EFFECT OF SIZE DISTRIBUTION AND WATER CONTENT ON PROPERTIES OF IRON ORE PELLETS A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENT FOR THE DEGREE OF Bachelor of Technology in Metallurgical and Materials Engineering BY MAHESH GOENKA (109MM0440) ABHISHEK NAIK (109MM0450) Under the guidance of DR. SMARAJIT SARKAR Department of Metallurgical and Materials Engineering National Institute of Technology Rourkela 2013 NATIONAL INSTITUTE OF TECHNOLOGY ROURKELA CERTIFICATE This is to certify that the thesis entitled “EFFECT OF FINE SIZE AND WATER CONTENT ON PROPERTIES OF IRON ORE PELLETS” submitted by Abhishek Naik (109MM0450) and Mahesh Goenka (109MM0440) in partial fulfilment of the requirements for the award of Bachelor of Technology Degree in Metallurgical and Materials Engineering at National Institute of Technology, Rourkela is an original work carried out by them under my supervision and guidance. The matter embodied in the thesis has not been submitted to any other University/ Institute for the award of any degree. Date: Prof. Smarajit Sarkar, Dept. of Metallurgical & Materials Engineering, National Institute of Technology, Rourkela-769008 1 ACKNOWLEDGEMENT We express our sincere gratitude to the Department of Metallurgical and Materials Engineering, NIT Rourkela for giving us an opportunity to work on this project and allowing us access to valuable facilities in the department. We avail this opportunity to express our indebtedness to our guide Dr. Smarajit Sarkar, Associate Professor, Department of Metallurgical and Materials Engineering, NIT Rourkela, for his valuable guidance, constant encouragement and kind help at various stages for the execution of this dissertation work. We would like to convey our heartfelt gratitude to Mr. Chandra Shekhar Dey to whom we are indebted for his relentless support and timely guidance during our project work. We are also grateful to Mr. Bhanja Naik, Department of Metallurgical and Materials Engineering, NIT Rourkela for providing valuable assistance and insight during the experimental process. Date: 9th May, 2013 Mahesh Goenka (109MM0440) Abhishek Naik (109MM0450) Department of Metallurgical and Materials Engineering, National Institute of Technology, Rourkela Rourkela-769008 2 ABSTRACT Iron ore fines are converted to iron by the following route: Fines Pellets Reduction to metallic Fe Therefore, the process of formation of pellets has to ensure that its product has required properties to perform as desired during the stage of reduction. This thesis, and the work done as recorded, aims at identifying the optimum values of properties of the chief raw materials of pelletization: iron ore fines and water (moisture) so that the prepared pellets exhibit maximum productivity. The size distribution and water content of the pellets need to be studied and correlated to such pellet properties as strength, percentage reduction and swelling during reduction to obtain relationships between these factors. These results can be used for adopting the most suitable values of process parameters in industrial pelletization. Keywords: Size distribution, Water Content, Green Strength, Swelling, Reduction Behaviour 3 TABLE OF CONTENTS Index Content Page Bonafide Certificate 1 Acknowledgement 2 Abstract 3 List of Tables 6 List of Tables 7 Chapter 1: Introduction 8 – 13 1.1 Introduction to Pelletizing 1.2 Definition of Pelletization 1.3 Pelletization: Advantages 1.4 Challenges faced by Pelletization Process 1.5 Stages of Pelletizing Chapter 2: Literature Review 14 – 20 2.1 Mechanism Of Green Ball Formation 2.2 Drop Number 2.3 Parameters affecting reduction behaviour of pellets 2.4 Swelling of Pellets during Reduction Chapter 3: Experimental Procedure 21 – 25 3.1 Sample Preparation: 3.1.1 For Green Strength Measurement 3.1.2 For Study of Reduction 3.2 Testing: 3.2.1 Green Strength Measurement: Drop Number 4 3.2.2 Reduction Behaviour: Swelling and Percentage Reduction Chapter 4: Results 26 – 39 4.1 Results: Drop Test 4.2 Results: Percentage Reduction 4.3 Results: Swelling 5.1 Chapter 5: Conclusion 40 – 41 References 42 5 LIST OF TABLES Sl. No. Name of Table Page Table 4.1 Drop number of samples for green strength measurement Table 4.2 Weight loss upon Reduction of Pellets of 13% water content Table 4.3 Weight loss upon Reduction of Pellets of 15% water content Table 4.4 Increase in diameter upon reduction for 13% water content Table 4.5 Increase in diameter upon reduction for 15% water content 6 LIST OF FIGURES: Sl. No. Name of Figure Page Fig. 2.1 Influence of water addition on green ball formation Fig. 2.2 Influence of capillary forces on bonding mechanisms Fig. 2.3 Alternatives for green pellet formation Fig.4.1 Sample of 15% Water Content, 90% 350 mesh size pellet Fig. 4.2 Drop Number vs. Water Content for 100% 350 mesh size Fig. 4.3 Drop Number vs. Water Content for 90% 350 mesh size Fig. 4.4 Drop Number vs. Water Content for 80% 350 mesh size Fig. 4.5 Drop Number vs. Water Content for 70% 350 mesh size Fig.4.6 Drop Number vs. % 350 mesh size Fig.4.7 Percentage Reduction vs. % of 350 mesh size Fig.4.8 %increase in diameter vs. % of 350 mesh size 7 CHAPTER – I INTRODUCTION 8 1.1 Introduction to Pelletizing India is one of the leading producers of steel, currently ranked 4th in the world with a production of 76.7 mtpa. Annual production of steel In India is expected to reach close to 200 million tonnes mark by the year 2020 making India world’s second largest steel producer. India has about 28.5 billion tonnes of Iron ore reserves. However, almost 60% of the ore that is mined is in the form of fines of low iron content. These iron ore fines cannot be directly used in the blast furnace as they pose the following threats: 1. Iron ore fines severely reduced the permeability of the bed, jeopardizing the reduction reaction in the blast furnace 2. The fines leave the blast furnace in combination with the flue (top) gas, bringing down the efficiency of the furnace. With the projected steel production, requirement of iron ore is expected to be around 350 to 400 million tonnes per year. This makes it imperial for the steel industry in the country, and even worldwide, to utilize the iron ore fines. Agglomeration processes are used for this purpose. The major agglomeration processes for iron ore fines are pelletisation and sintering. The two processes complement each other as they utilise fines of different size ranges. Other lesser-known agglomeration processes include stamping, briquetting, etc. However, these processes have more or less been outdated due to the low efficiency and lack of economic viability. With the fast-growing pellet industry and increasing use of iron ore pellets in the charge for ironmaking, pelletisation of iron ore fines has turned out to be an important area of metallurgical studies. Pellets now form a substantial part of the charge in blast furnaces and may be as high as 30% in some cases. It has already been used in secondary ironmaking processes with 100% pellet charging. Countries like South Korea and Japan have successfully reported 9