Chemistry and Physics of Complex Materials: Concepts and Applications PDF
Preview Chemistry and Physics of Complex Materials: Concepts and Applications
Chemistry and Physics of Complex Materials WTR Concepts and Applications ya erszjk pTCChroohisnp epT••Tecb hhrr eomotiiopisspicfek soteusiib smcsp,raro utrra oaptiecsoenkronnoevsd riytsldp,dpTTCCl t eaiara hhoernocoApoannhsniittvssnpp tpde iina eotlecdrib bpio maencrceedomoplspta osoippoioitctpe mck okfitaPsiialos s rn:i spp,c cntct whrarhaiapsatoeoonnia tormntyhvointdpholiye fdydps stb n namme cerosisAperaosc oeoispho pmvkrn arseelft ep:i php n ccd cpllaaarsooieoroctdti mexmvi dfPvaoh sempaunep it ghpnrciCnslaeoehtcr ttyhsoexanleoei e fstgdsrasmi nemiho cnainmsanotdclit stmv se paoe.seco ttrfph hil mip olaeetooernhlmedexxs ef sso.iim me cfcMCna oatptlnht aooepacetrreri mittocopaaenocltnss neprto.,sc fiaslea reetpehsltxaesss , c Moofn acetpetsr, ialsWertejuk TyszkiewicRajkiewicztejukkiewiczCiewiczWertejukTyszkiewiczRajkiewicz This •i m peomrtpahnat s•b i ozeoisks : p ar ecocilsleec tmioant hoefm chaatipctael rds etvhealto phmighelnigt hatn sdo amcetu iaml peoxrptearnimt aernetaasl of z H • is a cdoeltleaciltsion ocfu crhreanptt einrste trheastt hinig pholilgyhmt esro pmroed imucptso ratnadn tc ahreemasic oafl processes E current inter• e stf oinc upsoelysm oner t opproicdsu wctisth a mndo rceh eamdviacnalc epdro mceestsheosds M C • analyzes theories to formulate and prove the physicochemical principles • focuses on t•o picesm wpihtahs mizoesre p ardecvaisnec meda mtheetmhoadtiscal development and actual experimentCal I H • e•m phparosvizidese sp arendc eiustpae-i tlmso-adtahteem aantdic athl odreovueglohp mexepnots aitniodn a ocftu tahle e pxpreesreimnte nsttaatl e of H S E the art of complex materials T M details • analyzes theories to formulate and prove the physicochemical principleEs R • a•n alyfazemsi ltihaer•i oz reiesps rt ohtvoei d froeersam dauenrl au wtpei-t tahon -nddea pwter o aavsnep det hctehts op rohofyu stghihceo ectxehpceohmsniiitcqiaouln ep sor fiun stcheiepd l peinrse tsheen t state ofM Y IS • proviedxeasm ainn autpio-ttnho e-od faa rtpteo oalyfnm dcoe tmrhsop, rlioenuxc glmuhd aeitnxepgrio acslhsiteiomni coafl ,t hpeh ypsriecsoe-ncth esmtaticea ol fa nd ISC a T the aprut roefl yc op• mh ypsflaiecmxa ilml imaarteieztrheisoa ldtshs eo rfe eaxdaemr winiathti onnew aspects of the techniques used in the To n R • fa• m ildtieaecrshicznreiisbc ietahsne t e ahrxeneaad mtd ydeipnirsea wcstu iiootshnfs etnoesefc wtphh onaelisiyqrpm ueceecasrtp ssna, oboifnwil cit talhiuevedas ti,ine lalcgibmh clneihti qeatomtui eotischn aesul ,,sc aephndhed myi nsaii scpthtop e-alc inchdae tmioincsa l and RYnc d P C Y a CHEMISTRY and PHYSICS examination of ppuorleylmy eprhsy, siinccallu mdientgh cohdesm oifc eaxl,a pmhiynsaitcioo-nchemical and e n • dpAeubsrecolruyibt p ethhsy ets hiE•ce d a tilyt dtmopeerceesshsct nhroiiofbcd ietasesn cot hafhn neeid xqt ayudpmeisesicsn nu aoostfwsi oet neascv thahinelaiiqrb ulceea stp ona bothwilei t aicevhase,i lmalibmisletit aatotni dothn es ,c ahnedm aisptp alincdaCon tionands pts HYS onc d P CHEMISTRY and PHYSICS teMcahrniiac iRaanj kainedw diciszc, uDsSsce,s itsh Heier acda poafb tihlieti eDsi,v ilsimiointa otifo nthse, aInnsdt iatputpeli cfoart ions ce P an IC epCHHoEfM CIOSTMRPYL aEnXd M PHATYESRICIAS LS AMEnbagoriuinwcEaatoenn eRtemdglhlar i-eipnakjnk poenEgiespoe diorwlwtiiiftencnio sacwAMEgP r,szt nobs eaio,paolgl orfylDenni-ui mnkcadPSsteni oeacRtnoeorlh,lraayf wi esiiM mjnsnnlkt o oE ga iHeiwsec dntropeeow i fmaMttremioh idccaPaorepi zlosaotl s,oeefl lf iyiDscare smiitunSlttahd eldecliae sns r,o rD . 