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Glass-Fibre Databook PDF

261 Pages·1993·6.49 MB·English
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Glass- Fibre DATABOOI~ o E D 1 T 1 N 1 Compiled by Trevor F. Starr Technolex Crewkerne Somerset SPRINGER-SCIENCE+BUSINESS MEDIA, B.Y. First edition 1993 © 1993 Springer Science+Business Media Dordrecht Originally published by Chapman & HalI in 1993 ISBN 978-0-412-46280-1 ISBN 978-94-011-1492-9 (eBook) DOI 10.1007/978-94-011-1492-9 Apar! from any fair deal ing for the ]purposes of research or private study, or criticism or review, as permitted und,er the UK Copyright Designs and Patents Act, 1988, this publication may not be reproduced, stored, or transmitted, in any form or by any means, without the prior permission in writing of the publishers, or in the case of reprographic reproduction only in accordance with the terms of the licences issued by< the Copyright Licensing Agency in the UK,. or in accordance with the terms of licences issued by the appropriate Reproduction Rights Organization out side the UK. Enquiries concerning reproduction outside the terms stated here should be sent to the publishers at the London address printed on this page. The publisher makes no representation, express or implied, with regard to the accuracy of the illlformation contained in this book and cannot accept any legal responsibility or Iiability for any errors or omissions that may be made. A catalogue record for this book is available from the British Library Library of Congress Cataloging-in-Publication data available SCOPE Glass fibres are used in ever increasing variety for a wide range of application, each vital to modern society. Consequently there has been a strong need for a systematic compilation of those engaged in their manufacture, supply· and distribution, plus an all-important associated listing of properties under a number of standard material classifications. This Data Book provides a comprehensive answer to that need. It covers commercially available glass fibres, whether employed for reinforcement, filtration, insulation, optical or other applications. Part One, the Directory Section, provides a listing pf manufacturers, their sales offices, agents, subsidiaries and affiliates, complete with address, tetephone and facsimile number. Part Two, the Data Section then tabulates the major properties and relevant supply details, of all the different grades of glass:fibre available through the sources listed in Part One. This Glass Fibre Data Book will be an invaluable source of information for all those concerned with gJassfibres, whether design or research and development engineers, whether specifiers, purchase managers or others such as university professors and teaching staff. The comprehensive information provided within its pages, will enable anyone having an interest or involvement with glass fibre materials, to make the best choice of those available worldwide, to satisfy in a totally optimum manner, each specific application requirement. iii CONTENTS Scope iii Review vii Glass fibre nomenclature European & International Glass Fibre Standards x Technical Vocabulary xii English - French -German -Italian Index of Trade Names xv PART ONE: DIRECTORY SECTION GLASS FIBRE MATERIALS FOR THE COMPOSITES INDUSTRY A cOmprehensive listing of those who manufacture, supply or otherwise distribute a variety of glass fibre and allied materials based on glass, as employed by the composites industry REINFORCEMENTS FOR THERMOSETS: MANUFACTURERS 3 REINFORCEMENTS FOR THERMOPLASTICS: MANUFACTURERS 7 REINFORCEMENTS FOR CEMENT & GYPSUM: MANUFACTURERS 8 TISSUES, SURFACING VEILS & MATS: MANUFACTURERS 10 MANUFACTURERS' SALES OFFICES, AGENTS & SUBSIDIARIES 11 DISTRIBUTORS 21 GLASS FIBRE MATERIALS OTHER. THAN FOR THE COMPOSITES INDUSTRY A listing of companies who manufacture and supply a variety of glass fibre materials as employed by other than the composites industry FILTRATION MATERIALS: MANUFACTURERS 39 INSULATION MATERIALS: MANUFACTURERS 39 P!,IINTED CIRCUIT BOARDS: MANUFACTURERS 41 OTHERWISE UNCLASSIFIED GLASS FIBRE MATERIALS: MANUFACTURERS 42 OPTICAL FIBRES & CABLES FIBRES: MANUFACTURERS 45 FIBRE CABLES: MANUFACTURERS 46 AGENTS, DISTRIBUTORS & MANUFACTURING AFFILIATES 46 OPTICAL FIBRE CABLE, CORE SUPPORT MEMBERS 50 PART TWO: DATA SECTION A comprehensive tabulation of glass fibre materials as described by Part One. SECTION 1: CONTINUOUS FILAMENT YARNS List of Manufacturers 52 GLASS FIBRE MATERIALS FOR THE COMPOSITES INDUSTRY SECTION 2: REINFORCEMENTS FOR THERMOSETS Contents & List of Manufacturers 67 2. 