Asphaltenes: chemical transformation during hydroprocessing of heavy oils

441 Pages·2009·14.054 MB·English

by  Ancheyta Juárez, Jorge, Rana, Mohan Singh, Trejo, Fernando

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Asphaltenes
Chemical Transformation during
Hydroprocessing of Heavy Oils
66307_Book.indb 1 11/20/09 12:51:22 PM
CHEMICAL INDUSTRIES
ASeries of Reference Books and Textbooks
Founding Editor
HEINZ HEINEMANN
Berkeley, California
Series Editor
JAMES G. SPEIGHT
University of Trinidad and Tobago
O'Meara Campus, Trinidad
1. Fluid Catalytic Cracking with Zeolite Catalysts,Paul B. Venuto
and E. Thomas Habib, Jr.
2. Ethylene: Keystone to the Petrochemical Industry,Ludwig
Kniel, Olaf Winter, and Karl Stork
3. The Chemistry and Technology of Petroleum,
James G. Speight
4. The Desulfurization of Heavy Oils and Residua,
James G. Speight
5. Catalysis of Organic Reactions,edited by William R. Moser
6. Acetylene-Based Chemicals from Coal and Other Natural
Resources,Robert J. Tedeschi
7. Chemically Resistant Masonry,Walter Lee Sheppard, Jr.
8. Compressors and Expanders: Selection and Application
for the Process Industry,Heinz P. Bloch, Joseph A. Cameron,
Frank M. Danowski, Jr., Ralph James, Jr.,
Judson S. Swearingen, and Marilyn E. Weightman
9. Metering Pumps: Selection and Application,James P. Poynton
10. Hydrocarbons from Methanol,Clarence D. Chang
11. Form Flotation: Theory and Applications,Ann N. Clarke
and David J. Wilson
12. The Chemistry and Technology of Coal,James G. Speight
13. Pneumatic and Hydraulic Conveying of Solids,O. A. Williams
66307_Book.indb 2 11/20/09 12:51:22 PM
14. Catalyst Manufacture: Laboratory and Commercial
Preparations,Alvin B. Stiles
15. Characterization of Heterogeneous Catalysts,edited by
Francis Delannay
16. BASIC Programs for Chemical Engineering Design,
James H. Weber
17. Catalyst Poisoning,L. Louis Hegedus and Robert W. McCabe
18. Catalysis of Organic Reactions,edited by John R. Kosak
19. Adsorption Technology: A Step-by-Step Approach to Process
Evaluation and Application,edited by Frank L. Slejko
20. Deactivation and Poisoning of Catalysts,edited by
Jacques Oudar and Henry Wise
21. Catalysis and Surface Science: Developments in Chemicals
from Methanol, Hydrotreating of Hydrocarbons, Catalyst
Preparation, Monomers and Polymers, Photocatalysis
and Photovoltaics,edited by Heinz Heinemann
and Gabor A. Somorjai
22. Catalysis of Organic Reactions,edited by Robert L. Augustine
23. Modern Control Techniques for the Processing Industries,
T. H. Tsai, J. W. Lane, and C. S. Lin
24. Temperature-Programmed Reduction for Solid Materials
Characterization, Alan Jones and Brian McNichol
25. Catalytic Cracking: Catalysts, Chemistry, and Kinetics,
Bohdan W. Wojciechowski and Avelino Corma
26. Chemical Reaction and Reactor Engineering,edited by
J. J. Carberry and A. Varma
27. Filtration: Principles and Practices: Second Edition,edited by
Michael J. Matteson and Clyde Orr
28. Corrosion Mechanisms,edited by Florian Mansfeld
29. Catalysis and Surface Properties of Liquid Metals and Alloys,
Yoshisada Ogino
30. Catalyst Deactivation,edited by Eugene E. Petersen
and Alexis T. Bell
31. Hydrogen Effects in Catalysis: Fundamentals and Practical
Applications, edited by Zoltán Paál and P. G. Menon
32. Flow Management for Engineers and Scientists,
Nicholas P. Cheremisinoff and Paul N. Cheremisinoff
33. Catalysis of Organic Reactions,edited by Paul N. Rylander,
Harold Greenfield, and Robert L. Augustine
34. Powder and Bulk Solids Handling Processes: Instrumentation
