Cp* Ir(°-2,5- Synthesis and X-ray crystal structure of [Pd(2-{CH=N-(CH,).,- Me,T)?* (Me,T = 2,5-dimethylthiophene) with ( u-S),Fe,- 4'(MeO)C,H ,}-4,5-(MeO),C,H,)BrPPh,)] (J. Albert, J. (CO)2~ and ( u-COX u-RS)Fe,(CO); (J. Chen, C.L. Day, R.A. Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Jacobson and R.J. Angelici), 21 Organometallic Unusual chromic behaviour of the solid supramolecular 3D polymers Organometallic and carbonyl compounds of cadmium: analysis of [((Me;Sn),, Fe(CN),l. (n= 3/4) (S.E.H. Etaiw and A.M.A. crystallographic and structural data (C.E. Holloway and M. Ibrahim), 77 Melnik), 167 Subject Index of Volume 522 Organometallic hydrides Phosphines Organometallic hydrides as reactants in fullerene chemistry. Interac- Reaction of iron dicarbonyl phosphine complexes of 2- tion of the fullerenes C,. and C7) with HM(CO\PPh,), (M = Rh (phenylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- and Ir) and HIntC,H,,XPPh,;), (A.V. Usatov, K.N. Kudin, E.V. thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 Ackermann, F.V. Mikulec, A.J. Matzger, BJ. Antonio, M.C. Oxygen ligand Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Synthese von 7-Allyl—Palladium-Komplexen, stabilisiert durch Phosphorus dreizahnige Sauerstoffliganden [(C;H;)Co{P(OR),O},]” (B. Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden Domhover, H. Hamers, W. Klaui und M. Pfeffer), 197 (M. Herberhold, G. Frohmader und W. Milius), 185 *'P NMR Palladium Synthesis, *'— NMR data and X-ray analysis of a ruthenium(II) A way to obtain cyclopalladation of unsubstituted 2-phenylimidazole dimethylphenylphosphine complex with dimerized phenylacety- derivatives (F. Zamora, S. Luna, P. Amo-Ochoa, L.A. Martinez- lene: the structure of [(PhMe,P),Ru(n>-PhC ,CHPh)KPF,) (D.C. Cruz and A. Vegas), 97 Liles and P.F.M. Verhoeven), 33 at-Allyl—Palladium-Komplexe stabilisiert durch den tripodalen Sauer- Polymerization stoffliganden [(C;H,)Co{P(OMe),O},]~II . Eliminierung | statt Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- C-C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten stituierte Metallocenkomplex des Typs (C,,Hg_,,R,CR,C5H,)- Carbanionen (B. Domhéver und W. Kaui), 207 MCI,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = C- and O-metallation of N-benzylideneamines by palladium (II). Zr, Hf) (H.G. Alt und R. Zenk), 39 Synthesis and X-ray crystal structure of [Pd(2-(CH=N-(CH,),- Polymerization mechanism 4’-(MeO)C,,H ,}-4,5-(MeO),C,H,)Br(PPh,)] (J. Albert, J. Syndiospezifische Polymerisation von Propylen: Modellverbindungen Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 des Typs (C,,Hg_,R,,CMe,C;H,)ZrH,C=XPCMHe,R) (n= Cyclometallation of 2-phenylaniline and (R)-a-methylbenzylamine by 0, 2; R= H, Me; R’ = Me, Et) (H.G. Alt und R. Zenk), 177 palladium(I1) acetate. X-ray molecular structure of [Pd{2-(2’- Poly[(silanylene)thiophene] precursors NH,C,H,)C,H,}Br(PPh,)] (J. Albert, J. Granell, A. Luque, J. Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- Minguez, R. Moragas, M. Font-Bardia and X. Solans), 87 lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothienyl)di- Synthese von 7z-Allyl—Palladium-Komplexen, stabilisiert durch methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. dreizahnige Sauerstoffliganden [(C;H;)Co{P(OR),O},]” (B. Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), Domhover, H. Hamers, W. Klaui und M. Pfeffer), 197 213 Palladium catalysis Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- Reactivity pling reactions between primary or secondary phosphines and Synthesis reactivity and molecular structure of 2'-methylspiro{cyclo- functional aryliodides — a novel synthetic route to water soluble hexane-1,3’-3H-indole] chromium tricarbonyl complex (J.G. phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Stelzer), 69 Review P-C cross coupling Organometallic and carbonyl compounds of cadmium: analysis of Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- crystallographic and structural data (C.E. Holloway and M. pling reactions between primary or secondary phosphines and Melnik), 167 functional aryliodides — a novel synthetic route to water soluble Rhodates phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. Variable temperature multidimensional NMR study of anionic Rh(1) Stelzer), 69 anilido [(R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. Pentamethylcyclopentadiene Commenges, D. Neibecker and L. Rosenberg), 117 Reactions of Ru,(u-dppmXCO),, with unsaturated hydrocarbons. Rhodium Pentamethylcyclopentadiene. X-ray structure of Ru,( u-HX p,- Diastereoselective synthesis of a-silylphosphetanes. An approach to PPhCH,, PPh, X u-7' : 7°-CH,C,;Me,XCO), (M.I. Bruce, P.A. monodentate, P—O chelating and trans-chelating chiral ligands Humphrey, B.W. Skelton and A.H. White), 259 (A. Marinetti, V. Kruger, C. Le Menn and L. Ricard), 223 Pentamethylcyclopentadienyl Organometallic hydrides as reactants in fullerene chemistry. Interac- Unexpected products resulting from reactions of Cp* Ir(n°-2,5- tion of the fullerenes C,,. and C7) with HM(COPPh,), (M = Rh Me,T)** (Me,T = 2,5-dimethylthiophene) with (u-S),-Fe, and Ir) and HIr(C,H,,PPh,), (A.V. Usatov, K.N. Kudin, E.V. (CO);~ and ( u-COX u-RS)Fe,(CO)5 (J. Chen, C.L. Day, R.A. Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 Jacobson and R.J. Angelici), 21 Ruthenium Phenyl Reactions of Ru,(u-dppmXCO),,. with unsaturated hydrocarbons. 'H NMR spectra of Ph,SbX, PhSbX,, and Ph,SbX, (X = Cl, Br, I); Pentamethylcyclopentadiene. X-ray structure of Ru,( u-HX p;3- '21Sb Mossbauer spectra of PhSbX, and crystal structure of PPh,C PPHh, X u-7' : 7°-CH,C,Me,XCO), (M.I. Bruce, P.A. Ph,SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. Humphrey, B.W. Skelton and A.H. White), 259 Offermann), 237 Some neutral ruthenium vinylidene complexes and a novel 1,3- Phosphido complex elimination reaction: preparation of chiral ruthenium acetylides Synthesis and structural characterization of a phosphido-bridged het- (M.I. Bruce, B.C. Hall, N.N. Zaitseva, B.W. Skelton and A.H. erobimetallic transition metal complex, (CO),Fe( y- White), 307 PPh, ),Mo(CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Synthesis, *'P NMR data and X-ray analysis of a ruthenium(II) Au-Yeung and T.C.W. Mak), 155 dimethylphenylphosphine complex with dimerized phenylacety- Phosphine complexes lene: the structure of [(PhMe,P),Ru(n°-PhC ,CHPh)(PF,) (D.C. Variable temperature multidimensional NMR study of anionic Rh(I) Liles and P.F.M. Verhoeven), 33 anilido [(R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. Synthesis and structure of ruthenium(II)-diene complexes (E. Commenges, D. Neibecker and L. Rosenberg), 117 Meléndez, R. Ilarraza, G.P.A. Yap and A.L. Rheingold), | 326 Subject Index of Volume 522 Samarium methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. Reactions of SmI,(THF), with [Cp’Mo(CO),],Hg (Cp’= C,;H5 or Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), CMe; ): crystal and molecular structures of [((THF),1,Sm(- 213 OC)MACO),(C,H;)] and [((C,Me,)Mo(CO),], (G. Lin and W.