1 Milled Fibres 72 2. 2 Chopped Strands 73 2. 3 Chopped Strand Mats 76 2. 4 Continuous Strand (Filament) Mats 81 2. 5 Rovings 84 2. 6 Woven Rovings 94 2. 7 Unidirectional Woven Rovings 101 2. 8 Yarn Fabrics 102 2. 9 Scrim Fabrics 125 2.10 Needled Mats 128 2.11 Combination Materials - Woven Roving & Mats 129 2.12 Conformable & Multiaxial Fabrics 134 2.13 3D 'Distance' (or 'Space') Fabrics 143 2.14 Tapes 144 SECTION 3: REINFORCEMENTS FOR THERMOPLASTICS Contents & List of Manufacturers 149 3. 1 Milled Fibres 151 3. 2 Chopped Strands 152 3. 3 Chopped Strand Mats 157 3. 4 Continuous Strand (Filament) Mats 157 3. 5 Rovings 158 3. 6 Woven Rovings 159 3. 7 Yarn Fabrics 160 3. 8 Needled Mats 161 3. 9 Tapes 162 SECTION 4: REINFORCEMENTS FOR CEMENT & GYPSUM Contents & List of Manufacturers 163 4. 1 Chopped Strands 164 4. 2 Rovings 165 SECTION 5: TISSUES, SURFACING VEILS, MATS &~FABRICS Contents & List of Manufacturers 167 5. 1 Tissue, Surfacing Veils & Mats 168 5. 2 Surfacing Fabrics 169 GLASS FIBRE MATERIALS OTHER THAN FOR THE COMPOSITES INDUSTRY SECTION 6: FILTRATION MATERIALS Contents & List of Manufacturers 172 6. 1 Filtration of Air & Dust 173 6. 2 Filtration of Liquids & Solids 175 6. 3 Filtration of Metals . 176 v SECTION 7: INSULATION MATERIALS Contents & List of Manufacturers 177 7. 1 Acoustic Insulation 179 7. 2 Electrical Insulation -Braiding & Cord 186 -Fabrics 188 -Sheathing 193 -Adhesive Tapes 194 -Braided Tapes 194 - Plain Tapes 195 7. 3 Thermal Insulation -Bonded Materials 196 -Needled Fabrics 202 -Woven Cloths & Fabrics 203 -Woven Tapes 208 SECTION 8: GLASS FIBRE FABRICS FOR PRINTED CIRCUIT BOARDS List of Manufacturers 209 SECTION 9: MISCELLANEOUS MATERIALS Contents & List of Manufacturers 211 9. 1 Flake Glass 213 9. 2 Grinding Wheel Fabrics 214 9. 3 Microfibers 215 9. 4 Recycled 216 9. 5 Roofing Felt, Carpet & Flooring Reinforcement -Chopped Strand Mat 217 - Reinforcing Mesh 217 -Rovings 217 -Fabrics 218 -Scrim 220 9. 6 Screens & Allied 221 9. 7 Unclassified 222 MATERIALS FOR THE OPTICAL FIBRE INDUSTRY SECTION 10: FIBRES List of Manufacturers 224 SECTION 11: FIBRE CABLES List of Manufacturers 236 SECTION 12: OPTICAL FIBRE CABLE SUPPORT MEMBERS List of Manufacturers 243 Late Entries 245 Index to Advertisers 248 vi REVIEW Glass fibre is one - if not the most versatile of -the which are identical to both variants, is continuously materials now worked and employed by man. drawn -or spun -by high speed precision winders Suitable confirmation is provided by the pages of from platinum bushings. These bushings, this Data Book, showing the now widespread, vital numbering several score to more typically several cost-effective and important use of glass fibre hundreds, therefore dictate the number of individual across the whole spectrum of industry. Whether as glass filaments from. which the basic fibre 'strand' one of many forms of reinforcement, as fabrics or (or filament bundle) is then produced. A second other products for acoustic, electrical and thermal letter ·C" indicates continuous filaments, with the insulation,for filtration, or more recently for the alternatives "T· or ·5" (or in the teX/metric system, rapidly increasing utilisation iil its continuous, optical ·D"), describing respectively either a 'textured' or form for telecommunication and signalling, glass 'staple' product. fibre has no equal. The filament diameter follows, identified if using1he However the variety of basic formulation, type and metric system by a number denoting microns, (to grade now available, is far removed from a recent the nearest whole number), or if in inches, by a development. The art of spinning glass into fine descriptive letter. filaments - or fibres - has at its basis, expertise known for example to the craftsmen of ancient C 0.000175" Egypt. There is good evidence of their use of crude D ·0.000225" glass fibres as the strengthening component of DE 0.000250" decorative and other artifacts fabricated from E 0.000275· naturally