and Control, Koichi Iinoya, Hiroaki Masuda,
and Kinnosuke Watanabe
35. Reverse Osmosis Technology: Applications for High-Purity-
Water Production,edited by Bipin S. Parekh
36. Shape Selective Catalysis in Industrial Applications,
N. Y. Chen, William E. Garwood, and Frank G. Dwyer
66307_Book.indb 3 11/20/09 12:51:23 PM
37. Alpha Olefins Applications Handbook,edited by
George R. Lappin and Joseph L. Sauer
38. Process Modeling and Control in Chemical Industries,
edited by Kaddour Najim
39. Clathrate Hydrates of Natural Gases,E. Dendy Sloan, Jr.
40. Catalysis of Organic Reactions,edited by Dale W. Blackburn
41. Fuel Science and Technology Handbook,edited by
James G. Speight
42. Octane-Enhancing Zeolitic FCC Catalysts,Julius Scherzer
43. Oxygen in Catalysis, Adam Bielanski and Jerzy Haber
44. The Chemistry and Technology of Petroleum: Second Edition,
Revised and Expanded,James G. Speight
45. Industrial Drying Equipment: Selection and Application,
C. M. van’t Land
46. Novel Production Methods for Ethylene, Light Hydrocarbons,
and Aromatics, edited by Lyle F. Albright, Billy L. Crynes,
and Siegfried Nowak
47. Catalysis of Organic Reactions, edited by William E. Pascoe
48. Synthetic Lubricants and High-Performance Functional Fluids,
edited by Ronald L. Shubkin
49. Acetic Acid and Its Derivatives, edited by Victor H. Agreda
and Joseph R. Zoeller
50. Properties and Applications of Perovskite-Type Oxides,
edited by L. G. Tejuca and J. L. G. Fierro
51. Computer-Aided Design of Catalysts, edited by E. Robert
Becker and Carmo J. Pereira
52. Models for Thermodynamic and Phase Equilibria Calculations,
edited by Stanley I. Sandler
53. Catalysis of Organic Reactions, edited by John R. Kosak
and Thomas A. Johnson
54. Composition and Analysis of Heavy Petroleum Fractions,
Klaus H. Altgelt and Mieczyslaw M. Boduszynski
55. NMR Techniques in Catalysis, edited by Alexis T. Bell
and Alexander Pines
56. Upgrading Petroleum Residues and Heavy Oils,
Murray R. Gray
57. Methanol Production and Use, edited by Wu-Hsun Cheng
and Harold H. Kung
58. Catalytic Hydroprocessing of Petroleum and Distillates,
edited by Michael C. Oballah and Stuart S. Shih
59. The Chemistry and Technology of Coal: Second Edition,
Revised and Expanded,James G. Speight
60. Lubricant Base Oil and Wax Processing, Avilino Sequeira, Jr.
61. Catalytic Naphtha Reforming: Science and Technology,
edited by George J. Antos, Abdullah M. Aitani,
and José M. Parera
66307_Book.indb 4 11/20/09 12:51:23 PM
62. Catalysis of Organic Reactions, edited by Mike G. Scaros
and Michael L. Prunier
63. Catalyst Manufacture,Alvin B. Stiles and Theodore A. Koch
64. Handbook of Grignard Reagents, edited by Gary S. Silverman
and Philip E. Rakita
65. Shape Selective Catalysis in Industrial Applications:
Second Edition, Revised and Expanded, N. Y. Chen,
William E. Garwood, and Francis G. Dwyer
66. Hydrocracking Science and Technology, Julius Scherzer
and A. J. Gruia
67. Hydrotreating Technology for Pollution Control: Catalysts,
Catalysis, and Processes, edited by Mario L. Occelli
and Russell Chianelli
68. Catalysis of Organic Reactions, edited by Russell E. Malz, Jr.
69. Synthesis of Porous Materials: Zeolites, Clays,
and Nanostructures, edited by Mario L. Occelli
and Henri Kessler
70. Methane and Its Derivatives, Sunggyu Lee
71. Structured Catalysts and Reactors, edited by Andrzej Cybulski
and Jacob A. Moulijn
72. Industrial Gases in Petrochemical Processing,
Harold Gunardson
73. Clathrate Hydrates of Natural Gases: Second Edition,
Revised and Expanded, E. Dendy Sloan, Jr.
