Table Of Content

Author Index Akazome, M., Kondo, T. and Watanabe, Y. nickel(0) phosphine complexes immobi- Ruthenium complex-catalyzed selective lized on phosphinated poly (styrene-divi- deoxygenation of amidoximes to amidines nylbenzene) support 181 and its application to the facile synthesis Chang, J.-R., Xu,Z., Purnell,S.K. and of pyrimidines 383 Gates, B.C. Alcantara, A.R.., Sinisterra, J.V., Synthesis and decarbonylation of plati- Guanti, G.G., Thea, S. and Williams, A. num carbonyl cluster anions in zeolite NaY Importance of Hansch’s z parameter in the made basic by treatment withCsOH 49 catalytic action of microgel-immobilised Chaudhari, R.V., see Kelkar, A.A. 21 subtilisin dissolved in tetrahydrofuran Chen, Y., see Heinrich,B. 365 solvent 137 Cho, N.S., see Lee,C.W. 31 Alper, H., see El Ali, B. 377 Chvalovsky, V., see Cermak, J. 181 Andreev, A., see Buck, T. 253 Corain, B., see Mastrorilli, P. L5 Aparicio, J. and Sinisterra, J.V. Csanyi, L.J., Jaky, K. and Kiss, J.T. Influence of the chemical and textural Effects of water and onium ion phase- properties of the support in the immobili- transfer catalyst on the rate of liquid-phase zation of penicillin G-acylase from Kluy- oxidation of hydrocarbons 353 vena citrophila on inorganic Deweerdt, H., see Duprat,S. L9 supports 269 Duprat,S., Deweerdt,H., Jenck,J. and Augustine, R.L. and Tanielyan, S.K. Kalck, P. Correlation between the single turnover Dicarbonylation of 1,4-diacetoxy-but-2- (STO) site densities and the rates of 4-tert- ene in hex-3-ene dioate catalyzed by PdCl, butyl-1-methylcyclohexene hydrogena- in the presence of PBu,Cl L9 tion over silica supported palladium E] Ali, B. and Alper, H. catalysts 277 Regiochemical synthesis of straight chain Baird, M.C.,see Renaud, E. 43 acids by the palladium(II) catalyzed hy- Bhattacharya, P.K.,see Upadhyay,M.J. 1 drocarboxylation of olefins with oxalic Bischoff, H., Jaeger, N.I., Schulz-Ekloff, G. acid 377 and Kubelkova, L. Enzo, S., see Lenarda, M. 105 Interaction of CO with platinum species in Fache, F.,see Fahmi, K. 201 zeolites. Evidence for platinum carbonyls Fahmi, K., Fache, F. and Lemaire, M. in partially reduced zeolite PtNaX 95 A new and convenient method for the syn- Bohlen, H., see Buck, T. 253 thesis of 3-alkyl thiophenes 201 Bosch, P., Lopez,T., Lara, V.-H. and Filatov, M.J., Pelmenschikov,A.G. and Gomez, R. Zhidomirov, G.M. Pt/SiO, catalysts: a comparison of the im- On the nature of superactive centers in H- pregnation and the sol-gel methods 299 ZSM-5 zeolites: quantum chemical Broctawik, E., see Petelenz,P. 341 calculations 243 Brzyska, M., see Grzywnowicz, K. 117 Frank, A.J.,see Palmans,R. 327 Buck, T., Bohlen, H., Wéhrle, D., Schulz-Ek- Ganeshpure, P.A., see Upadhyay,M.J. 1 loff, G. and Andreev, A. Ganzerla, R., see Lenarda, M. 105 Influence of substituents and ligands of Gates, B.C., see Chang, J.-R. 49 various cobalt(II) porphyrin derivatives Gomez, R.,see Bosch, P. 299 coordinately bonded to silica on the oxi- Greppin, H., see Grzywnowicz, K. 117 dation of mercaptan 253 Grzywnowicz, K., Greppin, H., Brzyska, M. Cermak, J., Soukupova, L. and Chvalovsky, V. and Lobarzewski, J. Propadiene oligomerization catalyzed by Changes in activity of soluble and immo- 404 bilized peroxidases after treatment by var- Linn, Jr., D.E., King, R.B. and King, Jr., A.D. ious proteases and some metalions 117 Catalytic reactions of formate: Part 1. Guanti, G.G., see Alcantara, A.R. 137 Photocatalytic