Green Energy and Technology Avinash Kumar Agarwal Rashmi Avinash Agarwal Tarun Gupta Bhola Ram Gurjar Editors Biofuels Technology, Challenges and Prospects Green Energy and Technology More information about this series at http://www.springer.com/series/8059 Avinash Kumar Agarwal Rashmi Avinash Agarwal Tarun Gupta Bhola Ram Gurjar Editors Biofuels Technology, Challenges and Prospects 123 Editors Avinash KumarAgarwal Tarun Gupta Department ofMechanical Engineering Department ofCivil Engineering Indian Institute of Technology Kanpur Indian Institute of Technology Kanpur Kanpur,Uttar Pradesh Kanpur,Uttar Pradesh India India Rashmi Avinash Agarwal BholaRamGurjar Department ofChemistry Department ofCivil Engineering, Centre Indian Institute of Technology Kanpur forTransportation Systems (CTRANS) Kanpur,Uttar Pradesh Indian Institute of Technology Roorkee India Roorkee,Uttarakhand India ISSN 1865-3529 ISSN 1865-3537 (electronic) Green Energy andTechnology ISBN978-981-10-3790-0 ISBN978-981-10-3791-7 (eBook) DOI 10.1007/978-981-10-3791-7 LibraryofCongressControlNumber:2017930135 ©SpringerNatureSingaporePteLtd.2017 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpart of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission orinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped. 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Theregisteredcompanyaddressis:152BeachRoad,#21-01/04GatewayEast,Singapore189721,Singapore Preface Currentenergyscenarioclearlysuggeststhatoilandgasreservesarefiniteandwill last only few more decades. Therefore, massive research efforts are underway globally for developing energy from resources with lower carbon footprint for sustainable development and environmental protection. In order to ensure energy security and to reduce impact of global and local pollution from fossil fuels, utilizationofbiofuelshasbeenadoptedasanimmediatesolution.Biofuelsplayan important role in the future scientific research portfolio, which will affect energy independence and energy security, revitalize rural infrastructure and shift energy landscapeofthetwenty-firstcenturytowardsgreatersustainabilityandtowardslow carbon-intensity. Discussing multidisciplinary research dimensions of bioenergy and its potential for replacing fossil fuels in coming decades, this monograph provides a roadmap for understanding broad sweep of technological, sociological, and energy policy issues that intermingle and intertwine. Biotechnology and especiallysyntheticbiologycanplayakeyroleinpromotingsustainableproduction anduseofbioenergythroughdevelopmentofnext-generationbiofuelsfromlocally available biomass feedstocks using advanced sunlight-to-biomass-to-bioenergy conversion processes. Socio-economic and environmental challenges need to be duly considered while designing these technological solutions. This monograph covers such advanced techniques for efficient production of biofuels from locally availablerawbiomaterialsandtheirutilizationinICenginesandpowergenerating equipment. An international workshop, 3rd ISEES Workshop on “Sustainable Energy, Environment&SafetywithRailwayCentricTheme”,washeldatResearchDesigns and Standards Organisation (RDSO), Lucknow, India from December 21 to 23, 2015 under the aegis of International Society for Energy, Environment and Sustainability(ISEES).Thisworkshopprovidedaplatformfordiscussionsbetween eminent scientists and engineers from various countries including India, USA, South Korea, Thailand, and Austria. In this workshop, eminent speakers presented their views related to different aspects of biofuels, and alternative energy resource for sustainable development and cleaner environment. This research monograph is based on the topics covered at the workshop, and brings together a wealth v vi Preface of knowledge from renowned experts on the latest developments in selected technology domains with a focus on fundamentals, applications, and advanced teaching pedagogy. Main areas covered in this monograph are biofuels and their advantages,advancedbiofuelproductiontechniquesandtheirutilizationinvarious sectorssuchastransportationandpowergeneration.Thismonographalsoincludes methodologies of increasing biofuel yield from different resources. Research on using biofuel blended with conventional fossil fuels for power generation is also presented. In addition, novel technology developments in biofuel production from microalgae are also discussed. The editors would like to express their sincere gratitude to the authors for submitting their work in a timely manner and revising it appropriately at a short notice. We would like express our special thanks to Dr. Bhaskar Thallada, Dr. S. Venkata Mohan, Prof. Ashok Pandey, Prof. Atul Dhar, Prof. Santanu De, Prof. V.S. Moholkar, Prof. Dhananjay Srivastava, and Akhilendra Pratap Singh, who reviewed various chapters of this monograph and provided their valuable sugges- tionstoimprovethedraftmanuscripts.Weacknowledgethesupportreceivedfrom