Introduction to Algal Fuel LCA in GREET1_2011 Edward Frank, Michael Wang, Jeongwoo Han, Amgad Elgowainy, and Ignasi Palou-Rivera Center for Transportation Research Argonne National Laboratory GREET Workshop Argonne, IL Dec. 7-8, 2011 Plan Introduction and motivation Architecture and workflow Demo #1 Examining pre-configured pathway: Basics • Details to be covered by Jeongwoo separately Where to find results and highest level configuration Quick tour of APD worksheets Key concepts in APD Demo #2 Nutrients Configure a new model and run it 2 Supporting Documents: LCA Report and User Manual Available at http://greet.es.anl.gov/publications Motivation and Architecture Can algal biofuels meet GHG reduction APD goals? • System definition Must compare to other transportation • Technology selection pathways • Direct energy for op’s • Performance parameters • Nutrient tools Challenges for algae LCAs Many algae scenarios & process options Facilitate community LCAs Summarize & Copy Algae Process Description (APD) Assists GREET GREET Allows rapid definition of pathway • Co-product treatment New processes easy to add • Transport & distribution Assembles model and passes back to • Upstream treatment GREET for LCA • Fuel and vehicle • Results 4 What You Can Do with GREET and APD Assemble algae production model from process inventory Compute total energy use Fossil: petroleum, natural gas, and coal Renewable energy: biomass, nuclear, hydro, wind, and solar Compute total greenhouse gases (GHGs) CO CH and N O individually 2, 4, 2 CO e of the three including C in CO and VOC 2 Compute total criteria pollutants VOC, CO, NO PM PM and SO x, 10, 2.5, x Study many vehicle/fuel systems Compare algae results with many other feedstocks, fuels, and vehicles 5 Algae LCA System Boundary Energy & Materials Emissions to Air from all Fertilizer Production Algae & Lipid Lipid BD, RD, Fuel Fuel Combustion Oil Production Transport RG Production Transport in Vehicles CO2 Supply Residue N O from 2 Transport Soil Electricity, Glycerin, Soil Amendments, Heavy Oils Co-products Biogas, Fuel Gas Feed System boundary currently excludes infrastructure materials and land-use change 6 Pre-configured Pathway- See Reports for Details Recovered H20 Urea Bio- DAF & Homogenizer, DAP Open pond Transport 0.5 Flocculation 10 Centrifuge 200 g/L Hexane Extraction oil Flue gas g/L g/L Lipid-extracted Algae Recovered CO2 Biogas Anaerobic CHP Clean-up Digestion N,P in liquid N, P in solids Transport Electricity Soil Amendment Baseline: As shown Low-A: Catalytic hydrothermal gasification rather than AD Low-B: Different performance parameters 7 Fossil Energy and GHG Results GHG Emissions PTW Fossil Energy Use PTW WTP WTP WTW 1400000 120000 120000 101,234 100000 100000 1200000 D 80000 80000 D 1000000 B B -UT 60000 55,440 60000 -UT 800000 B B m m 1,000,000 m / 40000 40000 m / 600000 0 e U -2 20000 20000 TB O 400000 C g 0 0 548,329 Conventional LS Algae BD 200000 -20000 Diesel -20000 215,388 0 -40000 -40000 Conventional LS Diesel Algae BD Baseline scenario has significant GHG reduction Accurate treatment of recovery (AD, CHP) is essential 128,000 BTU-electricity imported (fossil) per mmBTU of biofuel Would be 514,000 BTU-electricity without AD recovery 76% of N and 100% of P recovered 8 Two Possible Workflows 1) Study pre-configured algae pathway Three options configured in GREET • See Technical Report for detailed description 2) Define Custom Algae Pathways Change unit-operation parameters in default configuration Choose different unit-operations 9 Workflow for Pre-configured Pathway Set values on • Set feedstock in Sec. 8.1 to, “algae.” GREET inputs tab • Consider share in BD, Sec. 11.1 Set values on • Co-product treatment, transportation GREET algae tab View results • Vehicle and fuel in GREET Done? No All work is performed in GREET 10
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