Anticorrosive Nanomaterials: Future Perspectives PDF
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N a n o s c i e n c e & N a n o t e c h n o l o g y S e r i e s Nanoscience & Nanotechnology Series Anticorrosive Nanomaterials Future Perspectives Edited by Chandrabhan Verma, Chaudhery Mustansar Hussain and Eno E. Ebenso Anticorrosive Nanomaterials Future Perspectives Nanoscience & Nanotechnology Series Editor-in-chief: ~ Nguyˆen T. K. Thanh, University College London, UK Series editors: Gabriel Caruntu, Central Michigan University, USA ShinyaMaenosono,JapanAdvancedInstituteofScienceandTechnology,Japan Neerish Revaprasadu, University of Zululand, South Africa Titles in the series: 1: Nanotubes and Nanowires 2: Fullerenes: Principles and Applications 3: Nanocharacterisation 4: Atom Resolved Surface Reactions: Nanocatalysis 5:BiomimeticNanoceramicsinClinicalUse:FromMaterialstoApplications 6: Nanofluidics: Nanoscience and Nanotechnology 7: Bionanodesign: Following Nature’s Touch 8: Nano-Society: Pushing the Boundaries of Technology 9: Polymer-based Nanostructures: Medical Applications 10: Metallic and Molecular Interactions in Nanometer Layers, Pores and Particles: New Findings at the Yoctolitre Level 11: Nanocasting: A Versatile Strategy for Creating Nanostructured Porous Materials 12: Titanate and Titania Nanotubes: Synthesis, Properties and Applications 13: Raman Spectroscopy, Fullerenes and Nanotechnology 14: Nanotechnologies in Food 15: Unravelling Single Cell Genomics: Micro and Nanotools 16: Polymer Nanocomposites by Emulsion and Suspension 17: Phage Nanobiotechnology 18: Nanotubes and Nanowires, 2nd Edition 19: Nanostructured Catalysts: Transition Metal Oxides 20: Fullerenes: Principles and Applications, 2nd Edition 21: Biological Interactions with Surface Charge Biomaterials 22:NanoporousGold:FromanAncientTechnologytoaHigh-TechMaterial 23: Nanoparticles in Anti-Microbial Materials: Use and Characterisation 24: Manipulation of Nanoscale Materials: An Introduction to Nanoarchitectonics 25:TowardsEfficientDesigningofSafeNanomaterials:InnovativeMerge of Computational Approaches and Experimental Techniques 26: Polymer–Graphene Nanocomposites 27: Carbon Nanotube-Polymer Composites 28: Nanoscience for the Conservation of Works of Art 29: Polymer Nanofibers: Building Blocks for Nanotechnology 30: Artificial Cilia 31: Nanodiamond 32: Nanofabrication and its Application in Renewable Energy 33: Semiconductor Quantum Dots: Organometallic and Inorganic Synthesis 34: Soft Nanoparticles for Biomedical Applications 35: Hierarchical Nanostructures for Energy Devices 36: Microfluidics for Medical Applications 37: Nanocharacterisation, 2nd Edition 38: Thermometry at the Nanoscale: Techniques and Selected Applications 39: Nanoceramics in Clinical Use: From Materials to Applications, 2nd Edition 40: Near-infrared Nanomaterials: Preparation, Bioimaging and Therapy Applications 41: Nanofluidics, 2nd Edition 42: Nanotechnologies in Food, 2nd Edition 43: ZnO Nanostructures: Fabrication and Applications 44: Diatom Nanotechnology: Progress and Emerging Applications 45: Nanostructured Materials for Type III Photovoltaics 46: Chemically Derived Graphene: Functionalization, Properties and Applications 47: Graphene-based Membranes for Mass Transport Applications 48: Carbon Nanostructures for Biomedical Applications 49: Surface Chemistry of Colloidal Nanocrystals 50: Reducing Agents in Colloidal Nanoparticle Synthesis 51: Carbon Nitride Nanostructures for Sustainable Energy Production and Environmental Remediation 52: Nanotubes and Nanowires, 3rd Edition 53: Bionanodesign: Old Forms for New Functions, 2nd Edition 54: Photothermal Nanomaterials 55: Concepts and Design of Materials Nanoarchitectonics 56: Anticorrosive Nanomaterials: Future Perspectives How to obtain future titles on publication: Astandingorderplanisavailableforthisseries.Astandingorderwillbring delivery of each new volume immediately on publication. For further information please contact: BookSalesDepartment,RoyalSocietyofChemistry,ThomasGrahamHouse, Science Park, Milton Road, Cambridge, CB4 0WF, UK Telephone: þ44 (0)1223 420066, Fax: þ44 (0)1223 420247 Email: [email protected] Visit our website at www.rsc.org/books Anticorrosive Nanomaterials Future Perspectives Edited by Chandrabhan Verma King Fahd University of Petroleum and Minerals, Saudi Arabia Email: [email protected] Chaudhery Mustansar Hussain New Jersey Institute of