-T. Synthesis reactivity and molecular structure of 2’-methylspiro|cyclo- Wong), 271 hexane-1,3’-3H-indole] chromium tricarbonyl complex (.G. '21Sb Mossbauer spectra Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 'H NMR spectra of Ph,SbX, PhSbX, ,a nd Ph ,SbX,, (X = Cl, Br, D; '2!Sb Méssbauer spectra of PhSbX, and crystal structure of Ph,SbI (G. Alonzo, HJ. Breunig, M. Denker, K.H. Ebert and W. Offermann), 237 Tellurium Selenium Synthesis and characterisation of CpCoFe (CO),( ;-SX 13-Te). Synthesis and characterisation of CpCoFe,(CO),( u3-SX w3-Te). Crystal structure of CpCoFe,(CO)¢( 2 3-SeX 3-Te) (P. Mathur, P. Crystal structure of CpCoFe,(CO),( 2 3-SeX 23-Te) (P. Mathur, P. Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 Tertiary and secondary phosphines Silicon Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- pling reactions between primary or secondary phosphines and lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothienyl)di- functional aryliodides — a novel synthetic route to water soluble methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), Stelzer), 69 213 Tetramercurated methane Lithiation and silylation reactions of 1,4-bis(1,1,1,3,3,3-hexafluoro-2- Synthesis and crystal structures of tetrakis(nitratomercurio)methane hydrox y-2-propyl)benzene (J.W. Fitch, III, P.E. Cassidy and M.J. monohydrate and bis(sulphatomercurio)bis(aquamercurio)methane Ahmed), 55 (D. Grdenié, B. Korpar-Colig and D. Matkovié-Calogovié), 297 Silyl Thienylsilanes Diastereoselective synthesis of a-silylphosphetanes. An approach to Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- monodentate, P—O chelating and trans-chelating chiral ligands lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothieny])di- (A. Marinetti, V. Kruger, C. Le Menn and L. Ricard), 223 methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. Solid-state structures Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ 213 (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and Thiophene N.K. Dalley), 9 Unexpected products resulting from reactions of Cp* In(n>-2,5- Spectroscopic data Me.T)** (Me,T = 2,5-dimethylthiophene) with (-S),Fe,- 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- (CO)¢~ and ( 4-COX w-RS)Fe,(CO); (J. Chen, C.L. Day, R.A. zink-Verbindungen: Zusammenhang zwischen Zn—N-Abstand und Jacobson and R.J. Angelici), 21 R-Zn—R’-Bindungswinkel (M. Westerhausen, M. Wieneke und Three-dimensional polymers W. Schwarz), 137 Unusual chromic behaviour of the solid supramolecular 3D polymers Spiroindolenine [((Me,Sn),, Fe(CN),l. (mn =3/4) (S.E.H. Etaiw and A.M.A. Synthesis reactivity and molecular structure of 2’-methylspiro[cyclo- Ibrahim), 77 hexane-1,3’-3H-indole] chromium tricarbonyl complex (J.G. Tin Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Unusual chromic behaviour of the solid supramolecular 3D polymers Stiboxane [((Me,Sn),,Fe(CN),L. (2 =3/4) (S.E.H. Etaiw and A.M.A. Adduct formation between (Ph,SbI),O and I, (M.J. Almond, M.G.B. Ibrahim), 77 Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 Titanium Sulfur Interaction of carbon dioxide with the bis(trimethylsilylacetylene Unexpected products resulting from reactions of Cp* Inn°-2,5- complex of permethyltitanocene: synthesis and structure of the Me,T)?* (Me,T = 2,5-dimethylthiophene) with ( -S),Fe,- binuclear carbonate complex of permethyltitanocene (Cp; Ti),CO, (CO)2~ and ( 4-COX u-RS)Fe,(CO)g (J. Chen, C.L. Day, R.A. (V.V. Burlakov, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, Jacobson and R.J. Angelici), 21 V.B. Shur, U. Rosenthal and U. Thewalt), 241 Supramolecular polymers TMEDA complexes Unusual chromic behaviour of the solid supramolecular 3D polymers 1,2-Bis(dimeth ylamino)ethan-Komplexe von heteroleptischen Alkyl- [((Me,Sn),,Fe(CN),}. (2 = 3/4) (S.E.H. Etaiw and A.M.A. zink-Verbindungen: Zusammenhang zwischen Zn—N-Abstand und Ibrahim), 77 R—Zn—R’-Bindungswinkel (M. Westerhausen, M. Wieneke und Syndiospecific polymerization of propylene W. Schwarz), 137 Syndiospezifische Polymerisation von Propylen: Modellverbindungen Tripledecker complexes des Typs (C,,H,_ ,,R,CMe,C.H ,)Zr(H,C=CHR’ XPMe,) (n= Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden 0, 2; R = H, Me; R’ = Me, Et) (H.G. Alt und R. Zenk), 177 (M. Herberhold, G. Frohmader und W. Milius), 185 Syndiotactic polypropylene Tripodal ligand Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- a-Allyl—Palladium-Komplexe stabilisiert durch den tripodalen Sauer- stituierte Metallocenkomplex des Typs (C,,Hg_,,R,CR,C5H,)- stoffliganden [(C,H,)Co{P(OMe),0},] II. Eliminierung _ statt MCI,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = C-—C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten Zr, Hf) (H.G. Alt und R. Zenk), 39 Carbanionen (B. Domhéver und W. Kaui), 207 Synthesis Synthese von 7-Allyl—Palladium-Komplexen, stabilisiert durch Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- dreizihnige Sauerstoffliganden [(C;H;)Co{P(OR),O},]> (B. lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothieny)di- Domhover, H. Hamers, W. Kaui und M. Pfeffer), 197 Subject Index of Volume 522 327 Uranium NH,C,H,)C,H,}BrPPh,)] (J. Albert, J. Granell, A. Luque, J. Reactivity of the cationic uranium amide compound [U(7- Minguez, R. Moragas, M. Font-Bardia and X. Solans), 87 C,H, XNEt, XOC,H;[)BP,h, ] (C. Boisson, J.C. Berthet, M. Synthesis and crystal structures of tetrakis(nitratomercurio)methane Ephritikhine, M. Lance and M. Nierlich), 249 monohydrate and bis(sulphatomercurio)bis(aquamercurio)methane (D. Grdenié, B. Korpar-Colig and D. Matkovié-Calogovié), 297 Vanadium Synthesis reactivity and molecular structure of 2’-methylspiro[cyclo- Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden hexane-1,3’-3H-indole] chromium tricarbonyl complex (J.G. (M. Herberhold, G. Frohmader und W. Milius), 185 Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Vinyl chlorosilanes X-ray structures Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- lane (H. Lang, M. Weinmann und L. Zsolnai), 277 zink- Verbindungen: Zusammenhang zwischen Zn—N-Abstand und Vinylidene R-—Zn—R’-Bindungswinkel (M. Westerhausen, M. Wieneke und Some neutral ruthenium vinylidene complexes and a novel 1,3- W. Schwarz), 137 elimination reaction: preparation of chiral ruthenium acetylides (M.I. Bruce, B.C. Hall, N.N. Zaitseva, B.W. Skelton and A.H. White), 307 Zinc 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- Water soluble phosphines zink- Verbindungen: Zusammenhang zwischen Zn—N-Abstand und Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- R—Zn—R’-Bindungswinkel (M. Westerhausen, M. Wieneke und pling reactions between primary or secondary phosphines and W. Schwarz), 137 functional aryliodides — a novel synthetic route to water soluble Zirconium phosphines (O. Herd, A. He8ler, M. Hingst, M. Tepper and O. Preparation, characterization and carbonylation of the ring-functional- Stelzer), 69 ized dibenzyl zirconocenes, (n°-C5H;),((5Hn 4°)P-(CC. - H5),)5_,Z"(CH,C,H5)> (x = 1, (1); x= 0, (2) (W. Tikkanen, J. X-ray crystallography Manning, P. Watkins, M. Gonzalez and M. Borja), 123 Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- (M. Herberhold, G. Frohmader und W. Milius), 185 stituierte Metallocenkomplex des Typs (C,,Hg_ ,R,,CR>C;H 4)- X-ray diffraction MCI,(n = 1,2; R= Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = Interaction of carbon dioxide with the bis(trimethylsilyDacetylene Zr, Hf) (H.G. Alt und R. Zenk), 39 complex of permethyltitanocene: synthesis and structure of the binuclear carbonate complex of permethyltitanocene (Cp; Ti),CO, (V.V. Burlakov, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, V.B. Shur, U. Rosenthal and U. Thewalt), 241 Book Reviews Synthesis, *'P NMR data and X-ray analysis of a ruthenium(ID Gmelin Handbook of Inorganic and Organometallic Chemistry (G.J. dimethylphenylphosphine complex with dimerized phenylacety- Leigh), 163 lene: the structure of [(PhMe,P),Ru(»’-PhC ,CHPh)KPF,) (D.C. Gmelin Handbook of Inorganic and Organometallic Chemistry (C. Liles and P.F.M. Verhoeven), 33 Eaborn), 164 Synthesis and characterisation of CpCoFe,(CO),( 4,-SX 3-Te). Lithium Chemistry: A Theoretical and Experimental Overview, A.