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M R A Editors Zanbdig RoaInnlfiasse doCtwii hot RuWmeetmeese.erti tcraHeyarZaaej cllnubi snhWhdkio ga, Wa e RnRsPnaaia edephsrdswse DoieDaorn, av Wwemsirevs, ce deEe hPPrtl x otorarapeyplosnaej fmuidntrenhktds e D,eWsT.n oPeeHHtavra hreD eemsaD laeahot,d p wapati ush,smso t e PfPwywe oM rtnoeDlohartlifie lklner Di etaedsOaedcss.rpr toyHgaaour as re tINa nyn aaht AsiD nzatTrtaidehisOtrtsu eeiDw e otLcMeaointor orre ioncklfrcifogh etta ar-edCoT nrr trehyda h are os eImnDm fn adP is tir S strrhewieotctcerasuhit yeesoti nbe ar tirooticfiffhoic neCt hr h eae nmdi swtrayATEs IAL TER EMdaitroiras RZWabijkikgtioenwrieWM Tiwcyaizks rW,zti aoDke riSRe rcTatwyejksjicuziekzkw,i, e PPiwhchDziDc, zD,S PchD also SRteusdeya rncaht iaoInnndsa tlDi treuevtpeer.le oHspeemn hteaanstti vsDeee.rpvuedty aDsi rtehcet oHre aandd o Df itrheec tOorrg oafn itzhaet ion for the ProhibitionRI S IA Wiktor TyszkieZwbiigczn,i ePhwD Wertejuk, PhD Institute. He haos fs Cerhveemd iacsa lt hWee aHpeoands o Efx tpheer tO Trgeaamniz aast iowne lflo ars t hae N PArToOh iLboitniogn-T erm ScientificA LS Zbigniew Wertejuk, PhD of Chemical WeSatpuodnys n Eaxtpioenrat lT reeapmre saesn wtaetlilv aes. a NATO ILSoBnNg:- T9e7r8m-1 S-9c2ie6n8t9if5i-c6 0-4 L 90000 S Study national representative. ISBN: 978-1-926895-60-4 90000 ISBN: 978-1-926895-60-4 90000 9 781926 895604 9 781926 895604 9 781926 895604 www.appleacademicpress.com CHEMISTRY AND PHYSICS OF COMPLEX MATERIALS Concepts and Applications CHEMISTRY AND PHYSICS OF COMPLEX MATERIALS Concepts and Applications Edited by Maria Rajkiewicz, DSc, Wiktor Tyszkiewicz, PhD, and Zbigniew Wertejuk, PhD Apple Academic Press TORONTO NEW JERSEY CRC Press Apple Academic Press, Inc Taylor & Francis Group 3333 Mistwell Crescent 6000 Broken Sound Parkway NW, Suite 300 Oakville, ON L6L 0A2 Boca Raton, FL 33487-2742 Canada © 2014 by Apple Academic Press, Inc. Exclusive worldwide distribution by CRC Press an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20131120 International Standard Book Number-13: 978-1-4822-1830-5 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. Reason- able efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. 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Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com For information about Apple Academic Press product http://www.appleacademicpress.com ABOUT THE EDITORS Maria Rajkiewicz, DSc Professor Maria Rajkiewicz is Head of the Division of the Institute for Engineering of Polymer Materials and Dyes, in Warsaw, Poland. She is a well-known specialist in the field of synthesis, investigation of proper- ties and applications of low molecular compounds, oligomers, polymers, composites, and nanocomposites. She is a contributor or co-contributor to several monographs and the author of about 100 original papers. Wiktor Tyszkiewicz, PhD Wiktor Tyszkiewicz, PhD, is Professor at the Military Institute of Chem- istry and Radiometry in Warsaw, Poland. He has a long and varied career, including being a member of the Polish Delegation to ICCS in Vietnam; he has participated in many NATO workshops on environmental problems emanating from military installations and activities. He has headed the Biological Laboratory at the Military Institute of Chemistry and Radiom- etry, among many other roles. Zbigniew Wertejuk, PhD ZbigniewWertejuk, PhD, is Professor at the Military Institute of Chemis- try and Radiometry in Warsaw, Poland. He has worked as a researcher and was also Research and Development Deputy Director and Director of the Institute. He has served as the Head of the Organization for the Prohibition of Chemical Weapons Expert Team as well as a NATO Long-Term Scien- tific Study national representative. CONTENTS List of Contributors ....................................................................................ix List of Abbreviations ................................................................................xiii List of Symbols ...........................................................................................xv Preface ....................................................................................................xvii 1. Active Packaging Based on the Release of Carvacrol and Thymol for Fresh Food ...........................................................................................01 Marina Ramos, Ana Beltrán, Arancha Valdés, Mercedes A. Peltzer, Alfonso Jiménez, and María C. Garrigós 2. Vegetable Oils as Platform Chemicals for Synthesis of Thermoplastic Bio-Based Polyurethanes ..........................................................................23 C. Bueno-Ferrer, N. Burgos, and A. Jiménez 3. New Concept of Using Genetically Engineered Microbial Biosensors ..................................................................................................45 Anamika Singh and Rajeev Singh 4. Degradation and Stabilization of Fur and Leather ................................67 Elena Pekhtasheva and Gennady Zaikov 5. Research Notes and Developments in Materials Chemistry and Physics ................................................................................................93 A. K. Haghi 6. Quantum-Chemical Calculation in Chemical Reaction ......................173 V. A. Babkin, A. K. Haghi, and G. E. Zaikov 7. Energy of a Homolytic Cleavage of Communication OH in 4-Replaced 2,6-di-tert.Butylphenols ......................................................205 A. A. Volodkin, G. E. Zaikov, N. M. Evteeva, and S. M. Lomakin 8. Reaction of Ozone With Some Oxygen Containing Organic Compounds ..............................................................................................215 S. Rakovsky, M. Anachkov, and G. E. Zaikov 9. The Kinetics and Mechanism of the Selective Ethylbenzene Oxidation .................................................................................................263 L. I. Matienko, V. I. Binyukov, L. A. Mosolova, and G. E. Zaikov viii Contents 10. Composite Materials on the Basis of Epoxycontainig Organosilicon Compounds ..............................................................................................281 E. Markarashvili, T. Tatrishvili, N. Koiava, A. Berlin, G. Zaikov, and J. Aneli, and O. Mukbaniani 11. The Reactivity of Terpenephenols and Their Phenoxyl Radicals in Reactions of Oxidation ...........................................................................357 L. I. Mazaletskaya, N. I. Sheludchenko, L. B. Dudnik, and L. N. Shishkina 12. Reactions of Ozone With Hydrocarbons – Kinetics and Mechanism ...............................................................................................375 S. Rakovsky, M. Anachkov, V. Georgiev, M. Belitski, and G. Zaikov 13. Adaptogens Decrease the Generation of Reactive Oxygen Species by Mitochondria ......................................................................................465 V. Zhigacheva and E. B. Burlakova Index .........................................................................................................481 LIST OF CONTRIBUTORS M. Anachkov Institute of Catalysis, Bulgarian Academy of Sciences, “11 Acad. G. Bonchev” str., 1113 Sofia Bulgaria J. Aneli Iv. Javakhishvili Tbilisi State University, Institute of Macromolecular Chemistry and Polymeric Materials, I. Chavchavadze Ave., 13, Tbilisi 0179, Georgia, E-mail: [email protected] V. A. Babkin 403343 SF VolgSABU, c. Mikhailovka, Region Volgograd, Michurina 21, Russia. E-mail: sfi@reg. avtlg.ru M. Belitski Institute of Catalysis, Bulgarian Academy of Sciences, 11 Bonchev Str., 1113 Sofia, Bulgaria Ana Beltrán Analytical Chemistry, Nutrition and Food Sciences Department, University of Alicante, P.O. Box 99, 03080. Alicante, Spain A. Berlin N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 Kosygin str., Moscow 119991 Russia, email: [email protected] V. I. Binyukov N M Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, ul. Kosygina 4, 119334 Moscow, Russian Federation. Tel. (7-495) 939 71 40, Fax (7-495) 137 41 01 C. Bueno-Ferrer Analytical Chemistry, Nutrition and Food Sciences Department, University of Alicante, P.O. Box 99, E-03080, Alicante, Spain N. Burgos Analytical Chemistry, Nutrition and Food Sciences Department, University of Alicante, P.O. Box 99, E-03080, Alicante, Spain E. B. Burlakova Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences, Moscow, Russia L. B. Dudnik Emanuel Institute of Biochemical Physics of Russian Academy of Sciences, Moscow, Russia N. M. Evteeva Establishment of the Russian Academy of Sciences Institute of biochemical physics of N.M. Emanuelja, Kosygina, 4, 119991 Moscow, Russia, Fax: (095 1374101)
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