Technology, USA Email: [email protected] and Eno Ebenso University of South Africa, South Africa Email: [email protected] Nanoscience&NanotechnologySeriesNo.56 PrintISBN:978-1-83916-411-8 PDFISBN:978-1-83916-625-9 EPUBISBN:978-1-83916-626-6 PrintISSN:1757-7136 ElectronicISSN:1757-7144 AcataloguerecordforthisbookisavailablefromtheBritishLibrary rTheRoyalSocietyofChemistry2022 Allrightsreserved Apartfromfairdealingforthepurposesofresearchfornon-commercialpurposesorfor privatestudy,criticismorreview,aspermittedundertheCopyright,DesignsandPatents Act1988andtheCopyrightandRelatedRightsRegulations2003,thispublicationmaynot bereproduced,storedortransmitted,inanyformorbyanymeans,withouttheprior permissioninwritingofTheRoyalSocietyofChemistryorthecopyrightowner,orinthe caseofreproductioninaccordancewiththetermsoflicencesissuedbytheCopyright LicensingAgencyintheUK,orinaccordancewiththetermsofthelicencesissuedbythe appropriateReproductionRightsOrganizationoutsidetheUK.Enquiriesconcerning reproductionoutsidethetermsstatedhereshouldbesenttoTheRoyalSocietyof Chemistryattheaddressprintedonthispage. Whilstthismaterialhasbeenproducedwithallduecare,TheRoyalSocietyofChemistry cannotbeheldresponsibleorliableforitsaccuracyandcompleteness,norforany consequencesarisingfromanyerrorsortheuseoftheinformationcontainedinthis publication.Thepublicationofadvertisementsdoesnotconstituteanyendorsementby TheRoyalSocietyofChemistryorAuthorsofanyproductsadvertised.Theviewsand opinionsadvancedbycontributorsdonotnecessarilyreflectthoseofTheRoyalSocietyof Chemistrywhichshallnotbeliableforanyresultinglossordamagearisingasaresultof relianceuponthismaterial. TheRoyalSocietyofChemistryisacharity,registeredinEnglandandWales, Number207890,andacompanyincorporatedinEnglandbyRoyalCharter (RegisteredNo.RC000524),registeredoffice:BurlingtonHouse,Piccadilly, LondonW1J0BA,UK,Telephone:þ44(0)2074378656. Forfurtherinformationseeourwebsiteatwww.rsc.org PrintedintheUnitedKingdombyCPIGroup(UK)Ltd,Croydon,CR04YY,UK Preface Corrosionisahighlychallenginganddamagingphenomenonandtherefore various methods of corrosion mitigation have been developed depending upon the nature of the metal and the environment. The use of organic corrosion inhibitors is one of the most popular, economic and effective methods of corrosion prevention. However, recently, nanomaterials and nanocomposite materials have been developed as the most noble and ef- fective alternatives to be used as corrosioninhibitors inplace of traditional organiccorrosioninhibitors.Becauseoftheirhighsurfacearea,theyprovide reasonably high anticorrosive activity. Nanomaterials and nanocomposites are used as corrosion inhibitors in both aqueous and solution phases. This book deals with the anticorrosive effect of nanomaterials and nanocompo- sites for different metals and alloys. The book has been divided into various chapters. Chapter 1 is about the basic properties and anticorrosive application of various types of nanoma- terials.Chapter2includesanintroductiontonanocompositesanddiscusses their synthesis, characterization and application, including their use as corrosion inhibitors. In Chapter 3, the basics of corrosion and corrosion prevention are discussed. The various forms of corrosion and their salient featureshavealsobeendiscussedinthischapter.Theanticorrosioneffectof carbonnanotubes(CNTs)isdiscussedinChapter4.Thesalientpropertiesof CNTsincorrelationwiththeircorrosioninhibitionpotentialhavealsobeen describedinthischapter.InChapters5and6,thepropertiesandcorrosion inhibition potential of nanocontainers and carbon dots (CDs) have been described, respectively. Chapters7and8areabouttheanticorrosioneffectofmetaloxidessuchas gold, copper, iron and zinc oxides. The mechanism of corrosion inhibition usingmetaloxideshasalsobeenpresented.Chapters9and10describethe Nanoscience&NanotechnologySeriesNo.56 AnticorrosiveNanomaterials:FuturePerspectives EditedbyChandrabhanVerma,ChaudheryMustansarHussainandEnoEbenso rTheRoyalSocietyofChemistry2022 PublishedbytheRoyalSocietyofChemistry,www.rsc.org vii viii Preface corrosion inhibition effectiveness of mesoporous materials and natural fiber-based nanocomposites, respectively. A detailed description on the anticorrosion effect of nanocomposites for steel corrosion is described in Chapter 11. The economics and commercialization of nanomaterials and nanocomposites as corrosion inhibitors are discussed in Chapter 12. Overall, this book is written for