hydrogen production from Harustiak, M., see Kaszonyi, A. L113 formate with chromium Heinrich, B., Chen, Y. and Hjortkjer, J. hexacarbonyl 151 Gas phase hydroformylation of propene Linn, Jr., D.E., King, R.B. and King, Jr., A.D. catalyzed by a polymer bound rhodium (1) Catalytic reactions of formate: Part 2. Al- complex 365 dehyde hydrogenation using chromium Heras, A., see Martin, M.T. 127 hexacarbonyl 165 Hevesi, L., see Proess,G. 395 Lobarzewski, J., see Grzywnowicz, K. 117 Hjortkjer, J.,see Heinrich,B. 365 Lopez, T.,see Bosch, P. 299 Houlding, V.H., see Palmans,R. 327 Martin, M.T., Sinisterra, J.V. and Heras, A. Hronec, M., see Kaszonyi,A. L13 Influence of the modification procedure of Iwamoto, M., see Mizuno, N. 229 support materials on the microenviron- Jaeger, N.I., see Bischoff,H. 95 ment of immobilized a- Jaky, K.,see Csdnyi,L.J. 353 chymotrypsin 127 Jenck, J.,see Duprat,S. L9 Mastrorilli, P., Nobile,C.F., Ravasio, N., Jenner, G. Corain, B. and Zecca, M. Novel catalytic procedure for selective Regioselective hydrogenation of 3-phen- homologation of primary alcohols Ll ylpropenal and of trans-2-hexenal to sat- Kagawa, S.,see Mizuno, N. 229 urated aldehydes catalysed by ultrafine Kalck, P., see Duprat,S. L9 rhodium particles dispersed on acrylic Kaszonyi, A., Hronec, M. and Harustiak, M. resins L5 Catalytic oxidation of hydrazodicarbox- McGarvey, G.B., Taylor, N.J. and amide to azodicarboxamide by Moffat, J.B. oxygen L13 Characterization of the compounds formed Kelkar, A.A., Ubale, R.S. and Chaudhari, R.V. from the interaction of divalent cations Carbonylation of methyl acetate to acetic with inorganic molecular metal-oxygen anhydride using homogeneous nickel com- clustercompounds 59 plex catalyst 21 Mieczynska, E., Trzeciak, A.M. and Kim, K.D., see Lee,C.W. 31 Zidtkowski, J.J. King, R.B., see Linn, Jr.,D.E. 151 Effect of carboxylic acids on the yield and King, R.B., see Linn, Jr.,D.E. 165 selectivity of the hydroformylation of hex- King, Jr., A.D., see Linn, Jr.,D.E. 151 l-ene catalyzed by King, Jr., A.D., see Linn, Jr.,D.E. 165 [Rh(acac)(CO)(PPh,)] 189 Kiss, J.T., see Csanyi, L.J. 353 Miskowski, V.M., see Palmans,R. 327 Kondo, T., see Akazome, M. 383 Mizuno, N., Mori,H., Tajima,M., Ka- Kubelkova, L., see Bischoff, H. 95 gawa,S., Ueno,H., Yahiro,H. and Lara, V.-H.,see Bosch, P. 299 Iwamoto, M. Lee, C.W., Lee, J.S., Cho, N.S., Kim, K.D., Formation of ketones from lower olefins Lee, S.M. and Oh, J.S. and water on ultrastable Y-type zeolite Palladium-catalyzed oxidation of catalyst 229 triphenylphosphine 31 Moffat, J.B., see McGarvey,G.B. 59 Lee, J.S., see Lee, C.W. 31 Moffat, J.B., see Nayak, V.S. 75 Lee, S.M., see Lee,C.W. 31 Mori, H.,see Mizuno, N. 229 Lemaire, M.,see Fahmi, K. 201 Nayak, V.S. and Moffat, J.B. Lenarda, M., Ganzerla,R., Enzo,S., Sto- Comparison of the surface properties of the raro, L. and Zanoni, R. metal-oxygen cluster compounds, 12- Vapour phase propene hydroformylation tungstophosphoric acid and ammonium catalyzed by the Rh/Al system on 12-tungstophosphate from the sorption of silica 105 benzene, nitrogen and pyridine 75 405 Nobile, C.F., see Mastrorilli, P. L5 Sinisterra, J.V.,see Alcantara, A.R. 137 Oh, J.S., see Lee,C.W. 31 Sinisterra, J.V.,see Aparicio, J. 269 Onishi, M. Soukupova, L., see Cermak, J. 181 Decomposition of formic acid catalyzed by Storaro, L., see Lenarda, M. 105 hydrido(phosphonite)cobalt(I1) under Stufkens, D.J.,see Vuurman, M.A. 209 photoirradiation 145 Tajima, M.,see