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Global Atmospheric Phenomena Involving Water: Water Circulation, Atmospheric Electricity, and the Greenhouse Effect PDF

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Springer Atmospheric Sciences Boris M. Smirnov Global Atmospheric Phenomena Involving Water Water Circulation, Atmospheric Electricity, and the Greenhouse Effect Springer Atmospheric Sciences More information about this series at http://www.springer.com/series/10176 Boris M. Smirnov Global Atmospheric Phenomena Involving Water Water Circulation, Atmospheric Electricity, and the Greenhouse Effect 123 Boris M.Smirnov JointInstitute for HighTemperatures Russian Academy of Sciences Moscow,Russia ISSN 2194-5217 ISSN 2194-5225 (electronic) SpringerAtmospheric Sciences ISBN978-3-030-58038-4 ISBN978-3-030-58039-1 (eBook) https://doi.org/10.1007/978-3-030-58039-1 ©TheEditor(s)(ifapplicable)andTheAuthor(s),underexclusivelicensetoSpringerNature SwitzerlandAG2020 Thisworkissubjecttocopyright.AllrightsaresolelyandexclusivelylicensedbythePublisher,whether thewholeorpartofthematerialisconcerned,specificallytherightsoftranslation,reprinting,reuseof illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmissionorinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilar ordissimilarmethodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfrom therelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, expressed or implied, with respect to the material contained hereinorforanyerrorsoromissionsthatmayhavebeenmade.Thepublisherremainsneutralwithregard tojurisdictionalclaimsinpublishedmapsandinstitutionalaffiliations. ThisSpringerimprintispublishedbytheregisteredcompanySpringerNatureSwitzerlandAG Theregisteredcompanyaddressis:Gewerbestrasse11,6330Cham,Switzerland Preface The analysis of elementary processes involving atmospheric water is combined in this book with the contemporary understanding of global atmospheric problems whichincludewatercirculationthroughtheatmosphere,atmosphericelectricity,the greenhouseeffectandotherglobalatmosphericproblems.Usingsimplemodels,as themodelofstandardatmosphere,allowsonetounderstanddeepertheseproblems and obtain the estimations for various parameters of global atmospheric processes. Thebasicattentionwepaytocondensedwaterthatisconcentratedincloudswhich consists mostly of water microdroplets. In addition, accompanied atmospheric processes are analyzed. As a result, each atmospheric phenomenon is a chain of certain processes. As one of these phenomena, water circulation consists in the evaporation of water from the Earth’s surface, capture of water molecules by air vortices in the course of convection, and partial condensation of water at altitudes of several kilometers with formation of clouds, consisting of water microdroplets. Returning water to the Earth’s surface proceeds both in the form of water molecules which partake in convection motion of air or by rain and water microdroplets. Atmospheric electricity is the secondary phenomenon with respect to water circulationandtheatmosphereisdividedintotwoparts,wherethefirstonecontains cumuluscloudswhichincludealmostallcondensedwaterintheatmosphereinthe form of water microdroplets mostly. Water microdroplets are formed as a result ofthemixingofwetairfromnear-surfaceatmosphericregionsandcoldlayersatan altitudeofafewkilometers.Simultaneouslygrowingmicrodropletsarechargedby attachment of molecular ions formed under the action of cosmic rays. These microdroplets become charged because of different mobilities of positive and negative molecular ions. Charged microdroplets fall down that leads to the sepa- ration of atmospheric charges and the creation of the atmospheric electric field. Because cumulus clouds consist of microdroplets with charges of the same sign, they have a high electric potential and may be a source ofatmosphericbreakdown intheformoflightning.So,chargingoftheEarthproceedsduetocumulusclouds, while its discharge results from the currents of molecular ions formed under the action of cosmic rays in regions of the clear-sky atmosphere. v vi Preface The greenhouse effect results from atmospheric emission in the infrared spec- trumrange.Wateristhemaingreenhousecomponent,suchthatapproximately50% of the atmospheric radiative flux toward the Earth is created by water molecules, and 30% of the radiative flux results from cloud emission. It is of importance that atmosphericemissiontotheEarthisseparatedtowardtheEarthandoutsidebecause of a large optical thickness of the atmosphere. In addition, emission of clouds and molecular components of the atmosphere are separated in regions of rare clouds which occupy the basic part of the atmosphere. In this book, we consider the above global atmospheric problems involving water in detail. Moscow, Russia Boris M. Smirnov Contents 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2 Global Properties of the Earth’s Atmosphere . . . . . . . . . . . . . . . . . . 7 2.1 Water in Atmosphere . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2.1.1 Parameters of Standard Atmosphere . . . . . . . . . . . . . . . . . 7 2.1.2 Atmospheric Water Vapor . . . . . . . . . . . . . . . . . . . . . . . . 8 2.1.3 Dynamics of Atmospheric Air . . . . . . . . . . . . . . . . . . . . . 14 2.1.4 Water Microdroplet in Atmospheric Air . . . . . . . . . . . . . . 16 2.2 Global Earth’s Energetics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 2.2.1 Contemporary Evolution of Global Temperature . . . . . . . . 