occurring resins and glues. G 0.000375" H 0.000425" To advantage, the required raw materials are K 0.000525" present in virtually unlimited supply, readily and economically obtained from widely available A number quantifying the strand weight (Le indigenous inorganic ores. But glass has a purity of 'tex'/metric system), or count (i.e. the US or imperial formulation, technology and design, as suitably system), comes next. The former figure relates to exampled by the multiplicity of product from the grams per 1000 metres of yarn, the (atter to one simple to the sophisticated, from commercial to hundredth of the nominal bare glass yardage in one advanced. It also covers other items such as window pound of the basic yarn strand. glass and glassware. Finally as demanded by the application, each alternative glass fibre product can If employing the US system, a second number be supplied in differing condition, open to different composed of two digits separated by a hash, shows post-spinning treatment. the quantity of basic strands in the yarn, where the first digit represents the original number of twisted Such wide-ranging complexity has demanded for strands and the second, the quantity of these strands glass fibre materials, an ease of specification plied (or twisted) together. In this case the total identification, provided for - as shown by a large number of strands is therefore given by multiplying proportion of the tabulations within the Directory both digits; a zero is always counted as 1. If Section of this Data Book - by the use of an employing the tex/metric system, then the yarn alphabetic and numeric code. A correct under construction from these twisted strands is. shown by standing of this system, together with associated a third number (immediately after that for the material and product descriptions, is essential if diameter), which indicates the number of strands in those concerned in any way with the use of glass the yarn. A second digit after an ·X· indicates the fibre materials, are to ensure careful product number of these strands twisted or plied together. In selection. However whilst universally adopted for both Situations, the letters ·5· or ·Z· describe the yarn products, the coding does continue to show direction of the visible spiral/helix pattern of twist in variation, typically respective to the mensuration the yarn, when held in a vertical fashion. system employed by the country of yarn manufacture or supply. A final number denotes either the number of turns per inch or the number per metre, in the finished Glass of the desired chemical formulation, as yarn. Yarn is therefore an assembly of fibres, of described by these first letter code examples, similar or variable length, held together by twisting. Yarns are used to weave fabrics. An 'end' is a C .. Chemical resistant* thread, yarn or tow etc., running along the length of E - 'Electrical' grade the fabric (the 'warp'), whereas the 'pick' is a thread, --' R (& 5) - High strerigth grade * Original formulation, now more exclusive to yarns vii yarn or tow etc., running across the width of a fabric. The thickness, weight, construction and finish (i.e. resin matrix compatibility), of fabrics woven from this Fibres, yarns and fabrics also employ the term wide variety of glass yarn, is variable over a wide 'denier', meaning the weight in grams of 9000 spectrum, as is the style of that weaving. The weave metres of a yarn (or tow, or roving). 'Denier'therefore style of a fabric has - like the yarn itself - a great equals 9 x 'tex', or using the US system, yards per influence on the properties of the woven fabric pound is converted to 'denier' by dividing a constant composed of warp and weft (fill) yarns. For whatever number, 4,464,492 by the yards per pound. purpose the fabric is to be employed, careful selection is therefore essential. The following As a summary of the coding system and to aid diagrams indicate some of the more common style clarification, the following variations can all equally variations possible. apply. Plain I Each warp end and weft pick passes over one crossing thread and under the next. (US System) 11 r- E C 9 331x xl2 J (Tex/Metric System) I I z xl21s 115011----:-1- ---, E C 9 341 Basket '" p, ,' ... l""--c-ha-ra"'~teri~es ~i1ve 1111' p;:urto ~r cnd~ ~ra :m,k!; pD!i~lr;J a ... C'- pa.r~ o· ~rO!i~ :1g It ·e':'J3. the glass composition l_ T,p. ol'Mn. ·oontin,,",·. •. ..p l.