Mizuno,N. 229 Oskam, A., see Vuurman, M.A. 209 Tanielyan, S.K., see Augustine, R.L. 277 Palmans, R., Frank, A.J., Houlding, V.H. and Taylor, N.J.,see McGarvey,G.B. 59 Miskowski, V.M. Thea, S., see Alcantara, A.R. 137 Photophysics and photosensitization be- Trzeciak, A.M., see Mieczynska,E. 189 havior of microcrystalline Ubale, R.S., see Kelkar, A.A. 21 [Pt(bpy)2]o[Pte(pop),]-nH,O 327 Ueno, H.,see Mizuno, N. 229 Pelmenschikov, A.G., see Filatov,M.J. 243 Upadhyay, M.J., Bhattacharya, P.K., Ga- Petelenz, P. and Broctawik, E. neshpure, P.A. and Satish, S. Finite supercluster model of vanadium ox- Oxidation of organic substrates catalysed ide catalysts. Part II. Adsorbate-adsor- by mixed ligand Ru"™ complexes. Investi- bate interactions 341 gation of active catalytic species and ter- Proess, G. and Hevesi, L. mination pathway 1 Synthesis of a new chiral porphyrin ligand Urbina-Villalba, G. and Ruette, F. and its Mn(III) complex as catalyst in Semiempirical study of carbon monoxide, asymmetric alkene epoxidation 395 oxygen and carbon adsorption on a mo- Purnell, S.K., see Chang, J.-R. 49 delled CoSi(100) surface 307 Ravasio, N., see Mastrorilli, P. L5 Vuurman, M.A., Wachs, I.E., Stufkens, D.J. Renaud, E. and Baird, M.C. and Oskam, A. 3!P spin lattice relaxation time measure- Characterization of chromium oxide sup- ments of the amphiphilic ligands ported on Al,O,, ZrO., TiO., and SiO, un- [Ph.P(CH.),,PMe,]* in solution and der dehydrated conditions 209 tethered to a solid cationic exchange resin Wachs, I.E., see Vuurman, M.A. 209 via the tetra-alkylphosphonium Watanabe, Y.,see Akazome, M. 383 groups 43 Williams, A., see Alcantara, A.R. 137 Ruette, F., see Urbina-Villalba,G. 307 Wohrle, D.,see Buck, T. 253 Salem, I.A. Xu, Z., see Chang, J.-R. 49 Role of aliphatic diamine ligands in hydro- Yahiro, H.,see Mizuno, N. 229 gen peroxide decomposition with Dowex- Zanoni, R., see Lenarda, M. 105 50W resin as transition metal complex Zecca, M., see Mastrorilli, P. L5 ions 11 Zhidomirov, G.M., see Filatov, M.J. 243 Satish, S.,see Upadhyay,M.J. 1 Zidtkowski, J.J., see Mieczyniska, E. 189 Schulz-Ekloff, G., see Bischoff, H. 95 Schulz-Ekloff, G., see Buck, T. 253 Sinisterra, J.V.,see Martin, M.T. 127 Subject Index acetic anhydride aluminium Carbonylation of methyl acetate to acetic Vapour phase propene hydroformylation anhydride using homogeneous nickel com- catalyzed by the Rh/Al system on plex catalyst 21 silica 105 acidic properties amidine Comparison of the surface properties of the Ruthenium complex-catalyzed selective metal-oxygen cluster compounds, 12- deoxygenation of amidoximes to amidines tungstophosphoric acid and ammonium and its application to the facile synthesis 12-tungstophosphate from the sorption of of pyrimidines 383 benzene, nitrogen and pyridine 75 amidoxime acrylic resins Ruthenium complex-catalyzed selective Regioselective hydrogenation of 3-phen- deoxygenation of amidoximes to amidines ylpropenal and of trans-2-hexenal to sat- and its application to the facile synthesis urated aldehydes catalysed by ultrafine of pyrimidines 383 rhodium particles dispersed on acrylic ammonium 12-tungstophosphate resins L5 Comparison of the surface properties of the active catalytic species metal-oxygen cluster compounds, 12- Oxidation of organic substrates catalysed tungstophosphoric acid and ammonium by mixed ligand Ru" complexes. Investi- 12-tungstophosphate from the sorption of gation of active catalytic species