Catalysis. Volume 32

246 Pages·2020·12.502 MB·English

by  Han, Yi-Fan, Shekhawat, Dushyant, Spivey, James J

Catalysis
Volume 32
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A Specialist Periodical Report
Catalysis
Volume 32
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4 A Review of Recent Literature
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8 Editors
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10 Yi-Fan Han, East China University of Science and Technology,
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1 Shanghai, China
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d Dushyant Shekhawat, National Energy Technology Laboratory, USA
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p Weijian Diao, University of South Carolina, USA
ps:// Yanze Du, SINOPEC Dalian Research Institute of Petroleum and
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0 Anne M. Gaffney, University of South Carolina and Idaho National
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20 Laboratories, USA
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ar L. Hu, Institute of Chemical Research of Catalonia, Spain
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an Ben W.-L. Jang, Texas A&M University–Commerce, USA
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17 Deeksha Jain, The Ohio State University, USA
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o Ruifeng Li, Taiyuan University of Technology, China
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he Yang Liu, Dalian University of Technology, China
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bli Jingjun Lu, Taiyuan University of Technology, China
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P Michal Mazur, Charles University, Czech Republic
John R. Monnier, University of South Carolina, USA
Umit S. Ozkan, The Ohio State University, USA
Paraskevi Panagiotopoulou, Technical University of Crete, Greece
D. Pinto, Delft University of Technology, The Netherlands
Bo Qin, SINOPEC Dalian Research Institute of Petroleum and
Petrochemicals, China
Hengshan Qiu, Zhengzhou University, China
Daniel N. Rainer University of St Andrews, UK
,
John R. Regalbuto, University of South Carolina, USA
John Meynard M. Tengco, University of South Carolina, USA
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A. Urakawa, Delft University of Technology, The Netherlands and
Japan Science and Technology Agency, Japan
Xenophon E. Verykios, University of Patras, Greece
Huigang Wang, SINOPEC Dalian Research Institute of Petroleum and
Petrochemicals, China
Qianqian Wang, Taiyuan University of Technology, China
Xiaoliang Yan, Taiyuan University of Technology, China
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ISBN: 978-1-78801-774-9
PDF ISBN: 978-1-78801-947-7
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0 EPUB ISBN: 978-1-78801-948-4
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7 Print ISSN: 0140-0568
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1 Electronic ISSN: 1465-1920
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10 r The Royal Society of Chemistry 2020
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doi: All rights reserved
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sc. Apart from fair dealing for the purposes of research for non-commercial
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p Rights Regulations 2003, this publication may not be reproduced, stored or
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Whilst this material has been produced with all due care, The Royal Society
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Preface
DOI: 10.1039/9781788019477-FP007
InChapter1, P.Panagiotopoulou(TechnicalUniversityofCrete,Greece)
and X. E. Verykios (University of Patras, Greece) reviews recent reports
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0 onMetal–SupportinteractionsofRu-basedcatalystsunderconditionsof
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7-F CO and CO2 Hydrogenation. In this chapter, Several parameters about
7 metal–support interactions including the nature of both the metallic
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1 phase and the support, the morphology and size of metal particles, the
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8 oxidationstateofthemetal,aswellasthenatureandspecificconditions
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8 under which the reaction is taking place have been reviewed. Such
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9/ interactions give rise to electronic, geometric and bifunctional effects,
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10 whichstronglyinfluencethereactivityofreactantmoleculesinanumber
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1 of applications. Ruthenium particles dispersed on oxide supports is a
doi: well-known catalyst formulation for its capacity to undergo metal–
g | support interactions, a parameter that could be utilized to influence
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c. theactivityandselectivityofseveralcatalyticreactions,includingtheCO
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ubs.r and CO2 hydrogenation. Finally, the general subject of metal–support
ps://p irnestepreaccttitoons(ao)ccvuarriroinugs opvheyrsRicuocbhaesmediccaaltaalnysdtsoipsedriastcinugssepdarianmdeettearislwainthd
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on (b) their effect in hydrogenating both CO and CO2.
0 InChapter2,X.Yan,J.Lu,Q.Wang(TaiyuanUniversityofTechnology,
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2 China), Y. Du, B. Qin, H. Wang (SINOPEC Dalian Research Institute of
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ar Petroleum and Petrochemicals, China), R. Li (Taiyuan University of
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an Technology China), and Ben W.-L. Jang (Texas A&M University, USA)
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17 review the work on Ni Catalysts from Laboratory Investigations to
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o Chemical Industry. Heterogeneous Ni catalysts exhibit promising inter-
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he ests and applications in laboratory and industry. It is thus desirable for
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bli researcherstodiscoveranddesignefficientcatalystsfrombotheconomic
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andecologicalaspects.Inthischapter,theauthorsdiscussthemaximum
Ni utilization, such as single atom Nicatalysts and some novel methods
forsuperiormetalutilization,theimportanceofinterfacebetweenNiand
support, the effect of location between Ni and support on catalytic per-
formance,andtheindustrialapplicationandreuseoftheNicatalyst.The
illustration from this chapter would bridge the gap from academic
studies in laboratory to practical applications in industry not only for
catalysis field but also for environmental protection.
