Environmental Forensics Proceedings of the 2013 INEF Conference 1 0 0 P F 7- 4 3 8 2 6 2 8 7 1 8 7 9 9/ 3 0 1 0. 1 oi: 5:35. org | d 4 09:4bs.rsc. 1u 0p 7/2p:// 24/0n htt on 4 o wnloaded 1 July 201 o0 Dn o d e h s bli u P View Online 1 0 0 P F 7- 4 3 8 2 6 2 8 7 1 8 7 9 9/ 3 0 1 0. 1 oi: 5:35. org | d 4 09:4bs.rsc. 1u 0p 7/2p:// 24/0n htt on 4 o wnloaded 1 July 201 o0 Dn o d e h s bli u P View Online Particle Science and Engineering Proceedings of the 2013 INEF Conference 1 Edited by 0 P0 F 7- Robert D Morrison 4 3 28 Morrison and Associates, Hawi, Hawaii 96719, USA 6 82 Email: [email protected] 7 1 8 7 9 9/ Gwen O'Sullivan 3 0 1 Mount Royal University, Calgary, Alberta, Canada 0. 1 oi: Email: [email protected] 4 09:45:35. bs.rsc.org | d 1u 0p 7/2p:// 24/0n htt on 4 o wnloaded 1 July 201 o0 Dn o d e h blis u P View Online The proceedings of International Network of Environmental Forensics Penn State Conference 2013 held at Pennsylvania State University, USA on 10-12 June, 2013. 1 0 0 P F 7- 34 8 2 6 2 8 17 78 9 9/ 03 0.1 Special Publication No. 348 1 oi: 5:35. org | d PPrDinFt eISISBBNN: :9 97788-1-1-8-748927632-9-84344--37 4 09:4bs.rsc. A catalogue record for this book is available from the British Library 01pu 7/2p:// © The Royal Society of Chemistry 2014 24/0n htt on 4 o All rights reserved wnloaded 1 July 201 Apupraprot sferos,m o ra ncyri ftaiciirs mde aolri nregv fioerw t haes ppeurrmpoitstee do fu rnedseera trhceh toerr mprsi voaf tteh es tUudKy Cfoorp nyoring-hcto, mDmeseirgcnias la nd o0 Patents Act, 1988 and the Copyright and Related Rights Regulations 2003, this publication may Dn o not be reproduced, stored or transmitted, in any form or by any means, without the prior d he permission in writing of The Royal Society of Chemistry or the copyright owner, or in the case s bli of reprographic reproduction only in accordance with the terms of the licences issued by the u P Copyright Licensing Agency in the UK, or in accordance with the terms of the licences issued by the appropriate Reproduction Rights Organization outside the UK. Enquiries concerning reproduction outside the terms stated here should be sent to The Royal Society of Chemistry at the address printed on this page. The RSC is not responsible for individual opinions expressed in this work. Published by The Royal Society of Chemistry, Thomas Graham House, Science Park, Milton Road, Cambridge CB4 0WF, UK Registered Charity Number 207890 Visit our website at www.rsc.org/books Printed in the United Kingdom by CPI Group (UK) Ltd, Croydon, CR0 4YY, UK PREFACE From June 10th to the 12th, the 3rd International Network of Environmental Forensics (INEF) environmental forensics conference was held at the Pennsylvania State University at University Park, Pennsylvania. The conference was attended by scientists, regulators, 05 academics and consultants from throughout the world. Given the advancement and refinement 0 P of environmental forensic techniques and the academic recognition of environmental forensics F 7- by universities throughout the world, this conference provided a forum for individuals to share 4 83 their experiences and research in an open and collaborative forum. 2 6 2 8 7 Since the first INEF conference held in Qingdao, China in 2008, significant advances in the 1 78 state of the art in environmental forensics have occurred, especially in the fields of compound 9 9/ specific isotope analysis (CSIA), biological and petroleum hydrocarbon pattern recognition 3 10 and the use of advanced multivariate techniques for interpreting environmental forensics data. 10. Of note in these proceedings is the application of environmental forensic techniques to 4 09:45:39. bs.rsc.org | doi: ei Anxstae wmrniiatnhtei o pcnroeavnl itaoatmutesin nptaiuonbntl iiicnsas ttuhieoesn p aoasfss tIo NsceiEvaFeter dapl r owyceietaher dsh.i ny gdsr,o foruarc kinintegn tw ihs itcoh mheams orericaeliivzeed a ncdo ndsoidcuermabenlet 1u the evolution of environmental forensic techniques for the international scientific community. 0p 7/2p:// It is our intent that the information in these proceedings provides useful information to you in 24/0n htt your practice and inspires you to contribute to the future advancement of environmental on 4 o forensics. wnloaded 1 July 201 GRowbeenr tO M’Sourlrliisvoann,, PPhh..DD.. o0 Dn o d e h s bli u P View Online 5 0 0 P F 7- 4 3 8 2 6 2 8 7 1 8 7 9 9/ 3 0 1 0. 