and ter- benzene, nitrogen and pyridine 75 mination pathway 1 asymmetric epoxidation adsorbate-adsorbate interactions Synthesis of a new chiral porphyrin ligand Finite supercluster model of vanadium ox- and its Mn(III) complex as catalyst in ide catalysts. Part II. Adsorbate-adsor- asymmetric alkene epoxidation 395 bate interactions 341 azodicarboxamide adsorption Catalytic oxidation of hydrazodicarbox- Semiempirical study of carbon monoxide, amide to azodicarboxamide by oxygen and carbon adsorption on a mo- oxygen L13 delled CoSi(100) surface 307 benzylic alcohols aldehydes A new and convenient method for the syn- Catalytic reactions of formate: Part 2. Al- thesis of 3-alkyl thiophenes 201 dehyde hydrogenation using chromium carbon hexacarbonyl 165 Semiempirical study of carbon monoxide, alkenes oxygen and carbon adsorption on a mo- Synthesis of a new chiral porphyrin ligand delled CoSi(100) surface 307 and its Mn(III) complex as catalyst in carbon monoxide asymmetric alkene epoxidation 395 Interaction of CO with platinum species in alkyl formates zeolites. Evidence for platinum carbonyls Novel catalytic procedure for selective in partially reduced zeolite PtNaX 95 homologation of primary alcohols Ll Semiempirical study of carbon monoxide, alkyl thiophenes oxygen and carbon adsorption on a mo- A new and convenient method for the syn- delled CoSi(100) surface 307 thesis of 3-alkyl thiophenes 201 Regiochemical synthesis of straight chain alumina acids by the palladium(II) catalyzed hy- Characterization of chromium oxide sup- drocarboxylation of olefins with oxalic ported on Al,O,, ZrO., TiO., and SiO, un- acid 377 der dehydrated conditions 209 408 carbonylation a-chymotrypsin Dicarbonylation of 1,4-diacetoxy-but-2- Influence of the modification procedure of ene in hex-3-ene dioate catalyzed by PdCl, support materials on the microenviron- in the presence of PBu,Cl L9 ment of immobilized a- carbonyl] cluster synthesis chymotrypsin 127 Synthesis and decarbonylation of plati- cluster compounds num carbonyl cluster anions in zeolite NaY Characterization of the compounds formed made basic by treatment withCsOH 49 from the interaction of divalent cations carbonyl complexes with inorganic molecular metal-oxygen Catalytic reactions of formate: Part 1. cluster compounds 59 Photocatalytic hydrogen production from cobalt formate with chromium Role of aliphatic diamine ligands in hydro- hexacarbonyl 151 gen peroxide decomposition with Dowex- Catalytic reactions of formate: Part 2. Al- 50W resin as transition metal complex dehyde hydrogenation using chromium ions 11 hexacarbonyl 165 Influence of substituents and ligands of carboxylic acids various cobalt(II) porphyrin derivatives Effect of carboxylic acids on the yield and coordinately bonded to silica on the oxi- selectivity of the hydroformylation of hex- dation of mercaptan 253 l-ene catalyzed by cobalt silicide [Rh(acac)(CO)(PPh,)] 189 Semiempirical study of carbon monoxide, Regiochemical synthesis of straight chain oxygen and carbon adsorption on a mo- acids by the palladium(II) catalyzed hy- delled CoSi(100) surface 307 drocarboxylation of olefins with oxalic copper acid 377 Role of aliphatic diamine ligands in hydro- cation exchange resins gen peroxide decomposition with Dowex- 3!P spin lattice relaxation time measure- 50W resin as transition metal complex ments of the amphiphilic ligands ions 11 [Ph,P(CH,),,PMe,]* in solution and counter ion effect tethered to a