74. Fluid Cracking Catalysts, edited by Mario L. Occelli
and Paul O’Connor
75. Catalysis of Organic Reactions, edited by Frank E. Herkes
76. The Chemistry and Technology of Petroleum: Third Edition,
Revised andExpanded, James G. Speight
77. Synthetic Lubricants and High-Performance Functional Fluids:
Second Edition, Revised and Expanded, Leslie R. Rudnick
and Ronald L. Shubkin
78. The Desulfurization of Heavy Oils and Residua,
Second Edition,Revised and Expanded, James G. Speight
79. Reaction Kinetics and Reactor Design: Second Edition,
Revised and Expanded, John B. Butt
80. Regulatory Chemicals Handbook, Jennifer M. Spero,
Bella Devito, and Louis Theodore
81. Applied Parameter Estimation for Chemical Engineers,
Peter Englezos and Nicolas Kalogerakis
82. Catalysis of Organic Reactions,edited by Michael E. Ford
83. The Chemical Process Industries Infrastructure: Function
and Economics, James R. Couper, O. Thomas Beasley,
and W. Roy Penney
84. Transport Phenomena Fundamentals, Joel L. Plawsky
66307_Book.indb 5 11/20/09 12:51:23 PM
85. Petroleum Refining Processes, James G. Speight
and Baki Özüm
86. Health, Safety, and Accident Management in the Chemical
ProcessIndustries, Ann Marie Flynn and Louis Theodore
87. Plantwide Dynamic Simulators in Chemical Processing
and Control, William L. Luyben
88. Chemical Reactor Design, Peter Harriott
89. Catalysis of Organic Reactions, edited by Dennis G. Morrell
90. Lubricant Additives: Chemistry and Applications, edited by
Leslie R. Rudnick
91. Handbook of Fluidization and Fluid-Particle Systems,
edited by Wen-Ching Yang
92. Conservation Equations and Modeling of Chemical
and Biochemical Processes, Said S. E. H. Elnashaie
and Parag Garhyan
93. Batch Fermentation: Modeling,Monitoring, and Control,
Ali Çinar, Gülnur Birol, Satish J. Parulekar, and Cenk Ündey
94. Industrial Solvents Handbook,Second Edition,
Nicholas P. Cheremisinoff
95. Petroleum and Gas Field Processing, H. K. Abdel-Aal,
Mohamed Aggour, and M. Fahim
96. Chemical Process Engineering: Design and Economics,
Harry Silla
97. Process Engineering Economics, James R. Couper
98. Re-Engineering the Chemical Processing Plant: Process
Intensification, edited by Andrzej Stankiewicz
and Jacob A. Moulijn
99. Thermodynamic Cycles: Computer-Aided Design
and Optimization, Chih Wu
100. Catalytic Naphtha Reforming: Second Edition,
Revised and Expanded, edited by George T. Antos
and Abdullah M. Aitani
101. Handbook of MTBE and Other Gasoline Oxygenates,
edited by S. Halim Hamid and Mohammad Ashraf Ali
102. Industrial Chemical Cresols and Downstream Derivatives,
Asim Kumar Mukhopadhyay
103. Polymer Processing Instabilities: Control and Understanding,
edited by Savvas Hatzikiriakos and Kalman B. Migler
104. Catalysis of Organic Reactions, John Sowa
105. Gasification Technologies: A Primer for Engineers
and Scientists, edited by John Rezaiyan
and Nicholas P. Cheremisinoff
106. Batch Processes, edited by Ekaterini Korovessi
and Andreas A. Linninger
107. Introduction to Process Control, Jose A. Romagnoli
and Ahmet Palazoglu
66307_Book.indb 6 11/20/09 12:51:23 PM
108. Metal Oxides: Chemistry and Applications, edited by
J. L. G. Fierro
109. Molecular Modeling in Heavy Hydrocarbon Conversions,
Michael T. Klein, Ralph J. Bertolacini, Linda J. Broadbelt,
Ankush Kumar and Gang Hou
110. Structured Catalysts and Reactors, Second Edition, edited by
Andrzej Cybulski and Jacob A. Moulijn
111. Synthetics, Mineral Oils, and Bio-Based Lubricants: Chemistry
and Technology, edited by Leslie R. Rudnick
112. Alcoholic Fuels, edited by Shelley Minteer
113. Bubbles, Drops, and Particles in Non-Newtonian Fluids,
Second Edition, R. P. Chhabra
114. The Chemistry and Technology of Petroleum, Fourth Edition,
James G. Speight
115. Catalysis of Organic Reactions, edited by Stephen R. Schmidt
116. Process Chemistry of Lubricant Base Stocks,
Thomas R. Lynch
117. Hydroprocessing of Heavy Oils and Residua, edited by
James G. Speight and Jorge Ancheyta
118. Chemical Process Performance Evaluation, Ali Cinar,
Ahmet Palazoglu, and Ferhan Kayihan
119. Clathrate Hydrates of Natural Gases, Third Edition,
E. Dendy Sloan and Carolyn Koh
120. Interfacial Properties of Petroleum Products, Lilianna Z. Pillon
121. Process Chemistry of Petroleum Macromolecules,
Irwin A. Wiehe
122. The Scientist or Engineer as an Expert Witness,
James G. Speight
123. Catalysis of Organic Reactions, edited by Michael L. Prunier
124. Lubricant Additives: Chemistry and Applications, Second
Edition, edited by Leslie R. Rudnick
125. Chemical Reaction Engineering and Reactor Technology,
Tapio O. Salmi, Jyri-Pekka Mikkola, and Johan P. Warna
126. Asphaltenes: Chemical Transformation during
Hydroprocessing of Heavy Oils, Jorge Ancheyta,
Fernando Trejo, and Mohan Singh Rana
66307_Book.indb 7 11/20/09 12:51:23 PM
Asphaltenes
Chemical Transformation during
Hydroprocessing of Heavy Oils
Jorge Ancheyta
Mexican Institute of Petroleum
National Polytechnic Institute (ESIQIE-IPN)
Mexico City, Mexico
Fernando Trejo
Research Center for Applied Science and Advanced Technology
National Polytechnic Institute
Mexico City, Mexico
Mohan Singh Rana
Kuwait Institute for Scientific Research
Ahmadi, State of Kuwait
Boca Raton London New York
CRC Press is an imprint of the
Taylor & Francis Group, an informa business
66307_Book.indb 9 11/20/09 12:51:23 PM