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Geothermal Power Plants: Principles, Applications, Case Studies and Environmental Impact Third Edition Ronald DiPippo, Ph.D. Chancellor Professor Emeritus University of Massachusetts Dartmouth NorthDartmouth, Massachusetts AMSTERDAM•BOSTON•HEIDELBERG•LONDON•NEWYORK•OXFORD PARIS•SANDIEGO•SANFRANCISCO•SINGAPORE•SYDNEY•TOKYO Butterworth-HeinemannisanimprintofElsevier Butterworth-HeinemannisanimprintofElsevier TheBoulevard,LangfordLane,Kidlington,Oxford,OX51GB,UK 225WymanStreet,Waltham,MA02451,USA Firstedition2005;Secondedition2008;Thirdedition2012 Copyrightr2012ElsevierLtd.Allrightsreserved Nopartofthispublicationmaybereproducedortransmittedinanyformorbyanymeans,electronicormechanical, includingphotocopying,recording,oranyinformationstorageandretrievalsystem,withoutpermissioninwritingfrom thepublisher.Detailsonhowtoseekpermission,furtherinformationaboutthePublisher’spermissionspoliciesandour arrangementswithorganizationssuchastheCopyrightClearanceCenterandtheCopyrightLicensingAgency,canbe foundatourwebsite:www.elsevier.com/permissions. ThisbookandtheindividualcontributionscontainedinitareprotectedundercopyrightbythePublisher(otherthanas maybenotedherein). Notices NeithertheauthornorthePublisher,noranyofitsemployees,makesanywarranty,expressorimplied,orassumesany legalliabilityorresponsibilityfortheaccuracy,completeness,orusefulnessofanyinformation,apparatus,product,or processdisclosed,orrepresentsthatitsusewouldnotinfringeprivatelyownedrights.Referencehereintoanyspecific commercialproduct,process,orservicebytradename,mark,manufacturer,orotherwise,doesnotnecessarilyconstitute orimplyitsendorsement,recommendation,orfavoringbytheauthororthePublisher. Knowledgeandbestpracticeinthisfieldareconstantlychanging.Asnewresearchandexperiencebroadenour understanding,changesinresearchmethods,professionalpractices,ormedicaltreatmentmaybecomenecessary. Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgeinevaluatingandusingany information,methods,compounds,orexperimentsdescribedherein.Inusingsuchinformationormethodstheyshouldbe mindfuloftheirownsafetyandthesafetyofothers,includingpartiesforwhomtheyhaveaprofessionalresponsibility. Tothefullestextentofthelaw,neitherthePublishernortheauthors,contributors,oreditors,assumeanyliabilityforany injuryand/ordamagetopersonsorpropertyasamatterofproductsliability,negligenceorotherwise,orfromanyuseor operationofanymethods,products,instructions,orideascontainedinthematerialherein. LibraryofCongressCataloging-in-PublicationData DiPippo,Ronald. Geothermalpowerplants:principles,applications,casestudies,andenvironmentalimpact/RonaldDiPippo.(cid:1)3rded. p.cm. Includesbibliographicalreferencesandindex. ISBN978-0-08-098206-9 1.Geothermalpowerplants.2.Geothermalresources.3.Geothermalengineering.I.Title. TK1055.D572012 621.44–dc23 2011052963 BritishLibraryCataloguing-in-PublicationData AcataloguerecordforthisbookisavailablefromtheBritishLibrary ForinformationonallButterworth-Heinemannpublications visitourwebsiteatwww.elsevierdirect.com PrintedintheUnitedStatesofAmerica 12131415 10987654321 Preface and Acknowledgements to the Third Edition This edition represents a major revision and extension of the original edition published in 2005. In the roughly six years since the First Edition appeared, the inexorable movement toward cleaner and more sustainable energy resources has continued. Despite growing evidence of global changes to our environment that will have huge consequences for future generations, the world has not moved as rapidly toward less polluting and more sustainable sources of primary energy as might be expected in the face ofthe coming crisis. Nevertheless geothermal energy can become a significant source of renewable, sus- tainable,andcleanenergytotheworld,bothfordirectheatandelectricpowergenera- tion. In the latter case (cid:1) the subject of this book (cid:1) it is worthwhile to repeat the words of my mentor Professor Joseph Kestin, who back in 1979, wrote: “Geothermal electricity, unlike fossil or nuclear, cannot be ordered: it must be developed, for there is noth- ingmorehazardousthanapremature orderforconversionequipment.”Apparentlythissim- ple lesson needs to be relearned by each generation and especially by those who aim to develop new sites, new resources, ornew technologies. It was in fact this unique aspect of geothermal