solid cationic exchange resin Gas phase hydroformylation of propene via the tetra-alkylphosphonium catalyzed by a polymer bound rhodium (1) groups 43 complex 365 chemisorption cyclohexene derivatives Interaction of CO with platinum species in Correlation between the single turnover zeolites. Evidence for platinum carbonyls (STO) site densities and the rates of 4-tert- in partially reduced zeolite PtNaX 95 butyl-1-methylcyclohexene hydrogena- chiral induction tion over silica supported palladium Synthesis of a new chiral porphyrin ligand catalysts 277 and its Mn(III) complex as catalyst in deactivation asymmetric alkene epoxidation 395 Gas phase hydroformylation of propene chromium catalyzed by a polymer bound rhodium (1) Catalytic reactions of formate: Part 1. complex 365 Photocatalytic hydrogen production from decarbonylation formate with chromium Synthesis and decarbonylation of plati- hexacarbonyl 151 num carbonyl cluster anions in zeolite NaY Catalytic reactions of formate: Part 2. Al- made basic by treatment withCsOH 49 dehyde hydrogenation using chromium density of states hexacarbonyl 165 Semiempirical study of carbon monoxide, Characterization of chromium oxide sup- oxygen and carbon adsorption on a mo- ported on Al,O,, ZrO., TiO., and SiO, un- delled CoSi(100) surface 307 der dehydrated conditions 209 deoxygenation formic acid decomposition Ruthenium complex-catalyzed selective Decomposition of formic acid catalyzed by deoxygenation of amidoximes to amidines hydrido(phosphonite)cobalt(I) under and its application to the facile synthesis photoirradiation 145 of pyrimidines 383 Grignard reaction diacetoxybutene A new and convenient method for the syn- Dicarbonylation of 1,4-diacetoxy-but-2- thesis of 3-alkylthiophenes 201 ene in hex-3-ene dioate catalyzed by PdCl, Hansch’s 2 parameter in the presence of PBu,Cl L9 Importance of Hansch’s z parameter in the diamine ligands catalytic action of microgel-immobilised Role of aliphatic diamine ligands in hydro- subtilisin dissolved in tetrahydrofuran gen peroxide decomposition with Dowex- solvent 137 50W resin as transition metal complex heteropolyacids ions 11 Catalytic oxidation of hydrazodicarbox- divalent cations amide to azodicarboxamide by Characterization of the compounds formed oxygen L13 from the interaction of divalent cations heteropoly oxometalates with inorganic molecular metal-oxygen Characterization of the compounds formed from the interaction of divalent cations clustercompounds 59 with inorganic molecular metal-oxygen double salts cluster compounds 59 Photophysics and photosensitization be- Comparison of the surface properties of the havior of microcrystalline metal-oxygen cluster compounds, 12- [Pt(bpy)2]2[Pt2(pop),]*nH,O 327 tungstophosphoric acid and ammonium Dowex-50W resin 12-tungstophosphate from the sorption of Role of aliphatic diamine ligands in hydro- benzene, nitrogen and pyridine 75 gen peroxide decomposition with Dowex- hexenal 50W resin as transition metal complex Regioselective hydrogenation of 3-phen- ions 11 ylpropenal and of trans-2-hexenal to sat- enzyme activation urated aldehydes catalysed by ultrafine Influence of the chemical and textural rhodium particles dispersed on acrylic properties of the support in the immobili- resins L5 zation of penicillin G-acylase from Kluy- hexene vena citrophila on inorganic Effect of carboxylic acids on the yield and supports 269 selectivity of the hydroformylation of hex- enzyme activity