22 2.2.2 Earth’s Temperature in the Past . . . . . . . . . . . . . . . . . . . . 24 2.2.3 Carbon Dioxide and Earth’s Temperature . . . . . . . . . . . . . 27 2.2.4 Energetic Balance for the Earth and Its Atmosphere . . . . . 29 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 3 Water Condensation Processes in Atmospheric Air . . . . . . . . . . . . . 37 3.1 Water Microdrops in Water Circulation . . . . . . . . . . . . . . . . . . . . 37 3.1.1 Clouds in Troposphere. . . . . . . . . . . . . . . . . . . . . . . . . . . 37 3.1.2 Water Circulation Through the Atmosphere. . . . . . . . . . . . 42 3.2 Formation of Clouds Under Equilibrium Conditions. . . . . . . . . . . 44 3.2.1 Conditions of Water Condensation in Atmospheric Air . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 3.2.2 Formation of the Condensed Phase resulted from Mixing of Atmospheric Layers. . . . . . . . . . . . . . . . . . . . . . . . . . . 47 3.2.3 Rate of Water Condensation. . . . . . . . . . . . . . . . . . . . . . . 50 3.3 Kinetics of Growth of Water Microdroplets in Atmospheric Air . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 3.3.1 Mechanisms of Drop Growth in Air . . . . . . . . . . . . . . . . . 53 3.3.2 Establishment of Equilibrium in Growth of Water Droplets . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 vii viii Contents 3.3.3 Gravitation Mechanism of Growth of Water Droplets . . . . 61 3.3.4 Displacement of Microdroplets of Cumulus Clouds . . . . . . 65 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 4 Processes Involving Atmospheric Ions . . . . . . . . . . . . . . . . . . . . . . . 71 4.1 Cosmic Rays in Atmospheric Ionization. . . . . . . . . . . . . . . . . . . . 72 4.1.1 Cosmic Rays in the Earth’s Atmosphere . . . . . . . . . . . . . . 72 4.1.2 Excitation of Atmospheric Air by Fast Protons . . . . . . . . . 73 4.1.3 Character of Absorption of Cosmic Rays by Atmosphere . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 4.1.4 Photoionization of Air Molecules in the Atmosphere . . . . . 80 4.2 Charging Processes in Low Atmosphere . . . . . . . . . . . . . . . . . . . 82 4.2.1 Droplet Charging in Plasma . . . . . . . . . . . . . . . . . . . . . . . 82 4.2.2 Charging of Water Droplets in Atmosphere. . . . . . . . . . . . 85 4.3 Ions in Tropospheric Processes . . . . . . . . . . . . . . . . . . . . . . . . . . 88 4.3.1 Mobility of Small Water Ions in Atmospheric Air . . . . . . . 88 4.3.2 Recombination of Ions in Atmospheric Air . . . . . . . . . . . . 91 4.3.3 Ions in Clear-Sky Atmosphere . . . . . . . . . . . . . . . . . . . . . 95 4.4 Electric Processes in Cumulus Clouds . . . . . . . . . . . . . . . . . . . . . 96 4.4.1 Ions in Cumulus Clouds. . . . . . . . . . . . . . . . . . . . . . . . . . 96 4.4.2 Processes in Cumulus Clouds Involving Water Microdroplets . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102 4.4.3 Stability of Cumulus Cloud . . . . . . . . . . . . . . . . . . . . . . . 106 4.4.4 Thermal Charge Release for Microparticles. . . . . . . . . . . . 107 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110 5 Processes of Atmospheric Electricity. . . . . . . . . . . . . . . . . . . . . . . . . 115 5.1 Global Electric Circuit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115 5.1.1 Earth as Electrical System . . . . . . . . . . . . . . . . . . . . . . . . 115 5.1.2 Electric Machine of Troposphere . . . . . . . . . . . . . . . . . . . 117 5.1.3 Study of Atmospheric Electricity and Lightning . . . . . . . . 120 5.1.4 Global Electric Atmospheric Processes . . . . . . . . . . . . . . . 122 5.2 Lightning as a Phenomenon of Atmospheric Electricity . . . . . . . . 127 5.2.1 Lightning as a Physical Phenomenon . . . . . . . . . . . . . . . . 127 5.2.2 Properties of the Conductivity Lightning Channel . . . . . . . 135 5.2.3 Heat Regime of the Conductivity Lightning Channel. . . . . 142 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 6 Greenhouse Phenomenon in the Earth’s Atmosphere . . . . . . . . . . . . 153 6.1 Character of Atmospheric Emission Toward the Earth . . . . . . . . . 154 6.1.1 Emission of Gaseous Layer . . . . . . . . . . . . . . . . . . . . . . . 154 6.1.2 Thermal Emission of Atmosphere. . . . . . . . . . . . . . . . . . . 160 6.1.3 Molecular Emission of Atmosphere . . . . . . . . . . . . . . . . . 162 6.1.4 HITRAN Data Bank in Spectroscopy of Atmosphere. . . . . 163 6.1.5 Spectrum of Atmospheric Emission . . . . . . . . . . . . . . . . . 166 Contents ix 6.2 Water in Atmospheric Radiation . . . . . . . . . . . . . . . . . . . . . . . . . 170 6.2.1 Water Molecules and Microdroplets as Atmospheric Radiators. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 6.2.2 Clouds as Absorbers . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177 6.2.3 Absorption of RF-radiation by Clouds with Microdroplets. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 6.3 Peculiarities of Emission of Wet Atmosphere. . . . . . . . . . . . . . . . 184 6.3.1 Emission of Greenhouse Atmospheric Components . . . . . . 184 6.3.2 Radiative Flux from Varied Atmosphere. . . . . . . . . . . . . . 187 6.3.3 Greenhouse Phenomenon of Atmosphere . . . . . . . . . . . . . 192 6.3.4 Outgoing Atmospheric Radiation . . . . . . . . . . . . . . . . . . . 196 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 7 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 Appendix: Appendices .. .... ..... .... .... .... .... .... ..... .... 211 Index .... .... .... .... .... ..... .... .... .... .... .... ..... .... 217

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