1 oi: 5:39. org | d 4 09:4bs.rsc. 1u 0p 7/2p:// 24/0n htt on 4 o wnloaded 1 July 201 o0 Dn o d e h s bli u P Author Biographies Robert Morrison, Ph.D. Dr. Morrison has a B.S. in Geology, a M.S. in Environmental Studies and a Ph.D. in Soil Physics from the University of Wisconsin at Madison. Dr. Morrison has worked for 44 years as an environmental consultant on projects related to soil and 07 groundwater contamination, including site investigations and 0 P remediation. Dr. Morrison currently specializes in the forensic review F 7- and interpretation of scientific data for the purpose of identifying the 4 83 source and age of a contaminant release. 2 26 8 7 Gwen O’Sullivan, Ph.D., MRSC. Dr Gwen O’Sullivan is an 1 78 Assistant Professor of Environmental Science at Mount Royal 9 9/ University. Dr O’Sullivan earned a B.Sc. in Environmental Science 3 10 from the University of Limerick and a Ph.D. in Environmental 0. 1 Chemistry from Queen’s University of Belfast. Over the course of 4 09:45:38. bs.rsc.org | doi: hdclaheenrevd mec laaiorsnpetdreey dr,,g irenotne uicvnnhiddrnouwinscatmartely er,n .c etSoaxnlhp seefu rotlhitrasaeesnn cswiyic nosa r,n kdteah diare c oaqdnau eranemlauiitsmay , e Doaronfr u.d sO e cn’roSevnsuiretloaalimnrvcmaihnne a nahtnteaaddsl 1u industrial projects including the development of technologies and 0p 7/2p:// remedial actions plans for the treatment of petroleum hydrocarbons, 24/0n htt chlorinated solvents, and saline impacted sites. She has also designed and managed on 4 o environmental forensic investigations involving compounds of concerns including drilling wnloaded 1 July 201 fpaluoutlihydocshr, elpoder tinrnoualmteeudemr od uhibsy edsnrcosiocea-nprtb-idfoiinco sx,a iprntosic lylaecnsyd,c ledidci biateerndoz mobafoutoircka nsh sy,sd ermroiceeasth rbaanonend s ,as npudoc lcyencsihtsrflaoutrlelisyn. a tcSeodhm eb pihpeathesed n alflysosor, o0 research grant both nationally and internationally. Dn o ed Chris Balouet, Ph.D. Chris is principal scientist at Environment h blis International, a French company he established in 1993. Trained as a u research scientist to the Paris Museum of Natural History and the P Smithsonian Institution, he has served governmental and intergovernmental organisations, industry, law firms and NGOs on complex environmental and forensic issues. His vocation started in 1967 when he did wet his short pants in Torrey Canyon oil slick. His experience is quite diverse, ranging from paleontology to ozone layer, air quality issues in aerospace industry, oil pollution in marine environment and polluted sites, but always at international level. Since 2002, he has been researching and developing environmental forensic methods based on trees, known as phytoscreening and dendrochemistry, serving over 150 forensic cases worldwide, and leading an international research program by ADEME, known as Pollution Investigation by Trees (PIT). He also serves as judicial expert to the French Appeal Court of Amiens. Chris enjoys serving environmental issues with best available science, even if new to the beneficiaries, communicating as a teacher or a writer, and with a profound sense of team collaborations. View Online viii Author Biographies Frank L. Dorman, Ph.D. Frank Dorman is currently an Associate Professor at The Pennsylvania State University in University Park, PA. Frank is a member of the Forensics Science Program, and in the Department of Biochemistry and Molecular Biology. In addition to Undergraduate and Graduate student instruction, Frank continues to pursue research interests in gas and liquid chromatography 07 fundamental characterization, instrumentation and column 0 P development, and application to trace analysis in complex sample F 7- matrices. Prior to joining the faculty at PSU, Frank was the Director 4 83 of Technical Development, at Restek Corporation, responsible for external research 2 26 collaborations, new technology identification, and product development. Frank has a B.S. in 8 7 Chemistry from Juniata College in Huntingdon, PA, and a Ph.D. in Analytical Chemistry from 1 78 the University of Vermont, Prior to coming to Restek, he worked for Inchcape Testing 9 9/ Services as Senior Chemist responsible for method development from 1991-96. Frank has 3 10 experience with both GC and LC separations, mass spectrometry, and atomic spectroscopy, 0. 