l-ene catalyzed by Changes in activity of soluble and immo- [Rh(acac)(CO)(PPh;)] 189 bilized peroxidases after treatment by var- homogeneous catalysis ious proteases and some metalions 117 Ruthenium complex-catalyzed selective finite supercluster model deoxygenation of amidoximes to amidines Finite supercluster model of vanadium ox- and its application to the facile synthesis ide catalysts. Part II. Adsorbate-adsor- of pyrimidines 383 bate interactions 341 homogeneous catalysts formate Carbonylation of methyl acetate to acetic Catalytic reactions of formate: Part 1. anhydride using homogeneous nickel com- Photocatalytic hydrogen production from plex catalyst 21 formate with chromium homologation hexacarbonyl 151 Novel catalytic procedure for selective Catalytic reactions of formate: Part 2. Al- homologation of primary alcohols Ll dehyde hydrogenation using chromium hydrazodicarboxamide hexacarbonyl 165 Catalytic oxidation of hydrazodicarbox- 410 amide to azodicarboxamide by hydrogen peroxide oxygen L13 Role of aliphatic diamine ligands in hydro- hydrido cobalt (I) gen peroxide decomposition with Dowex- Decomposition of formic acid catalyzed by 50W resin as transition metal complex hydrido(phosphonite)cobalt(I) | under ions 11 photoirradiation 145 immobilization hydrido (phosphonite )c obalt (1) 3'P spin lattice relaxation time measure- Decomposition of formic acid catalyzed by ments of the amphiphilic ligands hydrido(phosphonite)cobalt(I) under [Ph,P(CH,),PMe,]* in solution and photoirradiation 145 tethered to a solid cationic exchange resin hydrocarbons via the tetra-alky!phosphonium Effects of water and onium ion phase- groups 43 transfer catalyst on the rate of liquid-phase immobilized enzymes oxidation of hydrocarbons 353 Influence of the modification procedure of hydroformylation support materials on the microenviron- Vapour phase propene hydroformylation ment of immobilized a- catalyzed by the Rh/Al system on chymotrypsin 127 silica 105 Importance of Hansch’s z parameter in the Effect of carboxylic acids on the yield and catalytic action of microgel-immobilised selectivity of the hydroformylation of hex- subtilisin dissolved in tetrahydrofuran l-ene catalyzed by solvent 137 [Rh(acac)(CO)(PPh,)] 189 Influence of the chemical and textural Gas phase hydroformylation of propene properties of the support in the immobili- catalyzed by a polymer bound rhodium (1) zation of penicillin G-acylase from Kluy- complex 365 vena citrophila on inorganic hydrogen supports 269 Catalytic reactions of formate: Part 1. impregnation Photocatalytic hydrogen production from Pt/SiO, catalysts: a comparison of the im- formate with chromium pregnation andthe sol-gel methods 299 hexacarbonyl 151 infrared spectroscopy hydrogenation Interaction of CO with platinum species in Regioselective hydrogenation of 3-phen- zeolites. Evidence for platinum carbonyls ylpropenal and of trans-2-hexenal to sat- in partially reduced zeolite PtNaX 95 urated aldehydes catalysed by ultrafine inorganic supports rhodium particles dispersed on acrylic Influence of the chemical and textural resins L5 properties of the support in the immobili- Catalytic reactions of formate: Part 2. Al- zation of penicillin G-acylase from Kluy- dehyde hydrogenation using chromium vena citrophila on inorganic hexacarbonyl 165 supports 269 Correlation between the single turnover iron (STO) site densities and the rates of 4-tert- Role of aliphatic diamine ligands in