· 0' '""""",,,' ---.- .... Individual filament diameter Lf.f10 ,), I I 'e ". rll.;tr I '" ;'; H ~,1~. ,I' .,' ~,I~ r~ I,;ro~~ I),· 'Ih" t: .... Ar ,he r. c ;;, 150 x 100 = 15,000 yards per pound ____. -oJ J Glass 'tex' , weight of bare glass strand in grams/1000 metres 1.0 _ The original number of twisted strands 111!!lOJ nd underr 'Ilt! • ... ;)151 ano ..... ~. 1=. txJltl·{\ ~ 1.0-. The number of strands plied together - The type of twist given to the yarn The number of turns per metre :w::h ~r~ or;; : ~i r;; l'S ,'our .... ;:; Ifeu': orc lorlcr t ...· & ,Jou', During the drawing and spinning process, each ;rO' 111 11'r"",;:;,. 'I,th lh ... -:rv II' ~ O'lrlrnoy 10;1 ore 11' rao!'ld r"r strand is chemically treated by a 'size' whose J, 'I 10 \i'I' pi;;:~. purpose is to protect each individual glass fibre filament from breakage or other less serious damage during further processing. ------- viii ardEflrl(! ~f~'" C'tMever1 sou. . c~? _-,""""-~I$'_,,~• • __ .. IJIie::.l:Illltll~ ',;1\', r1lOJlo;!rl:ll~ ;lI'd rr,lI;hir.-:ry fm ~QU COl. d need t €I GRF ilncI REINFORCED .Ill"'.:t"_~.,,,,,,u, t::o pro'lldl!' I:!1,t:f,,;I. Iy UI~l ~1JU trt!t!t.l ','101.1 lilt: G ASS FIBRE ~OLVESTER RESINS & GELCQAT • FW PULTRU51QN W[AVlRS IlO'll'INGo • GP ~UIN 5F'RAY UP ROVING • ISO PI-l'IHALIC ~ ~51N . 5MC, ROVING • B.15PtlEN,OL IttslN CHOPPED STR NI)S (rOil: &MC FAl'P) • V~,.,.ntsUR ESI N • CI-lOPPiD STRAN D MAT • fUn RETARDlNl RnlN ' WOVIN 1l0YING , RIE;SIN rOIi! l'RANSLUCINT !l.I,uns • rAl!ilUCS • RESIN FOlt CASTING rlllnoN~ Qle.) • "C" GLAS 50 nAK ES • GELCOAT (CHAR .&:. CaLOURED~ • YARN (ECG U:o R tt..) • TOOl! I'II.G G-El,tO~ r CES & COMPANY I~ !) r,I!II'" rtn~::h tlf.!:1'1 K. r.~• . J"'" ~!;n JAII'IoII T~IH' ~~::J-':'>"U '+'J Tc I cln,.: .CEI!>":! -:D1:' r .. l~l'IJ,,·.l'" ~:J UI~'-:.! Tn (llJER 50 ES ---- EUROPEAN & INTERNATIONAL GLASS FIBRE STANDARDS (The work of Vetrotex Saint-Gobain in compiling this comparison is recognised and acknowledged.) Notes: 1. The standards quoted under the same title may have a slightly different technical content. 2. No account has been taken of the current status (draft proposal; draft standard; standard) of the listing. 3. The use of italics indicates that these standards are not specific to glass fibre products, but are considered applicable. 4; The UNI listing includes Uniplast Standards, published as UNI. Title DIN AFNOR BSI UNI UNE ISO General Basic concepts -Terminology 61850 NF ISO 6355 B001 8746 43-501-84 6355 86/41967 43-502-84 472 Sampling method 40080 T25001 87/38633 ISO 1886 1886 Standard conditioning atmosphere 53802 GOO-003 2782 p.10 EN 62 291 meth.1004 1051 Determination of combustible matter content 1887 B38-101 2782 p.10 8532 43-504-85 1887 meth.1002 Determination of moisture content 838-108 9413 3344 Determination of filament diameter 53811 B38-102 88/37460 43-509-85 1888 (3496) Glass fibre Designation 60850/1 NF ISO 2078 43-503-79 2078 Basis for a specification 60850/2 NF ISO 3598 3598 Basis for a specification of texturised fibres NF ISO 8516 8516 Determination of linear density 53830/1 NF ISO 1889 9412 43-505-85 1889 /3 838-105 Determination of twist 53832/1 NF ISO 1890 43-511-86 1890 Determination of twist balance index 838-109 43-512-85 3343 Determination of tensile strength 53834/1 NF ISO 3341 9411 43-508-85 3341 Glass fibre fabrics Different types 61854/2 Basis for a specification . 61854/1 838-205 9310 2113 Specification woven glass fabrics 3398(3parts) Specification woven roving fabrics 3749 Basis for a specification braided sheathing 65066 10122 Determination of surface density 53854 G07-150 3398 9311/4 4605 Determination of length & width of flat fabrics 53851 838-204 9311/2 5025 Determination of linear density of yarns 52853 G07-155 9311/1 4602 Determination of linear density on a small sample 53830/3 838-105 Determination of thickness of fabrics 53855/1 G07-153 9311/3 4603 Determination of slippage resistance/fibres/fabric 838-202 Determination of flexural stiffness 53864 838-206 4604. Determination of braking strength & elongation 53857/1 838-203 3396 9311/5 4606 at break using the strip method (traction) x

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