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5th International Symposium on High-Temperature Metallurgical Processing : proceedings of a symposium sponsored by the Minerals, Metals & Materials Society (TMS) held during TMS 2014, 143rd Annual Meeting & Exhibition, February 16-20, 2014, San Diego Conv PDF

672 Pages·2014·21.313 MB·English
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5th International Symposium on High-Temperature Metallurgical Processing Proceedings of a symposium sponsored by The Minerals, Metals & Materials Society (TMS) held during February 16-20, 2014 San Diego Convention Center San Diego, California, USA Edited by: Tao Jiang, Jiann-Yang Hwang, Mark E. Schlesinger, Onuralp Yucel, Rafael Padilla, Phillip J. Mackey, and Guifeng Zhou Copyright © 2014 by The Minerals, Metals & Materials Society. All rights reserved. Published by John Wiley & Sons, Inc., Hoboken, New Jersey. Published simultaneously in Canada. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of The Minerals, Metals, & Materials Society, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http:// www.wiley.com/go/permission. Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of mer- chantability or fitness for a particular purpose. No warranty may be created or extended by sales rep- resentatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages. Wiley also publishes books in a variety of electronic formats. Some content that appears in print may not be available in electronic formats. For more information about Wiley products, visit the web site at www.wiley.com. For general information on other Wiley products and services or for technical sup- port, please contact the Wiley Customer Care Department within the United States at (800) 762-2974, outside the United States at (317) 572-3993 or fax (317) 572-4002. Library of Congress Cataloging-in-Publication Data is available. ISBN 978-1-118-88811-7 Printed in the United States of America. 10 9 8 7 6 5 4 3 2 1 TABLE OF CONTENTS 5th International Symposium on High- Temperature Metallurgical Processing Preface.............................................................................................................. xiii About the Editors................................................................................................ xv High Efficiency New Metallurgical Technology Development of Process Flow Sheet for Looping Sulfide OxidationTMof Molybdenite Concentrates.................................................................................... 3 J. Lessard, L. Shekhter, D. Gribbin, and L. McHugh Slag Structures and Properties by Spectroscopic Analysis: Effect of Water Vapor Relevant to a Novel Flash Ironmaking Technology................................. 11 M. Mohassab-Ahmedand H. Sohn An Innovative Electro-Winning Process for Titanium Production.....................19 G. Granata, Y. Kobayashi, R. Sumiuchi, and A. Fuwa A New Bottom Gas Purging System for Stationary and Tilting Copper AnodeFurnaces..................................................................................................25 G. Vukovicand K. Gamweger A Pilot-Plant Scale Test of Coal-Based Rotary Kiln Direct Reduction of LateriteOre for Fe-Ni Production..................................................................33 G. Li, J. Liu, M. Rao, J. Luo, C. Wang, and Y. Zhang Preparation of Ferronickel Alloy Nugget through Reduction Roasting of NickelLaterite Ore.........................................................................................41 P. Chen, X. Lv, E. Guo, Q. Yuan, and M. Liu Preparation of High Melting Point Alloys and Refractory Compounds with ItsOwn Chemical Energy...........................................................................51 Z. Dou, G. Shi, T. Zhang, Y. Guan, M. Wen, X. Jiang, and L. Niu vv Reductive Sulfur-Fixation Smelting of Stibnite Concentrate in Sodium MoltenSalt.........................................................................................................59 H. Xue, Y. Chen, S. Yang, C. Tang, and M. Tang Separation of Perovskite Phase from CaO-TiO -SiO -Al O -MgO System 2 2 2 3 bySupergravity...................................................................................................67 J. Gao, J. Li, and Z. Guo New Process for Producing High Grade Iron Concentrate by Roasting SideriteOre with Microwave Energy................................................................. 