1 and has developed analytical methods for a variety of organic and organometallic compounds 5:38. org | doi: iMn ivkaer iFoouws slearm, pPlhe .mDa. trMiciekse. Fowler is a geochemist with over 20 14 09:4ubs.rsc. ycheaerms isttreya chati ngth ee xUpneirvieenrcsiet.i esH eo f sBturdisiteodl agnedo loBgiyr mianngdh amm,i nearnadl 0p 7/2p:// completed PhD research and an 1851 Research Fellowship at 24/0n htt Iinm pietsr iarle Cgioolnleagl e.g Heoec hheams iwstorryk egdr ofourp thaen dB riatti sht hGe eoNloEgRicCa l ISsuortovpeye ownloaded on 01 July 2014 o GObthrexeieo ffolUlorydng tiyovB etrCrhoseeoit nkUyte rnseoi ,vf U ebPnresoifvirtoetyrsr emso ifto tyGeu atlfhcoo hursi cni1eng3sc t eeyg rees2hao0ric0rshe.6 e, Fmbwruiohstm tehrry aeO s thbxoeef o egrnisde v oPhelorreyig n mihcsiatopspv apelay dt L aet cturer and Programme Don Manager for Geoscience courses. His main research interests have been in crustal evolution ed and environmental geochemistry, and more recently in chemical methods for source h blis attribution of industrial fugitive dusts with colleagues at DustScan Ltd. He has published forty u or so peer-reviewed papers on a variety of such topics, and written a roughly equivalent P number of consultancy reports. Mike likes all sports, and still plods around a squash court from time to time. John O. Goreham is a Project Manager at Matson & Associates, Inc. in State College, Pennsylvania. He evaluates manufacturing plants and other industrial facilities for compliance with industry standards and regulations including RCRA, TSCA, and the CWA concerning the use, handling, storage, treatment and disposal of chemicals and chemical-contaminated waste streams. Mr. Goreham’s expertise includes forensic investigation of a variety of industrial operations and practices to identify sources, amounts, and fate of chemical emissions resulting in environmental contamination. He conducts research on hazardous and toxic substances including PCBs, arsenic, methane, perchlorate, and chlorinated solvents and assists in preparing for deposition of fact witnesses and experts and in preparing for direct and cross exams of trial experts. View Online Author Biographies ix Alan W.A. Jeffrey, Ph.D. Alan Jeffrey is Senior Geochemist at Pace Analytical/Zymax Forensics in Escondido, California. Dr. Jeffrey has over 30 years of U.S. and international experience in environmental and petroleum geochemistry. Much of his work has focused on the use of geochemical and stable isotope techniques to solve environmental problems, including sources of spilled 07 hydrocarbon fuels and chlorinated solvents, and fugitive methane 0 P seeps. F 7- 4 3 Karl J. Jobst, Ph.D. Karl J. Jobst is a recent graduate of McMaster 8 62 University, where he received his Ph.D. (2011) with the guidance of 2 8 Professor Johan K. Terlouw. His thesis focused on the study of 7 1 8 catalysis in the chemistry of gas-phase organic ions using mass 7 9/9 spectrometry experiments and theoretical calculations. Some of this 3 0 research was relevant to the chemistry of interstellar space, but 1 0. following graduation, Karl pursued more Earth-oriented studies as a 1 oi: postdoctoral fellow at Environment Canada. He is presently a 5:38. org | d socfi ethneti sEt navt itrhoen mLeanbto. raHtoe ryal sSoe rhvoicldess aBdrjaunnccht opfr otfhees sOorn tsatraitou sM iinn itshtery D epartment of Chemistry 14 09:4ubs.rsc. aanndd Caphpelmiciactailo nB ioofl osgoyp ahti sMticcaMteads tmera Ussn isvpeercstirtoym. Ketarryl iasn cdu r(rmenutlltyid iinmteernessitoenda iln) tchher odmevaetologprmapehnyt 0p 7/2p:// techniques capable of tackling challenging environmental analytical problems. 