-M. Crystal structure of CpCoFe,(CO),( 4 3-Se w3-Te) (P. Mathur, P. Sapse and P. v. R. Schleyer (Eds.) (C. Eaborn), 163 Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 Organosilicon Chemistry II: from molecules to materials, N. Auner X-ray structure and J. Weis (Eds.) (C. Eaborn), 164 C- and O-metallation of N-benzylideneamines by palladium (II). Photochemistry and Photophysics of Metal Complexes, D.M. Round- Synthesis and X-ray crystal structure of [Pd(2-(CH=N-(CH,),- hill (Ed.) (M. Poliakoff), 162 4’-(MeO)C,H 4}-4,5-(MeO),C,H,)BrPPh,;)] (J. Albert, J. Stereodirected Synthesis with Organoboranes, D.S. Matteson (Ed.) (S. Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Caddick), 161 Cyclometallation of 2-phenylaniline and ( R)-a-methylbenzylamine b The Chemistry of Metal CVD, T.T. Kodas and M.J. Hampden-Smith palladium(II) acetate. X-ray molecular structure of [Pd{2-(2’- (Eds.) (J.D. Smith), 161

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oft Chemistry x= LSEVIER Journal of Organometallic Chemistry 522 (1996) 319-320 Author Index of Volume 522 Ackermann, M.N., 105 Frohmader, G., 185 Minguez, J., 87 Ahmed, M.J., 55 Moragas, R., 59, 87 Albert, J., 59, 87 Gonzalez, M., 123 Moreau, C., 213 Almond, M.J., 265 Granell, J., 59, 87 Alonzo, G., 237 Grdeni¢é, D., 297 Neibecker, D., 117 Alt, H.G., 39, 177 Grée, R., 311 Nierlich, M., 249 Amberger, H.-D., 317 Novikov, Y.N., 147 Amo-Ochoa, P., 97 Hall, B.C., 307 Angelici, R.J., 21 Hamers, H., 197 Offermann, W., 237 Antonio, B.J., 105 Herberhold, M., 185 Au- Yeung, S.C.F., 155 Herd, O., 69 Pawelke, G., 129 HeBler, A., 69 Pfeffer, M., 197 Hingst, M., 69 Barron, M.C., 105 Postel, M., 303 Holloway, C.E., 167 Bartsch, R.A., 9 Holwerda, R.A., 9 Berthet, J.C., 249 Rheingold, A.L., 1 Humphrey, P.A., 259 Biran, C., 213 Ricard, L., 223 Boisson, C., 249 Rice, D.A., 265 Ibrahim, A.M.A., 77 Bordeau, M., 213 Rodriguez, J.G., 231 Ilarraza, R., 1 Borja, M., 123 Rosenberg, L., 117 Brauer, D.J., 129 Rosenthal, U., 241 Breunig, H.J., 237 Jacobson, R.A., 21 Rothe, J., 129 Bruce, M.I., 259, 307 Rudolf, B., 313 Klaui, W., 197, 207 Brunet, J.-J., 117 Korpar-Colig, B., 297 Burger, H., 129 Salisbury, G., 265 Kou, X., 9 Burlakov, V.V., 241 Sanz, J., 231 Kruger, V., 223 Satyanarayana, C.V.V., 291 Kudin, K.N., 147 Cassidy, P.E., 55 Schwarz, W., 137 Kus, P., 9 Chan, J.C.C., 155 Sekar, P., 291 Chen, J., 21 Serein-Spirau, F., 213 Lance, M., 249 Cherkaoui, H., 311 Shur, V.B., 241 Lang, H., 277 Chupa, A.L., 105 Skelton, B.W., 259, 307 Le Menn, C., 223 Commenges, G., 117 Solans, X., 59, 87 Li, S.-L., 155 Czech, B.P., 9 Stelzer, O., 69 Liles, D.C., 33 Struchkov, Yu.T., 241 Lin, G., 271 Dalley, N.K., 9 Luna, S., 97 Damiano, J.P., 303 Taylor, M.J., 265 Luque, A., 87 Day, C.L., 21 Tepper, M., 69 Denker, M., 237 Thewalt, U., 241 Mahon, M.F., 291 Dolgushin, F.M., 241 Mak, T.C.W., 155 Tikkanen, W., 123 Domhiover, B., 197, 207 Todd, M.J., 105 Manning, J., 123 Drew, M.G.B., 265 Marinetti, A., 223 Dunogués, J., 213 Martelli, J., 311 Urtutia, A., 231 Martinez-Cruz, L.A., 97 Usatov, A.V., 147 Ebert, K.H., 237 Mathur, P., 291 Edelmann, F.T., 317 Matkovié-Calogovié, D., 297 Vegas, A., 97 Ephritikhine, M., 249 Maitzger, A.J., 105 Verhoeven, P.F.M., 33 Eiaiw, S.E.H., 77 Meeker, K., 105 Vinogradova, L.E., 147 Meléndez, E., | Vorontsov, E.V., 147 Fitch, III, J.W., 55 Melnik, M., 167 Fonseca, I., 231 Mikulec, F.V., 105 Watkins, P., 123 Font-Bardia, M., 59, 87 Milius, W., 185 Weinmann, M., 277 Elsevier Science S.A. 320 Author Index of Volume 522 Westerhausen, M., 137 Yanovsky, A.I., 241 Zamora, F., 97 White, A.H., 259, 307 Yap, G.P.A., | Zenk, R., 39, 177 Wieneke, M., 137 Zhang, Z.-Z., 155 Wong, W.-T., 271 Zaitseva, N.N., 307 Zsolnai, L., 277 Woods, C., 105 Zakrzewski, J., 313 ELSEVIER Journal of Organomeiallic Chemistry 522 (1996) 321-327 Subject Index of Volume 522 Acetylenes Amide Reaction of iron dicarbonyl phosphine complexes of 2- Reactivity of the cationic uranium amide compound [U(7- (phen ylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- H,XNEt, XOC,H,),[BPh,] (C. Boisson, J.C. Berihet, M. thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. Ephritikhine, M. Lance and M. Nierlich), 249 Ackermann, F.V. Mikulec, AJ. Matzger, B.J. Antonio, M.C. Amido rhodium(I) complexes Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Variable temperature multidimensional NMR study of anionic Rh(1) Acyl derivatives anilido [((R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. Preparation, characterization and carbonylation of the ring-functional- Commenges, D. Neibecker and L. Rosenberg), 117 ized dibenzyl zirconocenes, (n°-C;H;),(n°-C5H 4)P(Ce- Amines H5),)>-,ZM(CH,C,¢H;)> (x =1, (1); x= 0, (2) (W. Tikkanen, J. Cyclometallation of 2-phenylaniline and (R)-a-methylbenzylamine by Manning, P. Watkins, M. Gonzalez and M. Borja), 123 alladium(II) acetate. X-ray molecular structure of [Pd{2-(2’- Addition to the ethylenic bond NH,C,H4)C,H4}Br(PPh,)] (J. Albert, J. Granell, A. Luque, J. Addition of imidazoles and aminoacids to the ethylenic bond in Minguez, R. Moragas, M. Font-Bardia and X. Solans), 87 (7°-C.5H;)Fe(CO),(7'-N-maleimidato) (B. Rudolf and J. Za- Amino acid krzewski), 313 Addition of imidazoles and aminoacids to the ethylenic bond in Alk ylzinc-amide (n°-C;H)Fe(CO),(n'-N-maleimidato) (B. Rudolf and J. Za- 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- krzewski), 313 zink-Verbindungen: Zusammenhang zwischen Zn-N-Abstand und Anilides R—Zn—R-Bindungswinkel (M. Westerhausen, M. Wieneke und Variable temperature multidimensional NMR study of anionic Rh(1) W. Schwarz), 137 anilido [((R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. Alkylzinc-chloride Commenges, D. Neibecker and L. Rosenberg), 117 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- Antimony zink-Verbindungen: Zusammenhang zwischen Zn-N-Abstand und 'H NMR spectra of Ph,SbX, PhSbX,, and Ph,SbX, (X= Cl, Br, D; R-—Zn—R-Bindungswinkel (M. Westerhausen, M. Wieneke und "Sb Mossbauer spectra of PhSbX, sd cove structure of W. Schwarz), 137 