energy that intrigued me when I first becameinvolvedwithitbackinthe1970s.Asanacademicandaresearcher,Ilookedfor the basic principles that would guide the exploitation of geothermal energy. Beyond the fundamentalgeology,chemistry,andphysics,muchofwhatwasneededturnedouttobe highly site-specific. Back then there were few geothermal plants in operation and nearly all of them were dry-steam plants. Even so there were significant differences among the resourcesthatnecessitatedspecificengineeringdesignstocopewiththevariations. Nowthataverywidespectrumofresourcesisbeingtappedtogeneratepower,theneed to study and thoroughly characterize each site and then craft the power plant to match the resource is even more important. We may understand the basic science that governs the processes, but the applications will require innovative solutions to problems encoun- teredallthewayfromexplorationthroughdrillingandplantdesign,construction,opera- tion,andmaintenance.Therefore,thiseditionincludesmorecasestudiesinPartThree. Chapter 19 focuses on two new and growing power plants in Iceland, the Nesjavellir andHellisheidiplants.Icelandhasexperiencedaspectacularincreaseingeothermalpower generation since 2007, growing its installed capacity from 422.4MW to 715.4MW, a 69%increaseoverfouryears.Andthishasbeenaccomplishedwithoutretiringanyofits olderplants.Icelandnowhas31operatingunitscomparedto24in2007. xvi PrefaceandAcknowledgementstotheThirdEdition Chapter 20 tells the story of Raft River in Idaho, one of the first fields to be devel- oped for geothermal power back in the 1970s and early 1980s. The original pilot plant was soon dismantled after a short demonstration run but after 20 years of inac- tivity, the site has been brought back to life. The lessons learned from the original plantand the new one are presented inthis chapter. Chapter 21 highlights another country making great strides in geothermal develop- ment, thanks in large measure to legislative reforms that opened geothermal energy to private companies. Turkey now is host to eight geothermal units, three of them mod- ern gleaming examples of highly efficient units. Turkey went from having two units with an installed capacity of 27.8MW in 2007 to eight units at 95MW in mid-2011, more than tripling its geothermal generating capacity in four years. And more plants are expectedto bebuiltinthe near future. Chapter 22 deals with the future hope for geothermal power, Enhanced Geothermal Systems or EGS. In the Second Edition, EGS was covered as part of the presentation of advanced energy conversion systems (Chapter 9) but so much has happened in the last four years that even a chapter devoted solely to EGS is not adequate to address the subject. It is a tale full of hope yet disappointments. It is not yet certain what role EGS will play in the development of geothermal power, but it remains a most important technology that must be further refined before it can be truly considered commercial. The new chapter details many research and development efforts and the lessons that should belearned from them. The other new addition is an appendix that explains how a convenient new soft- ware program, REFPROP, developed by and available from the U.S. National Institute of Standards and Technology (NIST), can be used to implement spreadsheet systems simulators. Appendix H includes a tutorial on the use of the program and worked examples showing how to use it in conjunction with Excel to model a geothermal binary plant. All the data tables on power plants aroundthe world have been completely updated to mid-2011 (Appendix A). Updates and revisions have been made to several chapters from the Second Edition, with a new section on solar-geothermal hybrid plants (Chapter 9) and an extension of exergy analysis to pumps and to production well per- formance (Chapter 10). A couple of typos from the Second Edition have been corrected and hopefully not too manynew oneshavecreptinto this one. I wish to thank the following people for various forms of assistance during the writ- ing of the Third Edition. First of all, I extend my deepest appreciation to Lucien Bronicki, the Chairman and CTO of Ormat, for writing the Foreword. The previous edi- tions lacked a Foreword and to have one of the most successful geothermal enterpre- neurs write one for this edition is very special and meaningful to me. Several