variousfundingagenciesandorganizationsforthesuccessfulconductoftheISEES workshop, where these monographs germinated. These include Science and EngineeringResearchBoard,DepartmentofScienceandTechnology,Government ofIndia(SpecialthankstoDr.SanjayBajpai);RITESLtd,India(Specialthanksto Sh.PradeepGupta);OfficeofNavalResearchGlobal,Singapore(Specialthanksto Dr. Ramesh Kolar); TSI, India (Special thanks to Dr. Deepak Sharma); Caterpiller India;AVLIndia;DynomerkControls,India(SpecialthankstoSh.KishoreRaut); CEI Softwares, India; ESi Group, Pune; BHEL India; and Bosch India. This monograph is intended for researchers, practitioners of engineering and technology, and we hope that the monograph would be of great interest to the professionals involved in biofuels as well as students, government officials, deci- sionmakers,policymakers,andcivilsocietyorganizationsinterestedinrenewable energy and more specifically to those working in biofuelproduction, optimization, and their utilization in IC engines. Its objective is to promote a better and more accurate understanding of the nature, production, challenges, technological status, andusageofbiofuels fromvegetable oilsandalgae andtoprovideanupdatedand reliable reference and guidebook on biofuels. Kanpur, India Avinash Kumar Agarwal Kanpur, India Rashmi Avinash Agarwal Kanpur, India Tarun Gupta Roorkee, India Bhola Ram Gurjar Contents Part I General Introduction to Biofuels . .... ..... .... .... .... .... .... ..... .... 3 Avinash Kumar Agarwal, Rashmi Avinash Agarwal, Tarun Gupta and Bhola Ram Gurjar Sustainable Production of Chemicals and Energy Fuel Precursors from Lignocellulosic Fractions..... .... .... .... .... .... ..... .... 7 Bhumica Agarwal, Vivek Ahluwalia, Ashok Pandey, Rajender Singh Sangwan and Sasikumar Elumalai Microbial Electrochemical Platform: Biofactory with Diverse Applications... .... .... .... ..... .... .... .... .... .... ..... .... 35 S. Venkata Mohan, G. Velvizhi and P. Chiranjeevi Biomass-Derived HMF Oxidation with Various Oxidants ... ..... .... 51 S. Saravanamurugan, Ashok Pandey and Rajender Singh Sangwan Hydrothermal Liquefaction of Lignocellulosic Biomass Components: Effect of Alkaline Catalyst. .... .... .... .... ..... .... 69 Rawel Singh, Bhavya B. Krishna and Thallada Bhaskar Pretreatment Strategies of Lignocellulosic Biomass Towards Ethanol Yield: Case Study of Pine Needles... .... ..... .... 85 Sangeeta Negi Ultrasound-Assisted Biodiesel Synthesis: A Mechanistic Insight ... .... 103 Ritesh S. Malani, Arun Goyal and Vijayanand S. Moholkar Thermo-Chemical Ethanol Production from Agricultural Waste Through Polygeneration: Performance Assessment Through a Case Study .. .... ..... .... .... .... .... .... ..... .... 137 Kuntal Jana and Sudipta De vii viii Contents Microalgae Based Biofuel: Challenges and Opportunities ... ..... .... 157 Richa Katiyar, Amit Kumar and B.R. Gurjar Surrogates for Biodiesel: Review and Challenges.. .... .... ..... .... 177 Aditya Dilip Lele, Krishnasamy Anand and Krithika Narayanaswamy Response Surface Methodology Based Multi-objective Optimization of the Performance-Emission Profile of a CI Engine Running on Ethanol in Blends with Diesel .. ..... .... 201 Probir Kumar Bose, Vijay Narayan Bodkhe, Bishop Deb Barma and Rahul Banerjee Effect of Alcohol Blending on Performance of Kerosene Fuelled Four-Stroke Spark Ignition Genset .. .... .... .... ..... .... 229 Mritunjay Shukla, Eshan Singh and Sunil Pathak About the Editors Prof.AvinashKumarAgarwal joinedIITKanpurin 2001. He worked at ERC, University of Wisconsin, Madison,USAasapostdoctoral Fellow(1999–2001). His areas of interest include IC engines, combustion, alternative fuels, hydrogen, conventional fuels, lubri- cating oil tribology, optical diagnostics, laser ignition, HCCI, emission and particulate control, and large bore engines. He has published more than 200 peer-reviewed international journal and confer- encepapers.HeisassociateeditorofASMEJournalof Energy Resources Technology, and International JournalofVehicleSystemsModellingandTesting.He has edited “Handbook of Combustion” (5 Volumes; 3168 pages), published by Wiley VCH, Germany. He is a Fellow of SAE (2012), Fellow of ASME (2013) and a Fellow of INAE (2015). He is the recipient of prestigious Shanti Swarup Bhatnagar Prize-2016 in Engineering Sciences. Dr. Rashmi Avinash Agarwal is a senior researcher at IIT Kanpur. She completed her doctoral degree in Inorganic Chemistry from IIT Kanpur in 2014. She completed her M.Sc. in Organic Chemistry from Rajasthan University, Jaipur in 2002 and B.Sc. in Chemistry, from Kanoria College, Rajasthan University, Jaipur in 2000. She has expertise in coor- dination chemistry, coordination polymers, organic synthesis, inorganic synthesis, crystal structure deter- mination, supramolecular chemistry, porous materials, topology, florescence, SC (single crystal)-to-SC ix
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