hydro- butyl-1-methylcyclohexene hydrogena- gen peroxide decomposition with Dowex- tion over silica supported palladium 50W resin as transition metal complex catalysts 277 ions 11 Pt/SiO, catalysts: a comparison of the im- On the nature of superactive centers in H- pregnation and thesol-gel methods 299 ZSM-5 zeolites: quantum chemical hydrogen evolution calculations 243 Photophysics and photosensitization be- ketones havior of microcrystalline Formation of ketones from lower olefins [Pt(bpy)2Jo[Pt2(pop),]-nH,O 327 and water on ultrastable Y-type zeolite catalyst 229 low temperature water gas shift nitrogen Interaction of CO with platinum species in Characterization of the compounds formed zeolites. Evidence for platinum carbonyls from the interaction of divalent cations in partially reduced zeolite PtNaX 95 with inorganic molecular metal-oxygen manganese cluster compounds 59 Synthesis of a new chiral porphyrin ligand NMR spectroscopy and its Mn(III) complex as catalyst in 31P spin lattice relaxation time measure- asymmetric alkene epoxidation 395 ments of the amphiphilic _ ligands mercaptan [Ph,P(CH,),PMe,]* in solution and Influence of substituents and ligands of tethered to a solid cationic exchange resin various cobalt(II) porphyrin derivatives via the tetra-alkylphosphonium coordinately bonded to silica on the oxi- groups 43 dation of mercaptan 253 olefins metal ions Formation of ketones from lower olefins Changes in activity of soluble and immo- and water on ultrastable Y-type zeolite bilized peroxidases after treatment by var- catalyst 229 ious proteases and some metalions 117 Regiochemical synthesis of straight chain metal-oxygen cluster compounds acids by the palladium(II) catalyzed hy- Comparison of the surface properties of the drocarboxylation of olefins with oxalic metal-oxygen cluster compounds, 12- acid 377 tungstophosphoric acid and ammonium oligomerization 12-tungstophosphate from the sorption of Propadiene oligomerization catalyzed by benzene, nitrogen and pyridine 75 nickel(0) phosphine complexes immobi- methyl acetate lized on phosphinated poly (styrene-divi- Carbonylation of methyl acetate to acetic nylbenzene) support 181 anhydride using homogeneous nickel com- onium ion plex catalyst 21 Effects of water and onium ion phase- microgel transfer catalyst on the rate of liquid-phase Importance of Hansch’s z parameter in the oxidation of hydrocarbons 353 catalytic action of microgel-immobilised oxalic acid subtilisin dissolved in tetrahydrofuran Regiochemical synthesis of straight chain solvent 137 acids by the palladium(II) catalyzed hy- molybdenum drocarboxylation of olefins with oxalic Catalytic oxidation of hydrazodicarbox- acid 377 amide to azodicarboxamide by oxidation oxygen L113 Catalytic oxidation of hydrazodicarbox- 12-molybdophosphoric acid amide to azodicarboxamide by Characterization of the compounds formed oxygen L13 from the interaction of divalent cations Oxidation of organic substrates catalysed with inorganic molecular metal-oxygen by mixed ligand Ru™ complexes. Investi- cluster compounds 59 gation of active catalytic species and ter- nickel mination pathway 1 Propadiene oligomerization catalyzed by Palladium-catalyzed oxidation of nickel(9) phosphine complexes immobi- triphenylphosphine 31 lized on phosphinated poly (styrene-divi- Influence of substituents and ligands of nylbenzene) support 181 various cobalt(II) porphyrin derivatives nickel complexes coordinately bonded to silica