Ph, SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. Alkyne Offerman), 237 FeCl,-H,O: a specific system for arylacetylene hydration (J.P. Adduct formation between (Ph,SbI),0 and I, (M.J. Almond, M.G.B. Damiano and M. Postel), 303 Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 Alkyne complexes 7-Bonding Interaction of carbon dioxide with the bis(trimethylsilyl)acetylene Reaction of iron dicarbonyl phosphine complexes of 2- complex of permethyltitanocene: synthesis and structure of the (phenylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- binuclear carbonate complex of permethyltitanocene (Cp; Ti),CO; thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. (V.V. Burlakov, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, Ackermann, F.V. Mikulec, A.J. Matzger, B.J. Antonio, M.C. V.B. Shur, U. Rosenthal and U. Thewalt), 241 Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Alkyne dimerization Synthesis, *'P NMR data and X-ray analysis of a ruthenium(II) Boron dimethylphenylphosphine complex with dimerized phenylacety- [2 + 3] Cycloaddition reactions of dimethylamino-bis(trifluorometh- lene: the structure of [(PhMe, P),Ru(n°-PhC,;CHPh)KPF,) (D.C. yl)borane, (CF,),BNMe,, with nitrile oxides, nitrones and Liles and P.F.M. Verhoeven), 33 Me,C= SO,. Crystal and_molecular structure of (CF,), B-NMe,- Alkynyl chlorosilanes ‘BuC=N-O and (CF,), B-NMe,—CMe,-S(=O)-O (D.J. Brauer, Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- H. Biirger, G. Pawelke andJ . Rothe), 129 lane (H. Lang, M. Weinmann und L. Zsolnai), 277 Bromide Allyl Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- Synthese von 7-Allyl—Palladium-Komplexen, stabilisiert durch pling reactions between primary or secondary phosphines and dreizihnige Sauerstoffliganden [(C;H;)Co{P(OR),0},]” (B. functional aryliodides — a novel synthetic route to water soluble Domhéver, H. Hamers, W. Kaui und M. Pfeffer), 197 phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. Allyl, Oxygen ligand Stelzer), 69 a-Allyl-Palladium-Komplexe stabilisiert durch den tripodalen Sauer- stoffliganden [(C,H,;)Cof{P(OMe),0},I] . Eliminierung - statt Coo C—C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten Organometallic hydrides as reaciants in fullerene chemistry. Interac- Carbanionen (B. Domhiver und W. Kaui), 207 tion of the fullerenes C,,. and C7. with HM(COXPPh,), (M = Rh Elsevier Science S.A. Subject Index of Volume 522 and Ir) and HI(C,H,,PPh,), (A.V. Usatov, K.N. Kudin, E.V. Chromic behaviour Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 Unusual chromic behaviour of the solid supramolecular 3D polymers [((Me,Sn),, Fe(CN),]. (n= 3/4) (S.E.H. Etaiw and A.M.A. Cro Organometallic hydrides as reactants in fullerene chemistry. Interac- Ibrahim), 77 tion Of the fullerenes Cg and C7) with HM(COXPPh,), (M = Rh Chromium and Ir) and HIXC,H,,PPh;), (A.V. Usatov, K.N. Kudin, E.V. Synthesis reactivity and molecular structure of 2’-methylspiro{cyclo- Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 hexane-1,3’-3H-indole] chromium tricarbonyl complex (J.G. Cadmium Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Organometallic and carbonyl compounds of cadmium: analysis of Cluster crystallographic and structural data (C.E. Holloway and M. Reactions of Ru,(y-dppmXCO),. with unsaturated hydrocarbons. Melnik), 167 Pentamethylcyclopentadiene. X-ray structure of Ru,( u-HX p;- Carbon dioxide PPhCH, PPh, u-7': n°-CH,C;Me,XCO), (M.I. Bruce, P.A. Interaction of carbon dioxide with the bis(trimethylsilyl)acetylene Humphrey, B.W. Skelton and A.H. White), 259 complex of permethyltitanocene: synthesis and structure of the Synthesis and characterisation of CpCoFe,(CO),( 43-SX u3-Te). binuclear carbonate complex of permethyltitanocene (Cp; Ti),CO, Crystal structure of CpCoFe,(CO),( 2 3-SeX 2 3-Te) (P. Mathur, P. (V.V. Burlakov, F.M: Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 V.B. Shur, U. Rosenthal and U. Thewait), 241 C-metallation Carbonyl C- and O-metallation of N-benzylideneamines by palladium (II). Addition of imidazoles and aminoacids to the ethylenic bond in Synthesis and X-ray crystal structure of [Pd(2-(CH=N-~(CH,),- (n°-C5H,)Fe(CO),(y!-N-maleimidato) (B. Rudolf and J. Za- 4'-(MeO)C,H ,}-4,5-(MeO),€,H,)Br(PPh,)] (J. Albert, J. krzewski), 313 Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Bond shift isomerization in a heterodiene complexed to Fe(CO), (H. Cobalt Cherkaoui, J. Martelli and R. Grée), 311 Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- Organometallic and carbonyl compounds of cadmium: analysis of lane (H. Lang, M. Weinmann und L. Zsolnai), 277 crystallographic and structural data (C.E. Holloway and M. Synthesis and characterisation of CpCoFe,(CO),( 1 3-SX w3-Te). Melnik), 167 Crystal structure of CpCoFe,(CO),( w3-SeX 3-Te) (P. Mathur, P. Reactions of SmI,(THF), with [Cp’'Mo(CO),],Hg (Cp’= C,H; or Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 C,Me;): crystal and molecular structures of [(THF),1,Sm( p- Coordination ability OC)Mo(CO),(C;H)] and [((C;Me,)Mo(CO),], (G. Lin and W.-T. Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- Wong), 271 lane (H. Lang, M. Weinmann und L. Zsolnai), 277 Synthesis and characterisation of CpCoFe,(CO),( 3-SX u;-Te). Crystal structure Crystal structure of CpCoFe,(CO),( w3-SeX s23-Te) (P. Mathur, P. 'H NMR spectra of Ph, SbX, PhSbX, , and Ph,SbX, (X = Cl, Br, 1); Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 '?'Sb Mossbauer spectra of PhSbX, and crystal structure of Synthesis and structural characterization of a phosphido-bridged het- Ph,SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. erobimetallic transition metal complex, (CO),Fe( 4-PPh,),Mo- Offermann), 237 (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Au-Yeung and Adduct formation between (Ph,SbI),O and I, (M.J. Almond, M.G.B. T.C.W. Mak), 155 Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 Synthesis reactivity and molecular structure of 2’-methylspiro[cyclo- Organometailic and carbonyl compounds of cadmium: analysis of hexane-],3’-3H-indole] chromium tricarbonyl complex (J.G. crystallographic and structural data (C.E. Holloway and M. Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Melnik), 167 Carbonylation Reactions of Ru,(y-dppmXCO),. with unsaturated hydrocarbons. Preparation, characterization and carbonylation of the ring-functional- Pentamethylcyclopentadiene. X-ray structure of Ru,( u-HX p,- ized dibenzyl zirconocenes, (n°-C5H5),((n°-C;H4)P(C,- PPh,C PPHh, X u-7' : 7°-CH,C,Me,XCO), (M.I. Bruce, P.A. H,)2)2_ ,ZMCH,C,H;)> (x= 1, (I); x = 0, (2) (W. Tikkanen, J. Humphrey, B.W. Skelton and A.H. White), 259 Manning, P. Watkins, M. Gonzalez and M. Borja), 123 Reactions of Sm1,(THF), with [Cp’Mo(CO),],Hg (Cp’ = C,H5 or Catalysis C;Me; ): crystal and molecular structures of [(THF),I,Sm( p- Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- OC)MoACO),(C;H,)] and [(C; Me, )Mo(CO),], (G. Lin and W.