73 S. Ju, L. Zhang, J. Peng, S. Guo, X. Wang, and Y. Wang Fundamental Research of Metallurgical Process Effect of Water Vapor on the Activities of FeO and MgO in Slags Relevant to aNovel Flash Ironmaking Technology...........................................................83 M. Mohassab-Ahmedand H. Sohn Activities of NbOX in Some CaO-Al O -SiO -“Nb O ” Melts at 1873K..........91 2 3 2 2 5 B. Yan, Y. Wang, and J. Fan Reaction Behaviour of Sulfides Associated with Stibnite in Low Temperature Molten Salt Smelting Process without Reductant...............................................99 L. Ye, C. Tang, Y. Chen, M. Tang, and W. Zhang Reduction Product Separation by Vacuum Distillation in the Process of Titanium Sponge Preparation...........................................................................107 L. Li, K. Li, X. Chen, Y. Yang, C. Sun, and Q. Miao The Interface Reaction and Transport of Oxygen between the Molten Melt andCaO-MgO-Al O Slag................................................................................115 2 3 T. Zeng, J. Xu, J. Li, J. Zhang, and Y. Guo High-Temperature Creep Deformation and Change in Porous Structure of Graphite Cathode in Aluminum Electrolysis Process.......................................123 T. Chen, J. Xue, and X. Li The Dissolution Rate of Solid Alumina Inclusion into Molten CaF -CaO-MgO-Al O -SiO Slags...................................................................131 2 2 3 2 G. Shi, T. Zhang,L. Niu, and Z. Dou vvii Alloy and Materials Preparation A Refinement Study of SHS Alloys by Mini Vacuum Arc Melting System....139 M. Alkan, S. Sonmez, B. Derin, and O. Yücel An Investigation on the Self-Propagating High Temperature Synthesis of TiB ..............................................................................................................147 2 O. Yücel, M. Bugdayci, and A. Turan Characteristics of Solidification Structure of Wide-Thick Slab of Steel Q345....................................................................................................153 S. Luo, M. Zhu, W. Wang, S. Zheng, and F. Xu Determination of Surface Tension for FeCrMnNi Alloy with Varying Sulfur andPhosphorous Relevant to Gas Atomization................................................161 T. Dubbersteinand H. Heller Electrolysis Contribution to the Yield of Alloy Elements and the Exchange Current Density of Manganese and Chromium during DC-Arc Steel Melting/Refining Process.................................................................................169 J. Chenand M. Jiang Experimental Study of the Thermodynamics of the Fe-Nb-C Melts................177 B. Yan, D. Guo, L. Zhang, and J. Zhang Preparation of Nitrogenous Ferrovanadium by Gaseous Nitriding in the LiquidPhase Ferrovanadium..................................................................185 W. Liu, K.Dong, and R. Zhu Study on Key Technologies of 38CrMoAl Steel Produced by BOF-LF-RH-CCProcess..................................................................................193 Y. Chen, M. Zhang, J. Zeng, and H. Pan The Evolution and Morphology of Sulfide Inclusions in 95CrMo Hollow Steel.....................................................................................................201 J. Chen, S. Zhang, C. Cai, Y. Liu, H. Li, and J. Yang Electrochemically Preparing of Ni-Fe Alloys in Molten Sodium Hydroxide...209 J. Ge, J. Xiao, S. Jiao, and H. Zhu Roasting, Reduction and Smelting Commissioning of a Second Cobalt Recovery Furnace at Nchanga Smelter...217 M. Masanza, R. Cheeba, and K. Ng'andwe vviiii Analysis of the Attaching Slag to the Lining for Pillar and Walking Beam in theHot Rolling's Heating Furnaces..............................................................225 G. Xuand Y. Wang A Study of Benefiation of Siderite by Direct Reduction-Magnetic SeparationProcess............................................................................................231 D. Zhu, Y. Luo, and J. Pan Development and Industrial Application of an Improved Lead Oxygen-EnrichedFlash Smelting Process........................................................239 C. Wang, W. Gao, W. Yang, F. Yin, and B. Ma Effects of Reducer and Slag Concentrations in the Iron-Carbon Nuggets Coalescence in Self Reducing Processes..........................................................247 A. Nogueira, C.Takano, M. Mourão, and A. Pillihuaman Excavation of a 48 MVA Silicomanganese Submerged-arc SiMn Furnace in South Africa -Part I: Methodology and Observations......................................255 J. Gous, J. Zietsman, J. Steenkamp, and J. Sutherland Industrial Experimental Study on Dephosphorization Pretreatment in Combined-Blowing Converter Process.........................................................271 Z. Yan, X. Xing, J. Zhang, C. Zhao, P. Pei, and J. Rao Roasting Characteristics of Oxidized Pellets of Vanadium-Titanium MagnetiteConcentrates....................................................................................279 X. Chen, Y. Huang, M. Gan, X. Fan, L. Yuan, and W. Lv Thermodynamic Computation and Analysis for the Carbothermic Reduction ofTiO ..............................................................................................................287 2 L. Wen, J. Tu, L. Wang, G. Qiu, and C. Bai Kinetic Analysis of Smelting Reduction of V O in Blast Furnace Slag 2 3 byDissolved Carbon in Liquid Iron.................................................................295 X. Zeng, Y. Wang, H. Li, B. Xie, and J. Diao The Distribution of Boron between CaO-SiO -MgO-Al O -TiO 2 2 3 2 and Liquid Feby Chemical Equilibrium Technique.........................................303 S. Ren, J. Zhang, X. Xing, and Z. Liu Study on Limonite Powder by Flash-Magnetic Roasting.................................311 J. Li, Y. Yu, W. Chen, and X. Liu vviiiiii

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