on the oxi- Carbonylation of methyl acetate to acetic dation of mercaptan 253 anhydride using homogeneous nickel com- Effects of water and onium ion phase- plex catalyst 21 transfer catalyst on the rate of liquid-phase oxidation of hydrocarbons 353 412 oxygen phosphine ligands Catalytic oxidation of hydrazodicarbox- Propadiene oligomerization catalyzed by amide to aazodicarboxamide by nickel(0) phosphine complexes immobi- oxygen L13 lized on phosphinated poly (styrene-divi- Semiempirical study of carbon monoxide, nylbenzene) support 181 oxygen and carbon adsorption on a mo- phosphines delled CoSi(100) surface 307 *P spin lattice relaxation time measure- palladium ments of the amphiphilic ligands Dicarbonylation of 1,4-diacetoxy-but-2- [Ph,P(CH,),PMe,]* in solution and ene in hex-3-ene dioate catalyzed by PdCl, tethered to a solid cationic exchange resin in the presence of PBu,Cl L9 via the tetra-alkylphosphonium Palladium-catalyzed oxidation of groups 43 triphenylphosphine 31 Regiochemical synthesis of straight chain Correlation between the single turnover acids by the palladium(II) catalyzed hy- (STO) site densities and the rates of 4-tert- drocarboxylation of olefins with oxalic butyl-1-methylcyclohexene hydrogena- acid 377 tion over silica supported palladium photocatalysis catalysts 277 Catalytic reactions of formate: Part 1. Regiochemical synthesis of straight chain Photocatalytic hydrogen production from acids by the palladium(II) catalyzed hy- formate with chromium drocarboxylation of olefins with oxalic hexacarbonyl 151 acid 377 photophysics palladium reduction Photophysics and photosensitization be- A new and convenient method for the syn- havior of microcrystalline thesis of 3-alkyl thiophenes 201 [Pt(bpy)2Jo[Pt2(pop),]-nH,O 327 penicillin G-acylase photosensitization Influence of the chemical and textural Photophysics and photosensitization be- properties of the support in the immobili- havior of microcrystalline zation of penicillin G-acylase from Kluy- [Pt(bpy)2]2[Pte(pop),]*nH,O 327 vena citrophila on inorganic photocatalytic reaction supports 269 Decomposition of formic acid catalyzed by peroxidases hydrido(phosphonite)cobalt(I) under Changes in activity of soluble and immo- photoirradiation 145 bilized peroxidases after treatment by var- platinum ious proteases and some metalions 117 Synthesis and decarbonylation of plati- phase transfer catalyst num carbonyl cluster anions in zeolite NaY Effects of water and onium ion phase- made basic by treatment withCsOH 49 transfer catalyst on the rate of liquid-phase Pt/SiO, catalysts: a comparison of the im- oxidation of hydrocarbons 353 pregnation andthe sol-gelmethods 299 phenylacetylene platinum carbonyl complexes Pt/SiO, catalysts: a comparison of the im- Interaction of CO with platinum species in pregnation and the sol-gel methods 299 zeolites. Evidence for platinum carbonyls phenylpropenal in partially reduced zeolite PtNaX 95 Regioselective hydrogenation of 3-phen- platinum complexes ylpropenal and of trans-2-hexenal to sat- Photophysics and photosensitization be- urated aldehydes catalysed by ultrafine havior of microcrystalline rhodium particles dispersed on acrylic [Pt(bpy)2]2[Pt2(pop),]-nH,O 327 resins L5 polymer bound phosphine derivatives Gas phase hydroformylation of propene Dicarbonylation of 1,4-diacetoxy-but-2- catalyzed by a polymer bound rhodium (I) ene in hex-3-ene dioate catalyzed by PdCl, complex 365 in the presence of PBu,Cl L9