-T. stituierte Metallocenkomplex des Typs (C,,Hg_,,R,,CR>C5H,)- Wong), 271 MCI,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = Some neutral ruthenium vinylidene complexes and a novel 1,3- Zr, Hf) (H.G. Alt und R. Zenk), 39 elimination reaction: preparation of chiral ruthenium acetylides Cation (M.I. Bruce, B.C. Hall, N.N. Zaitseva, B.W. Skelton and A.H. Reactivity of the cationic uranium amide compound [U(7- White), 307 C,Hg XNEt,XOC,4H,),I[BPh,] (C. Boisson, J.C. Berthet, M. Synthese von 7-Allyl—Palladium-Komplexen, _ stabilisiert durch Ephritikhine, M. Lance and M. Nierlich), 249 dreizahnige Sauerstoffliganden [(C;H;)Co{P(OR),O},]> (B. Chirality Domhiéver, H. Hamers, W. Klaui und M. Pfeffer), 197 DiastereOselective synthesis of a-silylphosphetanes. An approach to Synthesis, *'P NMR data and X-ray analysis of a ruthenium(II) monodentate, P—O chelating and trans-chelating chiral ligands dimethylphenylphosphine complex with dimerized phenylacety- (A. Marinetti, V. Kruger, C. Le Menn and L. Ricard), 223 lene: the structure of [(PhMe,P),Ru(°-PhC ;CHPh)KPF,) (D.C. Some neutral ruthenium vinylidene complexes and a novel 1,3- Liles and P.F.M. Verhoeven), 33 elimination reaction: preparation of chiral ruthenium acetylides Synthesis and structural characterization of a phosphido-bridged het- (M.I. Bruce, B.C. Hall, N.N. Zaitseva, B.W. Skelton and A.H. erobimetallic transition metal complex, (CO), Fe( y-PPh,),Mo- White), 307 Subject Index of Volume 522 (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Au- Yeung and Ferrocenes T.C.W. Mak), 155 New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ Cubane cluster (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden N.K. Dalley), 9 (M. Herberhold, G. Frohmader und W. Milius), 185 Ferrocenophanes Cycloaddition reactions New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ [2 + 3] Cycloaddition reactions of dimethylamino-bis(trifluorometh- (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and ylborane, (CF,),BNMe,, with nitrile oxides, nitrones and N.K. Dalley), 9 Me,C=SO,. Crystal and_molecular structure of (CF;),B-NMe>- Fluorenyl ‘BuC=N-O and (CF, ),B—NMe,-CMe,—S(=0)—O (D.J. Brauer, Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- H. Birger, G. Pawelke and J. Rothe), 129 stituierte Metallocenkomplex des Typs (C,,Hg_ ,R,,CR’C5H ,)- Cyclometallation MCI,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = C- and O-metallation of N-benzylideneamines by palladium (II). Zr, Hf) (H.G. Alt und R. Zenk), 39 Synthesis and X-ray crystal structure of [Pd(2-(CH=N-(CH,),- 4'-(MeO)C, H,}-4,5-(MeO),C,H>)Br(PPh,)] (J. Albert, J. Group 12 Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Organometallic and carbonyl compounds of cadmium: analysis of Cyclometallation of 2-phenylaniline and (R)-a-methylbenzylamine by crystallographic and structural data (C.E. Holloway and M. alladium(II) acetate. X-ray molecular structure of [Pd{2-(2’- Melnik), 167 NH ,C,H,)C,H ,}Br(PPh,)] (J. Albert, J. Granell, A. Luque, J. Group 15 Minguez, R. Moragas, M. Font-Bardfa and X. Solans), 87 'H NMR spectra of Ph,SbX, PhSbX,, and Ph,SbX , (X = Cl, Br, I); Cyclooctatetraene 2'Sb Mossbauer spectra of PhSbX, and crystal structure of Reactivity of the cationic uranium amide compound [U(7- Ph, SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. C,gH,KXOC N,HEg),t][B,Ph, ] (C. Boisson, J.C. Berthet, M. Offermann), 237 Ephritikhine, M. Lance and M. Nierlich), 249 Cyclopalladation A way to obtain cyclopalladation of unsubstituted 2-phenylimidazole Hafnium derivatives (F. Zamora, S. Luna, P. Amo-Ochoa, L.A. Martinez- Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- Cruz and A. Vegas), 97 stituierte Metallocenkomplex des Typs (C,,Hg_ ,R,,CR>C;4H) - C- and O-metallation of N-benzylideneamines by palladium (II. MC1,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = Synthesis and X-ray crystal structure of [Pd(2-(CH=N-(CH,),- Zr, Hf) (H.G. Alt und R. Zenk), 39 4'-(MeO)C, H,}-4,5-(MeO),C,H>)BAPPh;)] (J. Albert, J. Halide Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothieny])di- Diene complexes methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. Synthesis and structure of ruthenium(II)—diene complexes (E. Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), Meléndez, R. Ilarraza, G.P.A. Yap and A.L. Rheingold), | 213 trans-Diene coordination Heterobimetallic complex Synthesis and structure of ruthenium(II)—diene complexes (E. Synthesis and structural characterization of a phosphido-bridged het- Meléndez, R. Ilarraza, G.P.A. Yap and A.L. Rheingold), | erobimetallic transition metal complex, (CO),Fe( 4.-PPh,),Mo Dimethylamino-bis(trifluormethy])borane (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Au-Yeung and [2 + 3] Cycloaddition reactions of dimethylamino-bis(trifluorometh- T.C.W. Mak), 155 yl)borane, (CF,),BNMe,, with nitrile oxides, nitrones and Heterodiene complex Me,C=SO,. Crystal and _m olecular structure_of (CF,), B-NMe,- Bond shift isomerization in a heterodiene complexed to Fe(CO), CH. BuC=N-O and (CF, ),B—NMe,-CMe,—S(=0)-O (D.J. Brauer, Cherkaoui, J. Martelli and R. Grée), 311 'H NMR spectra H. Birger, G. Pawelke and J. Rothe), 129 Diphosphine 'H NMR spectra of Ph,SbX, PhSbX,, and Ph,SbX , (X = Cl, Br, D); Diastereoselective synthesis of a-silylphosphetanes. An approach to '21Sb Mossbauer spectra of PhSbX, and crystal structure of monodentate, P—O chelating and trans-chelating chiral ligands Ph, SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. (A. Marinetti, V. Kruger, C. Le Menn and L. Ricard), 223 Offermann), 237 Hydration Electrochemical synthesis FeCl,—H,O: a specific system for arylacetylene hydration (J.P. Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- Damiano and M. Postel), 303 lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothienyl)di- Hydroamination methylchlorosilane, precursors of polyl[(silanylene)thiophene]s (C. Variable temperature multidimensional NMR study of anionic Rh(1) Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunoguss), anilido [(R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. 213 Commenges, D. Neibecker and L. Rosenberg), 117 Electrochemistry Hydroarylation New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ Variable temperature multidimensional NMR study of anionic Rh(1) (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and anilido [(R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. N.K. Dalley), 9 Commenges, D. Neibecker and L. Rosenberg), 117 Elimination reaction Hydrodesul furization a-Allyl—Palladium-Komplexe stabilisiert durch den tripodalen Sauer- Unexpected products resulting from reactions of Cp * In7>-2,5- stoffliganden [(C;H;)Co{P(OMe),O},]~ II. Eliminierung statt Me,T)?