people provided valuable information on the plants in Turkey: Umran Serpen (Instanbul Technical University); Marshall Ralph and Bill Harvey (Power Engineers); Henry Veizades (Veizades & Associates); and Riza Kaderli (Guris). Lucien Bronicki and Zvi Kreiger (Ormat) generously provided me with flow diagrams and performance data for several of their recent binary installations, and Lucien reviewed some new sections for accuracy. Einar Gunnlaugsson (Orkuveita Reykjav´ıkur) clarified the historical timeline of development for the Nesjavellir and Hellisheidi plants. Ernst Huenges and Stephanie Frick (Deutsches GeoForschungsZentrum-GFZ) were kind enough to send me a copy of PrefaceandAcknowledgementstotheThirdEdition xvii their excellent book, Geothermal Energy Systems, that was edited by Ernst and which has extensive research material related to EGS. Tiffany Gasbarrini, my editor at Elsevier, encouraged me to tackle this new edition and steered it through the proposal, approval, and implementation process in a professional and efficient manner. The Elsevier production team, particularly Lisa Lamenzo and Charles Roumeliotis, did an outstanding job of keeping the book on time and as free of errors as is humanly possi- ble. I finally thank all those who have helped me grasp the nuances and subtleties of geothermal power plants in various ways through planned and random conversations; any errors of commission oromission are solely mine. The color figures are designated with [WWW] at the end of the caption. All of the figuresusedinthisbookmaybeviewedatelsevierdirect.com/companions/9780080982069. Ronald DiPippo Dartmouth,Massachusetts August 2011 Contents Foreword to the Third Edition xi Preface and Acknowledgements to the Third Edition xv Preface and Acknowledgements to the Second Edition xix Preface and Acknowledgements to the First Edition xxi PART1 RESOURCE IDENTIFICATION AND DEVELOPMENT 1 1. Geology ofGeothermalRegions 3 1.1 Introduction 3 1.2 The Earth and its atmosphere 4 1.3 Active geothermal regions 6 1.4 Model ofa hydrothermal geothermal resource 9 1.5 Other types ofgeothermal resources 11 References 16 Problems 17 2. Exploration Strategies and Techniques 19 2.1 Introduction 19 2.2 Objectives ofan exploration program 20 2.3 Phases ofanexploration program 20 2.4 Synthesis and interpretation 33 2.5 The next step: Drilling 35 References 35 Problems 36 3. GeothermalWellDrilling 39 3.1 Introduction 39 3.2 Site preparation and drilling equipment 39 3.3 Drillingoperations 42 3.4 Safety precautions 46 References 47 4. Reservoir Engineering 49 4.1 Introduction 50 4.2 Reservoirand well flow 50 4.3 Well testing 60 vi Contents 4.4 Calcite scaling inwell casings 68 4.5 Reservoirmodeling and simulation 68 References 74 Problems 75 PART2 GEOTHERMAL POWER GENERATINGSYSTEMS 79 5. Single-Flash Steam Power Plants 81 5.1 Introduction 82 5.2 Gathering system design considerations 82 5.3 Energy conversion system 87 5.4 Thermodynamics ofthe conversion process 91 5.5 Example:Single-flashoptimization 97 5.6 Optimum separatortemperature:An approximate formulation 100 5.7 Environmental aspects for single-flash plants 102 5.8 Equipment list for single-flash plants 104 References 107 Nomenclature for figures inChapter5 108 Problems 108 6. Double-Flash Steam Power Plants 111 6.1 Introduction 112 6.2 Gathering system design considerations 112 6.3 Energy conversion system 114 6.4 Thermodynamics ofthe conversion process 115 6.5 Example:Double-flashoptimization 119 6.6 Scale potentialin waste brine 121 6.7 Environmental aspects for double-flashplants 125 6.8 Equipment list for double-flashplants 126 References 127 Nomenclature for figures inChapter6 127 Problems 128 7. Dry-Steam PowerPlants 131 7.1 Introduction 131 7.2 Originsand nature ofdry-steam resources 132 7.3 Steam gatheringsystem 138 7.4 Energy conversion system 138 7.5 Example:Optimum wellhead pressure 144 7.6 Environmental aspects ofdry-steam plants 147 7.7 Equipment list for dry-steam plants 147 References 148 Nomenclature for figures inChapter7 149 Problems 149 8. Binary Cycle Power Plants 151 8.1 Introduction 152 8.2 Basic binary systems 153 Contents vii 8.3 Workingfluidselection 159 8.4 Advancedbinary cycles 163 8.5 Example ofbinary cycle analysis 171 8.6 Environmental impact ofbinary cycles 175 8.7 Equipment list for basicbinary plants 176 References 178 Nomenclature for figures