24/0n htt Glenn W. Johnson, Ph.D. Dr. Glenn Johnson’s expertise is in the on 4 o area of environmental forensics, with a particular focus on wnloaded 1 July 201 mPenCuvBlitrisov, narmdiiaeotnext ianslts a tciasontnidcs aufll utmirnaegnt sh. owd istD har .n dRJ ooshuonxus rocenAs s, sspofaectnieat t eassne,d v etInrna cn.ys epao(rWrst eoisnft o0 Dn Deptford, New Jersey) and McLaren/Hart Environmental o d Engineering, Corp (Philadelphia, PA). He has been at the Energy & e sh Geoscience Institute (EGI) at the University of Utah since 1995, ubli where he has a faculty appointment in the Department of Civil and P Environmental Engineering. Dr. Johnson frequently consults, and has served as an expert witness in a number of environmental litigation matters involving multivariate statistics and environmental chemistry. Jun Lu, Ph.D. Dr. Lu has a BS in Geology from Hefei Polytechnic University, China and MS and PhD in Geochemistry from Virginia Tech. He is a California Professional Geologist, Certified Hydrogeologist and Certified Engineering Geologist. Over the last 27 years of his professional career, he has been involved in various scientific disciplines such as geology, hydrogeology and geochemistry. He specializes in contaminant source characterization for development and enhancement of conceptual site models for site investigation and remediation. Dr. Lu has provided technical support for legal teams for environmental liability related projects and View Online x Author Biographies also serves as a “Subject Matter Expert” of groundwater hydrogeology for the State of California Board of Professional Engineers and Land Surveyors. Dr. Lu’s experience extends globally across petroleum refineries, terminals and pipelines, underground storage tanks, oil fields, surface water spills, manufactured gas plants, chlorinated solvents and various other industrial facilities. He is currently a Principal Technical Specialist of AECOM, a global professional technical and management support service provider. 7 0 P0 David Megson David Megson obtained a BSc in Environmental F 7- Forensics and an MSc in Environmental Analysis and Assessment. 4 3 He has over four years experience working in the UK as an 8 62 environmental consultant, specializing in human health risk 2 78 assessment and contaminant fate and transport. He has undertaken 1 8 contaminated land assessments, remediation projects and forensic 7 9/9 investigations involving source identification. He has published 3 0 several papers and co-authored book chapters in the field of 1 0. environmental forensics focusing on POPs in the environment. Mr. 1 oi: Megson is a member of the Royal Society of Chemistry and the 5:38. org | d Sa ocPihetDy oaf tB rPolwymnfoieultdh RUisnki vAesrsseitsys m(eUntK. )H, e uiss icnugr remntullyt isdtiumdeyninsigo nfoarl 14 09:4ubs.rsc. ctohorol manadt otogr iadpehnyti ftoy acnreda ateg eh idgaht er ehsuomluatnio enx PpoCsBu rsei gton aPtCurBess. fo r use a s an ecological monitoring 0p 24/07/2n http:// Cofa rtrlaon Mspoorntt, i,f aPteh,. Dan. dD re.f fCecatrsl oo fM coonnttia smpiencaianltisz eins ianq tuhaet ice vhaalubaittaiotsn, on 4 o soil, sediment, and groundwater. He has managed and been the wnloaded 1 July 201 paessrtsiuneacsrsipimnaeel nwtsia ntvoeefr sst,a i gowacteiodaren vwoafar tieertfysie, lodaf,n dc olganbrtooaumranitdnowaryna,tt se r.ai nnD dlr a. kMtehseo, onrrtieiv tiehcraassl, o0 Dn also directed ecological risk assessments, cost allocation studies, o d and Environmental Liability assessments for sites involving soils, e sh sediments, and waters contaminated with dioxin, PCBs, DDT, ubli mercury, petroleum hydrocarbons, solvents, and other P contaminants. He has conducted fate and transport modeling at the basin level in a variety of river systems. Dr. Monti is an expert in environmental forensics. He has also conducted environmental due diligence assessments at a variety of industrial facilities in Europe, Asia, and Central and South America. Steven Mudge, Ph.D. Dr. Stephen Mudge is a Managing Scientist in Exponent’s Environmental Sciences practice. Dr. Mudge has been a practicing environmental scientist for 28 years, gaining his Ph.D. on the development of novel chemicals for use as non-toxic antifouling paint additives. He spent almost 6 years at Lancaster University as a post-doctoral research associate investigating the geochemistry of radionuclides in the environment, especially plutonium in estuaries and polonium-210 discharged from a metal smelter. These studies were funded by Her Majesty’s Inspectorate of Pollution, the forerunner to the Environment Agency in the UK.