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Environmental Chemistry for a Sustainable World Saravanan Rajendran Mu. Naushad Kumar Raju Rabah Boukherroub E ditors Emerging Nanostructured Materials for Energy and Environmental Science Environmental Chemistry for a Sustainable World Volume 23 SeriesEditors Eric Lichtfouse, Aix-Marseille University, CEREGE, CNRS, IRD, INRA, Coll France,AixenProvence,France JanSchwarzbauer,RWTHAachenUniversity,Aachen,Germany Didier Robert, CNRS, European Laboratory for Catalysis and Surface Sciences, Saint-Avold,France OtherPublicationsbytheEditors Books EnvironmentalChemistry http://www.springer.com/978-3-540-22860-8 OrganicContaminantsinRiverineandGroundwaterSystems http://www.springer.com/978-3-540-31169-0 SustainableAgriculture Volume1:http://www.springer.com/978-90-481-2665-1 Volume2:http://www.springer.com/978-94-007-0393-3 Bookseries EnvironmentalChemistryforaSustainableWorld http://www.springer.com/series/11480 SustainableAgricultureReviews http://www.springer.com/series/8380 Journals EnvironmentalChemistryLetters http://www.springer.com/10311 AgronomyforSustainableDevelopment http://www.springer.com/13593 Moreinformationaboutthisseriesathttp://www.springer.com/series/11480 (cid:129) (cid:129) Saravanan Rajendran Mu. Naushad (cid:129) Kumar Raju Rabah Boukherroub Editors Emerging Nanostructured Materials for Energy and Environmental Science Editors SaravananRajendran Mu.Naushad FacultyofEngineering,Departmentof ChemistryDepartment,CollegeofScience MechanicalEngineering KingSaudUniversity UniversityofTarapacá Riyadh,SaudiArabia Arica,Chile KumarRaju RabahBoukherroub EnergyMaterials Univ.Lille,CNRS,CentraleLille,ISEN, CSIRMaterialsScienceand Univ.Valenciennes,UMR8520–IEMN Manufacturing Lille,France Pretoria,SouthAfrica ISSN2213-7114 ISSN2213-7122 (electronic) EnvironmentalChemistryforaSustainableWorld ISBN978-3-030-04473-2 ISBN978-3-030-04474-9 (eBook) https://doi.org/10.1007/978-3-030-04474-9 LibraryofCongressControlNumber:2018968082 ©SpringerNatureSwitzerlandAG2019,correctedpublication2019 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpart of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation,broadcasting,reproductiononmicrofilmsorinanyotherphysicalway,andtransmissionor informationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt fromtherelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. Thepublisher,theauthors,andtheeditorsaresafetoassumethattheadviceandinformationinthisbook arebelievedtobetrueandaccurateatthedateofpublication.Neitherthepublishernortheauthorsorthe editorsgiveawarranty,expressorimplied,withrespecttothematerialcontainedhereinorforanyerrors oromissionsthatmayhavebeenmade.Thepublisherremainsneutralwithregardtojurisdictionalclaims inpublishedmapsandinstitutionalaffiliations. ThisSpringerimprintispublishedbytheregisteredcompanySpringerNatureSwitzerlandAG. Theregisteredcompanyaddressis:Gewerbestrasse11,6330Cham,Switzerland Preface Theever-increasingenergyconsumptionandenvironmentalpollutionarethemajor obstacles in the modern day society. Hence, this could be altered by an innovative and contemporary approach globally to make ease of the rapid growing energy hassles with zero environmental pollution. Advanced technologies exploiting the fascinating properties of nanostructured materials and nanoscale engineering have beenwidelyacceptedtorevolutionizetheperformanceofelectrocatalystplatforms, energystorageandconversionsystems,photocatalysts,efficientadsorptiontechnol- ogy,andcarboncapturingsystems.Amassiveamountofresearchhasbeendevoted on nanomaterials in the recent past to achieve sustainable development in clean energy and environmental protection. Also, for competent dealing with pollutants, identifyinguniquematerialshavinginherentadvantageslikesuperiorstructure and function as an active catalyst, electrode materials, and adsorbents remains a key challenge. Besides, fundamental understanding of their structural properties and operatingprinciplesisequallyimportanttodesignthestate-of-the-artnanomaterials forveryspecificchallenges.Thisbookdescribesthefundamentalaspectsofdiverse range ofnanomaterialsfor energy andenvironmentalapplications inacomprehen- sive manner from thespecialists who areatthe forefront ofresearch inthe fieldof energyandenvironmentalscience.Asthesetwotopicsaretremendouslybroad,and tosummarizetherecentdevelopmentsandfutureperspectives,wehavechosenthe chapterscarefullytocovertheimportantaspectsofenergyandenvironmentalfield, especiallyanefficientutilizationofnanomaterialstodeliversolutionsforthepublic consciousness. Arica,Chile SaravananRajendran Riyadh,SaudiArabia Mu.Naushad Pretoria,SouthAfrica KumarRaju Lille,France RabahBoukherroub v Acknowledgments Firstandforemost,wewouldliketothankAlmightyGodforthecompletionofthis