inChapter8 179 Problems 180 9. Advanced GeothermalEnergy Conversion Systems 183 9.1 Introduction 184 9.2 Hybrid single-flashand double-flashsystems 185 9.3 Hybrid flash-binarysystems 189 9.4 Example:Integrated flash-binaryhybrid system 193 9.5 Total-flow systems 196 9.6 Hybrid fossil-geothermal systems 203 9.7 Combinedheatand powerplants 207 9.8 Power plants for hypersaline brines 209 9.9 Solar-geothermalhybrid plants 212 References 215 Nomenclature for figures inChapter9 217 Problems 218 10. ExergyAnalysis Applied toGeothermalPowerSystems 223 10.1 Introduction 223 10.2 FirstLaw for open, steady systems 224 10.3 SecondLaw for open, steady systems 225 10.4 Exergy 225 10.5 Exergyaccounting for open,steadysystems 229 10.6 Exergyefficiencies and applicationsto geothermal plants 230 References 244 Problems 244 PART3 GEOTHERMAL POWER PLANT CASESTUDIES 247 11. Larderello Dry-Steam Power Plants, Tuscany,Italy 249 11.1 History ofdevelopment 249 11.2 Geology and reservoir characteristics 252 11.3 Powerplants 256 11.4 Mitigation of environmental impact 266 References 267 Nomenclature for figures inChapter11 268 12. The Geysers Dry-Steam Power Plants,Sonoma and Lake Counties, California,USA 269 12.1 History and earlypowerplants 269 12.2 Geographic and geologic setting 273 viii Contents 12.3 Welldrilling 275 12.4 Steampipeline system 276 12.5 Powerplants 277 12.6 Rechargingthe reservoir 283 12.7 Toward sustainability 286 References 287 13. CerroPrieto Power Station,BajaCalifornia Norte, Mexico 289 13.1 Overview ofMexican geothermal development 289 13.2 CerroPrietogeographical and geological setting 290 13.3 CerroPrietopower plants 294 13.4 Expansion ofCerro Prieto and nearby prospects 301 References 303 Nomenclature for figures inChapter13 304 14. Hatchobaru PowerStation,OitaPrefecture,Kyushu,Japan 305 14.1 Overview ofJapanese geothermal development 305 14.2 Hatchobaru geothermal field 307 14.3 Hatchobaru powerunits 310 14.4 Conclusion and forecast 316 References 316 Nomenclature for figures inChapter14 317 15. Mutnovsky Flash-Steam PowerPlant, Kamchatka Peninsula,Russia 319 15.1 Setting, exploration, and early developments 319 15.2 Conceptual modelof Mutnovsky geothermal field 320 15.3 Verkhne-Mutnovsky 12MW power plant 323 15.4 Mutnovsky first-stage 50MW powerplant 326 15.5 Future power units atMutnovsky 327 References 329 16. Miravalles PowerStation, Guanacaste Province, Costa Rica 331 16.1 Traveling toMiravalles 331 16.2 History ofgeothermal development 333 16.3 Wells 335 16.4 Powergeneration 336 16.5 Calcite inhibition system 340 16.6 Acidneutralization system 344 16.7 Environmental protectionand monitoring 345 16.8 Other geothermal power projects 346 References 347 17. HeberBinary Plants,Imperial Valley, California, USA 349 17.1 Introduction 349 17.2 Exploration and discovery 349 17.3 The firstHeberbinary plant 351 17.4 The secondHeberbinary plant 353 Contents ix References 358 Nomenclature for figures inChapter17 359 18. Magmamax Binary Power Plant, East Mesa, Imperial Valley, California, USA 361 18.1 Setting and exploration 361 18.2 Magmamax binary powerplant 362 18.3 Modified Magmamax binary power plant 368 18.4 Conclusion 373 References 373 19. Nesjavellir and HellisheidiPlants, Iceland 375 19.1 Introduction 375 19.2 Geology and geosciences 376 19.3 Nesjavellir powerplant 379 19.4 Hellisheidipowerplant 384 References 387 20. RaftRiverPlants,Idaho,USA 389 20.1 Introduction 389 20.2 Geology and geosciences 390 20.3 Originaldevelopment(cid:1) DOE pilot plant 393 20.4 New development (cid:1) U.S. Geothermal plant 403 References 414 21. GeothermalPowerPlants inTurkey 417 21.1 Geologic setting 417 21.2 K(cid:1)z(cid:1)ldere single-flash plant 419 21.3 Salavatl(cid:1) binary plants 425 21.4 Germencik double-flashplant 431 21.5 Environmental impact 437 21.6 Current state and future prospects ofgeothermal power 438 References 439 Nomenclature for figures inChapter21 441 22. Enhanced GeothermalSystems (cid:1)Projects and Plants 443 22.1 Definitions 443 22.2 Earlyprojects 445 22.3 Laterprojects 450 22.4 EGS power plants 463 22.5 Proposed projects 474 References 478 23. Environmental Impact of Geothermal Power Plants 483 23.1 Overview 484 23.2 Regulations 484 23.3 General impacts of electricity generation 485 23.4 Environmental advantages ofgeothermal plants 485

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