scholars in academia and industry, working in corrosion engineering, materials science and applied chem- istry. The editors and contributors are well-known professionals, scientists and researchers from academia and industry. We are very thankful to the authors for their amazing and passionate efforts in the making of this book. We give special thanks to Prof. M. A. Quraishi, who guided us continuously in the drafting of this book. Also, special thanks to Katie Morrey (Commissioning Editor) and Amina Headley (Editorial Assistant) for their dedicated support and help during this project. Finally, we thank the RSC for publishing this book. Chandrabhan Verma Chaudhery Mustansar Hussain Eno E. Ebenso Editor Biography Chandrabhan Verma, PhD, works at the Inter- disciplinary Research Center for Advanced Materials,KingFahdUniversityofPetroleumand Minerals, Dhahran 31261, Saudi Arabia. He is a memberoftheAmericanChemicalSociety(ACS). His research is mainly focused on the synthesis and design of environmentally-friendly corrosion inhibitors useful for industries. Dr. Verma is the author of numerous research and review articles publishedinpeer-reviewedinternationaljournals, includingplatformsofACS,Elsevier,RoyalSociety ofChemistry,WileyandSpringer.Dr.Vermacur- rently edits various books for the ACS, Elsevier, Royal Society of Chemistry and Wiley platforms. He has more than 5000 total citations with an H-index of 40 and i-10 index of 91. Dr. Verma has received severalnationalandinternationalawardsforhisacademicachievements. Nanoscience&NanotechnologySeriesNo.56 AnticorrosiveNanomaterials:FuturePerspectives EditedbyChandrabhanVerma,ChaudheryMustansarHussainandEnoEbenso rTheRoyalSocietyofChemistry2022 PublishedbytheRoyalSocietyofChemistry,www.rsc.org ix x EditorBiography ChaudheryMustansarHussain,PhD,isanadjunct professor, academic advisor, and director of che- mistryandEVSCLabsintheDepartmentofChe- mistry&EnvironmentalSciencesattheNewJersey InstituteofTechnology(NJIT),Newark,NewJersey, USA.Hisresearchisfocusedontheapplicationsof nanotechnologyandadvancedmaterials,environ- mental management, analytical chemistry and othervariousindustries.Dr.Hussainistheauthor of numerous papers in peer-reviewed journals as wellasaprolificauthorandeditorofaround100 books,includingscientificmonographsandhand- booksinhisresearchareas.Hehaspublishedwith Elsevier,RoyalSocietyofChemistry,JohnWiley&Sons,CRCPressandSpringer. EnoE.Ebenso,PhD,isafullProfessorofPhysical Chemistry in the Department of Chemistry at theNorth-WestUniversityandActingDirectorof Material Science Innovation and Modeling ResearchFocusAreainSouthAfrica.Hisresearch interests span through physical chemistry (elec- trochemistry, kinetics, adsorption, thermo- dynamicsofcorrosion)andextensiveresearchon corrosion inhibition in different media using electrochemical, gravimetric, gasometrical and thermometric methods; synergistic and an- tagonistic studies. Plant extracts, exudate gums, polymers, ionic liquids, synthetic organic and inorganiccompoundshavebeeninvestigatedasinhibitors.Hehaspublished extensivelyinlocalandinternationalpeer-reviewedjournalsofwidereadership withover300publications(articlesinnewspapers,plenary/invitedlecturesand conferenceproceedingsnotincluded).Hehaspublishedwidelyandextensively intheareaofcorrosioninhibitionchemistryandcurrentlyhasanH-Indexof 65 and over 10000 total citations from the Scopus Search Engine of Elsevier Science since 1996. According to the Elsevier SciVal Insights Report (2010–2015), he has a citation impact 10% above the world average, is the secondmostprolificauthorinthefieldofcorrosioninhibitionworldwideand hispublicationsarethefifthmostdownloadedgloballyinthefieldofcorrosion inhibition. His Google Scholar Citations since 2013 are over 8000 with an H-index of 67 and i10-index of 216. His RESEARCHERID account shows anH-indexof44withtotalcitationsof5779andaveragecitationperarticleof 24.78. Heis a member ofthe Chemical Society of Nigeria (MCSN), American ChemicalSociety(MACS),NewYorkAcademyofSciences,NigerianCorrosion Society,SocietyfortheAdvancementofElectrochemicalScience&Technology, InternationalSocietyofElectrochemistry(ISE),SouthAfricanChemicalInsti- tute,SouthAfricanCouncilforNaturalScientificProfessionsandmanyother scientific professional bodies. He is also a Fellow of the Royal Society of Chemistry(UK)andamemberofAcademyofScienceofSouthAfrica(ASSAf).
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