* (Me,T = 2,5-dimethylthiophene) with (-S),Fe,- C-C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten (CO){~ and ( u-COX u-RS)Fe,(CO); (J. Chen, C.L. Day, R.A. Carbanionen (B. Domhéver und W. Klaui), 207 Jacobson and R.J. Angelici), 21 324 Subject Index of Volume 522 Hydrogen bonding Kinetic studies New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ Bond shift isomerization in a heterodiene complexed to Fe(CO), (H. (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and Cherkaoui, J. Martelli and R. Grée), 311 N.K. Dalley), 9 Ligand substitution at-Allyl—Palladium-Komplexe stabilisiert durch den tripodalen Sauer- Imidazole stoffliganden [(C;H;)Co{P(OMe),O},]~ II. Eliminierung _ statt Addition of imidazoles and aminoacids to the ethylenic bond in C-—C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten (n>-C,H,)Fe(CO),(7'-N-maleimidato) (B. Rudolf and J. Za- Carbanionen (B. Domhéver und W. Klaui), 207 krzewski), 313 Lithium Imidazoles Lithiation and silylation reactions of 1,4-bis(1,1,1,3,3,3-hexafluoro-2- A way to obtain cyclopalladation of unsubstituted 2-phenylimidazole hydroxy-2-propyl)benzene (J.W. Fitch, III, P.E. Cassidy and M.J. derivatives (F. Zamora, S. Luna, P. Amo-Ochoa, L.A. Martinez- Ahmed), 55 Cruz and A. Vegas), 97 Iodide Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- Maleimide anion pling reactions between primary or secondary phosphines and Addition of imidazoles and aminoacids to the ethylenic bond in functional aryliodides — a novel synthetic route to water soluble (n°-C;H,)Fe(CO),(7'-N-maleimidato) (B. Rudolf and J. Za- phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. krzewski), 313 Stelzer), 69 Manganese Iodine Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- Adduct formation between (Ph,SbI),O and I, (M.J. Almond, M.G.B. lane (H. Lang, M. Weinmann und L. Zsolnai), 277 Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 Mercury Iridium Synthesis and crystal structures of tetrakis(nitratomercurio)methane Organometallic hydrides as reactants in fullerene chemistry. Interac- monohydrate and bis(sulphatomercurio)bis(aquamercurio)methane tion of the fullerenes C,, and C,, with HM(COXPPh,), (M = Rh (D. Grdenié, B. Korpar-Colig and D. Matkovié-Calogovié), 297 and Ir) and HIr(C,H,>PPh3), (A.V. Usatov, K.N. Kudin, E.V. Metallocenes Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 Preparation, characterization and carbonylation of the ring-functional- Unexpected products resulting from reactions of Cp* Ir(n>-2,5- ized dibenzyl zirconocenes, (n°-C,H,),((n°-C,H,4)P(C,- Me,T)?* (Me,T = 2,5-dimethylthiophene) with (u-S),Fe,- H5;),),_,ZMCH,C,H,;), (x= 1, (1); x = 0, (2) (W. Tikkanen, J. (CO)z~ and ( 4-COM p-RS)Fe,(CO); GW. Chen, C.L. Day, R.A. Manning, P. Watkins, M. Gonzalez and M. Borja), 123 Jacobson and R.J. Angelici), 21 Metallocycles Iron Reaction of iron dicarbonyl phosphine complexes of 2- Addition of imidazoles and aminoacids to the ethylenic bond in (phenylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- (n°-C,H,)Fe(CO),(7'-N-maleimidato) (B. Rudolf and J. Za- thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. krzewski), 313 Ackermann, F.V. Mikulec, A.J. Matzger, B.J. Antonio, M.C. Bond shift isomerization in a heterodiene complexed to Fe(CO), (H. Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Cherkaoui, J. Martelli and R. Grée), 311 Model complexes FeCl,—H,O: a specific system for arylacetylene hydration (J.P. Syndiospezifische Polymerisation von Propylen: Modellverbindungen Damiano and M. Postel), 303 des Typs (C,,H,_,,R,CMe,C;H,)ZrH,C=PCMHe,R) (n = Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- 0, 2; R= H, Me; R’ = Me, Et) (H.G. Alt und R. Zenk), 177 lane (H. Lang, M. Weinmann und L. Zsolnai), 277 Molecular adducts New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ Adduct formation between (Ph,SbI),O and I, (M.J. Aimond, M.G.B. (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 N.K. Dalley), 9 Molybdenum Reaction of iron dicarbonyl phosphine complexes of 2- Reactions of SmI,(THF), with [Cp’Mo(CO),],Hg (Cp’=C,;H5 or (phenylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- C;Me;s ): crystal and molecular structures of [(THF),1,Sm(p- thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. OC)MoACO),(C;H;)] and [(C;Me;)Mo(CO),], (G. Lin and W.-T. Ackermann, F.V. Mikulec, AJ. Matzger, B.J. Antonio, M.C. Wong), 271 Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Synthesis and structural characterization of a phosphido-bridged het- Synthesis and characterisation of CpCoFe,(CO),( 3-SX 3-Te). erobimetallic transition metal complex, (CO), Fe( u-PPh,),Mo- Crystal structure of CpCoFe,(CO),( 3;-SeX 3-Te) (P. Mathur, P. (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Au-Yeung and Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 T.C.W. Mak), 155 Synthesis and structural characterization of a phosphido-bridged het- erobimetallic transition metal complex, (CO), Fe( -PPh,)>Mo- (CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, $.C.F. Au-Yeung and O-metallation ; T.C.W. Mak), 155 C- and O-metallation of N-benzylideneamines by palladium (II). Unexpected products resulting from reactions of Cp* Ir(°-2,5- Synthesis and X-ray crystal structure of [Pd(2-{CH=N-(CH,).,- Me,T)?* (Me,T = 2,5-dimethylthiophene) with ( u-S),Fe,- 4'(MeO)C,H ,}-4,5-(MeO),C,H,)BrPPh,)] (J. Albert, J. (CO)2~ and ( u-COX u-RS)Fe,(CO); (J. Chen, C.L. Day, R.A. Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Jacobson and R.J. Angelici), 21 Organometallic Unusual chromic behaviour of the solid supramolecular 3D polymers Organometallic and carbonyl compounds of cadmium: analysis of [((Me;Sn),, Fe(CN),l. (n= 3/4) (S.E.H. Etaiw and A.M.A. crystallographic and structural data (C.E. Holloway and M. Ibrahim), 77 Melnik), 167 Subject Index of Volume 522 Organometallic hydrides Phosphines Organometallic hydrides as reactants in fullerene chemistry. Interac- Reaction of iron dicarbonyl phosphine complexes of 2- tion of the fullerenes C,. and C7) with HM(CO\PPh,), (M = Rh (phenylazo)pyridines with dimethyl acetylenedicarboxylate. Syn- and Ir) and HIntC,H,,XPPh,;), (A.V. Usatov, K.N. Kudin, E.V. thesis and crystal structure of a 2,3,1-diazaferrole complex (M.N. Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 Ackermann, F.V. Mikulec, A.J. Matzger, BJ. Antonio, M.C. Oxygen ligand Barron, M.J. Todd, K. Meeker, A.L. Chupa and C. Woods), 105 Synthese von 7-Allyl—Palladium-Komplexen, stabilisiert durch Phosphorus dreizahnige Sauerstoffliganden [(C;H;)Co{P(OR),O},]” (B. Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden Domhover, H. Hamers, W. Klaui und M. Pfeffer), 197 (M. Herberhold, G. Frohmader und W. Milius), 185 *'P NMR Palladium Synthesis, *'— NMR data and X-ray analysis of a ruthenium(II) A way to obtain cyclopalladation of unsubstituted 2-phenylimidazole dimethylphenylphosphine complex with dimerized phenylacety- derivatives (F. Zamora, S. Luna, P. Amo-Ochoa, L.A. Martinez- lene: the structure of [(PhMe,P),Ru(n>-PhC ,CHPh)KPF,) (D.C. Cruz and A. Vegas), 97 Liles and P.F.M. Verhoeven), 33 at-Allyl—Palladium-Komplexe stabilisiert durch den tripodalen Sauer- Polymerization stoffliganden [(C;H,)Co{P(OMe),O},]~II . Eliminierung | statt Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- C-C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten stituierte Metallocenkomplex des Typs (C,,Hg_,,R,CR,C5H,)- Carbanionen (B. Domhéver und W. Kaui), 207 MCI,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = C- and O-metallation of N-benzylideneamines by palladium (II). Zr, Hf) (H.G. Alt und R. Zenk), 39 Synthesis and X-ray crystal structure of [Pd(2-(CH=N-(CH,),- Polymerization mechanism 4’-(MeO)C,,H ,}-4,5-(MeO),C,H,)Br(PPh,)] (J. Albert, J. Syndiospezifische Polymerisation von Propylen: Modellverbindungen Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 des Typs (C,,Hg_,R,,CMe,C;H,)ZrH,C=XPCMHe,R) (n= Cyclometallation of 2-phenylaniline and (R)-a-methylbenzylamine by 0, 2; R= H, Me; R’ = Me, Et) (H.G. Alt und R. Zenk), 177 palladium(I1) acetate. X-ray molecular structure of [Pd{2-(2’- Poly[(silanylene)thiophene] precursors NH,C,H,)C,H,}Br(PPh,)] (J. Albert, J. Granell, A. Luque, J. Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- Minguez, R. Moragas, M. Font-Bardia and X. Solans), 87 lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothienyl)di- Synthese von 7z-Allyl—Palladium-Komplexen, stabilisiert durch methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. dreizahnige Sauerstoffliganden [(C;H;)Co{P(OR),O},]” (B. Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), Domhover, H. Hamers, W. Klaui und M. Pfeffer), 197 213 Palladium catalysis Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- Reactivity pling reactions between primary or secondary phosphines and Synthesis reactivity and molecular structure of 2'-methylspiro{cyclo- functional aryliodides — a novel synthetic route to water soluble hexane-1,3’-3H-indole] chromium tricarbonyl complex (J.G. phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Stelzer), 69 Review P-C cross coupling Organometallic and carbonyl compounds of cadmium: analysis of Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- crystallographic and structural data (C.E. Holloway and M. pling reactions between primary or secondary phosphines and Melnik), 167 functional aryliodides — a novel synthetic route to water soluble Rhodates phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. Variable temperature multidimensional NMR study of anionic Rh(1) Stelzer), 69 anilido [(R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. Pentamethylcyclopentadiene Commenges, D. Neibecker and L. Rosenberg), 117 Reactions of Ru,(u-dppmXCO),, with unsaturated hydrocarbons. Rhodium Pentamethylcyclopentadiene. X-ray structure of Ru,( u-HX p,- Diastereoselective synthesis of a-silylphosphetanes. An approach to PPhCH,, PPh, X u-7' : 7°-CH,C,;Me,XCO), (M.I. Bruce, P.A. monodentate, P—O chelating and trans-chelating chiral ligands Humphrey, B.W. Skelton and A.H. White), 259 (A. Marinetti, V. Kruger, C. Le Menn and L. Ricard), 223 Pentamethylcyclopentadienyl Organometallic hydrides as reactants in fullerene chemistry. Interac- Unexpected products resulting from reactions of Cp* Ir(n°-2,5- tion of the fullerenes C,,. and C7) with HM(COPPh,), (M = Rh Me,T)** (Me,T = 2,5-dimethylthiophene) with (u-S),-Fe, and Ir) and HIr(C,H,,PPh,), (A.V. Usatov, K.N. Kudin, E.V. (CO);~ and ( u-COX u-RS)Fe,(CO)5 (J. Chen, C.L. Day, R.A. Vorontsov, L.E. Vinogradova and Y.N. Novikov), 147 Jacobson and R.J. Angelici), 21 Ruthenium Phenyl Reactions of Ru,(u-dppmXCO),,. with unsaturated hydrocarbons. 'H NMR spectra of Ph,SbX, PhSbX,, and Ph,SbX, (X = Cl, Br, I); Pentamethylcyclopentadiene. X-ray structure of Ru,( u-HX p;3- '21Sb Mossbauer spectra of PhSbX, and crystal structure of PPh,C PPHh, X u-7' : 7°-CH,C,Me,XCO), (M.I. Bruce, P.A. Ph,SbI (G. Alonzo, H.J. Breunig, M. Denker, K.H. Ebert and W. Humphrey, B.W. Skelton and A.H. White), 259 Offermann), 237 Some neutral ruthenium vinylidene complexes and a novel 1,3- Phosphido complex elimination reaction: preparation of chiral ruthenium acetylides Synthesis and structural characterization of a phosphido-bridged het- (M.I. Bruce, B.C. Hall, N.N. Zaitseva, B.W. Skelton and A.H. erobimetallic transition metal complex, (CO),Fe( y- White), 307 PPh, ),Mo(CO), (S.-L. Li, Z.-Z. Zhang, J.C.C. Chan, S.C.F. Synthesis, *'P NMR data and X-ray analysis of a ruthenium(II) Au-Yeung and T.C.W. Mak), 155 dimethylphenylphosphine complex with dimerized phenylacety- Phosphine complexes lene: the structure of [(PhMe,P),Ru(n°-PhC ,CHPh)(PF,) (D.C. Variable temperature multidimensional NMR study of anionic Rh(I) Liles and P.F.M. Verhoeven), 33 anilido [(R,P),Rh(NHPh),]~, M* complexes (J.-J. Brunet, G. Synthesis and structure of ruthenium(II)-diene complexes (E. Commenges, D. Neibecker and L. Rosenberg), 117 Meléndez, R. Ilarraza, G.P.A. Yap and A.L. Rheingold), | 326 Subject Index of Volume 522 Samarium methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. Reactions of SmI,(THF), with [Cp’Mo(CO),],Hg (Cp’= C,;H5 or Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), CMe; ): crystal and molecular structures of [((THF),1,Sm(- 213 OC)MACO),(C,H;)] and [((C,Me,)Mo(CO),], (G. Lin and W.-T. Synthesis reactivity and molecular structure of 2’-methylspiro|cyclo- Wong), 271 hexane-1,3’-3H-indole] chromium tricarbonyl complex (.G. '21Sb Mossbauer spectra Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 'H NMR spectra of Ph,SbX, PhSbX, ,a nd Ph ,SbX,, (X = Cl, Br, D; '2!Sb Méssbauer spectra of PhSbX, and crystal structure of Ph,SbI (G. Alonzo, HJ. Breunig, M. Denker, K.H. Ebert and W. Offermann), 237 Tellurium Selenium Synthesis and characterisation of CpCoFe (CO),( ;-SX 13-Te). Synthesis and characterisation of CpCoFe,(CO),( u3-SX w3-Te). Crystal structure of CpCoFe,(CO)¢( 2 3-SeX 3-Te) (P. Mathur, P. Crystal structure of CpCoFe,(CO),( 2 3-SeX 23-Te) (P. Mathur, P. Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 Tertiary and secondary phosphines Silicon Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- pling reactions between primary or secondary phosphines and lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothienyl)di- functional aryliodides — a novel synthetic route to water soluble methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. phosphines (O. Herd, A. HeBler, M. Hingst, M. Tepper and O. Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), Stelzer), 69 213 Tetramercurated methane Lithiation and silylation reactions of 1,4-bis(1,1,1,3,3,3-hexafluoro-2- Synthesis and crystal structures of tetrakis(nitratomercurio)methane hydrox y-2-propyl)benzene (J.W. Fitch, III, P.E. Cassidy and M.J. monohydrate and bis(sulphatomercurio)bis(aquamercurio)methane Ahmed), 55 (D. Grdenié, B. Korpar-Colig and D. Matkovié-Calogovié), 297 Silyl Thienylsilanes Diastereoselective synthesis of a-silylphosphetanes. An approach to Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- monodentate, P—O chelating and trans-chelating chiral ligands lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothieny])di- (A. Marinetti, V. Kruger, C. Le Menn and L. Ricard), 223 methylchlorosilane, precursors of poly[(silanylene)thiophene]s (C. Solid-state structures Moreau, F. Serein-Spirau, M. Bordeau, C. Biran and J. Dunogués), New ferrocenophanes containing a hydrophobic, aromatic ‘pocket’ 213 (R.A. Bartsch, P. Kus, R.A. Holwerda, B.P. Czech, X. Kou and Thiophene N.K. Dalley), 9 Unexpected products resulting from reactions of Cp* In(n>-2,5- Spectroscopic data Me.T)** (Me,T = 2,5-dimethylthiophene) with (-S),Fe,- 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- (CO)¢~ and ( 4-COX w-RS)Fe,(CO); (J. Chen, C.L. Day, R.A. zink-Verbindungen: Zusammenhang zwischen Zn—N-Abstand und Jacobson and R.J. Angelici), 21 R-Zn—R’-Bindungswinkel (M. Westerhausen, M. Wieneke und Three-dimensional polymers W. Schwarz), 137 Unusual chromic behaviour of the solid supramolecular 3D polymers Spiroindolenine [((Me,Sn),, Fe(CN),l. (mn =3/4) (S.E.H. Etaiw and A.M.A. Synthesis reactivity and molecular structure of 2’-methylspiro[cyclo- Ibrahim), 77 hexane-1,3’-3H-indole] chromium tricarbonyl complex (J.G. Tin Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Unusual chromic behaviour of the solid supramolecular 3D polymers Stiboxane [((Me,Sn),,Fe(CN),L. (2 =3/4) (S.E.H. Etaiw and A.M.A. Adduct formation between (Ph,SbI),O and I, (M.J. Almond, M.G.B. Ibrahim), 77 Drew, D.A. Rice, G. Salisbury and M.J. Taylor), 265 Titanium Sulfur Interaction of carbon dioxide with the bis(trimethylsilylacetylene Unexpected products resulting from reactions of Cp* Inn°-2,5- complex of permethyltitanocene: synthesis and structure of the Me,T)?