In Chapter 3, D. Jain and U. S. Ozkan (Ohio State University, USA) dis-
cuss electrocatalytic applications of heteroatom-doped carbon nanostruc-
tures.Thischapterhighlightstheimportanceofcarbonnanostructuresin
four emerging low temperature electrocatalytic technologies: (i) energy
storageintheformofunitizedregenerativefuelcellsandsecondaryzinc–
air batteries; (ii) electrochemical carbon dioxide reduction; (iii) halogen
production using oxygen depolarized cathodes and (iv) direct electro-
chemical hydrogen peroxide synthesis. Additionally, it summarizes the
challenges as well as the progress in the development of carbon-based
catalysts for these applications, understanding electrocatalytic reaction
Catalysis,2020,32,vii–ix | vii
(cid:2)c TheRoyalSocietyofChemistry2020
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mechanisms while gaining insights into the nature of catalytically active
sites which will be useful in a rational catalyst design.
In Chapter 4, Yang Liu (Dalian University of Technology, China)
reviews catalytic decomposition of gas-phase benzene with respect to
material design, reaction mechanism and future prospect. In this chap-
ter, benzene is taken as the target volatileorganic compound (VOC) and
focus on the development during the past twenty years, including prep-
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1 InChapter5,researchersfromUniversityofSouthCarolina,Columbia,
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8 USA(W.Diao;J.M.M.Tengco;A.M.Gaffney–alsofromIdahoNational
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8 Laboratories,USA;J.R.Regalbuto;andJ.R.Monnier)reviewtheconcepts
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9/ of electroless deposition (ED) methods for preparation of bimetallic
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10 catalysts where both metals are co-existent in the same particle in a
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1 relatively-controlled manner of preparation. The compositions of the
doi: bimetallicparticlescanbevariedinasystematicmannerbychangingthe
org | amount and rate of second metal deposited on the base metal. Higher
c. coveragesofthesecondmetalresultinformationofcore–shellbimetallic
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bs.r particles that give more efficient use of the shell metal component and
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p parametersmakeitpossibletoconductEDoveraverywidecombination
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n of metals and metal salts. Continuous ED can be extended to co-
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2 uniform, bimetallic shells that provide the possibility of surface alloys
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a InChapter6,D.N.Rainer(UniversityofStAndrews,UK)andM.Mazur
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17 (Charles University, Czech Republic) provide an overview focused on
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o electron microscopy and related characterization techniques as well as
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he their utilization in the fields of design, synthesis, and formation of
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bli crystals, characterization, and performance of zeolites as heterogeneous
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catalysts. Scanning electron microscopy and atomic force microscopy
describe the morphology and surface of crystals of zeolite catalysts.
Transmission electron microscopy, including scanning mode (STEM),
supported by electron diffraction methods can give crucial information
about structure, especially when conventional methods are limited for
thefulldescriptionofsolidcatalysts,likezeolites.Oftenthosetechniques
are supported by energy-dispersive X-ray spectroscopy for the elemental
analysis of the samples.
In Chapter 7, H. Qiu (Zhengzhou University, China) discusses the
concepts of catalysis and surface science and the several promising
aspects of surface science studies related to heterogeneous catalysis.
Emphasis is given to the microscopic view on catalytic reactions, struc-
tural and electronic requirement of a catalyst, the surface science
approaching to explore mechanism of heterogeneous catalytic reactions
occurringonsurface,subsurfaceandsupportedmetalnanoparticles,and
the development of operando surface science techniques.
In Chapter 8, L. Hu (Institute of Chemical Research of Catalonia,
Spain), D. Pinto (Delft University of Technology, The Netherlands), and
viii | Catalysis,2020,32,vii–ix
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A. Urakawa (Japan Science and Technology Agency) review oxidative
couplingofmethane(OCM)toproduceethaneandethylene.Despitethe
extensive efforts over the last three decades, our general understanding
on OCM is rather poor due to the complexity arising from the reaction
network, and also from the various gradients such as temperature and
gaseous concentration present in OCM reactors. This chapter highlights
reactions active under OCM conditions and how they are interlinked.
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8 James J. Spivey, Louisiana State University, Baton Rouge, USA
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Catalysis,2020,32,vii–ix | ix
Editor biographies
DOI: 10.1039/9781788019477-FP010
JamesSpiveyisShiversProfessorofChemical
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1 Engineering at Louisiana State University,
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F USA. He is past Director of the Center for
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47 Atomic-levelCatalystDesign,andisFellowof
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01 the Royal Society of Chemistry. His research
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u Prof. Dr Yi-Fan Han received his PhD from
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o interested in heterogenous catalysts, espe-
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02 cially revealing the origin of dynamic active
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y sites using Operando spectroscopies. He has
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7 J fessional journals J. Am. Chem. Soc., Angew.
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Dr Dushyant Shekhawat is serving as a team
supervisor for Reaction Engineering team at
NationalEnergytechnology(U.S.Department
of Energy), Morgantown, USA. His research
interests include fuel processing for fuel cell
applications, reaction engineering, hetero-
geneous catalysis, energy, plasma and micro-
wave-assisted catalytic reactions. He has
published over 200 peer-reviewed journal
publications, conference proceedings, and
reports,sevenbook chapters, two books,and
16patents(disclosedorfull).Heisaregistered
Professional Engineer (PE) in West Virginia
and also serves in the NCEES’s PE Chemical Engineering Examination
Developmentcommittee.
x | Catalysis,2020,32,x
(cid:2)c TheRoyalSocietyofChemistry2020