book. We are grateful tothe series editor,EricLichtfouse, for his support,encour- agement, and trust during the process of writing this book. His observations, remarks, and eagerness have helped to improve the quality of this book. We would also like to express our gratitude to the publisher, Springer, for accepting thisbookaspartoftheseriesEnvironmentalChemistryforaSustainableWorld. Thisbookistheoutcomeoftheremarkablecontributionofexpertsfromvarious interdisciplinaryfieldsofscienceandcoversthemostcomprehensive,in-depth,and up-to-dateresearchandreviews.Wearethankfultoallthecontributingauthorsand theircoauthorsfortheiresteemedwork.Wewouldliketoexpressourgratitudetoall theauthors,publishers, andother researchers for granting usthecopyrightpermis- sions to use their illustrations. Although, every effort has been made to obtain the copyright permissions from the respective owners to include citation with the reproduced materials. We would still like to offer our deep apologies to any copyrightholderifunknowinglytheirrightisbeinginfringed. Saravanan Rajendran would like to thank the SERC (CONICYT/FONDAP/ 15110019), FONDECYT, Government of Chile (Project No.: 11170414), and School of Mechanical Engineering (EUDIM), University of Tarapaca, Arica, Chile, which made it possible to edit this book. Further, my sincere gratitude to Prof. Francisco Gracia (DIQBT, University of Chile), Prof. Lorena Cornejo Ponce (EUDIM, University of Tarapaca), and Prof. Rodrigo Palma (Director, SERC) for their continuous support, motivation, moral guidance, enthusiasm, and immense knowledgewhichhelpedmeatthetimeofresearchandeditingofthisbook. Mu.Naushadwouldliketoexpresshisdeepgratitude totheChairman, Depart- mentofChemistry,CollegeofScience,KingSaudUniversity,SaudiArabia,forhis valuablesuggestionsandconstantinspiration.HeisalsothankfultotheDeanshipof ScientificResearchatKingSaudUniversityforthesupport. vii viii Acknowledgments R. Boukherroub gratefully acknowledges the financial support from the Centre National de la Recherche Scientifique (CNRS), the University of Lille, and the Hauts-de-Franceregion. SaravananRajendran Mu.Naushad KumarRaju RabahBoukherroub Contents 1 EmergingNanomaterialsinEnergyandEnvironmental Science:AnOverview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 P.Thangadurai,S.Joicy,RosalinBeura,J.SanthoshKumar, andK.Chitrarasu 2 CarbonNanomaterialsinRenewableEnergyProduction andStorageApplications. . . .. . . .. . . .. . . .. . . .. . . .. . . .. . . .. 51 JoyitaBanerjee,KingshukDutta,andDipakRana 3 NanostructuredMaterialsforLi-IonBatteryApplications. . . . . . . 105 PushpendraKumar,PravinK.Dwivedi,PoonamYadav, andManjushaV.Shelke 4 NanomaterialsforCO Hydrogenation. . . . . . . . . . . . . . . . . . . . . . 173 2 ManuelRomero-Sáez,LeylaY.Jaramillo,WilsonHenao, andUnaidelaTorre 5 MetalOxideAdditivesIncorporatedHydrogenStorage Systems:FormationofInSituCatalystsandMechanistic Understanding. . . . . .. . . . .. . . . . .. . . . . .. . . . .. . . . . .. . . . . .. 215 D.Pukazhselvan,NarendarNasani,S.K.Singh, andDuncanPaulFagg 6 NanostructuredMetalOxidesforSupercapacitorApplications. . . . 247 KatlegoMakgopa,AbdulhakeemBello,KumarRaju, KwenaD.Modibane,andMpitloaneJ.Hato 7 Third-GenerationSolarCells:Concept,Materials andPerformance-AnOverview. . . . . . . . . . . . . . . . . . . . . . . . . . . 305 SoosaimanickamAnanthakumar,JeyagopalRamKumar, andSridharanMoorthyBabu ix x Contents 8 AnOverviewofCurrentTrendsinEmergenceof NanomaterialsforSustainableMicrobialFuelCells. . . . . . . . . . . . 341 GunaseelanKuppurangam,GajalakshmiSelvaraj, ThirumuruganRamasamy,VigneshVenkatasamy, andSathish-KumarKamaraj 9 FluorideToxicityandRecentAdvancesinWaterDefluoridation withSpecificEmphasisonNanotechnology. . . . . . . . . . . . . . . . . . . 395 KamyaParashar,KriveshiniPillay,RaghunathDas,andArjunMaity 10 Self-AssembledSoftMaterialsforEnergyandEnvironmental Applications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 443 AyyapillaiThamizhanban,KrishnamoorthyLalitha, andSubbiahNagarajan 11 ApplicationofNanoparticlesforSelf-CleaningSurfaces. . . . . . . . . 471 SivaramanSomasundaramandVigneshKumaravel 12 MetalandMetalOxide-BasedNanomaterialsfor ElectrochemicalApplications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 499 ChiranjitaGoswami,BhugendraChutia,andPankajBharali 13 NanobiotechnologyApproachfortheRemediation ofEnvironmentalHazardsGeneratedfromIndustrialWaste. . . . . 531 MounikaGudeppu,KrishnapriyaMadhuVarier, ArulvasuChinnasamy,SumathiThangarajan, JesudasBalasubramanian,YanmeiLi,andBabuGajendran Correctionto:NanobiotechnologyApproachfortheRemediation ofEnvironmentalHazardsGeneratedfromIndustrialWaste. . . . . . . . . C1 Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 563

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