* (Me,T = 2,5-dimethylthiophene) with ( -S),Fe,- binuclear carbonate complex of permethyltitanocene (Cp; Ti),CO, (CO)2~ and ( 4-COX u-RS)Fe,(CO)g (J. Chen, C.L. Day, R.A. (V.V. Burlakov, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, Jacobson and R.J. Angelici), 21 V.B. Shur, U. Rosenthal and U. Thewalt), 241 Supramolecular polymers TMEDA complexes Unusual chromic behaviour of the solid supramolecular 3D polymers 1,2-Bis(dimeth ylamino)ethan-Komplexe von heteroleptischen Alkyl- [((Me,Sn),,Fe(CN),}. (2 = 3/4) (S.E.H. Etaiw and A.M.A. zink-Verbindungen: Zusammenhang zwischen Zn—N-Abstand und Ibrahim), 77 R—Zn—R’-Bindungswinkel (M. Westerhausen, M. Wieneke und Syndiospecific polymerization of propylene W. Schwarz), 137 Syndiospezifische Polymerisation von Propylen: Modellverbindungen Tripledecker complexes des Typs (C,,H,_ ,,R,CMe,C.H ,)Zr(H,C=CHR’ XPMe,) (n= Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden 0, 2; R = H, Me; R’ = Me, Et) (H.G. Alt und R. Zenk), 177 (M. Herberhold, G. Frohmader und W. Milius), 185 Syndiotactic polypropylene Tripodal ligand Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- a-Allyl—Palladium-Komplexe stabilisiert durch den tripodalen Sauer- stituierte Metallocenkomplex des Typs (C,,Hg_,,R,CR,C5H,)- stoffliganden [(C,H,)Co{P(OMe),0},] II. Eliminierung _ statt MCI,(n = 1,2; R = Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = C-—C-Bindungsbildung bei der Reaktion mit resonanzstabilisierten Zr, Hf) (H.G. Alt und R. Zenk), 39 Carbanionen (B. Domhéver und W. Kaui), 207 Synthesis Synthese von 7-Allyl—Palladium-Komplexen, stabilisiert durch Electrochemical synthesis of bis(2-thienyl)silanes, 2-thienylchlorosi- dreizihnige Sauerstoffliganden [(C;H;)Co{P(OR),O},]> (B. lanes, bis[5-(2-bromothieny])]silanes, and 5-(2-bromothieny)di- Domhover, H. Hamers, W. Kaui und M. Pfeffer), 197 Subject Index of Volume 522 327 Uranium NH,C,H,)C,H,}BrPPh,)] (J. Albert, J. Granell, A. Luque, J. Reactivity of the cationic uranium amide compound [U(7- Minguez, R. Moragas, M. Font-Bardia and X. Solans), 87 C,H, XNEt, XOC,H;[)BP,h, ] (C. Boisson, J.C. Berthet, M. Synthesis and crystal structures of tetrakis(nitratomercurio)methane Ephritikhine, M. Lance and M. Nierlich), 249 monohydrate and bis(sulphatomercurio)bis(aquamercurio)methane (D. Grdenié, B. Korpar-Colig and D. Matkovié-Calogovié), 297 Vanadium Synthesis reactivity and molecular structure of 2’-methylspiro[cyclo- Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden hexane-1,3’-3H-indole] chromium tricarbonyl complex (J.G. (M. Herberhold, G. Frohmader und W. Milius), 185 Rodriguez, A. Urrutia, I. Fonseca and J. Sanz), 231 Vinyl chlorosilanes X-ray structures Koordinationsverhalten vinyl- und alkinylfunktionalisierter Chlorsi- 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- lane (H. Lang, M. Weinmann und L. Zsolnai), 277 zink- Verbindungen: Zusammenhang zwischen Zn—N-Abstand und Vinylidene R-—Zn—R’-Bindungswinkel (M. Westerhausen, M. Wieneke und Some neutral ruthenium vinylidene complexes and a novel 1,3- W. Schwarz), 137 elimination reaction: preparation of chiral ruthenium acetylides (M.I. Bruce, B.C. Hall, N.N. Zaitseva, B.W. Skelton and A.H. White), 307 Zinc 1,2-Bis(dimethylamino)ethan-Komplexe von heteroleptischen Alkyl- Water soluble phosphines zink- Verbindungen: Zusammenhang zwischen Zn—N-Abstand und Water soluble phosphines. VIII. Palladium-catalyzed P—C cross cou- R—Zn—R’-Bindungswinkel (M. Westerhausen, M. Wieneke und pling reactions between primary or secondary phosphines and W. Schwarz), 137 functional aryliodides — a novel synthetic route to water soluble Zirconium phosphines (O. Herd, A. He8ler, M. Hingst, M. Tepper and O. Preparation, characterization and carbonylation of the ring-functional- Stelzer), 69 ized dibenzyl zirconocenes, (n°-C5H;),((5Hn 4°)P-(CC. - H5),)5_,Z"(CH,C,H5)> (x = 1, (1); x= 0, (2) (W. Tikkanen, J. X-ray crystallography Manning, P. Watkins, M. Gonzalez and M. Borja), 123 Neue Vanadium-Komplexe mit substituentenfreien Phosphorliganden Syndiospezifische Polymerisation von Propylen: 2- und 2,7-sub- (M. Herberhold, G. Frohmader und W. Milius), 185 stituierte Metallocenkomplex des Typs (C,,Hg_ ,R,,CR>C;H 4)- X-ray diffraction MCI,(n = 1,2; R= Alkoxy, Alkyl, Aryl, Hal; R’ = Me, Ph; M = Interaction of carbon dioxide with the bis(trimethylsilyDacetylene Zr, Hf) (H.G. Alt und R. Zenk), 39 complex of permethyltitanocene: synthesis and structure of the binuclear carbonate complex of permethyltitanocene (Cp; Ti),CO, (V.V. Burlakov, F.M. Dolgushin, A.I. Yanovsky, Yu.T. Struchkov, V.B. Shur, U. Rosenthal and U. Thewalt), 241 Book Reviews Synthesis, *'P NMR data and X-ray analysis of a ruthenium(ID Gmelin Handbook of Inorganic and Organometallic Chemistry (G.J. dimethylphenylphosphine complex with dimerized phenylacety- Leigh), 163 lene: the structure of [(PhMe,P),Ru(»’-PhC ,CHPh)KPF,) (D.C. Gmelin Handbook of Inorganic and Organometallic Chemistry (C. Liles and P.F.M. Verhoeven), 33 Eaborn), 164 Synthesis and characterisation of CpCoFe,(CO),( 4,-SX 3-Te). Lithium Chemistry: A Theoretical and Experimental Overview, A.-M. Crystal structure of CpCoFe,(CO),( 4 3-Se w3-Te) (P. Mathur, P. Sapse and P. v. R. Schleyer (Eds.) (C. Eaborn), 163 Sekar, C.V.V. Satyanarayana and M.F. Mahon), 291 Organosilicon Chemistry II: from molecules to materials, N. Auner X-ray structure and J. Weis (Eds.) (C. Eaborn), 164 C- and O-metallation of N-benzylideneamines by palladium (II). Photochemistry and Photophysics of Metal Complexes, D.M. Round- Synthesis and X-ray crystal structure of [Pd(2-(CH=N-(CH,),- hill (Ed.) (M. Poliakoff), 162 4’-(MeO)C,H 4}-4,5-(MeO),C,H,)BrPPh,;)] (J. Albert, J. Stereodirected Synthesis with Organoboranes, D.S. Matteson (Ed.) (S. Granell, R. Moragas, M. Font-Bardia and X. Solans), 59 Caddick), 161 Cyclometallation of 2-phenylaniline and ( R)-a-methylbenzylamine b The Chemistry of Metal CVD, T.T. Kodas and M.J. Hampden-Smith palladium(II) acetate. X-ray molecular structure of [Pd{2-(2’- (Eds.) (J.D. Smith), 161

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